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    Unit 7 Released Frqs

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    james mwashimba
    This document contains two chemistry problems and their answers. The first problem provides data on the boiling points and water solubilities of four compounds: butane, chloroethane, acetone, and 1-propanol. It then asks to qualitatively explain the differences in boiling points and solubilities based on dipole moments and hydrogen bonding. The second problem describes four types of solids - ionic, metallic, covalent network, and molecular - and asks to identify the particles that make up each type of lattice and the binding forces between them. It also asks how each type could be identified in the laboratory.

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    Unit 7 Released Frqs

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    james mwashimba
    19 views2 pages
    This document contains two chemistry problems and their answers. The first problem provides data on the boiling points and water solubilities of four compounds: butane, chloroethane, acetone, and 1-propanol. It then asks to qualitatively explain the differences in boiling points and solubilities based on dipole moments and hydrogen bonding. The second problem describes four types of solids - ionic, metallic, covalent network, and molecular - and asks to identify the particles that make up each type of lattice and the binding forces between them. It also asks how each type could be identified in the laboratory.

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    AP CHEMISTRY UNIT 7

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    This document contains two chemistry problems and their answers. The first problem provides data on the boiling points and water solubilities of four compounds: butane, chloroethane, acetone, and 1-propanol. It then asks to qualitatively explain the differences in boiling points and solubilities based on dipole moments and hydrogen bonding. The second problem describes four types of solids - ionic, metallic, covalent network, and molecular - and asks to identify the particles that make up each type of lattice and the binding forces between them. It also asks how each type could be identified in the laboratory.

    Copyright:

    © All Rights Reserved
    Download as DOC, PDF, TXT or read online from Scribd
    Download as doc, pdf, or txt
    19 views2 pages

    Unit 7 Released Frqs

    Uploaded by

    james mwashimba
    This document contains two chemistry problems and their answers. The first problem provides data on the boiling points and water solubilities of four compounds: butane, chloroethane, acetone, and 1-propanol. It then asks to qualitatively explain the differences in boiling points and solubilities based on dipole moments and hydrogen bonding. The second problem describes four types of solids - ionic, metallic, covalent network, and molecular - and asks to identify the particles that make up each type of lattice and the binding forces between them. It also asks how each type could be identified in the laboratory.

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    © All Rights Reserved
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    Download as doc, pdf, or txt
    of 2

    AP Chemistry Name _______________________________

    Period ___ Date ___/___/___


    7  Liquids & Solids
    Released FRQs
    1979 D
    Butane, chloroethane, acetone, and 1-propanol all have approximately the same molecular weights. Data on their boiling points
    and solubilities in water are listed in the table below.
    Boiling Solubility in
    Compound Formula Pt.(˚C) water
    Butane CH3CH2CH2CH3 0 insoluble
    Chloroethane CH3CH2Cl 12 insoluble
    O
    ||
    Acetone 56 completely
    CH3CCH3
    miscible
    completely
    1-Propanol CH3CH2CH2OH 97 miscible

    On the basis of dipole moments (molecular polarities) and/or hydrogen bonding, explain in a qualitative way the differences in
    the
    (a) boiling points of butane and chloroethane.
    (b) water solubilities of chloroethane and acetone.
    (c) water solubilities of butane and 1-propanol.
    (d) boiling points of acetone and 1-propanol.
    Answer:
    (a) Butane is nonpolar; chloroethane is polar. Intermolecular forces of attraction in liquid chloroethane are larger due to
    dipole-dipole attraction; thus a higher boiling point for chloroethane.
    (b) Both chloroethane and acetone are polar. However, acetone forms hydrogen bonds to water much more effectively than
    chloroethane does, resulting in greater solubility of acetone in water.
    (c) Butane is non-polar and cannot form hydrogen bonds; 1-propanol is polar and can form hydrogen bonds. 1-propanol can
    interact with water by both dipole-dipole forces and hydrogen bonds. Butane can interact with water by neither means.
    Thus, 1-propanol is much more soluble.
    (d) Acetone molecules are attracted to each other by van der Waals attraction and dipole-dipole attraction. 1-propanol
    molecules show these two types of attraction. However, 1-propanol can also undergo hydrogen bonding. This
    distinguishing feature results in the higher boiling point of 1-propanol.

    1977 D (Mandatory)
    The state of aggregation of solids can be described as belonging to the following four types:
    (1) ionic (3) covalent network
    (2) metallic (4) molecular
    For each of these types of solids, indicate the kinds of particles that occupy the lattice points and identify forces among these
    particles. How could each type of solid be identified in the laboratory?
    Answer:
    _____________________________________________________
    Binding Experimental
    Particles Forces Identification
    _____________________________________________________
    ionic + & - ions electrostatic conductivity
    attraction of fused salt
    _____________________________________________________
    metallic + ions electrostatic conductivity
    attraction be- of the
    tween ions solid
    and electrons
    _____________________________________________________
    covalent atoms covalent high melting
    network bonds pt., extreme
    hardness, etc.
    _____________________________________________________
    molecular molecules van der low melting
    Waals pt., non-con-
    ductivity of
    fused salt, etc.
    _____________________________________________________

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