MITOCW - Tutorial: Solar Cell Operation: Professor

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MITOCW | Tutorial: Solar Cell Operation

[MUSIC PLAYING]

PROFESSOR: Hello everyone, today we're going to learn how a Solar Cell is able to turn light

generated mobile charges into electricity. Today's lesson will use everything we've

learned in the past videos to understand this effect. So, make sure you understand
the material from the previous videos before watching.

First, let's go over the structure of a Solar Cell. Here's a cell that I made. And we

can see that a metal ribbon is connected to the top metal contacts, which form a
grid. The spaces between the grid lines allow light to enter the cell. If we flip over
the cell we see the entire back surface is coated with metal, which allows easy

extraction of charge from the back surface. Additionally, we have another metal
ribbon that's connected to the backside.

Now, let's hook up our Solar Cell to an ammeter to measure the current. So, here
we have an ammeter connected to our Solar Cell and our light source which will

simulate the sun. And we can see that if we turn on our light source we start to read
a current flowing out of our Solar Cell. In this case about 0.12 amps or 120
milliamps. Now, if we turn off the light the output of the cell drops to zero and we no

longer read any current.

We know from our last demo the light generates mobile charges and silicon. But
how do these mobile charges become a electric current coming out of our Solar

Cell? The secret has to do with doping.

The top layer is doped with phosphorus, shown in blue. Well the bottom layer is
doped in boron, shown in red. The different dopants interact in a way, which we'll
describe shortly, to create an electric field in our device where the Boron-doped and
Phosphorous-doped regions meet. It is this electric field that acts as a one way

valve in our Solar Cell for electrons and holes.

An electric field is created when positive and negative charges are separated. As

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you know, opposite charges attract and like charges repel. We'll exploit this property
by creating a sheet of positive charges on the left and negative charges on the right,

thus producing an electric field, which we denote with the Greek letter z. If you were
to insert a negatively charged particle, such as an electron, into this field it would
move toward the positive charges. Alternatively, if you put a positively charged
particle it would move toward the negative charges.

We're able to create an electric field inside our Solar Cell by using different dopants

on either side of the device. Here we have our silicon lattice, which is un-doped.
We'll start by replacing some of the silicon atoms with phosphorus atoms on one
side. On the opposite side we'll put in boron atoms.

To focus on our dopant atoms and the mobile charges they introduce we'll fade out
the silicon lattice. Recall that phosphorus atoms introduce static positive charges in

mobile negative charges. While boron atoms introduce static negative charges in
mobile positive charges.

All the mobile charges are free to move around at random. A process known as
diffusion. Here we see a single electron moving around on its random walk. During

this random motion if an electron and hole encounter each other they neutralize and
effectively vanish.

As this process of holes and electrons randomly defusing and neutralizing as the

interface continues, the total number of mobile charges in the device decreases.
This leaves a region at the interface of immobile static charges where the net

charge is negative on one side and positive on the other.

These opposing sheets of charge create an electric field of the interface, which at

this point is very weak. As charges continue to diffuse, they're still able to move

across this weak electric field and neutralize. As this happens, the sheets of net
positive and net negative static charges widen and the electric field grows in

strength. Now that the electric field is stronger, as other mobile charges continue to
move and diffuse around the lattice, they're now repelled by the field and electrons

to the left and holes stay to the right. It is this electric field that separates light
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generated mobile charges and pushes them to the extreme ends of the device.

The image we see now is our Solar Cell in the dark. However, recall that our silicon

atoms are still present. And if light strikes our silicon atom, a mobile hole and
electron is generated. As these mobile charges move around randomly there's a

chance that they will randomly encounter the electric field. The mobile electron will

get repelled by the electric field. However, the mobile hole will get swept to the other
side by the electric field.

Now, let's zoom out. We can see that after the electric field has pushed our light
excited electron and hole to the left and right respectively, we now have an extra

negative charge on the left and extra positive charge on the right. If we connect a

wire to short the two opposite sides together the excess electrons are attracted to
the excess holes on the opposite side. This attraction is what drives electricity

through our wire. As light continually shines on the Solar Cell charges are constantly
being pushed out of the device and driving the electric current.

Now hopefully you understand the basics of how these amazing, but rather simple,

devices work. We hope that this knowledge will provide the basic foundation while
tackling more difficult and abstract concepts while you learn the material in this

course. I'm Joe Sullivan, thanks for watching.

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