Nanostructured Particles

by Spray Drying Process :

Variation & Application
Annie Mufyda Rahmatika

Webinar-200830
 Chemical Engineering
Faculty of Engineering

Annie Mufyda Rahmatika

Teknik Kimia Fyka
Fakultas Teknologi Industri

[email protected]

Dept. Teknologi Hayati dan Veteriner

Sekolah Vokasi
 Nanostructured
Particles
Nanostructure (Struktur nano)
Particles:
Partikel yang memiliki struktur
dengan ukuran yang lebih
besar dari molekul tapi lebih
kecil dari mikroskopis.

Biasanya memiliki detail dalam

ukuran nano (1-100 nm) dalam
partikel berskala nano-mikro.

Nandiyanto et. al., Adv. Powder. Tech, 22, 1-19 (2011)

 Atomization Nanostructured Particle
Decorated
Ultrasonic Nebulizer Two Fluid Nozzle Syringe Pump Droplet Macroporous
Aggregate Macroporous
Suspension
(Solid particles
suspended in
liquid)

Particle size : 500 nm - 5µm

Dd : 1 – 11 µm Dd : 11 – 599 µm Dd : 40 nm – 1 mm NPs : 5-40 nm Pore size : 50-500 nm Cellulose Nanofibers
Solution
Dd : Droplet size Process (Molecularly
mixed
solution)

Drying Chamber Spray Furnace Tubular Flame

200 nm
Reactive Molecular
Solution
(reactive molecular Hollow Core-shell
precursors solution)

200 nm

T: 100-200oC T: 200-1200oC T: ~1800oC

T: Temperature Application
Particle Collection
Paper Filter Bag Filter
Ƞ : 90 – 99% Ƞ : 90 – 99% Selective Catalyst
Gas Sensor Drug Delivery Agent
Dp,eff : < 2 µm Dp,eff : < 2 µm Inductor Functional Food Anti Weathering Material
Cost : Medium - High Cost : Medium - High Energy Storage
Capacity : Low Capacity : High (Capacitor, Conductor)

Electrostatic Precipitator Cyclone Precisely Designed

Ƞ : 85 – 95%
Nanostructured
Ƞ : 90 – 99%
Dp,eff : < 10 µm Dp,eff : > 1 µm Particles
Cost : High Cost : Medium
Capacity : High Capacity : High Gas phase Liquid Phase
Adsorbent : Selective adsorbent : Low Refractive Index Materials
Virus, CO2, Pollutant DNA, Protein, Antibody, Exosome Insulator
Ƞ : Collection Efficiency Dp,eff : Efficient size of particles be captured

https://takashiogi.amebaownd.com/
 Droplet
Suspension Suspension
(Solid particles
Spray drying process :
(Solid particles
suspended in
liquid) Penyemprotan cairan (liquid)
suspended in Solution
(Molecularly
mixed
ke dalam media pengering panas
liquid)
solution)
untuk menghasilkan partikel kering.
Reactive Molecular
Solution
(reactive molecular
precursors solution)
Penyemprotan ini disebut dengan
Solution proses atomisasi yang menghasilkan
(Molecularly droplet.
mixed solution)

Reactive Molecular
Solution
(reactive molecular Precisely Designed
Nanostructured
precursors solution) Particles

Nandiyanto et. al., Adv. Powder. Tech, 22, 1-19 (2011)

 Atomization
Ultrasonic Nebulizer Two Fluid Nozzle Syringe Pump Droplet
Suspension
(Solid particles
Spray drying process :
suspended in
liquid) Penyemprotan cairan (liquid)
Dd : 1 – 11 µm
Dd : Droplet size
Dd : 11 – 599 µm Dd : 40 nm – 1 mm
Solution
(Molecularly
mixed
ke dalam media pengering panas
solution)
untuk menghasilkan partikel kering.
Reactive Molecular
Solution
(reactive molecular
precursors solution)
Penyemprotan ini disebut dengan
proses atomisasi yang menghasilkan
droplet.

Precisely Designed
Nanostructured
Particles

Nandiyanto et. al., Adv. Powder. Tech, 22, 1-19 (2011)

 Atomization Ultrasonic Nebulizer
Ultrasonic Nebulizer Two Fluid Nozzle Syringe Pump Droplet
Suspension
(Solid particles
suspended in
liquid)

Dd : 1 – 11 µm Dd : 11 – 599 µm Dd : 40 nm – 1 mm
Solution
Dd : Droplet size (Molecularly
mixed
solution)

Reactive Molecular
Solution
(reactive molecular
precursors solution)

Two Fluid Nozzle

Syringe Pump
Precisely Designed
Nanostructured
Particles
 Atomization
Ultrasonic Nebulizer Two Fluid Nozzle Syringe Pump Droplet
Suspension
(Solid particles
suspended in
liquid) Drying Tubular Tubular
Dd : 1 – 11 µm
Dd : Droplet size
Dd : 11 – 599 µm Dd : 40 nm – 1 mm
Process
Solution
(Molecularly Chamber Furnace Flame
mixed
solution)

Drying Chamber Tubular Furnace Tubular Flame

Reactive Molecular
Solution
(reactive molecular
precursors solution)

T: 100-200oC T: 200-1200oC T: ~1800oC

T: Temperature

Precisely Designed
Nanostructured
Particles
 Atomization Nanostructured Particle
Decorated
Ultrasonic Nebulizer Two Fluid Nozzle Syringe Pump Droplet Porous
Aggregate Macroporous
Suspension
(Solid particles
suspended in
liquid)

Particle size : 500 nm - 5µm

Dd : 1 – 11 µm Dd : 11 – 599 µm Dd : 40 nm – 1 mm NPs : 5-40 nm Pore size : 50-500 nm Cellulose Nanofibers
Solution
Dd : Droplet size Process (Molecularly
mixed
solution)

Drying Chamber Spray Furnace Tubular Flame

200 nm
Reactive Molecular
Solution
(reactive molecular Hollow Core-shell
precursors solution)

200 nm

T: 100-200oC T: 200-1200oC T: ~1800oC

T: Temperature

Precisely Designed
Nanostructured
Particles
Particle Formation Mechanism
Porous Structure
 Particle Formation Mechanism

Specific surface area

Transmittance

Durability

Gradon et. al., Journal of Aerosol Science, 149, 105608 (2020)

 Atomization Nanostructured Particle
Decorated
Ultrasonic Nebulizer Two Fluid Nozzle Syringe Pump Droplet Macroporous
Aggregate Macroporous
Suspension
(Solid particles
suspended in
liquid)

Particle size : 500 nm - 5µm

Dd : 1 – 11 µm Dd : 11 – 599 µm Dd : 40 nm – 1 mm NPs : 5-40 nm Pore size : 50-500 nm Cellulose Nanofibers
Solution
Dd : Droplet size Process (Molecularly
mixed
solution)

Drying Chamber Spray Furnace Tubular Flame

200 nm
Reactive Molecular
Solution
(reactive molecular Hollow Core-shell
precursors solution)

200 nm

T: 100-200oC T: 200-1200oC T: ~1800oC

T: Temperature

Particle Collection
Paper Filter Bag Filter
Ƞ : 90 – 99% Ƞ : 90 – 99%
Dp,eff : < 2 µm Dp,eff : < 2 µm
Cost : Medium - High Cost : Medium - High
Capacity : Low Capacity : High

Electrostatic Precipitator Cyclone Precisely Designed

Ƞ : 85 – 95%
Nanostructured
Ƞ : 90 – 99%
Dp,eff : < 10 µm Dp,eff : > 1 µm Particles
Cost : High Cost : Medium
Capacity : High Capacity : High

Ƞ : Collection Efficiency Dp,eff : Efficient size of particles be captured

https://takashiogi.amebaownd.com/
 Particle Collection

Electrostatic
Paper Filter Bag Filter Cyclone
Precipitator
Ƞ : 90 – 99% Ƞ : 90 – 99% Ƞ : 90 – 99% Ƞ : 85 – 95%
Dp,eff : < 2 µm Dp,eff : < 2 µm Dp,eff : < 10 µm Dp,eff : > 1 µm
Cost : Medium - High Cost : Medium - High Cost : High Cost : Medium
Capacity : Low Capacity : High Capacity : High Capacity : High
 Atomization Nanostructured Particle
Decorated
Ultrasonic Nebulizer Two Fluid Nozzle Syringe Pump Droplet Macroporous
Aggregate Macroporous
Suspension
(Solid particles
suspended in
liquid)

Particle size : 500 nm - 5µm

Dd : 1 – 11 µm Dd : 11 – 599 µm Dd : 40 nm – 1 mm NPs : 5-40 nm Pore size : 50-500 nm Cellulose Nanofibers
Solution
Dd : Droplet size Process (Molecularly
mixed
solution)

Drying Chamber Spray Furnace Tubular Flame

200 nm
Reactive Molecular
Solution
(reactive molecular Hollow Core-shell
precursors solution)

200 nm

T: 100-200oC T: 200-1200oC T: ~1800oC

T: Temperature Application
Particle Collection
Paper Filter Bag Filter
Ƞ : 90 – 99% Ƞ : 90 – 99% Selective Catalyst
Gas Sensor Drug Delivery Agent
Dp,eff : < 2 µm Dp,eff : < 2 µm Inductor Functional Food Anti Weathering Material
Cost : Medium - High Cost : Medium - High Energy Storage
Capacity : Low Capacity : High (Capacitor, Conductor)

Electrostatic Precipitator Cyclone Precisely Designed

Ƞ : 85 – 95%
Nanostructured
Ƞ : 90 – 99%
Dp,eff : < 10 µm Dp,eff : > 1 µm Particles
Cost : High Cost : Medium
Capacity : High Capacity : High Gas phase Liquid Phase
Adsorbent : Selective adsorbent : Low Refractive Index Materials
Virus, CO2, Pollutant DNA, Protein, Antibody, Exosome Insulator
Ƞ : Collection Efficiency Dp,eff : Efficient size of particles be captured

https://takashiogi.amebaownd.com/
 Application of Nanostructured Particles
Selective Catalyst
Gas Sensor Energy Storage
Inductor (Capacitor, Conductor)

Gas phase Drug Delivery

Adsorbent : Agent
Virus, CO2, Pollutant Functional Food

Liquid Phase
Selective adsorbent : Drug Delivery
DNA, Protein, Agent
Antibody, Exosome Functional Food
Nanostructured Particles for Indonesia’s Future
Nanostructured Particles for Indonesia’s Future
Thank you
ありがとう ございます
Terima Kasih