Characteristics of New Oil Soluble

Polyalkylene Glycols

Dr. Govind Khemchandani

The Dow chemical Company

OSP
STLE HOUSTON CHAPTER
FEBURARY 9, 2011

[email protected]
Tel: 1-979-238-4045
 Introduction
• New OSP technology offers many benefits in lubricant
formulations
• OSPs offer options to upgrade hydrocarbon oils to boost
viscosity index and improve deposit control
• OSPs can provide improved friction control when used as
an additive. They may provide an alternative to synthetic
esters as friction modifiers.
• The flexibility of PAG chemistry provides a huge amount of
space for innovation and providing solutions to
specifications and standards of the future
Evolution to OSP™ technology

Current Refrigeration oils Quenchants

Applications Water glycol fluids Textile lubricants

Gear lubricants EO/PO EO Solder assist fluids

water soluble PAGs
Bearing oils Surfactants
Base Fluids
Hydraulic oils
Polymer design
Air Compressor fluids PO space BO/EO
Application
expansion

Base fluid or co-base

fluid for crankcase oils.
PO/BO BO Auto & Industrial gear oil.
Transmission fluids.
Metal rolling oils.
OSP™ technology Surfactants.
 Traditional PAG Polymerization Technologies

Ethylene oxide (EO) Propylene oxide (PO)

H 2C CH2 H 2C CH CH3
O O R=H, CH3

CLASSICAL POLYMER STRUCTURES BASED ON EO & PO

Block Random Inverse block

Polymerization Polymerization Polymerization
....
Initiator EO block Initiator Initiator PO block
PO block EO block
1 EO
1 PO
Initiators are typically monols, diols or triols
(for example butanol, propylene glycol, glycerol).

• Polymers can be designed having a wide range of viscosities (10-20,000 cSt at 40oC)
• Extremely versatile and can be tailored designed to have many specific functionalities
Traditional PAGs – Benefits & Perceived Challenges

BENEFITS CHALLENGE

✔Availability in a very wide ∆ Oil miscibility (compatibility)

range of viscosity grades
with design flexibility
✔High viscosity index
✔Good low temperature
properties
✔Excellent deposit control
and equipment cleanliness
✔Hydrolytic stability
✔Safe to Use
Synthetic Options in Designing Oil Soluble PAGs

Oil miscibility of
Homo-polymers H 2C CH R
O
Increasing the carbon to oxygen ratio H2C CH Higher alpha-
in PAGs improves oil miscibility O olefin oxides

Styrene
O Oxide
H2C CH CH2 CH3
O THF

H2C CH CH3 Butylene

O oxide

H 2C CH 2 Propylene PO Homo-polymers are partially oil miscible

O oxide
Ethylene EO Homo-polymers are water soluble and not oil miscible
oxide
Carbon/oxygen ratio
Oil miscibility in reference to Group I-IV Hydrocarbon oils
What is different?

CHEMICAL COMPOSITION: POLYALKYLENE GLYCOL VS. HYDROCARBON OILS

Mineral Oil – Petroleum- based Hydrocarbon Group I Base stock

Non-Polar
PAO- Poly Alpha Olefin- Synthetic Hydrocarbon Oil Group IV Heavily additized for
oxidation stability and
has poor solvency

PAG – Poly Alkylene Glycol Base Fluid Group V Polar

H(Me) H(Me)
Inherently thermo-
H(Me)

R1 O O O R2
O O O O
oxidatively stable
H(Me) H(Me)
with high VI
H(Me)
Oxidation Processes Comparison

Mineral & Synthetic Hydrocarbon Oil vs. Polyalkylene Glycols

High MW molecules grow,

High MW Agglomeration of Soft forming insoluble varnish that
Non-Polar Fluid Polar By-Products Contaminates adheres to surfaces

Temperature,
System, &
time
Additional degradation may
Low MW occur, but by-products
Polar Fluid Polar By-Products Homogeneous remain in solution
Solution
Controlling Deposit Formation using PAGs

Thousands of rotary screw air compressors

and other turbo-machinery use
conventional PAG technology
Mineral oil PAG synthetic

In recent years, there has been an increasing number of

reported cases associated with varnish and sludge
formation in turbine-generator applications and especially
gas turbines. PAGs are providing a solution.

Gas turbine

Field studies in emerging applications for PAGs

such as tunnel boring and wind turbine lubricants
show deposit free operation
Wind turbine Tunnel boring

Formulating lubricants by upgrading hydrocarbon oils with oil soluble PAGs

as a co-base oil may provide solutions to controlling deposits
Oil Soluble PAGs – Typical Physical
Properties
Viscosity at Viscosity at Viscosity CCS viscosity at
Grade 40oC, cSt 100oC, cSt Index -20oC, mPa.s
ASTM D445 ASTM D445 ASTM D2270 ASTM D5293
OSP-32 32 6.5 146 1750
OSP-46 46 8.5 164 2900
OSP-68 68 12 171 5400
OSP-150 150 23 186 17100
OSP-220 220 32 196 29100
OSP-680 680 77 196 n/d

Flash Point (COC), Fire Point, Four ball wear, Pour Point,
Grade oC oC mm oC

ASTM D92 ASTM D92 ASTM D4172 ASTM D97

OSP-32 216 242 n/d <-43
OSP-46 210 240 0.58 <-43
OSP-68 218 258 n/d <-40
OSP-150 228 258 0.43 -37
OSP-220 226 258 0.46 -34
OSP-680 243 260 0.38 -30
Comparison Typical Properties of OSP’s / PAO’s

UCON Grade Viscosity at Viscosity at Viscosity Pour Point

o o Index deg. C
40 C, cSt 100 C, cSt
ASTM D445 ASTM D445 ASTM D2270 ASTM D97
OSP-32 32 6.5 146 <-43
OSP-46 46 8.5 164 <-43
OSP-68 68 12 171 <-40
OSP-220 220 32 196 -34
OSP-680 680 77 196 -30

UCON Grade Viscosity at Viscosity at Viscosity Pour Point

40 oC, cSt 100 oC, cSt Index deg. C
ASTM D445 ASTM D445 ASTM D2270 ASTM D97
PAO-6 31 5.1 138 -57
PAO-8 48 8.0 139 -48
PAO-10 66 10 137 -48
PAO-40 396 29 147 -36
PAO-100 1240 100 170 -30
Expanding functionality of PAGs using OSPs

Use of OSPs
Expansion of formulators options
Primary base oil in formulations
• Compressor/refrigeration oils
• Hydraulic fluids
• Gear & Bearing Oils
• Engine/transmission Oils

Co-base oil
• Upgrade Group I-III mineral oils
• Upgrade PAO’s
• Improve additive solubility

Additives
• Deposit control additive
• Friction modifier
• Viscosity builder in mineral oils
Miscibility of OSPs in Common Base Oils
Typical Miscibility Features
Chemistry OSP/Base Oil OSP/Base Oil OSP/Base Oil
10/90 w/w 50/50 w/w 90/10 w/w
Group I Mineral oils Miscible Miscible Miscible
Group II and III Mineral Miscible Miscible Miscible
oils
PAO-4, 6, 8 Miscible Miscible Miscible
PAO-40 Partial Partial Partial
Miscible Miscible Miscible
Diesters & Polyol esters Miscible Miscible Miscible
Naphthenics Miscible Miscible Miscible
PAG’s - PO homo- Miscible Miscible Miscible
polymers
Miscibility defined as clear homogeneous solutions before and after storing at ambient
temperature and 80oC for 168 hours
•Example above shows specifically OSP-46 / OSP-36 fully miscible with PAO-40
•Miscibility improvements ongoing with higher viscosity PAOs
Stribeck Curves of OSPs versus Conventional PAGs (ISO VG-46)

Stribeck curv e s at 40oC, SRR = 50%, Pre ssure 1.1GPa Traction coefficients were
0.12 measured on a Mini Traction
Machine with a ¾ inch steel ball
rotating on a steel disk
0.1
EO/PO Random
Traction coefficient

0.08 copolymer

Directly comparing alkoxide

PO homopolymer
0.06

0.04 PO/BO copolymer chemistries

0.02

Friction coefficients
EO/PO< PO/BO < PO
0
0 200 400 600 800 1000
Speed, m m /sec

Stribeck curves at 100oC, SRR = 50%, Pressure = 1.1GPa

0.12

0.1 EO/PO random

Traction coefficient

Copolymer
0.08
PO Homopolymer
0.06
PO/BO copolymer
0.04

0.02

0
0 200 400 600 800 1000
Speed, m m /sec
Friction Performance of OSPs as Additives

Mini-Traction Machine, steel ball on steel disc,

temperature 80oC, , slide roll ratio = 10%, contact pressure = 0.9GPa

PAO
Friction coefficient

PAO + 10% OSP-46

Under high contact pressures, OSPs impart friction reducing properties in hydrocarbon base
stocks. The polar nature of PAGs helps migration to the metal surface. Mechanism of action
is being studied
Friction Performance of OSPs as Additives in PAO

Mini-traction machine, steel ball on steel disc, temperature 80oC, , SRR = 10%, Pressure = 0.9GPa

0.4

0.35

0.3
Friction Coefficient

0.25 PAO
PAO + 10% OSP
0.2 PAO + 8% OSP
PAO + 5% OSP
0.15 PAO + 8% Polyol ester

0.1

0.05

0
0 200 400 600 800 1000 1200 1400 1600 1800 2000
Time (s)

Polyalphaolefin is a PAO-8 base oil (un-additized)

OSP’s may offer another choice to esters and other film forming additives
Deposit Control : Extended ASTM D2893 at 120°C

Group I Mineral Oil

Deposit
formation

0d 50d

Group I Mineral Oil + OSP-46 (5%)

Deposit
free

0d 50d
Oxidation Stability Using RPVOT Method

Oil Soluble PAG Base Oil (ISOVG-46) with 2% anti-oxidant

Phenolic Phenolic Aminic Aminic RPVOT

AO 1 AO 2 AO 3 AO 4 (min)
Formulation % % % %
A (Base Oil) 0 0 0 0 15
B 2 0 0 0 70
C 0 2 0 0 60
D 0 0 2 0 935
E 0 0 0 2 966
F 0 1 1 0 440
Proprietary (2%) 1530

Method used was ASTM D2272 Rotary Pressure Vessel Oxidation Test
 NOACK Volatility

NOACK Volatility, CEC L-40

Test Duration 60 minute,
% Weight Evaporation Loss

30
Virgin OSP Temperature = 250oC
25 Base Oil
20
1% AO
15

10 2% AO
5

0
OSP-32 OSP-46 OSP-68 OSP-150 OSP-220
Viscosity Grade

GPC – Mol. Weight Distribution

OSP polymerization technology

produces a broad molecular weight
distribution
UCON OSP Recommended Applications & Uses

Base Oil Uses

Selection criteria’s based on typical viscosity requirements for specific applications

Additive Uses

PAGs are being used in grease formulations. OSP 220 has been used for Li
complex grease formulation.
 Conclusions
• The formulators and researchers have another option for using PAGs
as a “tool” for solving some of our industry problems.
• Formulators can now use Oil Soluble PAGs as a primary base oil, a
co-base oil or as an additive in formulations
• Equipment conversions from hydrocarbon oils to Oil Soluble PAGs is
simpler and less problematical
• OSPs offer options to upgrade hydrocarbon oils to boost viscosity
index and improve deposit control
• OSPs can provide improved friction control when used as an additive.
They may provide an alternative to synthetic esters as friction
modifiers.
• The flexibility of PAG chemistry provides a huge amount of space for
innovation and providing solutions to specifications and standards of
the future
 THANK YOU
Questions:
[email protected]
Tel:979-238-4045