Edith Cowan University

Research Online
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2009

Analysis of Bell materials: Tin Bronzes

Jaromir Audy
Edith Cowan University

Katarina Audy

This article was originally published as: Audy, J., & Audy, K. (2009). Analysis of Bell materials: Tin Bronzes. China Foundry, 58(1), 77-81.Original
article available here
This Journal Article is posted at Research Online.
https://ro.ecu.edu.au/ecuworks/76
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August 2008

Analysis of bell materials: Tin bronzes

*Jaromir Audy and Katarina Audy
(Edith Cowan University, South West Campus Bunbury, Robertson Drive, 6230, Western Australia)

Abstract: The present study was set up to examine the effect of alloying elements (including harmful elements)
on metallurgical features (material properties and qualitative parameters) of tin bronzes, with particular reference
to church bells from Middle Ages to Current times. A driving force of this study was to identify and demonstrate
features related to the quality of church bells made in different centuries. The findings have been derived via
metallographic and chemical analysis of specimens of bells from various parts of Australasia and Europe. The bell
materials consisted of a mixture of the α phase and the (α+β) eutectoid essentially, in proportions determined by tin
content and mould materials during casting. The samples from the 15th century to the one from the 20th century
showed a progressive increase in hardness, ranging from the minimum of ~280 VHM20g to a maximum of ~470
VHM20g for the (α+β) eutectoid, and ~160 VHM20g to ~230 VHM20g for the α phase. The investigation also shows
that the sound decay of the bell decreased with lowering the wt.% of tin and increasing the wt.% of lead and silver.
This information is expected to provide an additional interesting knowledge into manufacturing practices and their
significance in the quality of church bells over past centuries.

Key words: tin bronzes; bell material; church bells; microstructure; chemical composition; material properties; quality
CLC number: TG146.1+1 Document code: A Article ID: 1672-6421(2008)03-0199-06

T he success of bell materials in bell making applications

has to date largely been based on tin bronzes [1-6]. It has
been recognised that tin bronzes (Cu-Sn) vary widely in
bell material compositions, their properties and effects on
various qualitative/performance measures. The most important
findings are summarised in Table 1 with references to different
composition. Traditionally, bell materials consist of a wide literature sources [2-17].
variety of other elements such as Pb, Zn, Bi, Ag, Sb, As, Ni, From Table 1 it is evident that the most appropriate bell
Fe, P, S and Si [2, 3, 5-7]. Some of these elements (e.g. Pb, Zn, material characteristics (such as cast ability, tensile strength,
Ni, Fe, Ag, Sb) were used for alloying purposes, whereas
hardness, wear resistance, cast quality, sound, cost etc.) can
others such as S and P were impurities entering the bronze
probably be obtained by having a type bronze composition as:
liquid through the process of melting with coke and charcoal.
~20wt.%Sn, < 2wt.%Ni, < 1.5wt.%Pb, ~0.01wt.%P, < 1wt.%Sb,
Bell materials differ in both number of alloying elements and
their amount. This is because through the centuries the bell with balance of Cu.
makers have been searching for ‘best’ tin-bronze composition Table 2 from ref. [5] shows the composition of a standard
that would satisfy: (a) melting/casting requirements, (b) ‘modern and current’ bell material produced in France,
expectations in high quality of cast bell, (c) good bell material Switzerland, former Czechoslovakia and Germany.
properties, (d) long service life, and (d) nice bell sound. It is Table 2 indicates that the quantitative recommendations
therefore not surprising that the knowledge associated with of weight percentage of the main elements (as a whole) in tin
preparation of a bell material mixture was closely guarded bronze materials are incomplete and vary in detail for each
secret in different bell foundries. reference. Incomplete quantitative recommendations contribute
In the present study, the effects of individual elements on to the lack of knowledge about this popular and common
different type bell materials was investigated qualitatively –
bell material. Furthermore, it is also anticipated that large
assessed by material properties, casting properties, service
variations in bell material composition may occur in practice
life, and bell sound. Different bell materials produced from the
because of different bell manufacturers’ knowledge/experience/
Middle Ages to Current times were included for comparison.
preference as reported in the reference [2-11]. Therefore, it is
1 Effects of bell material composition necessary to determine the quality of different bell materials
by metallurgical and chemical analyses, including the
on qualitative measures of bells:
measurement of mechanical properties (e.g. microhardness)
reported data
whenever possible due to small size of specimens.
An extensive literature survey has been carried out on different
*Jaromir Audy 2 Experimental apparatus and methods
Male, born in 1962, Ph.D. Research interests: casting
Properties and characteristics of different types of original
technology and archaeo-metallurgy.
E-mail: [email protected]
bell materials ranging from a Gothic to Current Eras were
Received: 2008-01-22; Accepted: 2008-04-25 investigated using chemical and microstructural analyses prior

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Table 1 Number and amount of alloying elements in tin bronze bell materials and their possible effects on qualitative
parameters of church bells

Alloying element(s), wt.%

Variables effected Reference(s)
Sn Pb Zn Bi Ag Sb As S Ni Fe P

10-20 ~5 Tensile strength increases [2, 3, 6-10]

10-20 yes yes yes Tensile strength decreases [2, 3, 6, 8, 10]

Max. 23 Max.5 ~1 yes yes Hardness increases [2, 3, 6, 10]

>23 yes >1 yes Brittleness increases [2, 3, 6, 10]

yes yes yes Wear resistance increases [10]

up to 5 Ductility increases [2, 3, 7, 10]

<5 Ductility decreases [2, 5]

~20 Elastic limit increases [2, 5, 6, 7]

>23 Elastic limit deceases [2, 5, 6, 7]

yes Abrasion resistance increases [11]

Yes Toughness increases [2, 5, 6]

yes Toughness decreases [2, 5, 6]

yes Fatigue resistance increases [12]

yes yes Fluidity increases [5, 7, 10]

>2 Fluidity decreases [5, 7, 10]

~1 0.01 Acts as a deoxider [5]

yes Reduces deformation [13]

yes Rust resistance decreases [2, 3, 14]

>15 Crack resistance decreases [2, 5]

yes Changes the colour of castings [2, 5, 7, 15]

yes Crystallisation interval is reduced [2, 3, 5, 10, 15]

yes yes Cast-ability decreases [2, 3, 5-7, 10, 15]

yes yes yes Machinability improves [2, 3, 5, 6, 10, 15]

yes Machinability decreases [2, 3, 5-7]

<10 Porosity increases [2, 3, 5, 7, 15]

0.4-5 Porosity decreases [16, 17]

0.5-2 Structure softens [7, 16, 17]

2-4 Structure stabilises [7, 16, 17]

20-23 ~1 Sound quality improves [2, 3, 5-8]

>1.5 >1.5 yes Sound quality decreases [2, 3, 5-8]

yes yes yes Melting temperature decreases [2, 3, 5-8]

yes yes Cost increases [2, 3, 5-8]

yes Cost decreases [2, 3, 5-8]

Table 2 Composition of a standard ‘modern and current’ bell material produced in France, Switzerland, former
Czechoslovakia and Germany

Bell material composition, wt.%

Country
Sn Ag P Fe Zn Cu
France 26.5 1.5 0 -- --
Switzerland 25 0 0.5 -- --
Balance
Former Czechoslovakia 20.25 0 1.5 0.25 --
Germany 22-26 0 Max.1 0.3 0.5

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to the microhardness tests and sound measurements. to identify inclusions, porosity, and other casting defects, as
well as cracks. The specimens were etched in a 2% acid ferric
2.1 Chemical analysis
chloride solution for about 10 s to reveal internal microstructure.
A Perkin Elmer 2380 atomic absorption spectrometer was In addition, a scanning electron microscope (SEM) equipped
used to determine the metal elements present in the bells with an energy dispersive spectrometer (EDS) was also used to
investigated. The experimental conditions used for atomic quantify and map individual phase in the microstructure. The
absorption tests were selected from the recommendations EDS system only provides quantitative measurement of element
described in a manual of the Perkin Elmer Device [18]. The once its concentration is greater than 0.1wt.%. Therefore, Perkin
process was as follows: atomic absorption spectrometer was necessary for analysing
Firstly the debris was obtained from the bell specimens, tracing elements in the bronze debris.
then they were dissolved in a solvent mixture of H2O2 and The microhardness measurements were carried out using a
HCl and sprayed as an aerosol towards the air-acetylene Vicker microhardness tester under an indentation load of 20 g.
flame. Because of the burning solution in a cathodic lamp, The investigated areas were the a phase, the (a+d) eutectoid,
the light source created by the free atoms of an element being and inclusions.
determined was carried through the absorption environment
to a monochromator. The later was used to isolate the 2.3 Sound measurements and analysis
selected narrow spectral band from the spectrum of the light The sound of bells was recorded on a tape recorder and the
source. The light signal was transformed into the electric sound frequencies were analysed using a computer equipped
signal by a special photodiode situated in the output of the with Types Snap Master and Math-Cad softwares. The patterns
monochromator. The absorption level of the element being were plotted in a way to allow recognising one whole complete
investigated was determined from the level of this electric sound signal and the beginning part of the next beating.
signal. From this signal the weight percentage of a particular The frequency charts were presented in a pattern of voltage
element in the bell material was calculated. output/time graphs to give (1) overall information about the
It needs to be noted that sulphur levels could not be tone decay (sound duration) and (2) to plot the real width of
determined by the Perkin Elmer apparatus so it was done by an frequency sound charts.
iodometric method. The iodometric method involves burning
the bronze debris in an oxygen environment. After burning, 3 Features of the experimental bell
sulphur and oxygen reacts to form SO2 gas that can be easily
materials
absorbed in water. This solution is then mixed with excessive
iodine for quantitative analysis of sulphur after back filtration. 3.1 Chemical composition of specimens
The results from chemical analyses are given in Table 3. In
2.2 Microscopical observations and
the ‘Gothic’ bell materials investigated the amount of tin
microhardness tests
varied from 7 to 12 wt.%. This sort of bell-material has a
An optical m icroscope was employed to ca r r y out the solidification range of about 180℃ [5-7], so such bronzes are
metallographic analyses on the selected specimens. The inclined to develop a high level of inter-dendritic porosity.
specimens taken had a prismatic shape of approximately 3 mm3. For the ‘Empire’ bell materials the amount of tin varied in
They were mounted with epoxy resin and polished to a 1 micron the range of 12wt.% to 15.5wt.%. The ‘Modern’ bell material
finish. Optical examination was performed prior to etching showed tin levels in the range of 18 wt.% to 20wt.%, while the
Table 3 Experimental data on chemical analysis of world-wide bell materials produced in different centuries
wt.% Sn Pb Zn Bi Ag Sb As S Ni Fe Cu Era date
min. 7 2 0.02 0.026 0.2 3.2 0.48 0.09 0.27 0.2 Gothic
balance
max. 12 3 0.17 0.038 0.9 3.94 0.79 1.44 0.39 0.7 1150-1560
min. 11 1.5 0.14 0.017 0.15 0.32 0.13 0.08 0.05 0.11 Renaissance
balance
max. 12 1.7 0.47 0.021 0.16 1.34 0.54 1.3 0.32 0.2 1420-1620
min. 11 1.5 0.17 0.018 0.11 0.28 0.12 1.1 0.31 0.03 Baroque
balance
max. 14 1.8 0.23 0.02 0.2 1.2 0.45 1.2 0.42 0.15 1620-1750
min. 10 0.8 0.5 0.012 0.03 1.25 0.49 0.4 0.09 0.09 Rococo
balance
max. 15 1.74 0.64 0.033 0.11 3.62 0.8 0.6 0.41 0.76 1720-1800
min. 12 0.3 0.47 0.001 0.006 0.25 0.33 0.3 0.025 0.12 Empire
balance
max. 15.5 0.81 0.62 0.026 0.028 0.27 0.84 0.8 0.096 0.82 1800-1870
min. 18.57 0.25 0.06 0.008 0.004 0.21 0.05 0.41 0.028 0.34 Modern
balance
max. 20.86 0.32 0.1 0.011 0.007 0.35 0.1 0.63 0.029 2.4 1900-1950
min. 23.2 0.3 -- -- -- 0.8 -- 0.02 -- 0.15 Current
balance
max. 25 1.5 -- -- -- 1.2 -- 0.06 -- 0.26 1950-

Note: Silicon in amounts of about 0.21wt.% was observed from a specimen taken from a bell cast in Italy in the early Middle Ages. In addition, phosphorus, in
amounts of about 0.01wt.% was obtained from several specimens taken from the Modern and Current Bells.

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‘Current’ bells contained about 20wt.% to 24wt.% tin. These and Fe, decreasing trend in the elements of Ag and Pb, and
data clearly show that the weight percentage of tin in church stabilizing trend in the volume of other elements (Bi, Sb, S, P
bells increased from about 12wt.% in the Middle Ages to and As) which may easily became negative/harmful when their
about 25wt.% in the Modern Era. Further, chemical analysis amount increases over certain level (e.g. more than 1wt.% for
of such bell-materials has also indicated that the bronze alloys Sb and more than 1.5wt.% for Pb, as shown earlier in Table 1).
also contained other elements like Ni, Zn, Fe, Pb, As, Sb, Ag,
3.2 Microstructure of specimens
S and Bi as shown in Table 3 which adopted from ref. [5]. The
most important feature relevant to the wt.% of other elements Figure 1 shows three different types of microstructures
in bell materials from the Middle Ages to Current times is an observed from the bell-materials produced in the Gothic,
increasing trend in the wt.% of alloying elements of Ni, Zn Modern and Current Eras.

(a) Polished, but un-etched (b) Polished and etched (c) Polished and etched
1-α phase; 2-(α+δ) eutectoid; 3-Pb; 4-porosity; 5-CuS inclusion
Fig. 1 Optical micrographs of tin bell materials from bells cast in Gothic (a), Modern (b), and Current (c) eras

The above micrographs show that the bell materials mechanical properties of such alloys are crucially influenced
consisted essentially of a mixture of the a phase and the (a+d) by their microstructural features. During cooling, the solidified
eutectoid, in proportions determined by tin content and mould alloy undergoes a number of eutectoid reactions (as indicated
materials during casting. These latter affect the cooling rate, in Cu-Sn alloy phase diagram) resulting in the microstructure
which in turn, influences the grain size and the nature of the of a solid solution and (a+d) eutectoid. The d phase is an inter-
a phase (copper-tin solid solution) – the extent of coring – as metallic compound of Cu31Sn8. Increased amounts of d phase
well as the amount of the (a+d) inter-dendritic eutectoid, as in the microstructure will cause the bell artefact brittle. In order
depicted in Fig. 2. Figure 2 shows the photo-micrographs of to reduce the amount of d phase in the final microstructure,
eight different microstructures observed from the bell materials one can either reduce tin content and/or increase cooling rate
produced in the Empire, Modern and Current Eras. The to suppress equilibrium-like microstructures.

(a) (b) (c) (d)

(e) (f) (g) (h)

Fig. 2 Optical micrographs showing a wide variety of microstructures of different bell materials from different eras:
1846 (a); 1851 (b); 1856 (d); 1858 (e); 1921 (f); current (g) and (h)

Figure 2 also shows that variability in microstructures is variations in micro-hardness of ten specimens. Their
largely due to cooling rate. When the cooling rate was low chemical compositions are shown in Table 4, and the trend
the final microstructures usually showed larger grain size and in microhardness data is depicted in the form of a histogram
smaller amount of cracks and internal porosity. shown in Fig. 3.
Generally, there were some differences in the hardness
3.3 Microhardness of specimens
relating to the a phases (average of 180.3 VHM20g and standard
As a matter of interest it was decided to measure the deviation of 21.7 VHM 20g ), oxide inclusions (average of

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Table 4 The wt.% of individual elements in the bell specimens produced from the 15th century to the 20th century being
chosen for microhardness measurements

Bell material Composition, wt.%

Era Sn Pb Zn Bi Ag Sb As S Ni Fe
15th Century 7.9 2.2 0.2 0.03 0.15 1.72 0.51 1.3 0.41 0.8
16th Century 11.5 2.1 0.02 0.04 0.16 3.8 0.9 0.08 0.25 0.2
16th Century 12.1 0.52 0.04 0.02 0.03 0.31 0.15 1.1 0.06 0.32
17th Century 14.7 1.4 0.25 0.02 0.07 1.6 0.63 0.07 0.4 0.22
18th Century 15.2 1.5 0.15 0.19 0.07 1.5 0.52 0.1 0.32 0.15
19th Century 10.2 1.8 0.52 0.41 0.11 3.72 0.92 0.09 0.45 0.12
19th Century 18.4 0.32 0.09 0.007 0.003 0.22 0.06 0.15 0.03 0.56
20th Century 19.9 0.37 0.12 0.008 0.003 0.23 0.07 0.2 0.03 0.39
20th Century 20.8 0.29 0.08 0.013 0.003 0.3 0.1 0.12 0.027 0.56
20th Century 21.5 2.4 0.1 0.04 --- 0.3 --- 0.02 --- 0.12

Fig. 3 Histogram
summarising the
measured variations
in microhardness of
various experimental
bell materials
investigated

162.6 VHM 20g and standard deviation of 2.1 VHM 20g), and
eutectoid (average of 369 VHM20g and standard deviation of
52.3 VHM20g) when comparing sample by sample as well as
bell-material by bell-material. Following the age/origins of
the bell-materials there was a progressive increase in average
hardness, sample from the 15th Century to the one from the
20th Century, ranging from the minimum of ~280 VHM 20g,
to a maximum of ~470 VHM20g for the (a+d) eutectoid, the
levels which probably reflected the higher amounts of tin and
antimony in bells cast after the 18th century.

3.4 Sound of bells

As bell materials, it is critical to examine the impact of
chemical composition/microstructure on the quality of bell
sound considered from frequency and duration perspectives. Fig. 4 A plot showing concentrations of elements found in
Referring to Table 1 it appears that in Cu-Sn bronze alloys the different bell bronze materials produced from the
tin element (up to 23wt.%) improves the bell sound quality, 16th to the 20th century
whereas the Pb (over 1.5wt.%), Zn (over 1.5wt.%) and Ag in
any quantity have a negative effect on the sound in terms of
time existence. Figure 4 adopted from reference [6] indicates (a)
that there was an increasing trend in the wt.% of Sn, and
decreasing trend in the wt.% of potentially harmful elements
particularly Pb and Ag in different bell materials produced
from the 16th century to modern times.
Fig u re 5 shows t he f re quency-sou nd cha r t s of t wo
geometrically similar bells made of different Cu-Sn alloys. The
bell (a), contained ~15.2wt.% of Sn, ~1.57wt.% of (Pb+Ag),

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 CHINA FOUNDRY Vol.5 No.3

City (Czechoslovakia) for supporting initial ideas about this

(b)
type of topic in 1983. Secondly to Mgr. Dobrova, and Dr.
Kejlova (from East Slovak Museum in Kosice City) and
Ing Sarudyova (from Technical Museum in Kosice City),
as well as Slovakian government for permission to select
and evaluate such valuable specimens from bells. Thirdly to
Professor Strafford for his friendship, advice, help and support
associated with topics relevant to bells, and for his assistance
and supervisory work on the Ph.D project. Finally, to all
Fig. 5 The out-put frequency/sound charts of two Australian organisations/churches, and their representatives,
geometrically similar bells cast of different bell-
for allowing us to take the bell material specimens for
materials
analysing that enabled us to continue this research.
~2.93wt.% of (Zn+Bi+Sb+As+Ni+Fe), with balance of Cu.
The bell (b), contained ~20.8wt.% of Sn, ~0.293wt.% of
References
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Firstly to Ing Grigerova T and Doc. Cech J from TU in Kosice

This work was supported by the University of South Australia Postgraduate Research Program during a period of
1996 to 1999.

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