YVO4 ND

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CRYSTECH Nd:YVO4

Nd:YVO4

Introduction

Nd:YVO4 is one of the most efficient laser host crystal currently existing for diode
laser-pumped solid-state lasers. Nd:YVO4 is an excellent crystal for high power, stable
and cost-effective diode pumped solid-state lasers. Nd:YVO4 can produce powerful and
stable IR, green, blue lasers with the design of Nd:YVO4 and frequency doubling
crystals. For the applications in which more compact design and the
single-longitudinal-mode output are needed, Nd:YVO4 shows its particular advantages
over other commonly used laser crystals.
Low lasing threshold and high slope efficiency
Large stimulated emission cross-section at lasing wavelength
High absorption over a wide pumping wavelength bandwidth
Optically uniaxial and large birefringence emits polarized laser
Low dependency on pumping wavelength and tend to single mode output

Basic Properties:
Atomic Density: 1.26x1020 atoms/cm3 (Nd 1.0%)
Zircon Tetragonal, space group D4h-I4/amd
Crystal Structure:
a=b=7.1193, c=6.2892
Density: 4.22g/cm3
Mohs Hardness: 4-5 (Glass-like)
α a=4.43x10-6/K
Thermal Expansion Coefficient (300K):
α c=11.37x10-6/K
//C: 0.0523W/cm/K
Thermal Conductivity Coefficient (300K):
⊥ C: 0.0510W/cm/ Κ

Optical Properties:
Lasing wavelength: 1064nm, 1342nm
dno/dT=8.5x 10-6/K
Thermal optical coefficient (300K):
dne/dT=2.9x 10-6/K
SellmeierEquation no2=3.77834+0.069736/(λ2-0.04724)-0.0108133.λ2
(for pure YVO4 crystals): ne2=4.59905+0.110534/(λ2-0.04813)-0.0122676.λ2
Stimulated emission cross-section: 25x 10-19cm2 @1064nm
Fluorescent lifetime: 90µ s
Absorption coefficient: 31.4cm-1 @810nm
Intrinsic loss: 0.02cm-1 @1064nm
Gain bandwidth: 0.96nm @1064nm
Polarized laser emission: π polarization; parallel to optic axis(c-axis)
Diode pumped optical to optical
>60%
efficiency:
CRYSTECH Nd:YVO4
Laser Properties:

The Nd:YVO4 crystal has large stimulated emission cross-sections at both 1064nm and
1342nm. The stimulated emission cross-section of an a-axis cut Nd:YVO4 crystal at
1064nm is about 4 times higher than that of the Nd:YAG crystal. Although the lifetime of
Nd:YVO4 is about 2.7 times shorter than that of Nd:YAG. Because of its high pump
quantum efficiency, the slope efficiency of Nd:YVO4 can be very high if the laser cavity
is properly designed.

Laser Properties of Nd:YVO4


Laser crystal Doping(atm%) σ(x10-19cm2) a (cm-1) t (µs) la (mm) Pth(mW) h s(%)

Nd:YVO4(a-cut) 1.0 25 31.2 90 0.32 30 52


2.0 25 72.4 50 0.14 78 48.6

Nd:YVO4(c-cut) 1.1 7 9.2 90 231 45.5

Nd:YAG 0.85 6 7.1 230 1.41 115 38.6

Nd:YVO4’s Specification:
Nd: Dopant Level 0.1 - 3.0 atm%
Wavefront Distortion < λ/8 at 633 nm
Scattering Sites invisible, probed with a He-Ne laser
Orientation ±0.5deg.
Dimensional Tolerance ±0.1mm
End-faces Configuration Plano/Plano
Surface quality 10/5 Scratch/Dig per MIL-O-13830B
Flatness λ/10 at 633 nm
Clear Aperture > Central 90%
Parallelism < 10 arc sec.
Intrinsic Loss < 0.1% cm-1

Standard Products

Part No. Doping Dimension Coating Part No. Doping Dimension Coating

NYV01 2% 3x3x1mm HR/AR NYV0102 2% 3x3x1mm AR/AR

NYV03 1% 3x3x5mm AR/AR NYV0303 0.5% 3x3x10mm AR/AR

NYV05 0.27% 4x4x8mm AR/AR NYV0502 0.27% 4x4x10mm AR/AR

AR/AR: S1:AR@1064(R<0.1%)&532nm(R<0.5%) HT@808nm(R<5%); S2:AR@1064&532nm


HR/AR: S1:HR@1064(R>99.8%)&532nm(R>99%) HT@808nm(R<5%); S2:AR@1064&532nm

Note: Other specifications of Nd:YVO4 crystals and coatings are also available upon
request.

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