Safety Data Sheet

Ethanol 95 E5
Version 2.01 Revision Date 09.03.2018

SECTION 1. Identification of the substance/mixture and of the company/undertaking

Product identifier
Trade name Ethanol 95 E5

Product code 1806

Relevant identified uses of the substance or mixture and uses advised against

Use Solvent. Raw material for printing inks and printing ink
additives.
Manufacturer or supplier's details

Company Sasol Chemicals, a division of Sasol South Africa (Pty) Ltd

Address Sasol Place, 50 Katherine Street

Sandton
2090
South Africa
Telephone +27103445000

E-mail address [email protected]

Emergency telephone number +44 (0)1235 239 670 (Europe, Israel, Africa, Americas)

+44(0)1235 239 671 (Middle East, Arabic African countries)

+65 3158 1074 (Asia Pacific)

+86 10 5100 3039 (China)

+27 (0)17 610 4444 (South Africa)

+61 (2) 8014 4558 (Australia)

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Safety Data Sheet
Ethanol 95 E5
Version 2.01 Revision Date 09.03.2018

SECTION 2. Hazards identification

Classification of the substance or mixture

South Africa. GHS Classification and Labelling of Chemicals - SANS 10234

Classification
Flammable liquids Category 2
Eye irritation Category 2
Specific target organ toxicity - single exposure Category 3

Label elements

Pictogram

Signal word Danger

Hazard statements H225: Highly flammable liquid and vapour.

H319: Causes serious eye irritation.
H336: May cause drowsiness or dizziness.

Precautionary statements

Prevention P210: Keep away from open flames/hot surfaces. - No smoking.

P240: Ground/bond container and receiving equipment.
P241: Use explosion-proof electrical/ ventilating/ lighting equipment.
P242: Use only non-sparking tools.
P243: Take precautionary measures against static discharge.

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Safety Data Sheet
Ethanol 95 E5
Version 2.01 Revision Date 09.03.2018

P280: Wear protective gloves/ protective clothing/ eye protection/ face

protection.
P264: Wash skin thoroughly after handling.
P261: Avoid breathing dust/ fume/ gas/ mist/ vapours/ spray.
P271: Use only outdoors or in a well-ventilated area.

Response P303 + P361 + P353: IF ON SKIN (or hair): Remove/ Take off
immediately all contaminated clothing. Rinse skin with water/ shower.
P370 + P378: In case of fire: Use dry sand, dry chemical or alcohol-
resistant foam for extinction.
P305 + P351 + P338: IF IN EYES: Rinse cautiously with water for
several minutes. Remove contact lenses, if present and easy to do.
Continue rinsing.
P337 + P313: If eye irritation persists: Get medical advice/ attention.
P304 + P340: IF INHALED: Remove victim to fresh air and keep at rest
in a position comfortable for breathing.
P312: Call a POISON CENTER/doctor if you feel unwell.

Storage P403 + P233 + P235: Store in a well-ventilated place. Keep container

tightly closed. Keep cool.
P405: Store locked up.

Disposal Dispose of as hazardous waste in compliance with local and national

regulations.

Other hazards No data available

SECTION 3. Composition/information on ingredients

Mixture

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Safety Data Sheet
Ethanol 95 E5
Version 2.01 Revision Date 09.03.2018

Ethanol

Contents: >= 95.00 %W/W

CAS-No. 64-17-5 Index-No. 603-002-00-5 EC-No. 200-578-6
Hazard statements H225 H319

Ethyl acetate

Contents: >= 5.00 %W/W

CAS-No. 141-78-6 Index-No. 607-022-00-5 EC-No. 205-500-4
Hazard statements H225 H319 H336

For the full text of the H-Statements mentioned in this Section, see Section 16.

SECTION 4. First aid measures

Description of necessary first-aid measures

Inhalation Move to fresh air in case of accidental inhalation of vapours. If

breathing is irregular or stopped, administer artificial
respiration. If symptoms persist, call a physician.

Skin contact Wash off immediately with plenty of water for at least 15
minutes. If skin irritation persists, call a physician.

Eye contact Rinse immediately with plenty of water, also under the eyelids,
for at least 15 minutes. Remove contact lenses. If eye irritation
persists, consult a specialist.

Ingestion Do not induce vomiting without medical advice. Never give

anything by mouth to an unconscious person. Call a physician
immediately.

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Safety Data Sheet
Ethanol 95 E5
Version 2.01 Revision Date 09.03.2018

Most important symptoms/effects, acute and delayed

Refer to SECTION 11

SECTION 5. Firefighting measures

Suitable extinguishing Water spray. Dry powder. Foam.

media

Unsuitable extinguishing Water spray jet.

media

Special hazards arising Flash back possible over considerable distance. Do not allow
from the substance or run-off from fire fighting to enter drains or water courses.
mixture

Special protective In the event of fire, wear self-contained breathing apparatus.

equipment for firefighters Use personal protective equipment.

SECTION 6. Accidental release measures

Personal precautions Keep people away from and upwind of spill/leak. Remove all
sources of ignition. Do not breathe vapours or spray mist.

Environmental precautions Prevent product from entering drains. Prevent further leakage
or spillage if safe to do so.

Methods for cleaning up Soak up with inert absorbent material and dispose of as
hazardous waste.

Reference to other sections Refer to Section 8 and 13

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Safety Data Sheet
Ethanol 95 E5
Version 2.01 Revision Date 09.03.2018

SECTION 7. Handling and storage

Safe handling advice Do not breathe vapours or spray mist. Wear personal
protective equipment.

Advice on protection Keep away from open flames, hot surfaces and sources of
against fire and explosion ignition.Use explosion-proof equipment.

Requirements for storage Keep containers tightly closed in a cool, well-ventilated place.
areas and containers

Advice on common storage No data available

SECTION 8. Exposure controls/personal protection

Components with workplace control parameters

NATIONAL OCCUPATIONAL EXPOSURE LIMITS

Components Type Control Update Basis
parameters

ETHYL ALCOHOL TWA 1,900 mg/m3 1995 South Africa RELs

ETHANOL TWA 1,000 ppm 1995 South Africa RELs

ETHYL ACETATE TWA 1,400 mg/m3 1995 South Africa RELs

TWA 400 ppm 1995 South Africa RELs

Exposure controls

Engineering measures

Provide sufficient air exchange and/or exhaust in work rooms.

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Safety Data Sheet
Ethanol 95 E5
Version 2.01 Revision Date 09.03.2018

Personal protective equipment

Respiratory protection In case of insufficient ventilation, wear suitable respiratory

equipment.

Hand protection Gloves suitable for permanent contact:

Material: butyl-rubber
Break through time: 4 h
Material thickness: 0.5 mm

Eye protection Safety glasses with side-shields

Skin and body protection Safety shoes. Protective suit

Hygiene measures Wash hands before breaks and immediately after handling the
product.

SECTION 9. Physical and chemical properties

Information on basic physical and chemical properties

Form Liquid

State of matter Liquid; at 20 °C; 1,013 hPa

Colour Colourless

Odour Alcohol-like

Odour Threshold No data available

pH Neutral

Melting point/range -83.6 °C

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Safety Data Sheet
Ethanol 95 E5
Version 2.01 Revision Date 09.03.2018

Boiling point/boiling range 77 °C

Flash point 13 °C; closed cup

Evaporation rate No data available

Flammability (solid, gas) No data available

Auto-ignition temperature 363 °C

Lower explosion limit 3.3 %(V)

Upper explosion limit 19 %(V)

Relative vapour density 3.04

Density 0.79 g/cm3; 20 °C

Water solubility Completely miscible, Completely soluble

Viscosity, dynamic 1.41 mPa.s

SECTION 10. Stability and reactivity

Reactivity Stable under recommended storage conditions.

Chemical stability Stable under normal conditions.

Possibility of hazardous Heating can release hazardous gases.

reactions

Conditions to avoid Heat, flames and sparks. Extremes of temperature and direct
sunlight.

Materials to avoid Oxidizing agents. Acids and bases

Hazardous decomposition Carbon oxides.

products

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Safety Data Sheet
Ethanol 95 E5
Version 2.01 Revision Date 09.03.2018

SECTION 11. Toxicological information

Acute oral toxicity Ethanol:

LD50 Rat: > 2,000 mg/kg; OECD Test Guideline 401; GLP: no
(literature value)

Acute oral toxicity Ethyl acetate:

LD50 Rat: 2,000 mg/kg; (literature value)

Acute inhalation toxicity Ethanol:

LC50 Mouse: 4 h; > 20 mg/l; (literature value)

Acute dermal toxicity Ethanol:

LD50 Dermal Rabbit: > 2,000 mg/kg; OECD Test Guideline
402; (literature value)
Skin irritation Ethanol:
Rabbit: Not irritating; OECD Test Guideline 404 (literature
value)

Skin irritation Ethyl acetate:

Rabbit: Not irritating; (literature value)
Eye irritation Ethanol:
Rabbit: irritating OECD Test Guideline 405 (literature value)
Eye irritation Ethyl acetate:
Rabbit: Slightly irritating (literature value)

Sensitisation Ethanol:
Maximisation Test; Guinea pig: Not sensitizing; OECD Test
Guideline 406; (literature value)

Sensitisation Ethyl acetate:

Maximisation Test; Guinea pig: Not sensitizing; OECD Test

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Safety Data Sheet
Ethanol 95 E5
Version 2.01 Revision Date 09.03.2018

Guideline 406;
Mutagenicity Ethanol:
Ames test: Salmonella typhimurium; with and without; Not
mutagenic; OECD Test Guideline 471; (literature value)

Mutagenicity Ethyl acetate:

Ames test: Salmonella typhimurium; Not mutagenic; (literature
value)

SECTION 12. Ecological information

Toxicity to fish Ethanol:

static test; Leuciscus idus; 48 h; LC50; > 100 mg/l; OECD Test
Guideline 203; (literature value)

Toxicity to fish Ethyl acetate:

semi-static test; Salmo gairdneri; 96 h; > 100 mg/l; OECD Test
Guideline 203; (literature value)

Toxicity to daphnia and other Ethanol:

aquatic invertebrates static test; Daphnia magna (Water flea); 24 h; EC50; > 100
mg/l(literature value)

Toxicity to daphnia and other Ethyl acetate:

aquatic invertebrates static test; Daphnia magna (Water flea); 48 h; EC50; > 100
mg/l(literature value)

Toxicity to algae Ethanol:

static test; Chlorella pyrenoidosaEC50; > 100 mg/l; OECD Test

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Safety Data Sheet
Ethanol 95 E5
Version 2.01 Revision Date 09.03.2018

Guideline 201; (literature value)

Toxicity to algae Ethyl acetate:

static test; Desmodesmus subspicatus (green algae)72 h;
EC50; > 100 mg/l; (literature value)

Toxicity to bacteria Ethanol:

Pseudomonas putida; 16 h; 6,500 mg/l; Toxicity to bacteria

Biodegradability Ethanol:
aerobic; > 70 %; 5 d; Readily biodegradable.; OECD Guideline
301 D; (literature value)

Biodegradability Ethyl acetate:

aerobic; > 70 %; 28 d; Readily biodegradable.; OECD
Guideline 301 D; (literature value)

Mobility in soil No data available

Results of PBT and vPvB This substance is not considered to be persistent,

assessment bioaccumulating and toxic (PBT). This substance is not
considered to be very persistent and very bioaccumulating
(vPvB).

Chemical Oxygen Demand Ethanol:

(COD) ca.1,700 mg/g; Directive 84/449/EEC, C.9; GLP: no;

SECTION 13. Disposal considerations

Product Disposal should be in accordance with local, regional and

national legislations.

SECTION 14. Transport information

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Safety Data Sheet
Ethanol 95 E5
Version 2.01 Revision Date 09.03.2018

ADR

UN number: 1170

Class: 3

Packaging group: II; F1;

Proper shipping name: ETHANOL SOLUTION

RID

UN number: 1170

Class: 3

Packaging group: II; F1

Proper shipping name: ETHANOL SOLUTION

ADNR

UN number: 1170

Class: 3

Packaging group: II; F1

Proper shipping name: ETHANOL SOLUTION

IMDG

UN number: 1170

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Safety Data Sheet
Ethanol 95 E5
Version 2.01 Revision Date 09.03.2018

Class: 3

EmS: F-E, S-D

Packaging group: II

Proper shipping name: ETHANOL SOLUTION

Marine pollutant Not a Marine Pollutant

ICAO/IATA

UN number : 1170

Class: 3

Packaging group: II

Proper shipping name: ETHANOL SOLUTION

SECTION 15. Regulatory information

Safety, health and environmental regulations/legislation specific for the substance or mixture

USA TSCA Inventory All chemical constituents are listed in: USA TSCA Inventory
(See chapter 3)

Canadian Domestic Substances List (DSL) All chemical constituents are listed in: Canadian Domestic
Substances List (DSL) (See chapter 3)

Australian Inv. of Chem. Substances (AICS) All chemical constituents are listed in: Australian Inv. of Chem.
Substances (AICS) (See chapter 3)

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Safety Data Sheet
Ethanol 95 E5
Version 2.01 Revision Date 09.03.2018

New Zealand Inventory of Chemicals All chemical constituents are listed in: New Zealand Inventory of
(NZIoC) Chemicals (NZIoC) (See chapter 3)

Jap. Inv. of Exist. & New Chemicals (ENCS) All chemical constituents are listed in: Jap. Inv. of Exist. & New
Chemicals (ENCS) (See chapter 3)

Japan. Industrial Safety & Health Law (ISHL) All chemical constituents are listed in: Japan. Industrial Safety &
Health Law (ISHL) (See chapter 3)

Korea. Existing Chemicals Inventory (KECI) All chemical constituents are listed in: Korea. Existing
Chemicals Inventory (KECI) (See chapter 3)

Philippines Inventory of Chemicals and All chemical constituents are listed in: Philippines Inventory of
Chemical Substances (PICCS) Chemicals and Chemical Substances (PICCS) (See chapter 3)

China Inv. Existing Chemical Substances All chemical constituents are listed in: China Inv. Existing
(IECSC) Chemical Substances (IECSC) (See chapter 3)

SECTION 16. Other information

Full text of H-Statements

H225 Highly flammable liquid and vapour.

H319 Causes serious eye irritation.

H336 May cause drowsiness or dizziness.

All reasonable efforts were exercised to compile this SDS in accordance with the Globally Harmonized System of
Classification and Labelling of Chemicals (GHS). The SDS only provides information regarding the health, safety
and environmental hazards at the date of issue, to facilitate the safe receipt, use and handling of this product in
the workplace and does not replace any product information or product specifications. Since Sasol and its
subsidiaries cannot anticipate or control all conditions under which this product may be handled, used and
received in the workplace, it remains the obligation of each user, receiver or handler to, prior to usage, review this
SDS in the context within which this product will be received, handled or used in the workplace. The user, handler

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Safety Data Sheet
Ethanol 95 E5
Version 2.01 Revision Date 09.03.2018

or receiver must ensure that the necessary mitigating measures are in place with respect to health and safety.
This does not substitute the need or requirement for any relevant risk assessments to be conducted. It further
remains the responsibility of the receiver, handler or user to communicate such information to all relevant parties
that may be involved in the receipt, use or handling of this product.
Although all reasonable efforts were exercised in the compilation of this SDS, Sasol does not expressly warrant
the accuracy of, or assume any liability for incomplete information contained herein or any advice given. When
this product is sold, risk passes to the purchaser in accordance with the specific terms and conditions of sale.

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