SAFETY DATA SHEET

Revision Date 24-May-2018 Revision Number 1

SECTION 1: IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE

COMPANY/UNDERTAKING

1.1. Product identification

Product Description: 3,4'-Diisopropylbiphenyl

Cat No. : H27393
CAS-No 61434-46-6
Molecular Formula C18 H22

1.2. Relevant identified uses of the substance or mixture and uses advised against

Recommended Use Laboratory chemicals.

Uses advised against No Information available

1.3. Details of the supplier of the safety data sheet

Company Alfa Aesar .

Avocado Research Chemicals, Ltd.
Shore Road
Port of Heysham Industrial Park
Heysham, Lancashire LA3 2XY
United Kingdom
Office Tel: +44 (0) 1524 850506
Office Fax: +44 (0) 1524 850608
E-mail address [email protected]
www.alfa.com
Product Safety Department

1.4. Emergency telephone number

Call Carechem 24 at
+44 (0) 1865 407333 (English only);
+44 (0) 1235 239670 (Multi-language)

SECTION 2: HAZARDS IDENTIFICATION

2.1. Classification of the substance or mixture

CLP Classification - Regulation (EC) No 1272/2008

Physical hazards

Based on available data, the classification criteria are not met

Health hazards
Based on available data, the classification criteria are not met

Environmental hazards
Based on available data, the classification criteria are not met

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2.2. Label elements

Hazard Statements

Precautionary Statements

2.3. Other hazards

No information available

SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS

3.1. Substances

Component CAS-No EC-No. Weight % CLP Classification - Regulation (EC) No

1272/2008
3,4'-Diisopropylbiphenyl 61434-46-6 <=100 -

Full text of Hazard Statements: see section 16

SECTION 4: FIRST AID MEASURES

4.1. Description of first aid measures

Eye Contact Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes. Get
medical attention.

Skin Contact Wash off immediately with plenty of water for at least 15 minutes. Get medical attention
immediately if symptoms occur.

Ingestion Clean mouth with water and drink afterwards plenty of water. Get medical attention if
symptoms occur.

Inhalation Move to fresh air. Get medical attention immediately if symptoms occur.

Self-Protection of the First Aider No special precautions required.

4.2. Most important symptoms and effects, both acute and delayed

None reasonably foreseeable.

4.3. Indication of any immediate medical attention and special treatment needed

Notes to Physician Treat symptomatically.

SECTION 5: FIREFIGHTING MEASURES

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5.1. Extinguishing media

Suitable Extinguishing Media

Use extinguishing measures that are appropriate to local circumstances and the surrounding environment. Use water spray,
alcohol-resistant foam, dry chemical or carbon dioxide.

Extinguishing media which must not be used for safety reasons

No information available.

5.2. Special hazards arising from the substance or mixture

Thermal decomposition can lead to release of irritating gases and vapors.

Hazardous Combustion Products

None under normal use conditions.

5.3. Advice for firefighters

As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full
protective gear.

SECTION 6: ACCIDENTAL RELEASE MEASURES

6.1. Personal precautions, protective equipment and emergency procedures

Ensure adequate ventilation. Use personal protective equipment.

6.2. Environmental precautions

Should not be released into the environment. See Section 12 for additional ecological information.

6.3. Methods and material for containment and cleaning up

Sweep up or vacuum up spillage and collect in suitable container for disposal.

6.4. Reference to other sections

Refer to protective measures listed in Sections 8 and 13.

SECTION 7: HANDLING AND STORAGE

7.1. Precautions for safe handling

Wear personal protective equipment. Ensure adequate ventilation. Avoid contact with skin, eyes and clothing. Avoid ingestion and
inhalation.

Hygiene Measures
Handle in accordance with good industrial hygiene and safety practice. Keep away from food, drink and animal feeding stuffs. Do
not eat, drink or smoke when using this product. Remove and wash contaminated clothing before re-use. Wash hands before
breaks and at the end of workday.

7.2. Conditions for safe storage, including any incompatibilities

Keep container tightly closed in a dry and well-ventilated place.

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7.3. Specific end use(s)

Use in laboratories

SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION

8.1. Control parameters

Exposure limits
This product, as supplied, does not contain any hazardous materials with occupational exposure limits established by the region
specific regulatory bodies

Biological limit values

This product, as supplied, does not contain any hazardous materials with biological limits established by the region specific
regulatory bodies

Monitoring methods
BS EN 14042:2003 Title Identifier: Workplace atmospheres. Guide for the application and use of procedures for the assessment of
exposure to chemical and biological agents.

Derived No Effect Level (DNEL) No information available

Route of exposure Acute effects (local) Acute effects Chronic effects Chronic effects
(systemic) (local) (systemic)
Oral
Dermal
Inhalation

Predicted No Effect Concentration No information available.

(PNEC)

8.2. Exposure controls

Engineering Measures
None under normal use conditions.

Personal protective equipment

Eye Protection Safety glasses with side-shields (European standard - EN 166)

Hand Protection Protective gloves

Glove material Breakthrough time Glove thickness EU standard Glove comments

Nitrile rubber See manufacturers - EN 374 (minimum requirement)
Neoprene recommendations
Natural rubber
PVC
Skin and body protection Long sleeved clothing

Inspect gloves before use.

Please observe the instructions regarding permeability and breakthrough time which are provided by the supplier of the gloves.
(Refer to manufacturer/supplier for information)
Ensure gloves are suitable for the task: Chemical compatability, Dexterity, Operational conditions, User susceptibility, e.g.
sensitisation effects, also take into consideration the specific local conditions under which the product is used, such as the danger
of cuts, abrasion.
Remove gloves with care avoiding skin contamination.
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Respiratory Protection No protective equipment is needed under normal use conditions.

Large scale/emergency use Use a NIOSH/MSHA or European Standard EN 136 approved respirator if exposure limits
are exceeded or if irritation or other symptoms are experienced
Recommended Filter type: Particle filter

Small scale/Laboratory use Maintain adequate ventilation

Recommended half mask:- Valve filtering: EN405; or; Half mask: EN140; plus filter, EN
141

Environmental exposure controls No information available.

SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES

9.1. Information on basic physical and chemical properties

Appearance Colorless
Physical State Liquid

Odor No information available

Odor Threshold No data available
pH No information available
Melting Point/Range No data available
Softening Point No data available
Boiling Point/Range No information available
Flash Point No information available Method - No information available
Evaporation Rate No data available
Flammability (solid,gas) Not applicable Liquid
Explosion Limits No data available

Vapor Pressure No data available

Vapor Density No data available (Air = 1.0)
Specific Gravity / Density No data available
Bulk Density Not applicable Liquid
Water Solubility Immiscible
Solubility in other solvents No information available
Partition Coefficient (n-octanol/water)
Autoignition Temperature No data available
Decomposition Temperature No data available
Viscosity No data available
Explosive Properties No information available
Oxidizing Properties No information available

9.2. Other information

Molecular Formula C18 H22

Molecular Weight 238.37

SECTION 10: STABILITY AND REACTIVITY

10.1. Reactivity
None known, based on information available

10.2. Chemical stability

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Stable under normal conditions.

10.3. Possibility of hazardous reactions

Hazardous Polymerization No information available.

Hazardous Reactions None under normal processing.

10.4. Conditions to avoid

Incompatible products. Excess heat.

10.5. Incompatible materials

None known.

10.6. Hazardous decomposition products

None under normal use conditions.

SECTION 11: TOXICOLOGICAL INFORMATION

11.1. Information on toxicological effects

Product Information

(a) acute toxicity;

Oral No data available
Dermal No data available
Inhalation No data available

(b) skin corrosion/irritation; No data available

(c) serious eye damage/irritation; No data available

(d) respiratory or skin sensitization;

Respiratory No data available
Skin No data available

(e) germ cell mutagenicity; No data available

(f) carcinogenicity; No data available

There are no known carcinogenic chemicals in this product

(g) reproductive toxicity; No data available

(h) STOT-single exposure; No data available

(i) STOT-repeated exposure; No data available

Target Organs None known.

(j) aspiration hazard; No data available

Symptoms / effects,both acute and No information available

delayed
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SECTION 12: ECOLOGICAL INFORMATION

12.1. Toxicity
Ecotoxicity effects Contains no substances known to be hazardous to the environment or that are not
degradable in waste water treatment plants.

12.2. Persistence and degradability

Persistence Immiscible with water.

12.3. Bioaccumulative potential May have some potential to bioaccumulate

12.4. Mobility in soil Spillage unlikely to penetrate soil Is not likely mobile in the environment due its low water
solubility.

12.5. Results of PBT and vPvB No data available for assessment.

assessment

12.6. Other adverse effects

Endocrine Disruptor Information This product does not contain any known or suspected endocrine disruptors
Persistent Organic Pollutant This product does not contain any known or suspected substance
Ozone Depletion Potential This product does not contain any known or suspected substance

SECTION 13: DISPOSAL CONSIDERATIONS

13.1. Waste treatment methods

Waste from Residues / Unused Chemical waste generators must determine whether a discarded chemical is classified as a
Products hazardous waste. Consult local, regional, and national hazardous waste regulations to
ensure complete and accurate classification.

Contaminated Packaging Empty remaining contents. Dispose of in accordance with local regulations. Do not re-use
empty containers.

European Waste Catalogue (EWC) According to the European Waste Catalogue, Waste Codes are not product specific, but
application specific.
Other Information Waste codes should be assigned by the user based on the application for which the product
was used.

SECTION 14: TRANSPORT INFORMATION

IMDG/IMO Not regulated

14.1. UN number
14.2. UN proper shipping name
14.3. Transport hazard class(es)
14.4. Packing group

ADR Not regulated

14.1. UN number
14.2. UN proper shipping name
14.3. Transport hazard class(es)
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14.4. Packing group

IATA Not regulated

14.1. UN number
14.2. UN proper shipping name
14.3. Transport hazard class(es)
14.4. Packing group

14.5. Environmental hazards No hazards identified

14.6. Special precautions for user No special precautions required

14.7. Transport in bulk according to Not applicable, packaged goods

Annex II of MARPOL73/78 and the
IBC Code

SECTION 15: REGULATORY INFORMATION

15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture

International Inventories X = listed.

National Regulations

WGK Classification Water endangering class = non-hazardous to waters (self classification)

Take note of Control of Substances Hazardous to Health Regulations (COSHH) 2002 and 2005 Amendment.

15.2. Chemical safety assessment

A Chemical Safety Assessment/Report (CSA/CSR) has not been conducted

SECTION 16: OTHER INFORMATION

Full text of H-Statements referred to under sections 2 and 3

Legend

CAS - Chemical Abstracts Service TSCA - United States Toxic Substances Control Act Section 8(b)
Inventory
EINECS/ELINCS - European Inventory of Existing Commercial Chemical DSL/NDSL - Canadian Domestic Substances List/Non-Domestic
Substances/EU List of Notified Chemical Substances Substances List
PICCS - Philippines Inventory of Chemicals and Chemical Substances ENCS - Japanese Existing and New Chemical Substances
IECSC - Chinese Inventory of Existing Chemical Substances AICS - Australian Inventory of Chemical Substances
KECL - Korean Existing and Evaluated Chemical Substances NZIoC - New Zealand Inventory of Chemicals

WEL - Workplace Exposure Limit TWA - Time Weighted Average

ACGIH - American Conference of Governmental Industrial Hygienists IARC - International Agency for Research on Cancer
DNEL - Derived No Effect Level PNEC - Predicted No Effect Concentration
RPE - Respiratory Protective Equipment LD50 - Lethal Dose 50%
LC50 - Lethal Concentration 50% EC50 - Effective Concentration 50%
NOEC - No Observed Effect Concentration POW - Partition coefficient Octanol:Water
PBT - Persistent, Bioaccumulative, Toxic vPvB - very Persistent, very Bioaccumulative
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ADR - European Agreement Concerning the International Carriage of ICAO/IATA - International Civil Aviation Organization/International Air
Dangerous Goods by Road Transport Association
IMO/IMDG - International Maritime Organization/International Maritime MARPOL - International Convention for the Prevention of Pollution from
Dangerous Goods Code Ships
OECD - Organisation for Economic Co-operation and Development ATE - Acute Toxicity Estimate
BCF - Bioconcentration factor VOC - Volatile Organic Compounds
Key literature references and sources for data
Suppliers safety data sheet, Chemadvisor - LOLI, Merck index, RTECS

Training Advice
Chemical hazard awareness training, incorporating labelling, Safety Data Sheets (SDS), Personal Protective Equipment (PPE) and
hygiene.

Prepared By Health, Safety and Environmental Department

Revision Date 24-May-2018
Revision Summary SDS authoring systems update, replaces ChemGes SDS No. 61434-46-6.

Disclaimer
The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the
date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage,
transportation, disposal and release and is not to be considered a warranty or quality specification. The information
relates only to the specific material designated and may not be valid for such material used in combination with any other
materials or in any process, unless specified in the text

End of Safety Data Sheet

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