Neraca Massa Trial

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450000 ton/yr basis 2150 kmol/jam

56818.18181818 kg/jam

Komponen Komposisi Mr kmol/jam kg/jam


CH4 0.83805 16.043 1801.8075 28906.39772
C2H6 0.01746 30.07 37.539 1128.79773
C3H8 0.00374 44.1 8.041 354.6081
C4H10 0.0013 58.123 2.795 162.453785
C5H12 0.0006 72.15 1.29 93.0735
C6H14 0.0023 86.177 4.945 426.145265
CO2 0.12472 44.01 268.148 11801.19348
H2S 3E-05 34.082 0.0645 2.198289
N2 0.00915 28.013 19.6725 551.0857425
H2O 0.00265 18.015 5.6975 102.6404625
CO 0 28.01 0 0
H2 0 2.01588 0 0
CH3OH 0 32.04 0 0
ZnO 0 81.38 0 0
Total 1 2150 43528.59408

Desulfurisasi 97.474
N ZnO 0.0645 kmol/jam H2S ZnO ZnS
F ZnO 5.24901 kg/jam m 0.0645 0.0645 0
F ZnS 6.287073 r 0.0645 0.0645 0.0645
s 0 0 0.0645
Komponen Nin Nout Fin Fout
CH4 1801.8075 1801.8075 28906.39772 28906.39772
C2H6 37.539 37.539 1128.79773 1128.79773
C3H8 8.041 8.041 354.6081 354.6081
C4H10 2.795 2.795 162.453785 162.453785
C5H12 1.29 1.29 93.0735 93.0735
C6H14 4.945 4.945 426.145265 426.145265
CO2 268.148 268.148 11801.19348 11801.19348
H2S 0.0645 0 2.198289 0
N2 19.6725 19.6725 551.0857425 551.0857425
H2O 5.6975 5.762 102.6404625 103.80243
CO 0 0 0 0
H2 0 0 0 0
CH3OH 0 0 0 0
ZnO 0 0 0 0
Total 2150 2150 43528.59408 43527.55776

mixing point 1
Komponen Nin Nin steam Nout Fin Fin Steam Fout
CH4 1801.8075 1801.8075 28906.39772 0 28906.397723
C2H6 37.539 37.539 1128.79773 0 1128.79773
C3H8 8.041 8.041 354.6081 0 354.6081
C4H10 2.795 2.795 162.453785 0 162.453785
C5H12 1.29 1.29 93.0735 0 93.0735
C6H14 4.945 4.945 426.145265 0 426.145265
CO2 268.148 268.148 11801.19348 0 11801.19348
H2S 0 0 0 0 0
N2 19.6725 19.6725 551.0857425 0 551.0857425
H2O 5.762 2345.907646585 2351.669647 103.80243 42261.52625324 42365.328683
CO 0 0 0 0 0
H2 0 0 0 0 0
CH3OH 0 0 0 0 0
ZnO 0 0 0 0 0
Total 2150 2345.907646585 4495.907647 43527.55776 42261.52625324 85789.084008

Pre reforming
Komponen Nin Nout Fin Fout r
CH4 1801.8075 1925.33575 28906.39772 30888.16144 Nin C2H6
C2H6 37.539 0 1128.79773 0 Nin H2O
C3H8 8.041 0 354.6081 0 Nout C2H6
C4H10 2.795 0 162.453785 0 Nout H2O
C5H12 1.29 0 93.0735 0 Nout CH4
C6H14 4.945 0 426.145265 0 Nout CO2
CO2 268.148 291.12075 11801.19348 12812.22421
H2S 0 0 0 0
N2 19.6725 19.6725 551.0857425 551.0857425
H2O 2351.669647 -27.176 42365.32868 -489.57564
CO 0 0 0 0
H2 0 0 0 0
CH3OH 0 0 0 0
ZnO 0 0 0 0
Total 4495.907647 2208.953 85789.08401 43761.89575

Steam Reforming
Mr Komponen Nin Nout Fin Fout
16.043 CH4 1925.33575 317.6803988 30888.16144 5096.546637146
44.01 CO2 291.12075 315.2355803 12812.22421 13873.51788763
28.013 N2 19.6725 19.6725 551.0857425 551.0857425
18.015 H2O -27.176 -1658.94618 -489.57564 -29885.9154601
28.01 CO 0 1583.540521 0 44354.96999268
2.01588 H2 0 4847.080884 0 9771.133412476
32.04 CH3OH 0 0 0 0
Total 2208.953 5424.263703 43761.89575 43761.33821237

Separator 1
Mr Komponen Nin Nout V Nout L Fin Fout V
16.043 CH4 317.68039875 316.1371581 1.543240614 5096.546637146 5071.788428
44.01 CO2 315.2355802688 314.5417664 0.693813863 13873.51788763 13842.98314
28.013 N2 19.6725 19.61780032 0.054699676 551.0857425 549.55344047
18.015 H2O -1658.94618152 -397.031185 -1261.915 -29885.9154601 -7152.516794
28.01 CO 1583.540520981 1581.43141 2.109111413 44354.96999268 44295.893782
2.01588 H2 4847.080884019 4828.594174 18.48670998 9771.133412476 9733.8664236
32.04 CH3OH 0 0 0 0 0
Total 5424.2637025 6663.291124 -1239.02742 43761.33821237 66341.56842
Nin 5424.263703
Nout 5424.263703
Fin 43761.33821
Fout 43761.33821

Mixing point 2
Mr Komponen Nin FD1 Nin recycle Nout Fin FD1 Fin recycle
16.043 CH4 316.1371581361 664.9787 981.1158581 5071.788427978 10668.253284
44.01 CO2 314.5417664061 18.40105 332.9428164 13842.98313953 809.8302105
28.013 N2 19.6178003236 43.43463 63.05243032 549.5534404651 1216.7342902
18.015 H2O -397.031184789 2.447494 -394.583691 -7152.51679397 44.09160441
28.01 CO 1581.431409568 282.3639 1863.79531 44295.89378201 7909.012839
2.01588 H2 4828.594174036 2216.839 7045.433174 9733.866423555 4468.8814033
32.04 CH3OH 0 43.72447 43.72447 0 1400.9320188
Total 6663.291123681 3272.189244 9935.480368 66341.56841957 26517.73565

Reaktor Metanol
Mr Komponen Nin Nou Fin Fout
16.043 CH4 981.1158581361 981.1158581 15740.04171 15740.04171208
44.01 CO2 332.9428164061 26.63542531 14652.81335 1172.225068003
28.013 N2 63.0524303236 63.05243032 1766.287731 1766.287730655
18.015 H2O -394.583690789 -88.2762997 -7108.42519 -1590.29753901
28.01 CO 1863.795309568 412.7121999 52204.90662 11560.06871871
2.01588 H2 7045.433174036 3224.344781 14202.74783 6499.892157894
32.04 CH3OH 43.72447 1801.114971 1400.932019 57707.72366378
Total 9935.480367681 6420.699366 92859.30407 92855.9415121

Separator 2
Mr Komponen Nin Nout V Nout L Fin Fout V
16.043 CH4 981.1158581361 949.9696242 31.14623397 15740.04171208 15240.362681
44.01 CO2 26.63542531249 26.28720942 0.348215892 1172.225068003 1156.9000866
28.013 N2 63.0524303236 62.04947607 1.002954251 1766.287730655 1738.1919732
18.015 H2O -88.2762996953 -0.65663388 -87.6196658 -1590.29753901 -11.82925927
28.01 CO 412.7121998824 403.3770076 9.335192315 11560.06871871 11298.589982
2.01588 H2 3224.344781383 3166.912259 57.43252208 6499.892157894 6384.1150853
32.04 CH3OH 1801.11497078 62.46352183 1738.651449 57707.72366378 2001.3312396
Total 6420.699366122 4670.402464 1750.296902 92855.9415121 37807.661788
Nin 6420.699366
Nout 6420.699366
Fin 92855.94151
Fout 92855.94151

Splitter 0.7 0.3


Mr Komponen Nin Nrecycle Npurge Fin Frecycle
16.043 CH4 949.9696241683 664.9787 284.9908873 15240.36268053 10668.253284
44.01 CO2 26.28720942039 18.40105 7.886162826 1156.900086592 809.8302105
28.013 N2 62.04947607214 43.43463 18.61484282 1738.191973209 1216.7342902
18.015 H2O -0.65663387545 2.447494 -0.19699016 -11.8292592663 44.09160441
28.01 CO 403.3770075673 282.3639 121.0131023 11298.58998196 7909.012839
2.01588 H2 3166.9122593 2216.839 950.0736778 6384.115085278 4468.8814033
32.04 CH3OH 62.46352183391 43.72447 18.73905655 2001.331239559 1400.9320188
Total 4670.402464487 3272.189244 1401.120739 37807.66178786 26517.73565
Nin 4670.402464
Nout 4673.309983
Fin 37807.66179
Fout 37860.03419

Distilasi 1
Mr Komponen Umpan Fraksi Umpan Distilat Fraksi Distilat Bottom
16.043 CH4 31.1462339678 0.017794829 31.14623397 0.267026038543 0
44.01 CO2 0.348215892096 0.000198947 0.337769415 0.002895798863 0.0104464768
28.013 N2 1.002954251468 0.000573019 1.002954251 0.008598628678 0
18.015 H2O -87.6196658198 -0.05005989 0 0 -87.61966582
28.01 CO 9.335192315145 0.005333491 9.335192315 0.080033413527 0
2.01588 H2 57.43252208244 0.032813017 57.43252208 0.492386298486 0
32.04 CH3OH 1738.651448946 0.993346584 17.38651449 0.149059821903 1721.2649345
Total 1750.296901635 1 116.6411865 1 1633.6557151

alfa,ave 226.9181719
Nm 1.487894812

Mr Komponen fraksi umpan Numpan Fumpan fraksi distilat Ndistilat


16.043 CH4 0.017794828945 31.14623397 499.6790315 0.266461946363 31.010962427
44.01 CO2 0.000198946757 0.348215892 15.32498141 0.002902286443 0.3377694153
28.013 N2 0.000573019498 1.002954251 28.09575745 0.008607506168 1.0017454801
18.015 H2O -0.0500598874 -87.6196658 -1578.46828 -0.00077675953 -0.090399627
28.01 CO 0.005333490739 9.335192315 261.4787367 0.080129230931 9.3254763152
2.01588 H2 0.032813017054 57.43252208 115.7770726 0.493282022747 57.408386008
32.04 CH3OH 0.993346584412 1738.651449 55706.39242 0.149393766873 17.386514489
Total 1 1750.296902 55048.27972 1 116.38045451
Nin 1750.296902
Nout 1750.296902
Fin 55048.27972
Fout 55048.27972

Distilasi 2
Mr Komponen Umpan Fraksi Umpan Distilat Fraksi Distilat Bottom
16.043 CH4 0.135271540868 8.27898E-05 0.135271541 7.86628499E-05 0
44.01 CO2 0.010446476763 6.39352E-06 0.010446477 6.07481536E-06 0
28.013 N2 0.001208771411 7.398E-07 0.001208771 7.02922458E-07 0
18.015 H2O -87.5292661932 -0.05357022 -0.08752927 -5.08998529E-05 -87.44173693
28.01 CO 0.00971599994 5.94645E-06 0.009716 5.65002986E-06 0
2.01588 H2 0.024136074228 1.47719E-05 0.024136074 1.40355641E-05 0
32.04 CH3OH 1721.264934456 1.05345958 1719.54367 0.999945773671 1.7212649345
Total 1633.916447126 1 1719.636919 1 -85.72047199

alfa,ave 3.772827463
Nm 10.40311228

Mr Komponen fraksi umpan Numpan Fumpan fraksi distilat Ndistilat


16.043 CH4 8.27897541E-05 0.135271541 2.17016133 7.86628499E-05 0.1352715409
44.01 CO2 6.39351956E-06 0.010446477 0.459749442 6.07481536E-06 0.0104464768
28.013 N2 7.39800014E-07 0.001208771 0.033861314 7.02922458E-07 0.0012087714
18.015 H2O -0.05357022163 -87.5292662 -1576.83973 -5.08998529E-05 -0.087529266
28.01 CO 5.94644846E-06 0.009716 0.272145158 5.65002986E-06 0.0097159999
2.01588 H2 1.47719146E-05 0.024136074 0.048655429 1.40355641E-05 0.0241360742
32.04 CH3OH 1.053459580191 1721.264934 55149.3285 0.999945773671 1719.5436695
Total 1 1633.916447 53575.47334 1 1719.6369191

Nin 1633.916447
Nout 1633.916447
Fin 53575.47334
Fout 53575.47334
overall
Finput 85790.12033
Foutput 43816.63513
H2O
0
0.0645
0.0645

F =% fraksi x Mr

Mr C 12.0107
Komponen Mr Mr C C
CH4 16.043 12.0107 1348.93532
C2H6 30.07 24.0214 29.98800581
C3H8 44.1 36.0321 6.569934605
C4H10 58.123 48.0428 2.310266607
C5H12 72.15 60.0535 1.073721622
C6H14 86.177 72.0642 4.135180721
CO2 44.01 12.0107 73.17984966
H2S 34.082
N2 28.013
H2O 18.015
CO 28.01
H2 2.01588
CH3OH 32.04
ZnO 81.38
Total 1466.192279

37.539 r 8.041 r 2.795


37.539 Nin C3H8 8.041 Nin C4H10 2.795
2351.66964659 Nin H2O Nin H2O -8.041
0 Nout C3H8 0 Nout C4H10 0
2332.90014659 Nout H2O -8.041 Nout H2O -12.2335
65.69325 Nout CH4 20.1025 Nout CH4 9.08375
9.38475 Nout CO2 4.0205 Nout CO2 2.09625

X 0.835 X 0.015
r 1607.6553513 r 24.11483027
Nin CH4 1925.33575 Nin CO 1607.655351
Nin H2O -27.176 Nin H2O -1634.83135
Nout CH4 317.68039875 Nout CO 1583.540521
Nout H2O -1634.8313513 Nout H2O -1658.94618
Nout CO 1607.6553513 Nout CO2 24.11483027
Nout H2 4822.9660538 Nout H2 24.11483027

T 90 P 29.61
Fout L Senyawa A B C
24.7582091685 CH4 3.7687 395.744 266.681
30.5347480944 CO2 3.8191 291.743 268
1.53230203491 N2 3.6195 255.68 266.55
-22733.3986661 H2O 8.0557 1723.643 233.08
59.0762106734 CO 6.9356 1347.786 273
37.2669889209 H2 2.9493 67.5078 275.7
0
-22580.2302072 Pbubble 1081.149882 aliran top
yi/pisat -0.4402949 aliran bawah
P dew -2.27120505
V 0.930893512
L 0.069106488

Fout
81366.70175
609229.687971
15394.6405277
-128852.590043
1240727.98483
19622.3066459
0
1837488.73169

X 0.8 X 0.8 X
r 1491.0362477 r 266.3542531 r
Nin CO 1863.7953096 Nin CO2 332.9428164 Nin CO2
Nin H2 7045.433174 Nin H2 4063.360679 Nin H2
Nout CO 372.75906191 Nout CO2 66.58856328 Nout CO2
Nout H2 4063.3606787 Nout H2 3264.297919 Nout H2
Nout CH3OH 1491.0362477 Nout CH3OH 266.3542531 Nout CO
Nout H2O 266.3542531 Nout H2O

T 40 P 19.74
Fout L Senyawa A B C
499.679031545 CH4 3.7687 395.744 266.681
15.3249814111 CO2 3.8191 291.743 268
28.0957574464 N2 3.6195 255.68 266.55
-1578.46827974 H2O 8.0557 1723.643 233.08
261.478736747 CO 6.9356 1347.786 273
115.777072616 H2 2.9493 67.5078 275.7
55706.3924242 CH3OH 5.1504 1549.48 236.642
55048.2797242
Pbubble 351.0150398 aliran top
yi/pisat 0.61528142 aliran bawah
P dew 1.625272546
V 0.669736518
L 0.330263482

Fpurge recycle
4572.10880416 664.978736918
347.070025977 18.4010465943
521.457591963 43.4346332505
-3.54877777988 -0.4596437128
3389.57699459 282.363905297
1915.23452558 2216.83858151
600.399371868 43.7244652837
11342.2985364 3269.28172514

Tdew 296.086089 23.0860891


Fraksi Bottom Senyawa A B
0 CH4 13.58 968
6.39453997E-06 CO2 (lk) 15.38 1956
0 N2 13.45 658
-0.05363410724 H2O 16.54 3985
0 CO 13.87 770
0 H2 12.78 232
1.0536277127 CH3OH (hk) 16.49 3593
1

Tbottom 342.364863 69.3648633


Senyawa A B
CH4 13.58 968
Fdistilat fraksi bottom Nbottom Fbottom CO2 (lk) 15.38 1956
497.508870215 8.2789754E-05 0.13527154087 2.17016133014067 N2 13.45 658
14.8652319688 6.3935196E-06 0.01044647676 0.459749442334091 H2O 16.54 3985
28.0618961328 7.3980001E-07 0.00120877141 0.033861313522769 CO 13.87 770
-1.62854927378 -0.0535702216 -87.529266193 -1576.8397304704 H2 12.78 232
261.206591589 5.9464485E-06 0.00971599994 0.272145158312906 CH3OH (hk) 16.49 3593
115.728417186 1.4771915E-05 0.02413607423 0.048655429314584
557.063924242 1.0534595802 1721.26493446 55149.3284999785
1472.80638206 1 1633.91644713 53575.4733421817 Tfeed 349.251862 76.2518617
Senyawa A B
CH4 13.58 968
CO2 (lk) 15.38 1956
N2 13.45 658
H2O 16.54 3985
CO 13.87 770
H2 12.78 232
CH3OH (hk) 16.49 3593

Distribusi komponen
CH4
alpha,av 846.425377
Xad/Xaw 229.249717
Xaw.W 0.13527154
Xad.D 31.0109624

Tdew 337.876329 64.8763294


Fraksi Bottom Senyawa A B
0 CH4 13.58 968
0 CO2 15.38 1956
0 N2 13.45 658
1.020079975 H2O (hk) 16.54 3985
0 CO 13.87 770
0 H2 12.78 232
-0.020079975 CH3OH (lk) 16.49 3593
1

Tbottom 373.026102 100.026102


Senyawa A B
CH4 13.58 968
Fdistilat fraksi bottom Nbottom Fbottom CO2 15.38 1956
2.17016133014 -9.2424E-32 7.922629E-30 1.27102736661E-28 N2 13.45 658
0.45974944233 -2.130508E-28 1.8262816E-26 8.03746545753E-25 H2O (hk) 16.54 3985
0.03386131352 -3.099654E-37 2.6570383E-35 7.44316141575E-34 CO 13.87 770
-1.57683973047 1.020079975 -87.441736927 -1575.26289073993 H2 12.78 232
0.27214515831 -6.495158E-37 5.5676804E-35 1.55950728158E-33 CH3OH (hk) 16.49 3593
0.04865542931 -1.805439E-38 1.5476305E-36 3.11983735801E-36
55094.1791715 -0.020079975 1.72126493446 55.1493284999785
55095.5869044 1 -85.720471993 -1520.11356223995 Tfeed 350.451897 77.4518968
Senyawa A B
CH4 13.58 968
CO2 (lk) 15.38 1956
N2 13.45 658
H2O 16.54 3985
CO 13.87 770
H2 12.78 232
CH3OH (lk) 16.49 3593

Distribusi komponen
CH4
alpha,av 1005.00711
Xad/Xaw 1.7074E+28
Xaw.W 7.92263E-30
Xad.D 0.13527154
3720.305

r 1.29 r 4.945
Nin C5H12 1.29 Nin C6H14 4.945
Nin H2O -12.2335 Nin H2O -14.8135
Nout C5H12 0 Nout C6H14 0
Nout H2O -14.8135 Nout H2O -27.176
Nout CH4 5.16 Nout CH4 23.48875
Nout CO2 1.29 Nout CO2 6.18125
log P P (bar) P (atm) Zi Ki Ki-1 ZiKi yi
2.65918197129 456.2280374 450.297073 0.058566548 15.20760125 14.20760125 0.8906567 0.062608709
3.00417541899 1009.660623 996.5350349 0.058115829 33.6553541 32.6553541 1.95590879 0.062292753
2.90240562333 798.7403483 788.3567238 0.00362676 26.62467828 25.62467828 0.09656131 0.003885165
2.72066533366 525.6120748 0.691594835 -0.30583804 0.0233568 -0.9766432 -0.0071434 -0.078629194
3.22269090909 1669.901709 1648.192986 0.291936493 55.66339029 54.66339029 16.2501749 0.313191208
2.76470114848 581.7027923 574.140656 0.893592412 19.39009308 18.39009308 17.32684 0.956268627
1.319617268
5049.41189073
374.85181177
5424.2637025

0.6
39.953137969
66.588563281
3264.2979194
26.635425312
3224.3447814
39.953137969
39.953137969

log P P (bar) P (atm) Zi Ki Ki-1 ZiKi yi


2.4782907474 300.8089456 296.8984293 0.152805139 15.04044728 14.04044728 2.29825764 0.220914083
2.8718824675 744.5304555 734.8515596 0.004148368 37.22652277 36.22652277 0.15442932 0.006113053
2.7854435655 610.1597641 602.2276872 0.009820181 30.50798821 29.50798821 0.29959397 0.014429517
1.7438390069 55.44201511 0.07295002 -0.0137487 0.003695543 -0.996304457 -5.0809E-05 -0.000152699
2.6295744409 426.1617242 420.6216218 0.064278387 21.30808621 20.30808621 1.36964942 0.093804749
2.7354647133 543.8319433 536.762128 0.502179684 27.19159716 26.19159716 13.6550677 0.736460936
-0.4505994894 0.354323951 0.34971774 0.280516945 0.017716198 -0.982283802 0.00496969 0.014525803
1.086095442
4300.1768393
2120.5225269
6420.6993661

P 101.32
C ln Pi Pi Ki alfa yi/alfa xi
-3.72 10.2690825 28827.42594 284.5186137 1905.372301 0.000140144 0.00093852
-2.11 8.72639764 6163.48498 60.83186913 407.3805822 7.108338E-06 4.7603E-05
-2.85 11.20607429 73576.00907 726.1745861 4863.066513 1.76815E-06 1.1841E-05
-39 1.039355782 2.827394969 0.027905596 0.186878984 0 0
1.64 11.28373018 79517.32297 784.813689 5255.762516 1.522775E-05 0.00010198
8.08 12.01725883 165588.1277 1634.308406 10944.68277 4.498863E-05 0.00030128
-35.22 2.7166498 15.12955023 0.14932442 1 0.149059822 0.99822803
0.99962925

P 101.32
C ln Pi Pi Ki alfa xi alfa yi
-3.72 10.72154826 45322.01866 447.3156204 376.0083621 0 0
-2.11 9.631367987 15235.26349 150.3677802 126.3974254 0.000808253 0.00096153
-2.85 11.51194052 99901.55383 986.0003339 828.8205323 0 0
-39 3.404002784 30.08428023 0.296923413 0.249590404 -0.013386558 -0.0159252
1.64 11.63165955 112607.0441 1111.399962 934.2300162 0 0
8.08 12.1179843 183135.9962 1807.500949 1519.364494 0 0
-35.22 4.791936874 120.534603 1.189642746 1 1.053627713 1.25344057
1.23847688

P 101.32
C Xi ln Pi Pi Ki xi
-3.72 0.017794829 10.77852174 47979.14595 473.5407219 3.757824E-05
-2.11 0.000198947 9.745415941 17075.77277 168.5330909 1.180461E-06
-2.85 0.000573019 11.5504721 103826.0418 1024.73393 5.591886E-07
-39 -0.05005989 3.695596816 40.26959895 0.397449654 -0.125952776
1.64 0.005333491 11.67559174 117664.3947 1161.314595 4.592632E-06
8.08 0.032813017 12.13074359 185487.6524 1830.711137 1.792365E-05
-35.22 0.993346584 5.048485815 155.7863963 1.537568065 0.646050479
0.520159537

N2 H2O CO
alpha,av 2007.63776 alpha,av 0.215970371 alpha,av 2215.872537
Xad/Xaw 828.7302887 Xad/Xaw 0.001032793 Xad/Xaw 959.8061314
Xaw.W 0.001208771 Xaw.W -87.5292662 Xaw.W 0.009716
Xad.D 1.00174548 Xad.D -0.09039963 Xad.D 9.325476315

P 101.32
C ln Pi Pi Ki alfa yi/alfa xi
-3.72 10.68315228 43614.82013 430.4660495 1765.918639 4.4545E-08 1.8274E-07
-2.11 9.554520109 14108.32192 139.2451827 571.2312596 1.06346E-08 4.3627E-08
-2.85 11.48597526 97340.97098 960.7280989 3941.234528 1.783508E-10 7.3166E-10
-39 3.206725973 24.6980915 0.24376324 1 -5.08999E-05 -0.0002088
1.64 11.60206785 109323.6302 1078.993587 4426.39992 1.276439E-09 5.2364E-09
8.08 12.10939513 181569.7448 1792.042488 7351.569852 1.909193E-09 7.8322E-09
-35.22 4.618449165 101.3367536 1.000165354 4.103019605 0.243709724 0.99978046
0.99957189

P 101.32
C ln Pi Pi Ki alfa xi alfa yi
-3.72 10.95886812 57461.36662 567.1275821 571.9625305 0 0
-2.11 10.10657028 24503.47627 241.8424425 243.9042285 0 0
-2.85 11.67246764 117297.3734 1157.692197 1167.561903 0 0
-39 4.609794633 100.4635156 0.991546739 1 1.020079975 1.01145697
1.64 11.81483676 135244.1257 1334.821611 1346.201403 0 0
8.08 12.17124564 193154.4958 1906.380732 1922.633252 0 0
-35.22 5.853720862 348.5287984 3.439881547 3.469207664 -0.069661603 -0.0690727
0.94238424

P 101.32
C Xi ln Pi Pi Ki xi
-3.72 8.27898E-05 10.78821762 48446.60874 478.1544487 1.731444E-07
-2.11 6.39352E-06 9.764827039 17410.47018 171.8364605 3.7207E-08
-2.85 7.398E-07 11.55702989 104509.1485 1031.476002 7.172246E-10
-39 -0.05357022 3.745086752 42.31267775 0.417614269 -0.128276799
1.64 5.94645E-06 11.68307094 118547.7299 1170.032865 5.082292E-09
8.08 1.47719E-05 12.13291671 185891.1764 1834.693805 8.051433E-09
-35.22 1.05345958 5.092041745 162.7217594 1.606018154 0.655945001
0.527668427

N2 CO2 CO
alpha,av 2145.142253 alpha,av 373.2636062 alpha,av 2441.070622
Xad/Xaw 4.54932E+31 Xad/Xaw 5.72008E+23 Xad/Xaw 1.74507E+32
Xaw.W 2.65704E-35 Xaw.W 1.82628E-26 Xaw.W 5.56768E-35
Xad.D 0.001208771 Xad.D 0.010446477 Xad.D 0.009716
xi
0.0041169
0.0018509
0.0001459
-3.366437
0.0056265
0.0493174
-3.305379

xi
0.014688
0.000164
0.000473
-0.04132
0.004402
0.027084
0.819917
0.825408
H2
alpha,av 4077.862479
Xad/Xaw 2378.530388
Xaw.W 0.024136074
Xad.D 57.40838601
H2
alpha,av 3759.570807
Xad/Xaw 1.55955E+34
Xaw.W 1.54763E-36
Xad.D 0.024136074
kapasitas metonol
1. Komponen NG
Komponen Komposisi Mr kg/jam kmol/jam
CH4 0.2713 16.043 4352.4659 271.3 Neraca Massa Komponen
C2H6 0.0014 30.07 42.098 1.4 F1.N1 = F2.N2 + F3.N3…
C3H8 0.0002 44.1 8.82 0.2
C4H10 0.0001 58.123 5.8123 0.1
CO2 0.7122 44.01 31343.922 712.2
H2S 0.0143 34.082 487.3726 14.3
Total 0.9995 36240.491 999.5

a. Distilasi CFZ

Komponen N(in) N(out) F(in) F(out)


CH4 271.3 271.3 4352.4659 4352.466
C2H6 1.4 1.4 42.098 42.098
C3H8 0.2 0.2 8.82 8.82
C4H10 0.1 0.1 5.8123 5.8123
CO2 712.2 14.244 31343.922 485.464
H2S 14.3 0 487.3726 0
Total 999.5 287.244 36240.491 4894.66

b. saturator

Komponen N(in) N(out) F(in) F(out)


CH4 271.3 271.3 4352.4659 4352.466
C2H6 1.4 1.4 42.098 42.098
C3H8 0.2 0.2 8.82 8.82
C4H10 0.1 0.1 5.8123 5.8123
CO2 14.244 0.02 485.46401 485.464
Total 287.244 273.02 4894.6602 4894.66

c. MIXING POINT
Komponen N(in) N (in) Steam N(out) F(in) F(in) Steam F(out)
CH4 271.3 0 271.3 4352.466 0 4352.4659
C2H6 1.4 0 1.4 42.098 0 42.098
C3H8 0.2 0 0.2 8.82 0 8.82
C4H10 0.1 0 0.1 5.8123 0 5.8123
CO2 0.02 0 0.02 0.8802 0 0.8802
H2O 0 79.70931651 79.709317 0 1435.56479 1435.56479025709
Total 273.02 352.72932 4410.076 1435.56479 5845.64119025709

D. pre reformer

Komponen N(in) N(out) F(in) F(out)


CH4 271.3 4352.4659
C2H6 1.4 42.098
C3H8 0.2 8.82
C4H10 0.1 5.8123
CO2 0.02 0.8802
H2O 79.70931651
Total 273.02 0 4410.0764 0
pertahun perhari perjam(kg/jam) Basis 1000 kmol/jam
200000 27.777777777778

mr = c 12.0107
Komponen Mr Mr C C
CH4 16.043 12.0107 0.00276
C2H6 30.07 24.0214 0.570607
C3H8 44.1 36.0321 4.085272
C4H10 58.123 48.0428 8.265712
CO2 44.01 12.0107 13.64542
Total 26.56977

r 271.3 r 1.4 r 0.2


N(in) C2H6 271.3 Nin C3H8 1.4 Nin C3H8 0.2
N(in) H2O 79.709316505 N(in H2O)

N(out) CH4 271.3 Nout C2H6 0 Nout C3H8 0


N(out) H2 542.6 Nout CH4 3.5 Nout CH4 0.65
N(out) CO 271.3 Nout CO2 0.7 Nout CO2 0.15
r C4H10
Nin C4H10 C4H10

Nout C4H1#VALUE!
Nout CH4 #VALUE!
Nout CO2 C4H10
kapasitas umpan masuk

fraksi berat laju umpan


11.98% 13660.4786864
0.12% 136.8328416
0.02% 22.8054736
0.01% 11.4027368
86.52% 98656.4787936
1.35% 1539.369468
114027.368

Fi Mr
ch4 13660.4786864 16.043
c2 136.8328416 30.07
c3 22.8054736 44.1
c4 11.4027368 58.123
co2 98656.4787936 44.01
h2s 1539.369468 34.082
114027.368

1. unit cfz

Fi Ni f keluaran atas
ch4 13660.4786864 851.491534401297 13660.4786864
c2 136.8328416 4.55047694047223 136.8328416
c3 22.8054736 0.517130920634921 22.8054736
c4 11.4027368 0.196182867367479 11.4027368
co2 98656.4787936 2241.683226394 0
h2s 1539.369468 45.1666412769204 0
total 114027.368 3143.60519280069 13831.5197384

2. SATURATOR
f keluaran atas Ni atas
ch4 13660.4786864 851.491534401297
c2 136.8328416 4.55047694047223
c3 22.8054736 0.517130920634921
c4 11.4027368 0.196182867367479
co2 0 0
h2s 0 0
total 13831.5197384 856.755325129771
3. MIXER
Fi aliran dari saturator Fi Aliran Steam Fi keluaran
ch4 13660.4786864 0 13660.4786864
c2 136.8328416 0 136.8328416
c3 22.8054736 0 22.8054736
c4 11.4027368 0 11.4027368
co2 0 0 0
h2s 0 0 0
H2O 0 17334.3720128828 17334.3720128828
total 31165.8917512828

pre reforming
Fi Masuk Fi Keluar Ni masuk
ch4 13660.4786864 851.491534401297
c2 136.8328416 0 4.55047694047223
c3 22.8054736 0 0.517130920634921
c4 11.4027368 0 0.196182867367479
co2 0 0
h2s 0 0 0
H2O 17334.3720128828 962.485952964062
CO 0 0
H2 0
TOTAL 31165.8917512828 0 1819.24127809383
Ni keluar
ch4 913.055695341769
co2 61.5641609404722
h2o 839.357631083117
h2 161.887009221417

ATR Ni Masuk steam oksigen


ch4 913.055695341769 0 0
c2 0 0 0
c3 0 0 0
c4 0 0 0
co2 61.5641609404722 0 0
h2s 0 0 0
H2O 839.357631083117 683.525456651165 0
CO 0 0 0
H2 161.887009221417 0 0
O2 0 0 444.291546823257
1975.86449658678

SEPARATOR

Ni Masuk Ni keluar atas Ni keluar bawah


ch4 13.6958354301265 13.6958354301265 0
c2 0 0 0
c3 0 0 0
c4 0 0 0
co2 61.5641609404722 61.5641609404722 0
h2s 0 0 0
H2O 1445.27335363023 0 1445.27335363023
CO 899.359859911642 899.359859911642 0
H2 2038.21646314875 2038.21646314875 0
O2 33.4164839194615 33.4164839194615 0
total 4491.52615698069 3046.25280335045 1445.27335363023

R 2.05703287597645 MASUK KEDALAM RANGE YANG DISARANKAN

REAKTOR METANOL

Ninput N output
ch4 13.6958354301265 13.6958354301265
co2 61.5641609404722 11.081548969285
co 899.359859911642 161.884774784096
h2 2038.21646314875 411.818456980096
o2 33.4164839194615 33.4164839194615
meoh 0 787.957697098734
h2o 0 50.4826119711872
3046.25280335045 1470.33740915299

61.5641609404722 36.9384965642833
40.016704611307
37.8787878 0.001999111438217
114027.368 KG/JAM O2 PLANT
ALIRAN 1 KG/ JAM
O2 0.233161522784026
Ar 0.000556471414759
N2 0.760459923624298
H2O 0.005822082176916

%mol
20.95
0.04
78.09
Ni % 0.93
851.491534401297 27.08646544901
4.55047694047223 0.14475344903
0.517130920634921 0.016450250236
0.196182867367479 0.006240696759
2241.683226394 71.3093117268
45.1666412769204 1.436778428168 1973.13
3143.60519280069 100

f keluaran bawah Ni atas Ni bawah


0 851.4915344013 0
0 4.550476940472 0
0 0.517130920635 0
0 0.196182867367 0
98656.4787936 0 2241.68322639
1539.369468 0 45.1666412769
100195.8482616 856.7553251298 2286.84986767
KEBUTUHAN STEAM 1, 5MOL H2O/ MOL C

Fi mr Ni bmol C bmol c/mr


ch4 13660.4786864 16.043 851.4915 12.01 0.748613102287602
c2 136.8328416 30.07 4.550477 24.02 0.798802793481876
c3 22.8054736 44.1 0.517131 36.03 0.817006802721088
c4 11.4027368 58.123 0.196183 48.04 0.826523063159162
co2 0 44.01 0 12.01 0.272892524426267

JUMLAH MOL STEAM ADALAH

reaksi
c2h6 + h20 --> CO + CH4 + 2 H2
AWAL 4.550476940472 962.485952964 0 0 0
REAKSI 4.550476940472 4.55047694047 4.550477 4.550477 9.10095388094446
SISA 0 957.935476024 4.550477 4.550477 9.10095388094446

c3h8 + h20 --> CO + 2CH4 + H2


AWAL 22.8054736 957.935476024 0 0 0
REAKSI 22.8054736 22.8054736 22.80547 45.61095 22.8054736
SISA 0 935.130002424 22.80547 45.61095 22.8054736

c4h10 + 3h20 --> 3CO + CH4 + 6H2


AWAL 11.4027368 935.130002424 0 0
REAKSI 11.4027368 34.2082104 34.20821 11.4027368
SISA 0 900.921792024 34.20821 11.4027368

CO + H2O -----> CO2 + H2


AWAL 61.56416094047 900.921792024 0 0
REAKSI 61.56416094047 61.5641609405 61.56416 61.5641609404722
SISA 0 839.357631083 61.56416 61.5641609404722

Ni keluar ch4 1/2 O2 CO


13.6958354301265 913.055695342 444.2915 0
0 821.750125808 410.8751 821.750125807592
0 91.3055695342 33.41648 821.750125807592
0
61.5641609404722
0 CH4 H2O CO
1445.27335363023 91.3055695342 1522.883 0
899.359859911642 77.6097341041 77.60973 77.6097341040503
2038.21646314875 13.6958354301 1445.273 77.6097341040503
33.4164839194615
4491.52615698069

R 2.057032875976

mr Ni
14

44 1.39918547592

18
30 29.97866199705
2 1019.108231574
32 32.434

GE YANG DISARANKAN

reaktor 1
CO 2 H2
899.3599 2038.216
359.7439 719.4879
539.6159 1318.729

CO2 3 H2
61.56416 1318.729
24.62566 73.87699
36.9385 1244.852

c eff 0.82
25214.6464122

13.1963052421111 37.8219696183
0.357250740271625
ALIRAN 4 AIR ALIRAN 14 N2 ALIRAN 16 O2
3314.9341957562 0 0 0 0 1 3314.934
7.911537460039 0 0 0 0 0 0
10811.70930445 0 0 1 10811.709304 0 0
82.77446067565 1 82.77446067565 0 0 0 0
14217.32949834

mr massa %massa
32 670.4 0.233161522784
40 1.6 0.000556471415
28 2186.52 0.760459923624
18 16.74 0.005822082177
Ni keluaran
851.4915344013
C 4.550476940472
637.4377191398 0.517130920635
3.634933691724 0.196182867367
0.422499480056 0
0.162149664476 0
0 962.4859529641
641.657301976

962.4859529641 Kmol/jam
17334.37201288 Kg / jam

CH4 H2O CO 3 H2
913.0557 900.9217920236 ch4
0 0 0 c2
913.0557 900.9217920236 0 0 c3
c4
co2
h2s
H2O
CO
H2
TOTAL
0
68.4164208
68.4164208

2 H2
0
1643.500251615
1643.500251615

3H2
0
232.8292023122
232.8292023122

reaktor 2
CH3OH CO 2 H2 CH3OH
539.615915947 1244.852
359.7439439647 377.7311411629 755.4623 377.73114116289
359.7439439647 161.8847747841 489.3893 377.73114116289

CH3OH H2O CO2 3 H2 CH3OH H2O


36.93849656428 489.3893
24.62566437619 24.62566 25.856947595 77.57084 25.856947594998 25.85695
24.62566437619 24.62566 11.08154896929 411.8185 25.856947594998 25.85695

787.9577 25214.646307
1 114027.36847
Ni Keluar
913.0557
0
0
0
61.56416
0
839.3576
0
161.887
1975.864

steam dan oksigen yang dibutuhkan


mr Ni ar c ar c / mr Mol c
ch4 16.043 913.0557 12.01 0.748613 683.5255
co2 44.01 61.56416 12.01 0.272893 16.8004
700.3259

steam 683.5255 kmol/jam 12310.29 kg/jam


60% mol c
oksigen 444.2915 kmol/jam 14217.33 kg/jam
80% mol c

547.8334
37,968.08 16 12 0.75 28476.06
1,507.01 30 24 0.8 1205.608
491.1106 44 36 0.818182 401.8178
258.9321 58 48 0.827586 214.2886
60.2662 72 60 0.833333 50.22183
239.9424 86 72 0.837209 200.882
0
14,214.44 44 12 0.272727 3876.665
34425.54
2373.00506875
50.2336466667 1779.754
11.1616045455 40.18692
4.46434655172 9.132222
0.83703055556 3.694632
2.79002790698 0.697525
2.335837
323.055406818 0
88.10602
1923.907
kapasitas umpan masuk

fraksi berat laju umpan


11.98% 3029.79721582
0.12% 30.34855308
0.02% 5.05809218
0.01% 2.52904609
86.52% 21881.30677068
1.35% 341.42122215
25290.4609

Fi Mr Ni
ch4 3028.797216 16.043 188.79245
c2 30.34855308 30.07 1.0092635
c3 5.05809218 44.1 0.114696
c4 2.52904609 58.123 0.043512
co2 21881.30677 44.01 497.18943
h2s 341.4212222 34.082 10.01764
697.16699

1. unit cfz

Fi Ni f keluaran atas f keluaran


ch4 3028.797216 188.792446300567 3028.797216 0
c2 30.34855308 1.00926348786166 30.34855308 0
c3 5.05809218 0.114695967800454 5.05809218 0
c4 2.52904609 0.043511967551572 2.52904609 0
co2 21881.30677 497.189428993411 0 21881.307
h2s 341.4212222 10.0176404612405 0 341.42122
total 25289.46089955 697.166987178432 3066.73290735 22222.728

2. SATURATOR
3. MIXER
Fi aliran dari saturator Fi Aliran Steam keluaran
ch4 3028.797216 0 3028.797216
c2 30.34855308 0 30.34855308
c3 5.05809218 0 5.05809218 ch4
c4 2.52904609 0 2.52904609 c2
co2 0 0 0 c3
h2s 0 0 0 c4
H2O 0 7686.76016280562 7686.76016280562 co2
total 10753.4930701556

pre reforming
Fi Masuk Fi Keluar Ni masuk
ch4 3028.797216 3042.45170993786 188.792446300567
c2 30.34855308 0 1.00926348786166 AWAL
c3 5.05809218 0 0.114695967800454 REAKSI
c4 2.52904609 0 0.043511967551572 SISA
co2 0
h2s 0 0
H2O 7686.76016280562 399.496129437193 426.805117312916 AWAL
CO 0 0 REAKSI
H2 0 SISA
TOTAL 10753.4930701556 3441.94783937505
Ni keluar
ch4 202.446940238429 AWAL
co2 13.6544939378617 REAKSI
h2o 399.496129437193 SISA
h2 35.905389633585

AWAL
REAKSI
SISA

ATR Ni Masuk steam oksigen fi keluar


ch4 202.446940238429 0 0 3.0367041
c2 0 0 0 0
c3 0 0 0 0
c4 0 0 0 0
co2 13.6544939378617 0 0 13.654494
h2s 0 0 0 0
H2O 399.496129437193 93.1683847805936 0 475.45652
CO 0 0 0 199.41024
H2 35.905389633585 0 0 417.51787
O2 0 0 124.224513040791 33.12339
651.502953247068 1142.1992

SEPARATOR

Fi Masuk Fi keluar atas Fi keluar bawah mr


ch4 3.03670410357644 3.03670410357644 0 14
c2 0 0 0
c3 0 0 0
c4 0 0 0
co2 13.6544939378617 13.6544939378617 0 44
h2s 0 0 0
H2O 475.45652429752 0 475.45652429752 18
CO 199.410236134852 199.410236134852 0 30
H2 417.517871983024 417.517871983024 0 2
O2 33.1233899334984 33.1233899334984 0 32
total 1142.19922039033 666.742696092812 475.45652429752

R 1.89549616169383 MASUK KEDALAM RANGE YANG DISARANKAN

REAKTOR METANOL

finput f output
ch4 3.03670410357644
co2 13.6544939378617
co 199.410236134852
h2 417.517871983024
o2 33.1233899334984
meoh 0
h2o 0
25290.4609

%
27.07994637908
0.144766391184
0.016451721024
0.006241254728
71.31568736575
1.436906888231 437.6261
100

Ni atas Ni bawah
188.7924463006 0
1.009263487862 0
0.1146959678 0
0.043511967552 0
9.943788579868 487.2456
0 10.01764
199.9037063037 497.2633
KEBUTUHAN STEAM 3 MOL H2O/ MOL C Ni keluaran
188.7924463006
Fi mr Ni bmol C bmol c/mr C 1.009263487862
3028.797216 16.043 188.7924 12.01 0.748613102 141.3325 0.1146959678
30.34855308 30.07 1.009263 24.02 0.798802793 0.806202 0.043511967552
5.05809218 44.1 0.114696 36.03 0.817006803 0.093707 0
2.52904609 58.123 0.043512 48.04 0.826523063 0.035964
0 44.01 0 12.01 0.272892524 0
142.2684

JUMLAH MOL STEAM ADALAH 426.8051 Kmol/jam


7686.76 Kg / jam

reaksi
c2h6 + h20 --> CO + CH4 + 2 H2
1.009263487862 426.8051 0 0 0
1.009263487862 1.009263 1.009263 1.009263 2.018526976
0 425.7959 1.009263 1.009263 2.018526976

c3h8 + h20 --> CO + 2CH4 + H2


5.05809218 425.7959 0 0 0
5.05809218 5.058092 5.058092 10.11618 5.05809218
0 420.7378 5.058092 10.11618 5.05809218

c4h10 + 3h20 --> 3CO + CH4 + 6H2


2.52904609 420.7378 0 0 0
2.52904609 7.587138 7.587138 2.52904609 15.17428
0 413.1506 7.587138 2.52904609 15.17428

CO + H2O -----> CO2 + H2


13.65449393786 413.1506 0 0
13.65449393786 13.65449 13.65449 13.65449394
0 399.4961 13.65449 13.65449394

ch4 1/2 O2 CO 2 H2
202.4469 124.2245 0 0
182.2022 91.10112 182.2022462 364.4045
20.24469 33.12339 182.2022462 364.4045

CH4 H2O CO 3H2


20.24469 492.6645 0 0
17.20799 17.20799 17.20798992 17.20799
3.036704 475.4565 17.20798992 17.20799

1.895496161694

Ni

0.310329407679

6.647007871162
208.7589359915
29.96097
steam dan oksigen yang dibutuhkan
mr Ni ar c ar c / mr Mol c
ch4 16.043 202.4469 12.01 0.748613 151.5544
co2 44.01 13.65449 12.01 0.272893 3.726209
155.2806

steam 93.16838 kmol/jam


60% mol c
oksigen 124.2245 kmol/jam
80% mol c
1677.963 kg/jam

3975.184 kg/jam

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