®

BioVex
MATERIAL SAFETY DATA SHEET
SECTION 1: CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

PRODUCT NAME
BioVex®
CHEMICAL FAMILY
Mixture of Oxychlorine Compounds
MANUFACTURER
Bio-Cide International, Inc., 2650 Venture Drive Drive, Norman, OK 73069 U.S.A.
(800.323.1398)
EPA REGISTRATION NUMBER:
9804-1
EFFECTIVE DATE:
May 2008
SUPERSEDES:
March 2007

SECTION 2: COMPOSITION/INFORMATION ON INGREDIENTS

Chemical Name C.A.S. No. % by Wt.

Sodium Chlorite 7758-19-2 3.35%

SECTION 3: HAZARDS IDENTIFICATION

EMERGENCY OVERVIEW
Clear liquid with very faint chlorinous odor
May cause skin reaction. May cause eye irritation.
POTENTIAL HEALTH EFFECTS
INHALATION: Prolonged inhalation of fog or mist may be irritating to nose and throat.
SKIN: Based on rabbit studies, product is listed as “practically not an irritant”.
Prolonged exposure may produce localized irritation, contact dermatitis, mild
erythema and edema.
EYE: Based on rabbit studies, product has been given an EPA Category III rating as a
mild irritant. Exposure can produce slight irritation of conjunctiva, cornea and
eyelid.
INGESTION: Ingestion may produce gastric discomfort, nausea, vomiting and diarrhea. Intake
of large quantities may produce methemoglobinemia.
SYSTEMS OF OVER EXPOSURE
Skin and eye irritation. Exposures to chlorine dioxide from activation can produce coughing.
MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE
Skin disorders, such as dermal allergies and dermatitis. Exposure to chlorine dioxide produced
by activation can aggravate pulmonary disorders, such as emphysema.

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CHRONIC EXPOSURE EFFECTS
May cause localized irritation to areas exposed to product.

SECTION 4: FIRST AID MEASURES

The following procedures are recommended as emergency first aid only. They are not intended to
replace or supplant the treatment advice of a physician or other authorized health care specialist.
Inhalation: Move person to fresh air. If person is not breathing, call 911 or an ambulance, and then
give artificial respiration, preferably mouth-to-mouth if possible. Call a poison control center or doctor for
further treatment advice.
Skin Contact: Take off contaminated clothing. Rinse skin immediately with plenty of water for 15-20
minutes. Call a poison control center or doctor for further treatment advice.
Eye Contact: Hold eye open and rinse slowly and gently with water for 15-20 minutes. Remove
contact lenses, if present, after the first 5 minutes, then continue rinsing eye. Call a poison control center
or doctor for further treatment advice.
If Swallowed: Call a poison control center or doctor immediately for treatment advice. Have person
sip a glass of water if able to swallow. Do not induce vomiting unless told to do so by a poison control
center of doctor. Do not give anything by mouth to an unconscious person.
NOTES TO PHYSICIAN
Chlorine dioxide vapors are emitted when this product contacts acids or chlorine. If these vapors
are inhaled, monitor patient closely for delayed development of pulmonary edema which may
occur up to 48-72 hours post inhalation.

SECTION 5: FIRE FIGHTING MEASURES

FLAMMABLE PROPERTIES
Autoignition temperature Not Applicable
Flash Point Not Applicable
Flammable Limits – LEL Not Applicable
Flammable Limits – UEL Not Applicable

EXTINGUISHING MEDIA
Water unless contraindicated by other materials involved in the fire.
FIRE-FIGHTING EQUIPMENT
Standard protective gear with self-contained breathing apparatus.

SPECIAL FIRE-FIGHTING PROCEDURES

Do not allow product to evaporate to dryness. If chlorine dioxide gas is produced, vent to
atmosphere. Open or vent any large containers.
UNUSUAL FIRE OR EXPLOSIVE HAZARDS
The sodium chlorite in dried BioVex® is a strong oxidizer, which supports combustion. Chlorine
dioxide, which may evolve from BioVex® solutions, is explosive in the gaseous phase at
concentrations greater than 10% by volume. Do not allow chlorine dioxide gas to accumulate
within a confined space.

Note: See STABILITY AND REACTIVITY (SECTION 10) for hazardous combustion and
thermal decomposition information.

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 SECTION 6: ACCIDENTAL RELEASE MEASURES

ENVIRONMENTAL NOTIFICATION
All spills and leaks involving more than 10 gallons should be reported to the nearest regional EPA
office or designated state emergency response office with 24 hours. Spills from ocean vessels or
which may contaminate U.S. costal waterways should be reported to the nearest Coast Guard
office within 24 hours.
SPILL OR LEAK PROCEDURE
Small spills, involving less than 10 gallons, may be flushed to a designated and permitted sewer
system with the amount of water that is about 10 times the amount of the spill.
Large spills, involving more than 10 gallons, should be contained and neutralized using any one
of the three neutralizers: i) sodium sulfite, ii) sodium bisulfite, or iii) sodium thiosulfate. The
neutralization reaction can be extremely exothermic, and therefore, care should be taken to add
the neutralizer in small increments. Sodium sulfite is the most preferred (least exothermic)
neutralizer that can be used in the ratio of 1 lb per gallon of spilled material. Sodium thiosulfate
can be used in the ratio of 2 lbs of anhydrous salt or 3 lbs of pentahydrate salt per estimated
gallon of the spilled material. The neutralized solution can then be flushed to a designated and
permitted sewer system with double the amount of water. The product that is not neutralized may
be disposed of as chemical waste in the manner indicated below. The vicinity of the spill should
be thoroughly flushed with water after clean-up. At no time should the spilled material be allowed
to dry to a crystalline salt. Do not discharge this product to storm drains or to any surface or
groundwater source unless specifically allowed under a valid NPDES permit.
If the neutralizer is not available, volumes larger than 10 gallons should be carefully transferred
into a container and taken to an authorized chemical disposal site (Class I or landfill) in
accordance with all federal, state, and local regulations. Consult with selected facility regarding
the need for prior neutralization of waste.

SECTION 7: HANDLING AND STORAGE

HANDLING
Use product only as directed by the label. Avoid contact with skin and eyes; avoid breathing any
vapors or fumes resulting from product activation. Wash thoroughly after handling. Thoroughly rinse
all protective gear and handling equipment, such as transfer pumps and lines, with water prior to
reuse or storage. Keep away from children, animals, and unauthorized personnel.

PRODUCT STORAGE
Store in a cool, dry, well-ventilated location away from acids, chlorine and chlorine compounds,
hypochlorites (bleach), organic solvents, sulfur and sulfite compounds, phosphorus,
combustible/flammable materials, and direct sunlight. Keep containers tightly closed when not in
use and open carefully to prevent spillage. Storage on wooden floors and pallets is not
recommended. Do not contaminate water, food or feed by storage or disposal.

SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION

ENGINEERING CONTROLS
VENTILATION
Open air or good room ventilation is normally adequate for safe use of this product. Avoid
breathing any vapors or fumes resulting from acid activation.

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PERSONAL PROTECTIVE EQUIPMENT (PPE)
Eye/Face Protection
Good manufacturing practice recommends use of chemical safety goggles for all applications
involving chemical handling.
Skin Protection
Good manufacturing practice recommends that, at a minimum, rubber, neoprene, or other
chemically impervious gloves be worn for all applications involving chemical handling.
Respiratory Protection
In accordance with OSHA regulations (29 CFR 1910.134 and 29 CFR 1910.1000), fogging or
spraying applications may require worker respiratory protection, such as: (1) NIOSH/MSHA
approved air-purifying respirators, or (2) NIOSH/MSHA approved canister/cartridge facial
respirators rated for chlorine/acid vapors or specified for chlorine dioxide.
General
Product should be stored and applied in close proximity to a safety shower, chemical eyewash
station or other fresh water source.

SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES

Odor, Color, Grade Clear liquid with very faint chlorinous odor
General Physical Form Liquid
Volatile Organic Compounds <0.1% by weight
Flash Point Not applicable
Evaporation Rate Comparable to water
Solubility in Water Complete
Boiling Point 213ºF (100.5ºC)
Vapor Density 0.02 kg/m3
Vapor Pressure 23.7 mm Hg (25ºC)
Specific Gravity 1.03 g/ml (20ºC)
pH 8.0 – 8.5
Melting point: Not determined.

SECTION 10: STABILITY AND REACTIVITY

CHEMICAL STABILITY
Stable

Materials and Conditions to Avoid:

Avoid storing product under conditions in which it could evaporate to crystalline salt. Avoid
accidental contact of concentrate with acids, chlorine compounds, hypochlorites (bleach), sulfur
and sulfite compounds, phosphorous, organic solvents and combustible/flammable material
Hazardous Reaction and Decomposition Products:
Exposure to acids or chlorine compounds can produce uncontrolled generation of chlorine dioxide
gas.
Hazardous Polymerization:
Hazardous polymerization will not occur

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 SECTION 11: TOXICOLOGICAL INFORMATION

ANIMAL TOXICOLOGY
Inhalation LC50: >5.61 mg/l
Dermal LD50: >2,020 mg/kg (rabbit)
Oral LD50: 4,360 mg/kg (rat)
CARCINOGENICITY
Active ingredients are not listed by ROTECS, OSHA, IARC, NTP or EPA. No evidence to date
implicating product as a carcinogen or tumor promoter.
MUTAGENICITY
Though product active ingredient is a chemical oxidant, no evidence to date for mutagenicity from
whole animal or in vitro studies.

REPRODUCTIVE/DEVELOPMENTAL TOXICITY
No known effects to date.

SECTION 12: ECOLOGICAL INFORMATION

ECOTOXICOLOGICAL INFORMATION
This product is toxic to fish and aquatic organisms. Do not discharge effluent containing this
product into lakes, streams, ponds, estuaries, oceans or other waters unless in accordance with
the requirements of a National Pollutant Discharge Elimination System (NPDES) permit and the
permitting authority has been notified in writing prior to discharge. Do not discharge effluent
containing this product to sewer systems without previously notifying the sewage treatment plant
authority. For guidance, contact your State Water Board or Regional office of the EPA.

SECTION 13: DISPOSAL CONSIDERATIONS

CONTAINER DISPOSAL
Triple rinse. Then offer for recycling or reconditioning; or puncture and dispose of in a sanitary
landfill; or by incineration; or, if allowed by state and local authorities, by burning. If burned, stay
out of smoke.
PESTICIDE DISPOSAL
Wastes resulting from the use of this product may be disposed of on site or at an approved waste
disposal facility.

DISPOSAL PROCEDURE
Small quantities, less than 10 gallons, may be flushed to an authorized and permitted sewer with
copious amounts of water. Larger volumes should be taken to an authorized chemical disposal
site (Class I or landfill) in accordance with all federal, state and local regulations. Consult with
selected facility regarding the need for prior neutralization of waste.

SECTION 14: TRANSPORT INFORMATION

Not DOT Regulated

Transportation emergency 24 hour telephone # 800-424-9300 Chemtrec

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 SECTION 15: REGULATORY INFORMATION
US FEDERAL REGULATIONS
TSCA
All product ingredients are in inventory
SARA TITLE 312/313
Neither the product nor its constituent ingredients are listed under SARA reporting requirements.
Chlorine dioxide produced from activation is listed under SARA 313.
RCRA
Not considered a hazardous waste either categorically or by chemical listing.
FIFRA
BioVex® is an EPA registered sanitizer (EPA No. 9804-1)
FEDERAL OSHA REGULATIONS
Neither product nor constituent ingredients is classified as an acute or chronic health hazard by
OSHA. Chlorine dioxide produced by activation is regulated with an air exposure limit of 0.1 ppm
TL V and 0.3 ppm STEL.

STATE LAWS
CALIFORNIA: Not regulated under the provisions of Proposition 65 (Safe Drinking Water and
Toxic Enforcement Act of 1986)
NEW JERSEY: Sodium Chlorite is listed under New Jersey’s Chemical Inventory Notification
Requirement (NJAC 7:1Z). Estimated release notification, however, is not required.

NOTE: Regulatory requirements are subject to change and may vary from one location to
another. It is the user’s responsibility to ensure compliance with all applicable federal, state and
local regulations pertaining to the purchase, transport, storage, use and disposal of this product.
CHEMICAL INVENTORIES
This material contains one or more substances listed on the TSCA Inventory. Commercial use of
this material is regulated by the EPA.

This MSDS has been prepared to meet the U.S. OSHA Hazard Communication Standard, 29 CFR 1910.1200

SECTION 16: OTHER INFORMATON

NFPA Hazard Classification

Health: 1 Flammability: 0 Reactivity: 1 Special Hazards: None
National Fire Protection Association (NFPA) hazard ratings are designed for use by emergency response
personnel to address the hazards that are presented by short-term, acute exposure to a material under
conditions of fire, spill, or similar emergencies. Hazard rating primarily based on the inherent physical
and toxic properties of the material but also include the toxic properties of combustion or decomposition
products that are known to be generated in significant quantities.

NOTICE: Manufacturer believes the information contained herein is accurate; however we make no
guarantees with respect to such accuracy and assume no liability in connection with the use of the
information contained herein by any party. Any party using this product should review all such laws, rules
or regulations prior to use.
Product may bleach clothing and fabric materials, such as draperies and carpets.
NO WARRANTY IS MADE, EXPRESS OR IMPLIED FOR A PARTICULAR PURPOSE
OR OTHERWISE

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