All NCERT Books PDF From WWW - Ncert.online
All NCERT Books PDF From WWW - Ncert.online
All NCERT Books PDF From WWW - Ncert.online
C onsider the following situations of daily life and think what happens
when –
milk is left at room temperature during summers.
an iron tawa/pan/nail is left exposed to humid atmosphere.
grapes get fermented.
food is cooked.
food gets digested in our body.
we respire.
In all the above situations, the nature and the identity of the initial
substance have somewhat changed. We have already learnt about physical
and chemical changes of matter in our previous classes. Whenever a chemical
change occurs, we can say that a chemical reaction has taken place.
You may perhaps be wondering as to what is actually meant by a
chemical reaction. How do we come to know that a chemical reaction
has taken place? Let us perform some activities to find the answer to
these questions.
CAUTION: This Activity needs
the teacher’s assistance. It
would be better if students
wear suitable eyeglasses.
Clean a magnesium ribbon
about 3-4 cm long by rubbing
it with sandpaper.
Hold it with a pair of tongs.
Burn it using a spirit lamp or
burner and collect the ash so
formed in a watch-glass as
shown in Fig. 1.1. Burn the
magnesium ribbon keeping it
away as far as possible from
your eyes. Figure 1.1
What do you observe? Burning of a magnesium ribbon in air and collection of magnesium
oxide in a watch-glass
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Is there any other shorter way for representing chemical equations?
Chemical equations can be made more concise and useful if we use
chemical formulae instead of words. A chemical equation represents a
chemical reaction. If you recall formulae of magnesium, oxygen and
magnesium oxide, the above word-equation can be written as –
Mg + O2 → MgO (1.2)
Count and compare the number of atoms of each element on the
LHS and RHS of the arrow. Is the number of atoms of each element the
same on both the sides? If yes, then the equation is balanced. If not,
then the equation is unbalanced because the mass is not the same on
both sides of the equation. Such a chemical equation is a skeletal
chemical equation for a reaction. Equation (1.2) is a skeletal chemical
equation for the burning of magnesium in air.
Recall the law of conservation of mass that you studied in Class IX; mass
can neither be created nor destroyed in a chemical reaction. That is, the
total mass of the elements present in the products of a chemical reaction
has to be equal to the total mass of the elements present in the reactants.
In other words, the number of atoms of each element remains the
same, before and after a chemical reaction. Hence, we need to balance a
skeletal chemical equation. Is the chemical Eq. (1.2) balanced? Let us
learn about balancing a chemical equation step by step.
The word-equation for Activity 1.3 may be represented as –
Zinc + Sulphuric acid → Zinc sulphate + Hydrogen
The above word-equation may be represented by the following
chemical equation –
Zn + H2SO4 → ZnSO4 + H2 (1.3)
Let us examine the number of atoms of different elements on both
sides of the arrow.
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Step II: List the number of atoms of different elements present in the
unbalanced equation (1.5).
Element Number of atoms Number of atoms
in reactants (LHS) in products (RHS)
Fe 1 3
H 2 2
O 1 4
Step IV: Fe and H atoms are still not balanced. Pick any of these elements
to proceed further. Let us balance hydrogen atoms in the partly balanced
equation.
To equalise the number of H atoms, make the number of molecules
of hydrogen as four on the RHS.
Atoms of In reactants In products
hydrogen
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Step V: Examine the above equation and pick up the third element
which is not balanced. You find that only one element is left to be
balanced, that is, iron.
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1. Why should a magnesium ribbon be cleaned before burning in air?
2. Write the balanced equation for the following chemical reactions.
(i) Hydrogen + Chlorine → Hydrogen chloride
(ii) Barium chloride + Aluminium sulphate → Barium sulphate +
Aluminium chloride
(iii) Sodium + Water → Sodium hydroxide + Hydrogen
3. Write a balanced chemical equation with state symbols for the
following reactions.
(i) Solutions of barium chloride and sodium sulphate in water react
to give insoluble barium sulphate and the solution of sodium
chloride.
(ii) Sodium hydroxide solution (in water) reacts with hydrochloric
acid solution (in water) to produce sodium chloride solution and
water.
Take a small amount of calcium oxide
or quick lime in a beaker.
Slowly add water to this.
Touch the beaker as shown in Fig. 1.3.
Do you feel any change in temperature?
Figure 1.3
Formation of slaked
lime by the reaction of
calcium oxide with Calcium oxide reacts vigorously with water to produce slaked lime
water (calcium hydroxide) releasing a large amount of heat.
CaO(s) + H2O(l) → Ca(OH)2(aq) + Heat (1.13)
(Quick lime) (Slaked lime)
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A solution of slaked lime produced by the reaction 1.13 is used for whitewashing
walls. Calcium hydroxide reacts slowly with the carbon dioxide in air to form a thin
layer of calcium carbonate on the walls. Calcium carbonate is formed after two to
three days of whitewashing and gives a shiny finish to the walls. It is interesting to note
that the chemical formula for marble is also CaCO3.
Ca(OH)2(aq) + CO2(g) → CaCO3(s) + H2O(l) (1.14)
(Calcium (Calcium
hydroxide) carbonate)
(iii)
The decomposition of vegetable matter into compost is also an
example of an exothermic reaction.
Identify the type of the reaction taking place in Activity 1.1, where
heat is given out along with the formation of a single product.
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Take about 2 g ferrous sulphate crystals
in a dry boiling tube.
Note the colour of the ferrous sulphate
crystals.
Heat the boiling tube over the flame of
a burner or spirit lamp as shown in
Fig. 1.4.
Observe the colour of the crystals after
heating.
Figure 1.4
Have you noticed that the green colour of the ferrous sulphate crystals
Correct way of heating
the boiling tube has changed? You can also smell the characteristic odour of burning
containing crystals sulphur.
of ferrous sulphate
Heat
2FeSO4(s)
and of smelling the → Fe2O3(s) + SO2(g) + SO3(g) (1.19)
odour
(Ferrous sulphate) (Ferric oxide)
In this reaction you can observe that a single reactant breaks down
to give simpler products. This is a decomposition reaction. Ferrous
sulphate crystals (FeSO4, 7H2O) lose water when heated and the colour
of the crystals changes. It then decomposes to ferric oxide (Fe2O3),
sulphur dioxide (SO2) and sulphur trioxide (SO3). Ferric oxide is a solid,
while SO2 and SO3 are gases.
Decomposition of calcium carbonate to calcium oxide and carbon
dioxide on heating is an important decomposition reaction used in
various industries. Calcium oxide is called lime or quick lime. It has
many uses – one is in the manufacture of cement. When a decomposition
reaction is carried out by heating, it is called thermal decomposition.
Heat
CaCO3(s) → CaO(s) + CO2(g) (1.20)
(Limestone) (Quick lime)
Take about 2 g lead nitrate powder in a boiling
tube.
Hold the boiling tube with a pair of tongs and
heat it over a flame, as shown in Fig. 1.5.
What do you observe? Note down the change,
if any.
Figure 1.5
You will observe the emission of brown fumes.
Heating of lead nitrate and These fumes are of nitrogen dioxide (NO2). The
emission of nitrogen dioxide reaction that takes place is –
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Heat
2Pb(NO3)2(s) → 2PbO(s) + 4NO2(g) + O2(g) (1.21)
(Lead nitrate) (Lead oxide) (Nitrogen (Oxygen)
dioxide)
Take a plastic mug. Drill two holes at its
base and fit rubber stoppers in these holes.
Insert carbon electrodes in these rubber
stoppers as shown in Fig. 1.6.
Connect these electrodes to a 6 volt
battery.
Fill the mug with water such that the
electrodes are immersed. Add a few drops
of dilute sulphuric acid to the water.
Take two test tubes filled with water and
invert them over the two carbon electrodes.
Switch on the current and leave the
apparatus undisturbed for some time.
You will observe the formation of bubbles Figure 1.6
at both the electrodes. These bubbles displace water in the Electrolysis of water
test tubes.
Is the volume of the gas collected the same in both the test tubes?
Once the test tubes are filled with the respective gases, remove
them carefully.
Test these gases one by one by bringing a burning candle close
to the mouth of the test tubes.
CAUTION: This step must be performed carefully by the teacher.
What happens in each case?
Which gas is present in each test tube?
Take about 2 g silver chloride in a china dish.
What is its colour?
Place this china dish in sunlight for some time
(Fig. 1.7).
Observe the colour of the silver chloride after some
time.
Figure 1.7
You will see that white silver chloride turns grey in sunlight. This is Silver chloride turns grey
due to the decomposition of silver chloride into silver and chlorine by in sunlight to form silver
metal
light.
Sunlight
2AgCl(s) → 2Ag(s) + Cl2(g) (1.22)
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Take about 2 g barium hydroxide in a test tube. Add 1 g of ammonium chloride and mix
with the help of a glass rod. Touch the bottom of the test tube with your palm. What do you
feel? Is this an exothermic or endothermic reaction?
1. A solution of a substance ‘X’ is used for whitewashing.
(i) Name the substance ‘X’ and write its formula.
(ii) Write the reaction of the substance ‘X’ named in (i) above with
water.
2. Why is the amount of gas collected in one of the test tubes in Activity
1.7 double of the amount collected in the other? Name this gas.
Take three iron nails and clean them by
rubbing with sand paper.
Take two test tubes marked as (A) and
(B). In each test tube, take about 10 mL
copper sulphate solution.
Tie two iron nails with a thread and
immerse them carefully in the copper
sulphate solution in test tube B for
about 20 minutes [Fig. 1.8 (a)]. Keep one
iron nail aside for comparison.
After 20 minutes, take out the iron nails
from the copper sulphate solution.
Compare the intensity of the blue colour
of copper sulphate solutions in test tubes
(A) and (B) [Fig. 1.8 (b)].
Also, compare the colour of the iron nails
Figure 1.8 dipped in the copper sulphate solution
(a) Iron nails dipped in copper sulphate solution with the one kept aside [Fig. 1.8 (b)].
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Figure 1.8 (b) Iron nails and copper sulphate solutions compared before and after the experiment
Why does the iron nail become brownish in colour and the blue colour
of copper sulphate solution fades?
The following chemical reaction takes place in this Activity–
Fe(s) + CuSO4(aq) → FeSO4(aq) + Cu(s) (1.24)
(Copper sulphate) (Iron sulphate)
Take about 3 mL of sodium sulphate
solution in a test tube.
In another test tube, take about 3 mL of
barium chloride solution.
Mix the two solutions (Fig. 1.9).
What do you observe?
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Recall Activity 1.2 2, where you have mixed the solutions of lead(II) nitrate
and potassium iodide.
(i) What was the colour of the precipitate formed? Can you name the compound
precipitated?
(ii) Write the balanced chemical equation for this reaction.
(iii) Is this also a double displacement reaction?
Heat a china dish containing about 1 g
copper powder (Fig. 1.10).
What do you observe?
(1.30)
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Have you ever tasted or smelt the fat/oil containing food materials left
for a long time?
When fats and oils are oxidised, they become rancid and their smell
and taste change. Usually substances which prevent oxidation
(antioxidants) are added to foods containing fats and oil. Keeping food
in air tight containers helps to slow down oxidation. Do you know that
chips manufacturers usually flush bags of chips with gas such as
nitrogen to prevent the chips from getting oxidised ?
1. Why does the colour of copper sulphate solution change when
an iron nail is dipped in it?
2. Give an example of a double displacement reaction other than
the one given in Activity 1.10.
3. Identify the substances that are oxidised and the substances
that are reduced in the following reactions.
(i) 4Na(s) + O2(g) → 2Na2O(s)
(ii) CuO(s) + H2(g) → Cu(s) + H2O(l)
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A complete chemical equation represents the reactants, products and their physical
states symbolically.
A chemical equation is balanced so that the numbers of atoms of each type involved
in a chemical reaction are the same on the reactant and product sides of the
equation. Equations must always be balanced.
In a combination reaction two or more substances combine to form a new single
substance.
Decomposition reactions are opposite to combination reactions. In a decomposition
reaction, a single substance decomposes to give two or more substances.
Reactions in which heat is given out along with the products are called exothermic
reactions.
Reactions in which energy is absorbed are known as endothermic reactions.
When an element displaces another element from its compound, a displacement
reaction occurs.
Two different atoms or groups of atoms (ions) are exchanged in double displacement
reactions.
Precipitation reactions produce insoluble salts.
Reactions also involve the gain or loss of oxygen or hydrogen by substances.
Oxidation is the gain of oxygen or loss of hydrogen. Reduction is the loss of oxygen
or gain of hydrogen.
1. Which of the statements about the reaction below are incorrect?
2PbO(s) + C(s) → 2Pb(s) + CO2(g)
(a) Lead is getting reduced.
(b) Carbon dioxide is getting oxidised.
(c) Carbon is getting oxidised.
(d) Lead oxide is getting reduced.
(i) (a) and (b)
(ii) (a) and (c)
(iii) (a), (b) and (c)
(iv) all
2. Fe2O3 + 2Al → Al2O3 + 2Fe
The above reaction is an example of a
(a) combination reaction.
(b) double displacement reaction.
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12. Write one equation each for decomposition reactions where energy is supplied in
the form of heat, light or electricity.
13. What is the difference between displacement and double displacement reactions?
Write equations for these reactions.
14. In the refining of silver, the recovery of silver from silver nitrate solution involved
displacement by copper metal. Write down the reaction involved.
15. What do you mean by a precipitation reaction? Explain by giving examples.
16. Explain the following in terms of gain or loss of oxygen with two examples each.
(a) Oxidation
(b) Reduction
17. A shiny brown coloured element ‘X’ on heating in air becomes black in colour.
Name the element ‘X’ and the black coloured compound formed.
18. Why do we apply paint on iron articles?
19. Oil and fat containing food items are flushed with nitrogen. Why?
20. Explain the following terms with one example each.
(a) Corrosion
(b) Rancidity
Perform the following activity.
Take four beakers and label them as A, B, C and D.
Put 25 mL of water in A, B and C beakers and copper sulphate solution in beaker D.
Measure and record the temperature of each liquid contained in the beakers above.
Add two spatulas of potassium sulphate, ammonium nitrate, anhydrous copper
sulphate and fine iron fillings to beakers A, B, C and D respectively and stir.
Finally measure and record the temperature of each of the mixture above.
Find out which reactions are exothermic and which ones are endothermic in nature.
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