Material Science Notes
Material Science Notes
Material Science Notes
Hardening and Hardness are two very different things. One is a process of heat treatment and other is
a extrinsic property of a material.
Hardening is a heat treatment process in which steel is rapidly cooled from austenizing temperature.
As a result of hardening, the hardness and wear resistance of steel are improved, for example in
Gears, shafts and bearings. Hardening treatment generally consists of heating to hardening
temperature, holding at that temperature, followed by rapid cooling such as quenching in oil or water
or salt baths.
The hardening temperature depends on chemical composition. For plain carbon steels, it depends on
the carbon content alone. Hypoeutectoid steels are heated to about 30 – 50 0C above the upper critical
temperature, whereas eutectoid and hyper eutectoid steels are heated to about 30 – 50 0C above lower
critical temperature. Ferrite and pearlite transform to austenite at hardening temperature for
hypoectectoid steel. This austenite transforms to martensite on rapid quenching from hardening
temperature. The presence of martensite accounts for high hardness of quenched steel.
Tempering
Hardened steels are so brittle that even a small impact will cause fracture. Toughness of such steels
can be improved by tempering. However, there is small reduction in strength and hardness.
Tempering consists of reheating of hardened steel to a temperature below Lower critical temperature
and is held for a period of time, and then slowly cooled in air to room temperature. At tempering
temperature, carbon atoms diffuses out and form fine cementite and softer ferrite structure left behind.
Thus, the structure of tempered steel consists of ferrite and fine cementite and allowing microstructure
to become BCC. Also, cracks, distortion can be reduced because of tempering.
Hardenability is one of the most important properties of a steel because it describes the ease
with which a given steel can be quenched to form martensite or the depth to which martensite
is formed on a given quench.
Hardness ≠ Hardenability
This method is the most useful and widely accepted. The Jominy test involves heating a standard test
piece of diameter 25 mm and length 100 mm to the austenite state, fixing it to a frame in a vertical
position and then quenching the lower end by means of a jet of water. A plot is made of the hardness
reading against the distance from the quenched end of the test peice/bar.