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Volume (V) Absolute Celsius scale Kelvin Scale

Zero -273 0
 Si unit in Liters (L)
- 1liter = 1000ml Freezing Point 0
- 1 ml = 1 cubic cm Of Water degree 273
- 1 cubic m = 1000 cubic cm Boiling Point 100
373
Pressure is the force exerted per unit area Of Water degrees

P= f / a
℃ = 5/9 (℉ - 32) ℉ = (9/5*℃) + 32 K= ℃ +
= n / m2 = 1 pa 273
1n = 1kg m/s2 5/9 = 0.56 9/5 = 1.8
 P symbol – Si unit is in Pascal Pa Operating & Process (O.P.)
 P = force / area
 P = (mass)(acceleration) / area + & - (Transposition)

CONVERSION FACTOR × (Divided both sides)

1atm (atmosphere) = 760 mmHg (millimetres of ÷ (Criss-cross)


mercury) = 760torr (Evangilista torrcelli) =
Transposition (+&-) Dividing both sides Criss-cross
1.01325bar = 101.325
a=b+c a= bc b = a/c
kPa (kilopascal) = 101.325 x 10 E3 N.m-2
Unknown = b Unknown = b Unknown = a
Evangilista torrcelli – Italian physicist and
mathematician b=a–c b = a/c a = bc
APPARATUS USED TO MEASURE

 Barometer – used to measure atmospheric


pressure
 Manometer – used to measure gas pressure
 Closed-tube manometer – used to measure
pressure below atmospheric pressure
 Open-tube manometer – is used to measure
pressure equal to or greater than the atmospheric
pressure

Temperature (T)

- The amount of kinetic energy


- Anders Celsius (Degree Celsius)
- William Thomson / Lord Kelvin (Kelvin) Si unit
- Gabriel Daniel Fahrenheit (Degree Fahrenheit)
BOYLE’S LAW: VOLUME AND PRESSURE Equation: V2 = V1T2 Solution:
RELATIONSHIP
T1 = (2.75L)(318K)
Anglo – Irish Chemist Robert Boyle, which states that
“the volume of a given mass of gas held at constant 291K
temperature is inversely proportional to its temperature” = 874.5
FORMULA: P1 V1 = P2 V2 291
PROBLEM 1 =3.01L
Freon In an air-conditioning unit has a volume of 0.30L. GAY LUSSAC’S LAW: TEMPARATURE AND
it is allowed to function in a room where pressure is PRESSURE RELATIONSHIP
about 628 mmHg assuming that the temperature is in a
constant state and the final pressure of Freon when it’s French chemist and physicist Joseph Louis Gay-Lussac
volume is increased to 0.95L He is known mostly for his discovery that water is made
of two parts hydrogen and one part oxygen.
Given: Solution:
FORMULA: P1/T1 = P2/T2
V1 = 0.30L = (628mmHg)(0.30L)
PROBLEM 1:
P1 = 628 mmHg 0.95L
The pressure in an automobile tire is 1.88atm at 25.0℃.
V2 = 0.95L = 198.32mmHg What will be the pressure if the temperature warms up to
Unknown: P2 37.0℃?

Equation: P2 = P1V1 Given:

V2 P1 = 1.88atm

CHARLE’S LAW: VOLUME AND TEMPERATURE T1 = 25.0℃


RELATIONSHIP T2 = 37.0℃
French physicist Jacques Alexandre César Charles wrote Unknown: P2
almost nothing about mathematics. Also a member of the
Paris Academy of Sciences. Equation: P2= P1T1

FORMULA: V1/T1 = V2/T2 T2

PROBLEM 1: Solution:

A balloon full of air has a volume of 2.75L at a = (1.88atm)(298K)


temperature of 18℃. What is the balloon’s volume at
45℃? 310K

Given: =560.24

V1 = 2.75L 310

T1 = 18℃ =1.81atm

T2 = 45 ℃

Unknown: V2
COMBINED GAS LAW:BOYLE'S LAW, AVOGADRO’S LAW: VOLUME AND
CHARLES' LAW, AND GAY-LUSSAC'S LAW. MOLECULES RELATIONSHIP

It states that the ratio of the product of pressure and Amedeo Avogadro is an Italian scientist. Avogadro's law
volume and the absolute temperature of a gas is equal to states that "equal volumes of all gases, at the same
a constant. temperature and pressure, have the same number of
molecules."
FORMULA: P1V1/T1 = P2V2/T2
FORMULA: V1/n1 = V2/n2
STP:
PROBLEM 1:
T = 0℃, 273K, 32℉
A sample with 0.15 moles of gas has a volume of 2.5L.
P = 1atm, 101325kPa, 760 mmHg, 760torr, 14.7 P What is the volume if the sample is increased to
0.55mole?
PROBLEM 1:
Given: Unknown: V2
Solution of the last e.g.
n1 = 0.15mol Equation: V2 = V1n2
Given: Unknown: V2
V1 = 2.5L n1
P1 = 99.3 kPa Equation: V2 = P1V1T2
n2 = 0.55mol
V1 = 350 cm3 T1
Solution:
T1 = 22 ℃
= (2.5L)(0.55mol)
P2 = 101325kPa
0.15mol
T2 = 273K
= 1.375
Solution:
0.15
= (99300kPa)(0.35L)(273K)
=9.16 L
(101325kPa)(295K)

= 9488115L

29890875

= 0.32L

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