Chemistry 2 Practice Exam 1

New York City College of Technology. Department of Chemistry.
CHEM 1210. General Chemistry II. Practice exam.
Chapters 11 and 12
1. Which one of the following substances will have both dispersion forces and dipole-dipole
forces?
A) HCl B) BCl3 C) Br2 D) H2 E) CO2

Ans: A
2. Which two properties are more typical of molecular compounds than of ionic compounds?
1. They are gases or liquids at room temperature.

2. They have high melting points.
3. Solids do not conduct electricity, but liquids do.
4. Atoms share electrons.
A) 1 and 4 B) 1 and 3 C) 2 and 3 D) 2 and 4 E) 3 and 4

Ans: A
3. Which of the following characteristics indicates the presence of weak intermolecular forces in
a liquid?
A) a low heat of vaporization D) a high boiling point

B) a high critical temperature E) None of the above.
C) a low vapor pressure
Ans: A
4. The intermolecular forces present in CO include which of the following?
I. dipole-dipole
II. ion-dipole
III. dispersion
IV. hydrogen bonding
A) I, II, III, and IV B) I and III C) I, III, and IV D) I and II E) II and IV

Ans: B
5. Which of the following would be expected to have the highest vapor pressure at room
temperature?
A) ethanol, bp = 78°C C) water, bp = 100°C

B) methanol, bp = 65°C D) acetone, bp = 56°C
Ans: D
6. Octane is a liquid component of gasoline. Given the following vapor pressures of octane at
various temperatures, estimate the boiling point of octane in Leadville, Colorado, where
the atmospheric pressure is 496 mmHg.
400 mmHg @ 104°C, 500 mmHg @ 111°C, 600 mmHg @ 117°C, 700 mmHg @ 122°C,
760 mmHg @ 125°C
A) 125°C B) 120°C C) 115°C D) 110°C E) 105°C

Ans: D
7. Use the graph of vapor pressure to determine the normal boiling point of CHCl3.
A) 19°C B) 52°C C) 60°C D) 64°C E) 70°C

Ans: D
8. The vapor pressure of a liquid in a closed container depends upon
A) the amount of liquid. D) the temperature.

B) the surface area of the liquid. E) None of the above.
C) the volume of the container.
Ans: D
9. What mass of water would need to evaporate from your skin in order to dissipate 1.7 × 105 J of
heat from your body?
H2O(l)  H2O(g) Hvap = 40.7 kJ/mol
A) 58.4 g B) 75.2 g C) 418 g D) 7.52 × 104 g E) 6.92 × 106 g

Ans: B
10. How much energy (heat) is required to convert 25.5 g of H2O(l) at 35.0°C to H2O(g) at
115.0°C?
specific heat of ice: 2.09 J/g·°C Hfus = 6.02 kJ/mol

specific heat of water: 4.18 J/g·°C Hvap = 40.7 kJ/mol
specific heat of steam: 1.84 J/g·°C
A) 207 J B) 7,630 J C) 8,530 J D) 9,130 J E) 65,200 J

Ans: E
11. The vapor pressure of ethanol is 400 mmHg at 63.5°C. Its molar heat of vaporization is 39.3
kJ/mol. What is the vapor pressure of ethanol, in mmHg, at 34.9°C?
A) 0.0099 mmHg D) 200 mmHg

B) 4.61 mmHg E) 1,510 mmHg
C) 100 mmHg
Ans: C
12. Based on the phase diagram shown below, how will the melting point of the substance
change if the pressure is increased above 1 atm?
A) The melting point will decrease.

B) The melting point will remain the same.
C) The melting point will increase.
D) The substance will not melt at pressures of 1 atm and above; instead, the solid
sublimes to form the gas phase.
Ans: C
13.Which one of the following would be immiscible with water?
A) A B) B C) C D) D E) E
Ans: C
14. In which of the following solvents would you expect KBr to be most soluble?
A) C6H14 (hexane) D) CCl4 (carbon tetrachloride)

B) CH3CH2OH (ethanol) E) C6H12 (cyclohexane)
C) C6H6 (benzene)
Ans: B
15. A 9.50 % by mass solution of acetone (C3H6O) in water has a density of 0.9849 g/mL at
20°C. What is the molarity of this solution?
A) 0.621 M B) 1.61 M C) 1.66 M D) 1.71 M E) 16.9 M

Ans: B
16. Calculate the molality of a 20.0% by mass ammonium sulfate (NH4)2SO4 solution. The
density of the solution is 1.117 g/mL.
A) 0.150 m B) 1.51 m C) 1.70 m D) 1.89 m E) 2.10 m

Ans: D
17. Which of the following gases is expected to have a higher solubility in water than what is
predicted using Henry's law?
A) N2 B) CH4 C) Ar D) NH3 E) H2
Ans: D
18. The vapor pressure of water at 45.0 °C is 71.93 mmHg. What is the vapor pressure of water
over a solution prepared from 75.0 g of citric acid (C6H8O7) in 0.420 kg of water at this
temperature?
A) 1.22 mmHg D) 70.7 mmHg

B) 42.3 mmHg E) 73.2 mmHg
C) 43.0 mmHg
Ans: D
19. The solubility of oxygen in lakes high in the Rocky Mountains is affected by the altitude. If
the solubility of O2 from the air is 2.67 × 10–4 M at sea level and 25°C, what is the
solubility of O2 at an elevation of 12,000 ft where the atmospheric pressure is 0.657 atm?
Assume the temperature is 25°C, and that the mole fraction of O2 in air is 0.209 at both
12,000 ft and at sea level.
A) 3.66 × 10–5 M D) 4.06 × 10–4 M

B) 1.75 × 10–4 M E) None of the above.
C) 2.67 × 10–4 M
Ans: B
20. A solution of chloroform, CHCl3, and acetone, (CH3)2CO, exhibits a negative deviation from
Raoult's law. This result implies that
A) chloroform-chloroform interactions are stronger than chloroform-acetone

interactions.
B) chloroform-chloroform interactions are weaker than chloroform-acetone
interactions.
C) acetone-acetone interactions are stronger than chloroform-acetone interactions.
D) acetone-acetone interactions are weaker than chloroform-acetone interactions.
E) Both B and D.
F) Both A and C.
Ans: E
21.Which of the following aqueous solutions has the highest boiling point (assume 100%
dissociation for all soluble ionic compounds)?
A) 0.10m Al(NO3)3 D) 0.18m NaCl

B) 0.11m Na2SO4 E) 0.35m C6H12O6
C) 0.15m K2CO3
Ans: C
22. Calculate the freezing point of a solution made from 22.0 g of octane (C8H18) dissolved in
148.0 g of benzene. Benzene freezes at 5.50°C and its Kf value is 5.12°C/m.
A) –1.16°C B) 0.98°C C) 5.49°C D) 6.66°C E) 12.2°C

Ans: A

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New York City College of Technology. Department of Chemistry.

CHEM 1210. General Chemistry II. Practice exam.

A) HCl B) BCl3 C) Br2 D) H2 E) CO2

1. They are gases or liquids at room temperature.

A) 1 and 4 B) 1 and 3 C) 2 and 3 D) 2 and 4 E) 3 and 4

A) a low heat of vaporization D) a high boiling point

4. The intermolecular forces present in CO include which of the following?

A) I, II, III, and IV B) I and III C) I, III, and IV D) I and II E) II and IV

A) ethanol, bp = 78°C C) water, bp = 100°C

A) 125°C B) 120°C C) 115°C D) 110°C E) 105°C

A) 19°C B) 52°C C) 60°C D) 64°C E) 70°C

8. The vapor pressure of a liquid in a closed container depends upon

A) the amount of liquid. D) the temperature.

H2O(l)  H2O(g) Hvap = 40.7 kJ/mol

A) 58.4 g B) 75.2 g C) 418 g D) 7.52 × 104 g E) 6.92 × 106 g

specific heat of ice: 2.09 J/g·°C Hfus = 6.02 kJ/mol

A) 207 J B) 7,630 J C) 8,530 J D) 9,130 J E) 65,200 J

A) 0.0099 mmHg D) 200 mmHg

A) The melting point will decrease.

A) C6H14 (hexane) D) CCl4 (carbon tetrachloride)

A) 0.621 M B) 1.61 M C) 1.66 M D) 1.71 M E) 16.9 M

A) 0.150 m B) 1.51 m C) 1.70 m D) 1.89 m E) 2.10 m

A) 1.22 mmHg D) 70.7 mmHg

A) 3.66 × 10–5 M D) 4.06 × 10–4 M

A) chloroform-chloroform interactions are stronger than chloroform-acetone

A) 0.10m Al(NO3)3 D) 0.18m NaCl

A) –1.16°C B) 0.98°C C) 5.49°C D) 6.66°C E) 12.2°C

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