LS - 0 - 2 - 2d3125 - 0246d18e06a2d-Group Theory

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PHYSICAL CHEMISTRY

Daily Assignment

Group Theory (3)

1. The number of C2 axes in CCl4 is _________


2. The point group of IF7 is
(a) D6h (b) D5h (c) C6v (d) C5v
3. The symmetry point group of the BF3 molecule is
(a) C3v (b) D3h (c) C2v (d) D2h
4. The point group symmetry of the free nitrate ion is:
(a) D3h (b) C3v (c) C3h (d) D3
5. A molecule has a 2-fold axis and a mirror plane perpendicular to that. The point group must have a
(a) C2 axis (b) Centre of inversion
(c) h plane (d) v plane
6. The symmetry elements that are present in BF3 are

7.
CHEM ACADEMY
(a) C3 ,  v ,  h ,3C 2
The point group of NSF3 is
(b) C3 , 3C 2 ,S2 ,  v (c) C3 , 3C 2 , h ,S2 (d) C3 , h ,  v ,i

(a) D3d (b) C3h (c) D3h (d) C3v


8. The symmetry point group of ethane in its staggered conformation is
(a) C3v (b) D3d (c) D3h (d) S6
9. The molecule with a C2 axis of symmetry among the following is
(a) BH2Cl (b) CH3Cl (c) NH2Cl (d) HOCl
10. The correct relation involving symmetry operations

(a) S24  S2 (b) (xz)(yz)  C 2 (x)

(c) S34  C34 (d) S36  S2


11. The compound N2F2 has two isomers. Choose the correct option from the following
(a) both isomers possess v plane (b) both isomers possess h plane

(c) one isomer has a h plane while the other has a v plane

(d) none of them have a h plane


12. What is the point group of Taj Mehal
(a) C4h (b) D4h (c) C4V (d) D2h

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13. The point group of Indian Flag considering its colour:
(a) C2h (b) C2V (c) D2h (d) D4h
14. The point group of S8 is
(a) D4d (b) D3d (c) C2v (d) S8
15. The point group of gauche (C2H6) and Co(OX)33– is
(a) D3 and D3d (b) D3 & D3 (c) D3h & D3 (d) None
16. The point group of cyclohexane (chair) and UF6 are
(a) D3d & D4d (b) D3d & Oh (c) Oh & D3h (d) None
17. Point group of CH3– and PCl4F is
(a) C2v (b) C3v (c) D3d (d) D2d
18. Point group of P(O)FClBr & NHClBr is
(a) C1 (b) Cs (c) Ci (d) C2
19. The point group of HOCl, R2NH, SOCl2 are
(a) C1 (b) CS (c) Ci (d) C2

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North Delhi: 72, Mall Road, G.T.B. Nagar, New Delhi - 110009
South Delhi: 28B/7, Jia Sarai, Near IIT, Hauz Khas, New Delhi - 110016. Mob.: 8860108204 2
Toll Free: 1800 120 5848, Ph.: 011-41415514, 09136597244, Web.: www.chemacademy.co.in

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