Sodium Metal Analysis

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SODIUM METAL ANALYSIS

As a part of the alkali metal group in the periodic table, sodium is highly reactive and is
never found pure in nature. It tarnishes easily and has a low melting point and
density. Therefore, sodium is usually stored in mineral oil or kerosene. Chemically, sodium is
highly reactive with the halogen family to form ionic salts. For example, sodium is commonly
found combined with chloride to form NaCl, known to us as table salt. It has one electron in the
outermost electron shell and thus wants to give up one electron to a highly electronegative
element.
Within the alkali metals, sodium is more reactive than lithium but less reactive than
potassium. Its ionization energy is higher than potassium but lower than lithium. Sodium is also
more metallic than lithium. When exposed to air, sodium oxidizes immediately. When burned,
sodium forms sodium peroxide (Na2O2) or oxide (NaO2). If burned in oxygen under pressure,
sodium superoxide (NaO2) is formed.
Sodium reacts exothermically with water, releasing heat when in contact with water.
The chemical equation:

sodium + water → sodium hydroxide + hydrogen gas


2Na(s)+2H2O(l)→2NaOH(aq)+H2(g

HAZARDS IDENTIFICATION

GHS Classification (29 CFR 1910.1200): Substances and mixtures which, in contact with
water, emit flammable gases, category 1, Skin corrosion/irritation, category 1B, Eye
damage/irritation, category 1.

GHS Label Elements:

Signal Word: Danger

Hazard Statements
In contact with water releases flammable gases which may ignite spontaneously
Causes severe skin burns and eye damage

PRECAUTIONARY STATEMENTS

Prevention
 Do not breathe dust/fume/gas/mist/vapors/spray
 Wash face, hands and any exposed skin thoroughly after handling
 Wear protective gloves/protective clothing/eye protection/face protection
 Keep away from any possible contact with water, because of violent reaction and
possible flash fire
 Handle under inert gas. Protect from moisture
Response
Immediately call a POISON CENTER or doctor/physician
Inhalation
IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing
Skin
IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with
water/shower
Wash contaminated clothing before reuse
Brush off loose particles from skin. Immerse in cool water/wrap with wet bandages
Eyes
IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present
and easy to do. Continue rinsing
Ingestion
IF SWALLOWED: Rinse mouth. DO NOT induce vomiting
Fire
In case of fire: Use CO2, dry chemical, or foam for extinction
Storage
Store locked up
Store in a dry place. Store in a closed container
Disposal
Dispose of contents/container to an approved waste disposal plant
Hazards not otherwise classified (HNOC)
Reacts violently with water

PHYSICAL AND CHEMICAL PROPERTIES


Form: Solid
Color: Silver metallic
Odor: Not determined
Odor Threshold: Not determined
Melting Point: 97.8 oC
Boiling Point: 883 oC
Flammability: Flammable solid
Vapor Pressure: 1 mm at 439 oC
Relative Density (Specific Gravity): 0.97 g/cc
Solubility in H2O: Decomposes

APPROPRIATE ENGINEERING CONTROLS

Handle in an inert gas such as argon. Handle in an enclosed, controlled process. Use
local exhaust to maintain exposure at low levels. Whenever possible the use of local exhaust
ventilation or other engineering controls is the preferred method of controlling exposure to
airborne dust and fume to meet established occupational exposure limits. Do not use tobacco or
food in work area. Wash thoroughly before eating or smoking. Do not blow dust off clothing or
skin with compressed air. Prepare for the possibility of a fire. Keep extinguishing agents, tools
for handling and protective clothing readily available.

REFERENCES: http://www.espimetals.com/index.php/msds/278-sodium
https://chem.libretexts.org/Bookshelves/Inorganic_Chemistry/Supplemental_
Modules_(Inorganic_Chemistry)/Descriptive_Chemistry/Elements_Organize
d_by_Group/Group_01%3A_Hydrogen_and_the_Alkali_Metals/Z%3D011_C
hemistry_of_Sodium_(Z%3D11)

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