MATERIAL SAFETY DATA SHEET

I. CHEMICAL PRODUCT

 General Product Name: Glycerol

 Other names: Glycerin,1,2,3- Propanetriol, 1,2,3-Trihydroxypropane
1,2,3-Propanetriol
 Product Description:
- Molecular Formula: C3H8O3
- Density: 1.26 g/cm³
- Molar mass: 92.09382 g/mol
- Melting point: 17.8 °C
- Boiling point: 290 °C

II. COMPOSITION/INFORMATION ON INGREDIENTS

 Composition
- Chemical name: Glycerol
- CAS Number: 56-81-5
- % by Weight: 100
- Toxicological Data on Ingredients: Glycerol: ORAL (LD50):
Acute: 12600 mg/kg [Rat]. 4090 mg/kg [Mouse]. DERMAL
(LD50): Acute: 10000 mg/kg [Rabbit]. MIST(LC50): Acute: >570
mg/m 1 hours [Rat].

III. HAZARDS IDENTIFICATION

 Potential Acute Health Effects: Slightly hazardous in case of skin

contact (irritant, permeator), of eye contact (irritant), of ingestion, of
inhalation.
 Potential Chronic Health Effects: CARCINOGENIC EFFECTS: Not
available. MUTAGENIC EFFECTS: Not available. TERATOGENIC
EFFECTS: Not available. DEVELOPMENTAL TOXICITY: Not
available. The substance may be toxic to kidneys. Repeated or
prolonged exposure to the substance can produce target organs
damage.

IV. FIRST AID MEASURES

 EYE CONTACT: Check for and remove any contact lenses. In case of
contact, immediately flush eyes with plenty of water for at least 15
minutes. Cold water may be used. Get medical attention if irritation
occurs.
 SKIN CONTACT: Wash with soap and water. Cover the irritated skin
with an emollient. Get medical attention if irritation develops. Cold
water may be used.
 SERIOUS SKIN CONTACT: Not available.
 INHALATION: If inhaled, remove to fresh air. If not breathing, give
artificial respiration. If breathing is difficult, give oxygen. Get medical
attention immediately.
 INGESTION: Do not induce vomiting unless directed to do so by
medical personnel. Never give anything by mouth to an unconscious
 person. Loosen tight clothing such as a collar, tie, belt or waistband.
Get medical attention if symptoms appear.
 SERIOUS INHALATION: Not available
 SERIOUS INGESTION: Not available.

V. FIRE FIGHTING MEASURES

 Flammability of the Product: May be combustible at high temperature.

 Auto-Ignition Temperature: 370°C (698°F)(NFPA Fire Protection
Guide to Hazardous Materials, 13th ed., 2002; NIOSH ICSC, 2001;
CHRIS, 2001) 392 C (739 F) (Lewis, 1997)
 Flash Points: Closed Cup: 160°C (320°F). (Chemical Hazard Response
Information System, 2001; Lewis, 1997). OPEN CUP: 177°C
(350.6°F) (Budavari, 2000; Chemical Response Information System,
2001; NIOSH ICSC, 2001) OPEN CUP: 199 C(390 F) (National Fire
Protection Association, Fire Protection Guide to Hazardous Materials,
13 ed., 2002)
 Products of Combustion: These products are carbon oxides (CO, CO2)
, irritating and toxic fumes.
 Flammable Limits: LOWER: 0.9%
 Fire Fighting Media and Instructions: SMALL FIRE: Use DRY
chemical powder. LARGE FIRE: Use water spray, fog or foam. Do not
use water jet.
 Fire Hazards in Presence of Various Substances: Slightly flammable to
flammable in presence of open flames and sparks, of heat, of oxidizing
materials. Non-flammable in presence of shocks.
 Explosion Hazards in Presence of Various Substances: Risks of
explosion of the product in presence of mechanical impact: Not
available. Risks of explosion of the product in presence of static
discharge: Not available. Explosive in presence of oxidizing materials.
 Special Remarks on Fire Hazards: Not available.
 Special Remarks on Explosion Hazards: Glycerin is incompatible with
strong oxidizers such as chromium trioxide, potassium chlorate, or
potassium permanganate and may explode on contact with these
compounds. Explosive glyceryl nitrate is formed from a mixture of
glycerin and nitric and sulfuric acids. Perchloric acid , lead oxide +
glycerin form perchloric esters which may be explosive. Glycerin and
chlorine may explode if heated and confined.

VI. ACCIDENTAL RELEASE MEASURES SPILL CLEAN-U

PROCEDURES

 Small Spill: Dilute with water and mop up, or absorb with an inert dry
material and place in an appropriate waste disposal container. Finish
cleaning by spreading water on the contaminated surface and dispose
of according to local and regional authority requirements.
 Large Spill: Stop leak if without risk. If the product is in its solid form:
Use a shovel to put the material into a convenient waste disposal
container. If the product is in its liquid form: Do not get water inside
container. Absorb with an inert material and put the spilled material in
an appropriate waste disposal. Do not touch spilled material. Use water
 spray to reduce vapors. Prevent entry into sewers, basements or
confined areas; dike if needed. Eliminate all ignition sources. Call for
assistance on disposal. Finish cleaning by spreading water on the
contaminated surface and allow to evacuate through the sanitary
system. Be careful that the product is not present at a concentration
level above TLV. Check TLV on the MSDS and with local authorities.

VII. HANDLING AND STORAGE

 Precautions: Keep away from heat. Keep away from sources of

ignition. Ground all equipment containing material. Do not ingest. Do
not breathe gas/fumes/ vapor/spray. Wear suitable protective clothing.
If ingested, seek medical advice immediately and show the container
or the label. Keep away from incompatibles such as oxidizing agents.
 Storage: Keep container tightly closed. Keep container in a cool, well-
ventilated area. Hygroscopic.

VIII. EXPOSURE CONTROL/PERSONAL PROTECTION

 Engineering Controls: Provide exhaust ventilation or other engineering

controls to keep the airborne concentrations of vapors below their
respective threshold limit value. Ensure that eyewash stations and
safety showers are proximal to the work-station location.
 Personal Protection: Safety glasses. Lab coat. Vapor respirator. Be sure
to use an approved/certified respirator or equivalent. Gloves.
 Personal Protection in Case of a Large Spill: Splash goggles. Full suit.
Vapor respirator. Boots. Gloves. A self contained breathing apparatus
should be used to avoid inhalation of the product. Suggested protective
clothing might not be sufficient; consult a specialist BEFORE
handling this product
 Exposure Limits: TWA: 10 (mg/m3) from ACGIH (TLV) [United
States] [1999] Inhalation Total. TWA: 15 (mg/m3) from OSHA (PEL)
[United States] Inhalation Total. TWA: 10 STEL: 20 (mg/m3)
[Canada] TWA: 5 (mg/m3) from OSHA (PEL) [United States]
Inhalation Respirable.Consult local authorities for acceptable exposure
limits.
IX. PHYSICAL AND CHEMICAL PROPERTIES

 Physical state and appearance: Liquid. (Viscous (Syrupy)

liquid.)
 Odor: Mild
 Taste: Sweet.
 Molecular Weight: 92.09 g/mole
 Color: Clear Colorless.
 pH (1% soln/water): Not available.
 Boiling Point: 290°C (554°F)
 Melting Point: 19°C (66.2°F)
 Critical Temperature: Not available.
 Specific Gravity: 1.2636 (Water = 1)
 Vapor Pressure: 0 kPa (@ 20°C)
 Vapor Density: 3.17 (Air = 1)
 Volatility: Not available.
 Odor Threshold: Not available.
  Water/Oil Dist. Coeff.: The product is more soluble in water;
log(oil/water) = -1.8
 Ionicity (in Water): Not available.
 Dispersion Properties: See solubility in water, acetone.
 Solubility:
Miscible in cold water, hot water and alcohol. Partially soluble
in acetone. Very slightly soluble in diethyl ether (ethyl ether).
Limited solubility in ethyl acetate. Insoluble in carbon
tetrachloride, benzene, chloroform, petroleum ethers, and oils

X. STABILITY AND REACTIVITY

 Stability: The product is stable.

 Instability Temperature: Not available.
 Conditions of Instability: Avoid contact with incompatible materials,
excess heat and ignition, sources, moisture.
 Incompatibility with various substances: Highly reactive with oxidizing
agents.
 Corrosivity: Non-corrosive in presence of glass.
 Special Remarks on Reactivity: Hygroscopic. Glycerin is incompatible
with strong oxidizers such as chromium trioxide, potassium chlorate, or
potassium permanganate. Glycerin may react violently with acetic
anhydride, aniline and nitrobenzene, chromic oxide, lead oxide and
fluorine, phosphorous triiodide, ethylene oxide and heat, silver
perchlorate, sodium peroxide, sodium hydride.
 Special Remarks on Corrosivity: Not available
 Polymerization: Will not occur.