Nimonic Alloy 105 PDF

Download as pdf or txt
Download as pdf or txt
You are on page 1of 24

www.specialmetals.

com

NIMONIC® alloy 105 (W. Nr. 2.4634) is a wrought Composition, %


nickel-cobalt-chromium-base alloy strengthened by
additions of molybdenum, aluminum and titanium. It
has been developed for service up to 950°C, and com- The composition stated in BS HR 3 is as follows:
bines the high strength of the age-hardening nickel-base
alloys with good creep resistance. Carbon.........................................................................0.17 max
NIMONIC alloy 105 is produced by high frequency Silicon............................................................................1.0 max
Copper...........................................................................0.2 max
melting in air followed by casting in air, or, for more
Iron.................................................................................1.0 max
critical applications the alloy is produced by vacuum Manganese....................................................................1.0 max
melting and electroslag refining. Chromium....................................................................14.0-15.7
The alloy is used for turbine blades, discs, forgings, Titanium...........................................................................0.9-1.5
ring sections, bolts and fasteners. Aluminum.........................................................................4.5-4.9
Cobalt..........................................................................18.0-22.0
Molybdenum...................................................................4.5-5.5

NIMONIC alloy 105


Heat Treatment Lead.........................................................................0.0015 max
Sulfur..........................................................................0.010 max
The heat treatment recommended is dependent on the Boron.......................................................................0.003-0.010
intended service condition. Zirconium.....................................................................0.15 max
Nickel............................................................................Balance*
Two heat treatments are recommended as follows: *Reference to the ‘balance’ of an alloy’s composition does not guaran-
tee this is exclusively of the element mentioned, but that it predomi-
(a) 4 h/1150°C/AC+16 h/1050-1065°C/AC+16 nates and others are present only in minimal quantities.
h/850°C/AC
(b) 4 h/1125°C/AC+16 h/850°/AC

In general, heat treatment (a) is intended for optimum


long-term creep strength and ductility at operating tem-
peratures in the range 850-950°C. Heat-treatment (b)
may be used where long-term properties are not of para-
mount importance and tensile strength, elongation and
impact strength may be enhanced for operating temper-

®
atures up to 700°C. When applying heat-treatment (b)
it is essential to ensure that cooling from 1125°C takes
place freely and is not delayed due to close packing of
components.

Examples of the use of these heat treatments are as


follows:

(a) turbine blades, discs, forgings and ring sections,


all of which may be produced from as-extruded,
as-forged or subsequently cold worked starting
stock

(b) bolts and fasteners for which extruded and cold


worked bar or section is recommended as starting
stock.
NIMONIC ® alloy 105

Physical Properties Table 3 - Mean Coefficient of Linear Thermal Expansion


Temperature range, °C 10-6/ °C
Density 8.01 g/cm³ 20-100 12.2
0.289 lb/in³ 20-200 12.8
20-300 13.1
The exact density is dependent on compositional variation 20-400 13.4
within the release specification.
20-500 13.7
20-600 14.0
Melting Range Liquidus temperature 1345°C
Solidus temperature 1290°C 20-700 14.5
20-800 15.3
The liquidus temperature was determined by inverse cool- 20-900 16.5
ing techniques and the solidus temperature obtained by met- 20-1000 18.0
allographic examination. The accuracy of determination was Extruded section subsequently cold rolled given heat treatment
± 5°C for the liquidus temperature and +0, -10°C for the 4 h/1150°C/AC + 16 h/1050°C/AC + 16 h/850°C/AC.
solidus temperature. These data are average and subject to approximately ±5% variation.

Table 1 - Specific Heat Table 4 - Electrical Properties


Electrical resistivity at 20°C = 131 microhm cm
Temperature, °C Specific Heat, J/kg•°C
20 419 Temperature °C Relative Resistance
100 461 20 1.000
200 502 100 1.021
300 502 200 1.044
400 544 300 1.066
500 544 400 1.089
600 586 500 1.107
700 628 600 1.155
800 628 700 1.117
900 670 800 1.106
1000 670 900 1.088
1000 1.055
Hot rolled bar subsequently cold drawn (wire) and given heat treatment 15
min/1150°C/AC + 1 h/1050°C/AC + 16 h/850°C/AC.

Table 2 - Thermal Conductivity

Temperature ,°C Thermal Conductivity, W/m •°C


Table 5 - Magnetic Properties
20 10.89
100 12.10 Magnetic permeability from
200 13.57 0.02T-0.2T 1.000715
300 14.99
400 16.33 Extruded bar subsequently forged and given heat treatment 4 h/1150°C/AC
+ 16 h/1050°C/AC + 16 h/850°C/AC.
500 17.67
600 18.63
700 20.56
800 22.23
900 24.03
1000 26.21

These values have been calculated from electrical resistance measurements


on a single 3-stage heat-treated specimen using the modified Wiedemann-
Franz equations.

2
NIMONIC ® alloy 105

Table 6 - Dynamic Young’s Modulus

Extruded bar, Extruded bar,


Temperature Extruded bar subsequently subsequently
°C forged
cold rolled
GPa GPa GPa
20 188 223 220
100 184 219 216
200 179 212 210
300 174 206 204
400 168 200 198
500 161 193 191
600 154 186 185
700 147 178 177
800 139 168 168
900 129 155 154
1000 110 138 137

Heat treatment 4 h/1150°C/AC + 16 h/1050°C/AC + 16 h/850°C/AC.

Tensile Properties: Extruded Bar


The data given in Table 7 and presented graphically in Figures 1 and 2 represent the tensile properties for extruded bar after
the 3-stage heat treatment.

Strain rate 0.005/min to proof stress (at room temperature), 0.002/min to proof stress (at elevated temperatures) and 0.1/min
thereafter.

Table 7 - Heat treatment 4 h/1150°C/AC + 16 h/1050-1065°C/AC + 16 h/850°C/AC

0.1% proof stress 0.2% proof stress Tensile strength


Elongation on 5.65 Reduction of area,
Temperature, °C MPa MPa MPa √ So, % %
20 751 776 1140 22 31
100 739 762 1123 20 31
200 712 735 1084 21 38
300 712 735 1091 20 30
400 718 743 1101 24 39
500 711 740 1064 23 37
600 694 720 1038 25 38
700 706 732 1018 28 36
800 647 677 813 25 37
900 373 400 496 30 47
1000 144 152 175 42 73
1100 26 29 51 172 99
Average results of tests on 15 casts.

3
NIMONIC ® alloy 105

Temperature, °F
200 400 600 800 1000 1200 1400 1600 1800
1600 80
100 220
200
80 180 60

Reduction of Area, %
1200
160 Stress, MPa
R. of A.
140
60
120 800 40
100
40
80
60 20
400
20 40
20
0.2% Proof Stress
0 0 0
0
ton/in² 10³ lb/in² 0 200 400 600 800 1000

Temperature, °C

Figure 1. Heat treatment 4h/1150°C/AC + 16h/1050-1065°C/AC + 16h/850°C/AC

98% confidence region calculated on 15 casts

Temperature, °F
200 400 600 800 1000 1200 1400 1600 1800
1600 80
100 220
200 Tensile Strength
80 180 1200 60
160
Elongation, %
Stress, MPa

140
60
120 800 40
Elongation
100
40
80
60 400 20
20 40
20
0 0
0 0
ton/in² 10³ lb/in² 0 200 400 600 800 1000
Temperature, °C

Figure 2. Heat treatment 4h/1150°C/AC + 16h/1050-1065°C/AC + 16h/850°C/AC

98% confidence region calculated on 15 casts

4
NIMONIC ® alloy 105

Tensile Properties: Extruded Bar Subsequently Forged


The data given in Table 8 and presented graphically in Figures 3 and 4 represent the tensile properties for extruded bar sub-
sequently forged after the 3-stage heat treatment.

Strain rate 0.005/min to proof stress (at room temperature), 0.002/min to proof stress (at elevated temperatures) and 0.1/min
thereafter.

Table 8 - Heat treatment 4 h/1150°C/AC + 16 h/1050-1065°C/AC + 16 h/850°C/AC

0.1% proof stress 0.2% proof stress Tensile strength


Elongation on 5.65 Reduction of area,
Temperature, °C MPa MPa MPa √ So, % %
20 796 827 1180 16 16
100 760 793 1185 21 24
200 745 774 1188 24 34
300 739 766 1162 20 24
400 732 763 1126 23 33
500 748 782 1148 23 31
600 735 769 1111 22 32
700 739 768 1075 26 33
800 680 714 836 24 34
900 390 411 491 28 38
1000 152 156 189 43 60
1100 28 31 56 132 99
Average results of tests on 15 casts.

Temperature, °F
200 400 600 800 1000 1200 1400 1600 1800
1600 80
100 220
200
80 180
Reduction of Area, %

1200 60
160
Stress, MPa

140 R. of A.
60
120 800 40
100
40
80
60
400 20
20 40 0.2% Proof Stress
20

0 0 0 0
ton/in² 10³ lb/in² 0 200 400 600 800 1000
Temperature, °C

Figure 3. Heat treatment 4h/1150°C/AC + 16h/1050-1065°C/AC + 16h/850°C/AC


98% confidence region calculated on 15 casts

5
NIMONIC ® alloy 105

Temperature, °F

200 400 600 800 1000 1200 1400 1600 1800


1600 80
100 220
200 Tensile Strength

80 180 1200 60
160

Elongation, %
Stress, MPa
140
60
120 800 40
Elongation
100
40
80
60 400 20
20 40
20
0 0
0 0
ton/in² 10³ lb/in² 0 200 400 600 800 1000
Temperature, °C

Figure 4. Heat treatment 4h/1150°C/AC + 16h/1050-1065°C/AC + 16h/850°C/AC


98% confidence region calculated on 15 casts

Tensile Properties: Extruded Section Subsequently Cold Rolled


The data given in Table 9 and presented graphically in Figures 5 and 6 represent the tensile properties for extruded section
subsequently cold rolled after the 3-stage heat treatment.

Strain rate 0.005/min to proof stress (at room temperature), 0.002/min to proof stress (at elevated temperatures) and 0.1/min
thereafter.

Table 9 - Heat treatment 4 h/1150°C/AC + 16 h/1050-1065°C/AC + 16 h/850°C/AC

0.1% proof stress 0.2% proof stress Tensile strength


Elongation on 5.55 Reduction of area,
Temperature, °C MPa MPa MPa √ So, % %
20 795 826 1246 25 29
100 780 811 1220 24 30
200 755 785 1234 26 31
300 744 772 1239 26 31
400 744 783 1226 27 31
500 752 785 1195 27 31
600 743 775 1177 25 31
700 744 778 1092 31 31
800 681 718 856 25 31
900 392 420 533 31 39
1000 168 176 221 48 61

Average results of tests on 15 casts.

6
NIMONIC ® alloy 105

Temperature, °F
200 400 600 800 1000 1200 1400 1600 1800
100 1600 80
220
200
80 180
60

Reduction of Area, %
1200
160 Stress, MPa
140
60
0.2% Proof Stress
120
800 40
100
40
80
60
400 20
20 40 R. of A.

20

0 0 0 0
ton/in² 10³ lb/in² 0 200 400 600 800 1000

Temperature, °C

Figure 5. Heat treatment 4h/1150°C/AC + 16h/1050-1065°C/AC + 16h/850°C/AC


98% confidence region calculated on 15 casts

Temperature, °F

200 400 600 800 1000 1200 1400 1600 1800


100 220 1600 80
200 Tensile Strength
80 180
1200 60
160
Elongation, %

140
Stress, MPa

60
120
800 40
100 Elongation
40
80
60
20 400 20
40
20

0 0 0 0
ton/in² 10³ lb/in²
0 200 400 600 800 1000

Temperature, °C

Figure 6. Heat treatment 4h/1150°C/AC + 16h/1050-1065°C/AC + 16h/850°C/AC


98% confidence region calculated on 15 casts

7
NIMONIC ® alloy 105

Tensile Properties: Extruded Bar Subsequently Cold Stretched


The data given in Table 10 and presented graphically in Figure 7 represent the tensile properties for extruded bar subsequently
cold stretched after the 2-stage heat treatment.

Strain rate 0.005/min to proof stress (at room temperature), 0.002/min to proof stress (at elevated temperatures) and 0.1/min
thereafter.

Table 10 - Heat treatment 4 h/1125°C/AC + 16 h/850°C/AC

0.1% proof stress 0.2% proof stress Tensile strength


Elongation on 5.55 Reduction of area,
Temperature, °C MPa MPa MPa √ So, % %
20 791 811 1220 25 35
100 749 777 1177 24 39
200 731 757 1186 27 34
300 732 752 1183 25 36
400 740 760 1143 28 35
500 740 771 1140 28 35
600 726 759 1106 26 35
700 723 752 1060 30 33
800 678 706 817 27 35
900 407 430 496 27 35
1000 155 161 210 46 59
Test on 1 cast.

Temperature, °F

200 400 600 800 1000 1200 1400 1600 1800


1600 80
100 220
Elongation and Reduction of Area, %

200
80 180 Tensile Strength
1200 60
160
Stress, MPa

140
60
120 800 0.2% Proof Stress 40
100
40 R. of A.
80
60 Elongation 20
400
20 40
20

0 0 0 0
ton/in² 10³ lb/in² 0 200 400 600 800 1000

Temperature, °C

Figure 7. Heat treatment 4h/1125°C/AC + 16h/850°C/AC

8
NIMONIC ® alloy 105

Creep Properties
The creep characteristics for NIMONIC alloy 105 have been determined for bar after the 3-stage heat treatment.
Creep-rupture properties for extruded bar subsequently forged are shown in Table 11 and Figures 8 and 9, by Larson-
Miller presentation and Graham and Walles technique.
Creep-rupture properties for extruded bar subsequently cold stretched are shown in Table 12 and Figures 10 and 11.
Derived total plastic strain data were created from test specimens 9.1 - 11.7 mm diameter x 76 mm gauge length (0.357 -
0.461 in diameter x 3 in gauge length) and are shown in Table 13.

Creep-Rupture Properties: Extruded Bar Subsequently Forged


The data given in Table 11 and presented graphically in Figures 8 and 9 represent the average results of 15 casts of extruded
bar subsequently forged.

Table 11 - Heat treatment 4 h/1150°C/AC + 16 h/1050-1065°C/AC + 16 h/850°C/AC

Stress to Elongation
Test produce at fracture
temperature rupture in
100 h 300 h 1000 h 3000 h 10 000 h 30 000 h 100 000 h on 5.65
°C
MPa MPa MPa MPa MPa MPa √ So, %
MPa
750 GW 456 394 340 270 (201) (154) (83)
12-18
LM 448 417 363 317 (263) (224) (178)
815 GW 324 278 232 178 (130) (77) (42)
8-21
LM 324 270 224 185 (144) (116) (85)
870 GW 208 178 131 99 (54) (31) (17)
7-17
LM 208 173 134 102 (77) (54) (39)
940 GW 108 82 (60) (36) (20) — —
10-21
LM 108 85 (62) (39) (25) — —
980 GW 68 51 31 (17) — — —
12-22
LM 68 51 32 (19) — — —
GW=Graham and Walles analysis. LM=Larson-Miller analysis. ( ) =Outside range of determination.

9
NIMONIC ® alloy 105

Creep-Rupture Properties: Extruded Bar Subsequently Forged


Figure 8 - Larson-Miller Parameter, T(20 + log t) x10-3; T in °K, t in hours; Heat treatment 4 h/1150°C/AC + 16 h/1050-1065°C/AC +
16 h/850°C/AC
5 10 15 20 25 30 35

MPa x 101
100
90
80
70
60
50
40

30
25
20

15

10
°F °C 9
8
7
20 6
100 5
200 100 4
300
3
400 200
2
500

600 300 1.5

700
400 1
800

900
500
1000

1100 600
1200

1300 700

1400
1500 800

1600
900
1700
1800 1000
1900
2000 1100
2100

2200 1200
10-1 100 101 102 103 104 105
2300

Time, hours

1MPa x 101 = 107 N/m2 ; 1 N/mm2 (1 MN/m2) = 0.1 hbar = 1.02 kgf/mm2 = 0.0647 tonf/in2
10
NIMONIC ® alloy 105

Creep-Rupture Properties: Extruded Bar Subsequently Forged

1000
140
60 900
130
55 120 800
50 110
700
45 100
40 90 600
35 80
750°C
500
70
30
65
28
60 815°C
26 400
24 55
22 50
20 45 300
870°C
18 40
16 35

14 30
200
28
12
26
24 940°C
10 22
9 20
Stress, MPa

8 18
16 980°C
7
14 100
6
90
12
5 80
10 70
4 9
60
8
7
3 50

6
2.5 40
5
2
4 30

1.5
3
20
ton/in² 10³ lb/in² 10 000
10 100 1000 100 000
Time, hours

Figure 9. Heat-treatment 4 h/1150°C/AC + 16h/1050-1065°C/AC + 16 h/850°C/AC


11
NIMONIC ® alloy 105

Creep-Rupture Properties: Extruded Bar Subsequently Cold Stretched


The data given in Table 12 and presented graphically in Figure 10 represent the creep-rupture properties of extruded bar sub-
sequently cold stretched.

Table 12 - Heat treatment 4 h/1125°C/AC + 16 h/850°C/AC

Stress to produce
rupture in Elongation at
Test temperature, 100h 300h 1000h fracture on 5.65 √
°C
MPa MPa MPa So, %

550 1050 1020 989 18-21


600 958 911 865 8-17
650 819 742 680 9-13
700 634 572 495 13-19

Test on 1 cast.

12
NIMONIC ® alloy 105

Creep-Rupture Properties: Extruded Bar Subsequently Cold Stretched

Figure 10 - Larson-Miller Parameter, T(20 + log t) x10-3; T in °K, t in hours.


Heat treatment 4 h/1125°C/AC +16 h/850°C/AC
5 10 15 20 25 30 35

MPa x 101
100
90
80
70
60
50
40

30
25
20
15

10
9
8
°F °C 7
6
100 20
5
200 100 4
300
3
400 200
500 2

600 300 1.5

700
400 1
800
900
500
1000
1100 600
1200
1300 700
1400
1500 800
1600
900
1700

1800
1000
1900
2000 1100
2100
2200 1200
10-1 100 101 102 103 104 105
2300
Time, hours

1MPa x 101 = 107 N/m2


1 N/mm2 (1 MN/m2) = 0.1 hbar = 1.02 kgf/mm2 = 0.0647 tonf/in2

13
NIMONIC ® alloy 105

Creep-Rupture Properties: Extruded Bar Subsequently Cold Stretched

10 000
Notched
}
Plain

650°C
700°C
550°C
600°C

1000

Life to rupture, hours

100
550°C

600°C

650°C

700°C

10
1400 1200 1000 800 600 400 200

Stress, MPa

Figure 11. Heat-treatment 4 h/1125°C/AC + 16 h/850°C/AC

14
NIMONIC ® alloy 105

Total Plastic Strain Data

This data has been determined on ‘as extruded bar’ and ‘extruded section’ subsequently cold worked.

Test Stress to give total plastic strain in


temperature Strain % 100 h 300 h 1000 h 3000 h 10 000 h 30 000 h
°C
MPa MPa MPa MPa MPa MPa
650 0.1 599 541 479 422 (358) —
0.2 625 568 510 456 394 —
0.5 667 602 539 486 428 (375)
rupture 772 703 618 549 471 410
750 0.1 314 275 233 196 (154) —
0.2 358 317 275 238 196 (159)
0.5 391 352 310 273 232 (195)
rupture 479 427 368 314 263 (209)
815 0.1 190 139 97 74 57 —
0.2 241 190 134 100 74 49
0.5 — 229 181 136 93 57
rupture 309 263 218 178 135 99
870 0.1 133 105 76 54 37 —
0.2 156 128 97 71 46 34
0.5 170 142 111 83 54 (37)
rupture 193 164 130 99 65 40
980 0.1 22 — — — — —
0.2 28 17 — — — —
0.5 36 26 15 — — —
rupture 60 43 31 22 12 —
( ) = Outside range of determination Tests on 3 casts.

15
NIMONIC ® alloy 105

Fatigue Properties: Extruded Section Subsequently Cold Rolled

Fatigue properties for extruded section subsequently cold Table 14 - Heat treatment 4 h/1150°C/AC + 4 h/1080°C/AC + 8
rolled given the heat treatment 4h/1150°C/AC + 4 h/850°C/AC
h/1080°C/AC + 8 h/850°C/AC are given in Table 14.
Stress for lives of
Gerber Diagrams Test tempera - Stress 50 h 500 h
ture form (3 x 107 cycles) (3 x 108 cycles)
Figures 12 to 17 illustrate the fatigue properties of °C MPa MPa
NIMONIC alloy 105 extruded section subsequently cold O±P 348 248
rolled (heat treatment 4 h/1150°C/AC + 4 h/1080°C/AC + 20 P ± 2P 155 116
8 h/850°C/AC) at 20°C, 400°C, 650°C, 750°C, 870°C and P±P 271 209
980°C respectively, under conditions of uniaxial stressing P ± ½P 433 356
with varying mean stress. The abscissae represent the P ± ¼P 618 556
mean stress and the ordinate fluctuating stress. Thus a O±P 232 232
point on the horizontal axis represents the steady stress 400 193
P±P 193
which will produce fracture in a specific time in a normal
P ± ½P 371 371
creep rupture test. A point on the vertical axis indicates the
P ± ¼P 618 618
fluctuating stress required to produce a pure fatigue failure
in the same time at the particular testing frequency adopt- P±O 1004 1004
ed. The lines radiating from the origin correspond to stress O±P 271 271
conditions of the form P ±CP where P is the steady stress 650 P±P 240 240
and C is a constant for any line. The full lines join points P ± ½P 417 417
corresponding to lines of 50 and 500 hours for varying P ± ¼P 711 688
stress conditions. P±O 834 688
O±P 263 248
750 P±P 232 209
P ± ½P 417 371
P ± ¼P 502 386
P±O 502 386
O±P 240 193
870 P±P 201 155
P ± ½P 240 155
P ± ¼P 240 155
P±O 240 155
O±P 170 124
980 P±P 84 46
P ± ½P 84 46
P ± ¼P 84 46
P±O 84 46

16
NIMONIC ® alloy 105

Fatigue Properties: Extruded Section Subsequently Cold Rolled

Mean tensile stress, ton/in²

0 10 20 30 40 50 60 70
800
50

Semi-range of alternating stress, ton/in²


700
Semi-range of alternating stress, MPa

50 h, 3 x 107 Cycles
600 500 h, 3 x 108 Cycles 40

500
30
2P
O±P

400
P

300 ½P 20

200 P±¼P
10
100

0 0
0 100 200 300 400 500 600 700 800 900 1000 1100 1200

Mean tensile stress, MPa

Figure 12. Fatigue properties at room temperature.


Heat treatment 4 h/1150°C/AC + 4 h/1080°C/AC + 8 h/850°C/AC

Mean tensile stress, ton/in²

0 10 20 30 40 50 60 70
800
50
Semi-range of alternating stress, ton/in²

700
Semi-range of alternating stress, MPa

50 h, 3 x 107 Cycles
600 500 h, 3 x 108 Cycles 40

500
30
O±P

400
P

300 ½P 20

200 P±¼P
10
100
P±O
0 0
0 100 200 300 400 500 600 700 800 900 1000 1100 1200

Mean tensile stress, MPa

Figure 13. Fatigue properties at 400°C.


Heat treatment 4 h/1150°C/AC + 4 h/1080°C/AC + 8 h/850°C/AC

17
NIMONIC ® alloy 105

Fatigue Properties: Extruded Section Subsequently Cold Rolled

Mean tensile stress, ton/in²


0 10 20 30 40 50 60
800
50

Semi-range of alternating stress, ton/in²


700
Semi-range of alternating stress, MPa

50 h, 3 x 107 Cycles
600 40
500 h, 3 x 108 Cycles

500
30
O±P

400 P

20
300 ½P

200 P±¼P
10

100
P±O
0 0
0 100 200 300 400 500 600 700 800 900 1000

Mean tensile stress, MPa

Figure 14. Fatigue properties at 650°C.


Heat treatment 4 h/1150°C/AC + 4 h/1080°C/AC + 8 h/850°C/AC

Mean tensile stress, ton/in²


0 10 20 30 40 50 60
800
50
Semi-range of alternating stress, ton/in²

700
Semi-range of alternating stress, MPa

50 h, 3 x 107 Cycles
600 40
500 h, 3 x 108 Cycles
500
30
O±P

400
P

20
300 ½P

200 P±¼P
10

100
P±O
0 0
0 100 200 300 400 500 600 700 800 900 1000

Mean tensile stress, MPa

Figure 15 . Fatigue properties at 750°C.


Heat treatment 4 h/1150°C/AC + 4 h/1080°C/AC + 8 h/850°C/AC

18
NIMONIC ® alloy 105

Fatigue Properties: Extruded Section Subsequently Cold Rolled

Mean tensile stress, ton/in²


0 2 4 6 8 10 12 14
250
Semi-range of alternating stress, MPa

14

200

Semi-range of alternating stress, ton/in²


12
O±P

P

10
150
7
50 h, 3 x 10 Cycles
8 8
500 h, 3 x 10 Cycles

100 ½P
P± 6

4
P±¼P
50

P±O
0 0
0 50 100 150 200 250

Mean tensile stress, MPa

Figure 16. Fatigue properties at 870°C.


Heat treatment 4 h/1150°C/AC + 4 h/1080°C/AC + 8 h/850°C/AC

Mean tensile stress, ton/in²


0 2 4 6 8 10 12 14
250
Semi-range of alternating stress, MPa

14
7
200 50 h, 3 x 10 Cycles
Semi-range of alternating stress, ton/in²
O±P

12
500 h, 3 x 108 Cycles

10
150

8
P

100
6

½P
P± 4
50
P±¼P 2

P±O
0 0
0 50 100 150 200 250
Mean tensile stress, MPa

Figure 17. Fatigue properties at 980°C.


Heat treatment 4 h/1150°C/AC + 4 h/1080°C/AC + 8 h/850°C/AC

19
NIMONIC ® alloy 105

Stress Relaxation Properties


Stress relaxation data is given for extruded bar given the two recommended heat treatments. It should be noted that only very
limited data has been established, and that Tables 15 and 16 only give a general guide to the level of these properties.

Stress Relaxation Properties: Extruded Bar Subsequently Hot Rolled

0.15% Initial Strain Table 15 - Heat treatment 4 h/1150°C/AC + 16 h/1050°C/AC + 16 h/850°C/AC

Test condition Time (h) to reach indicated residual stress Final Reading
Temp. Stress Time Stress
°C MPa 232 201 186 170 155 139 124 109 93 77 62 h MPa
600 274 10 000 — — — — — — — — — — 10 000 232
650 280 8000 — — — — — — — — — — 8613 231
700 277 14 000 4600 7400 10 500 — — — — — — — 13 427 161
750 269 17 160 310 600 1120 2100 4000 7200 — — — 16 546 99
800 243 — 3 9 20 40 74 130 250 450 810 1750 2014 60
850 223 — — — — — 10 21 38 70 140 290 698 33

Stress Relaxation Properties: Extruded Bar Subsequently Cold Stretched

0.30% Initial Strain Table 16 - Heat treatment 4 h/1125°C/AC + 16 h/850°C/AC

Test Condition Residual Stress at stated time in MPa Final reading

Temp. Stress Time Stress


°C MPa 100 h 300 h 1000 h 3000 h h MPa
650 539 525 501 445 382 3841 366
700 502 374 325 283 249 4104 238

20
NIMONIC ® alloy 105

Impact Data: Impact Data:


Extruded Bar Subsequently Forged Extruded Section Subsequently
Cold Rolled
The room temperature Charpy impact strength for The room temperature Charpy impact strength of
NIMONIC alloy 105 extruded bar subsequently forged NIMONIC alloy 105 extruded section subsequently cold
and given the recommended heat treatment of 4 rolled and given the recommended heat treatment of 4
h/1150°C/AC + 16 h/1050°C/AC + 16 h/850°C/AC is of h/1150°C/AC + 16 h/1050°C/AC + 16 h/850°C/AC is of
the order of 16 J. the order of 20 J.
Long-term embrittlement of this alloy has been inves- Long-term embrittlement of this alloy has been
tigated by Charpy impact testing at room and elevated investigated by Charpy impact testing at room and ele-
temperatures and the results of duplicate tests are given in vated temperatures and the results of duplicate tests are
Tables 17 and 18 respectively. given in Tables 19 and 20 respectively.
Charpy test specimen had square cross-section of 10 Charpy test specimen had square cross-section of 10
mm, test area of 80 mm² and V-notch angle of 45°. mm, test area of 80 mm² and V-notch angle of 45°.

Table 17 - Room Temperature Impact Values Table 19 - Room Temperature Impact Values
Soaking temperature, °C Soaking temperature, °C
Soaking Soaking
700 750 800 850 900 700 750 800 850 900
time, time,
h J J J J J h J J J J J
30 11 : 11 9:8 14 : 16 23 : 22 22 : 22 30 11 : 11 14 : 14 14 : 19 20 : 20 24 : 26
100 8 : 11 11 : 12 16 : 16 26 : 19 20 : 19 100 8:9 15 : 12 18 : 15 23 22 : 23
300 8:8 14 : 15 16 : 19 16 : 19 12 : 11 300 5:8 11 14 : 16 16 : 18 18 : 16
1000 9 : 11 12 : 14 15 : 14 16 : 14 8:9 1000 7:8 12 : 12 19 : 16 16 : 20 11 : 11
3000 8:5 14 : 15 14 : 15 14 : 12 8:8 3000 9:9 14 : 12 14 : 12 12 : 12 7 : 9
10 000 11 : 8 11 : 11 9 : 11 7:9 8:5 10 000 12 : 12 15 : 14 15 : 14 8:9 9 : 5

Table 18 - Elevated Temperature Impact Values Table 20 - Elevated Temperature Impact Values
Soaking and test temperature, °C Soaking and test temperature, °C
Soaking Soaking
700 750 800 850 900 700 750 800 850 900
time, time,
h J J J J J h J J J J J
0 24 : 30 23 : 22 23 : 22 23 : 24 27 : 27 0 33 : 30 22 : 22 22 : 19 23 : 22 28 : 30
30 16 : 19 19 : 19 19 : 23 23 : 23 24 : 26 30 16 : 19 14 : 14 19 : 26 23 : 24 28 : 27
100 18 : 9 15 : 19 23 : 23 22 : 24 23 : 26 100 20 : 18 12 : 15 24 : 26 24 : 24 30 : 30
300 8 : 11 19 : 20 23 : 20 24 : 23 22 : 26 300 16 : 16 18 : 20 26 : 26 24 : 24 28 : 26
1000 18 : 14 22 : 19 20 : 20 22 : 20 19 : 19 1000 16 : 15 22 : 24 30 : 27 23 : 23 22 : 24
3000 15 : 15 18 : 19 15 : 23 20 : 19 22 : 20 3000 18 : 18 22 : 24 24 : 24 19 : 19 22 : 20
10 000 14 : 16 20 : 20 18 : 19 16 : 15 27 : 22 10 000 20 : 20 23 : 24 23 : 22 15 : 16 18 : 18

21
NIMONIC ® alloy 105

Impact Data: Table 21 - Room Temperature Impact Values

Extruded Bar Subsequently Cold Soaking temperature, °C


Soaking
Stretched time,
500 550 600 650
h J J J J
The room temperature Charpy impact strength of 100 31 33 28 24
NIMONIC alloy 105 extruded bar subsequently cold 300 33 33 21 16
stretched and given the heat treatment of 4h/1125°C/AC 1000 24 27 17 8
+ 16h/850°C/AC is of the order of 36 J.
Long-term embrittlement of this alloy has been
investigated by Charpy impact testing at room and ele- Table 22 - Elevated Temperature Impact Values
vated temperatures and the results of single tests are
given in Tables 21 and 22 respectively. Soaking temperature, °C
Charpy test specimen had square cross-section of 10 Soaking 500 550 600 650
mm, test area of 80 mm² and V-notch angle of 45°. time,
h J J J J
0 48 43 47 47
100 45 47 44 41
300 45 48 37 28
1000 44 41 29 15

Corrosion Resistance
Oxidation in Air Cyclic Heating
(15 min in furnace, 5 min outside furnace)
Continuous Heating
Time to onset Rate of Weight change
Descaled weight loss (mg/cm²) after 100 hours at Temperature of spalling (h) spalling in 100 h
800°C 900°C 950°C 1000°C 1100°C °C at max cycle (mg/cm²/h) at (mg/cm²) at
temperature of max cycle max cycle
0.11 0.49 0.99 1.43 6.41
°C temperature of temperature of
°C °C
Intermittent Heating 890 >1000 — +0.66
(Cooling to room temperature every 24 hrs) 910 >1000 — +1.05
990 600 0.150 -51.9
Descaled weight loss (mg/cm²) after 100 hours at 1010 300 0.408 -229
800°C 900°C 950°C 1000°C 1100°C 1090 150 0.946 -748
— 1.19 1.59 1.61 13.3 1110 75 1.170 -955

Resistance to Atmospheres Containing SO2


Descaled weight loss (mg/cm²) after
1000 hours at
Atmosphere
600°C 700°C 800°C 1000°C
3% SO2-Argon 1.6 8.7 15.0 —
3% SO2-Air 2.3 1.1 0.6 0.6
3% SO2-5% O2-Argon 2.1 0.5 0.6 2.1

22
NIMONIC ® alloy 105

Fabrication Available Products and Specifications


Hot working NIMONIC alloy 105 is generally available in the following
forms, subject to minimum order quantities. Other forms are
NIMONIC alloy 105 may be hot worked in the temperature subject to enquiry.
range 1050-1200°C.
Bar and billet for forging
Annealing Rod and bar for machining
Extruded section, rectangular or profiled, for
Interstage annealing of NIMONIC alloy 105 should be car- machining, rolling and welding to rings, etc.
ried out at 1150°C followed by air cooling of fluidized bed Extruded and cold worked section
quenching. Water quenching is not recommended as severe
surface cracking may result from thermal shock. NIMONIC alloy 105 is designated W. Nr. 2.4634 and is avail-
able to the following specifications:
Machining
BS. HR3 billets, bars and forgings
NIMONIC alloy 105 should be in the fully heat-treated con- AICMA Ni-P61-HT billets, bars and forgings
dition for all machining operations. The high hardness Swedish Defence Material Administration MH.14 forged bar
range, 320-385 HV, necessitates the use of tungsten carbide DIN designation NiCo20Cr15MoAlTi forged bar
tipped tools. High speed steel shock-proof tools can be used AFNOR NCKD 20ATv
if the cut is of an intermittent nature. AECMA PrEn 2179-2181

Welding
Units of stress
Fusion welding of NIMONIC alloy 105 using conventional
processes such as T.I.G. or M.I.G. welding is not recom- The primary units for property data are those of the SI sys-
mended as microfissuring can occur both in the weld and tem. The unit of stress is the Megapascal. Its relationship
heat affected zones. Electron beam welding has been used with other units is as follows:
successfully but the danger of microfissuring still exists and
welding trials should always be carried out before the 1MPa = N/mm² = 1 MN/m² = 0.1 hbar = 0.102 kgf/mm² =
process is specified. 0.0647 tonf/in².
Similar difficulties can be expected with resistance spot,
stitch or seam welding. Flash-butt welding is, however, quite
satisfactory and in regular use for the production of turbine
rings.

High temperature brazing Publication SMC-081


Copyright © Special Metals Corporation, 2007 (Jan 07)
High temperature brazing in vacuum, dry hydrogen or inert
atmospheres is satisfactory for joining NIMONIC alloy NIMONIC is a trademark of the Special Metals Corporation
105. However, the brazing cycle chosen should not involve group of companies.
temperatures above the solution treatment temperature
(1150°C) as this could adversely affect the properties of the The data contained in this publication is for informational purposes only and may be
material. revised at any time without prior notice. The data is believed to be accurate and reli-
able, but Special Metals makes no representation or warranty of any kind (express or
implied) and assumes no liability with respect to the accuracy or completeness of the
information contained herein. Although the data is believed to be representative of the
product, the actual characteristics or performance of the product may vary from what is
shown in this publication. Nothing contained in this publication should be construed as
guaranteeing the product for a particular use or application.

23
www.specialmetals.com

U.S.A. India Affiliated Companies


Special Metals Corporation
Special Metals Services Ltd. Special Metals Welding
Billet, rod & bar, flat No. 60, First Main Road, Products
& tubular products First Block 1401 Burris Road
3200 Riverside Drive Vasantha Vallabha Nagar Newton, NC 28658, U.S.A.
Huntington, WV 25705-1771 Subramanyapura Post Phone +1 (828) 465-0352
Phone +1 (304) 526-5100 Bangalore 560 061 +1 (800) 624-3411
+1 (800) 334-4626 Phone +91 (0) 80 2666 9159 Fax +1 (828) 464-8993
Fax +1 (304) 526-5643 Fax +91 (0) 80 2666 8918
Canada House
Billet & bar products The Netherlands Bidavon Industrial Estate
4317 Middle Settlement Road Waterloo Road
New Hartford, NY 13413-5392 Special Metals Service BV Bidford-On-Avon
Phone +1 (315) 798-2900 Postbus 8681 Warwickshire B50 4JN, U.K.
+1 (800) 334-8351 3009 AR Rotterdam Phone +44 (0) 1789 491780
Fax +1 (315)798-2016 Phone +31 (0) 10 451 44 55 Fax +44 (0) 1789 491781
Fax +31 (0) 10 450 05 39
Shape Memory Alloys Controlled Products Group
4317 Middle Settlement Road China 590 Seaman Street, Stoney Creek
New Hartford, NY 13413-5392 Ontario L8E 4H1, Canada
Phone +1 (315) 798-2939 Special Metals Pacific Pte. Ltd. Phone +1 (905) 643-6555
Fax +1 (315) 798-6860 Room 1802, Plaza 66 Fax +1 (905) 643-6614
1266 West Nanjing Road
United Kingdom Shanghai 200040 A-1 Wire Tech, Inc.
Phone +86 21 3229 0011 A Special Metals Company
Special Metals Wiggin Ltd. Fax +86 21 6288 1811 4550 Kishwaukee Street
Holmer Road Rockford, IL 61109, U.S.A.
Hereford HR4 9SL Special Metals Pacific Pte. Ltd. Phone +1 (815) 226-0477
Phone +44 (0) 1432 382200 Room 1409 +1 (800) 426-6380
Fax +44 (0) 1432 264030 United International Building Fax +1 (815) 226-0537
No. 19 DongSanHuanNanLu
Special Metals Wire Products Chaoyang District Rescal SA
Holmer Road Beijing 100021, China A Special Metals Company
Hereford HR4 9SL Phone +86 10 8766 7100 200 Rue de la Couronne des Prés
Phone +44 (0) 1432 382556 Fax +86 10 8766 7101 78681 Epône Cédex, France
Fax +44 (0) 1432 352984 Phone +33 (0) 1 30 90 04 00
Special Metals Pacific Pte. Ltd. Fax +33 (0) 1 30 90 02 11
Room 16B, Yuntian Bldg.
Germany #12 Fengcheng Er Road DAIDO-SPECIAL METALS
Xi’an Economnic & Industrial Ltd.
Special Metals Deutschland Ltd. Development Zone A Joint Venture Company
Postfach 20 04 09 Xi’an 7100016 China Daido Shinagawa Building
40102 Düsseldorf Phone +86 29 8210 6151 6-35, Kohnan 1-chome
Phone +49 (0) 211 38 63 40 Fax +86 29 8652 4031 Minato-ku, Tokyo 108-0057, Japan
Fax +49 (0) 211 37 98 64 Phone +81 (0) 3 5495 7237
Singapore Fax +81 (0) 3 5495 1853
Hong Kong
Special Metals Pacific Pte. Ltd.
Special Metals Pacific Pte. Ltd. 24 Raffles Place
Unit A, 17th Floor, On Hing Bldg #27-04 Clifford Centre
1 On Hing Terrace Singapore 048621
Central, Hong Kong Phone +65 6532 3823
Phone +852 2439 9336 Fax +65 6532 3621
Fax +852 2530 4511

You might also like