UNICOOL R-404A

SAFETY DATA SHEET

SECTION 1 Identification of the substance/mixture and of the

company/undertaking

1.1 Product identifier

- Product Name: UNICOOL R-404A
- Product Part Number: 905623 (9.5 kg), 905606 (45 kg)
1.2 Relevant identified uses of the substance or mixture and uses advised against
- Use of the substance/mixture: Refrigerant
1.3 Details of the supplier of the safety data sheet
- Name of Supplier: Wilhelmsen Ships Service AS
- Address of Supplier: Willem Barentszstraat 50, 3165AB Rotterdam, The Netherlands
- Telephone: +31 4877 777 Fax: +31 4877 888
-
- Head office: Wilhelmsen Ships Service AS
- Strandveien 20, N1324 Lysaker
- Norway, Tel: (47) 6349 440 35
-
- Other suppliers SEE SECTION 16!!!
- For quotations contact your local Customer Services
-
- Responsible Person: Product HSE Manager,
- Email: Email: [email protected]
- Telephone: Tel.: +31 10 4877775
1.4 Emergency telephone number
- ****ONLY TO BE USED IN CASE OF AN INCIDENT****
-
- International 24hrs Emergency NCEC:+ 44 1865 407333
- American Chemistry Council 24hrs +1 703 527 3887
- American 24hrs Emergency CHEMTREC (800) 424 9300
- Greece: Poisoning emergency center, +30 210 7793777
- Norway: Poison information centre, +47 22591300
- Sweden: Poison information centre, +46 08 33 12 31
- China NRCC 24hrs emergency telephone number: +86-0532-8388 9090
- Wilhelmsen Ships Service, Melbourne, AUSTRALIA Emergency 24hrs: +61 3 9630 0998

SECTION 2 Hazards identification

2.1 Classification of the substance or mixture

- Dangerous Substances Directive (67/548/EEC). Classification, packaging and labelling of
dangerous substances
- Counsil Directive 1999/45/EEC Classification, packing and labelling of dangerous
preparations.
- Not Classified
-
- Regulations 1272/2008/EEC. Classification, labeling and packing of dangerous
substances and preparations
- Symbols: GHS04
- Signal Word: Warning
- Liq. Gas

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SECTION 2 Hazards identification (....)
- Contains gas under pressure; may explode if heated (H280).
-
2.2 Label elements

- Signal Word: Warning

-
- Contains:
- Pentafluoroethane
- 1,1,1,2-Tetrafluoroethane (R 134a)
- Trifluoroethane (R143a)
-
- Hazard phrases
Contains gas under pressure; may explode if heated (H280).
- Precautionary Phrases
Store in a well-ventilated place (P403).
2.3 Other hazards
- Not a PBT according to REACH Annex XIII
- Inhalation: In cases of severe exposure, dizziness, confusion, headache or stupor may
develop, In cases of severe exposure, anaesthesia may develop, Asphyxiant

SECTION 3 Composition/information on ingredients

3.1 Mixtures

- Pentafluoroethane
Concentration: 44%
CAS Number: 354-33-6
EC Number: 206-557-8
R/H Phrases: Not applicable
Symbols: Not applicable
Categories: Not applicable
- 1,1,1,2-Tetrafluoroethane (R 134a)
Concentration: 4%
CAS Number: 811-97-2
EC Number: 212-377-0
R/H Phrases: H280
Symbols: Not applicable
Categories: Liq. Gas
- Trifluoroethane (R143a)
Concentration: 52%
CAS Number: 420-46-2
EC Number: 206-996-5
R/H Phrases: R12 - H220, H280
Symbols: F+
Categories: Flam. Gas 1, Liq. Gas

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SECTION 4 First aid measures

4.1 Description of first aid measures

- In case of contact with liquid, thaw frosted parts with water. Do not attempt to remove
clothing which has stuck to the skin
- Burns must be treated by a physician.
- If substance has got into eyes, immediately wash out with plenty of water for several
minutes
- Never give anything by mouth to an unconscious person
- Apply artificial respiration only if patient is not breathing
- If breathing is difficult, oxygen should be given by a trained person
- If heartbeat is absent, give external cardiac compression
- Rescuers should take suitable precautions to avoid becoming casualties themselves
- Rescuers should put on approved respiratory protection before entering the area to
render first aid
4.2 Most important symptoms and effects, both acute and delayed
- In cases of severe exposure, dizziness, confusion, headache or stupor may develop
- In cases of severe exposure, anaesthesia may develop
- Aspiration hazard
- Possible frost-bite of affected areas
4.3 Indication of any immediate medical attention and special treatment needed
- No information available

SECTION 5 Fire-fighting measures

5.1 Extinguishing media

- Keep container(s) exposed to fire cool, by spraying with water
- Not flammable. In case of fire use extinguishing media appropriate to surrounding
conditions
5.2 Special hazards arising from the substance or mixture
- Inform Fire Brigade of potential danger of exploding and rocketing cylinders
- Pressurized container
- Hydrogen fluoride
- Carbon oxides may be formed
5.3 Advice for firefighters
- Wear chemical protection suit and positive-pressure breathing apparatus

SECTION 6 Accidental release measures

6.1 Personal precautions, protective equipment and emergency procedures

- Shut off source of leak if safe to do so
- In poorly ventilated areas or confined spaces, use an airline respirator or self-contained
breathing apparatus
6.2 Environmental Precautions
- Stop leak if safe to do so (P376).
- Do not allow to enter public sewers and watercourses
6.3 Methods and material for containment and cleaning up
- Shut off source of leak if safe to do so
- Allow product to evaporate
- Ventilate area
6.4 Reference to other sections
- See Section 13

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SECTION 7 Handling and storage

7.1 Precautions for safe handling

- Restricted to professional users
- Wear protective clothing as per section 8
- Ensure adequate ventilation
7.2 Conditions for safe storage, including any incompatibilities
- Keep in a cool, dry, well ventilated place
- Do not store above 45 °C
7.3 Specific end use(s)
- Contact supplier for further information

SECTION 8 Exposure controls/personal protection

8.1 Control parameters

- 1,1,1-Trifluoroethane (R-143a)
TLV (TWA) 1000 ppm
- Pentafluoroethane (R125)
TLV (TWA) 1000 ppm
- 1,1,1,2-Tetrafluoroethane
(R-134a)
TLV (TWA) 1000 ppm
8.2 Exposure controls
- The undiluted product must not be used in a confined space without good ventilation
8.3 Occupational exposure controls

- In poorly ventilated areas or confined spaces, use an airline respirator or self-contained

breathing apparatus
- Wear safety boots when handling cylinders.

SECTION 9 Physical and chemical properties

9.1 Information on basic physical and chemical properties

- Odour: Sweet ether-like odour
- Appearance: Liquefied pressure gas
- pH - not applicable
- Boiling point -46.6 °C to 760 °C
- Vapour pressure 690 kPa @ 25 °C
- Vapour density (air = 1) 3.42
- Melting point < -100 °C to 760 °C
- Insoluble in water
- Density 1060 kg/m3 at 20 °C
- Not flammable
- Unstable above 250 deg C
- Auto-ignition point >700 deg C at 760 mm Hg
9.2 Other information
- No information available

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SECTION 10 Stability and reactivity

10.1 Reactivity
- No hazardous reactions known if used for its intended purpose
10.2 Chemical stability
- Considered stable under normal conditions
10.3 Possibility of hazardous reactions
- No hazardous reactions known if used for its intended purpose
10.4 Conditions to avoid
- No special precautions are required for this product
10.5 Incompatible materials
- None
10.6 Hazardous Decomposition Products
- Hydrogen fluoride
- Carbon oxides may be formed

SECTION 11 Toxicological information

11.1 Information on toxicological effects

- No experimental data available
- Asphyxiant
11.2 Contact with eyes
- May cause frost-bite
11.3 Contact with skin
- May cause frost-bite
11.4 Ingestion
- Not regarded as a potential route of exposure.
11.5 Inhalation
- In cases of severe exposure, anaesthesia may develop
- May disturb the respiration, heart and nervous system

SECTION 12 Ecological information

12.1 Toxicity
- On available data, substance is not harmful to aquatic life
12.2 Persistence and degradability
- Volatile portion is significant
12.3 Bioaccumulation Potential
- Bioaccumulation of the components in this product is insignificant.
12.4 Mobility in soil
- This substance is volatile
- Insoluble in water
12.5 Results of PBT and vPvB assessment
12.6 Other Adverse Effects
- Gobal Warming Potential: 3260 (CO2 = 1; 100 years)
- Ozone Depletion Potential: 0
- GWP and ODP values according to IPCC/ASHRAE/ARI.
- IPCC = Intergovernmental Panel on Climate Control
- ASHRAE = American Society of Heating, Refrigeration and Air-Conditioning Engineers

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SECTION 12 Ecological information (....)
- ARI = American Refrigeration Institute

SECTION 13 Disposal considerations

13.1 Waste treatment methods

- Disposal should be in accordance with manufacturer's instructions
13.2 Classification
- Not applicable

SECTION 14 Transport information

14.1 UN
- UN No.: UN3337
- Proper Shipping Name: REFRIGERANT GAS R 404A
- Hazard Class: 2.2
- Packing Group: Not applicable
14.2 Environmental hazards
- Not applicable
14.3 Special precautions for user
- Gas cylinders must be equipped with valve protection caps during transport.
14.4 Transport in bulk according to Annex II of MARPOL 73/78 and the IBC code
- Not applicable
14.5 Road/Rail (ADR/RID)
- ADR UN No.: UN3337
- Proper Shipping Name: REFRIGERANT GAS R 404A
- ADR Hazard Class: 2.2
- ADR Packing Group: Not applicable
14.6 Sea (IMDG)
- IMDG UN No.: UN3337
- Proper Shipping Name: REFRIGERANT GAS R 404A
- IMDG Hazard Class: 2.2
- IMDG Pack Group.: Not applicable
- IMDG EmS: F-C, S-V
14.7 Air (ICAO/IATA)
- ICAO UN No.: UN3337
- Proper Shipping Name: REFRIGERANT GAS R 404A
- ICAO Hazard Class: 2.2
- ICAO Packing Group: Not applicable
14.8 DOT / CFR (US Department of Transportation)
- Identification Number: UN3337
- DOT Proper Shipping Name: REFRIGERANT GAS R 404A
- DOT Labels: 2.2
- Product RQ (lbs): Not applicable

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SECTION 15 Regulatory information

15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture
- Counsil Directive 1999/45/EEC Classification, packing and labelling of dangerous
preparations.
- Dangerous Substances Directive (67/548/EEC). Classification, packaging and labelling of
dangerous substances
- Regulations 1272/2008/EEC. Classification, labeling and packing of dangerous
substances and preparations
- This Safety Data Sheet is provided in compliance with the EC Directive 1907/2006-
453/2010
15.2 Chemical Safety Assessment
- None

SECTION 16 Other information

Text not given with phrase codes where they are used elsewhere in this safety data sheet:- H220:
Extremely flammable gas. H280: Contains gas under pressure; may explode if heated. R12:
Extremely Flammable.
The information provided about the product on this Safety Data Sheet has been compiled from
knowledge of the individual constituents
The data given here only applies when product used for proper application(s). The product is not
sold as suitable for other applications - usage in such may cause risks not mentioned in this sheet.
Do not use for other application(s) without seeking advice from manufacturer
The data given here is based on current knowledge and experience. This Safety Data Sheet
describes the product in terms of safety requirements and does not signify any warranty with
regard to the product's properties
The most up-to-date version of this MSDS can be found on www.wilhelmsen.com/shipsservice

OTHER CONTACT INFORMATION MAJOR CHEMICAL OFFICES

Wilhelmsen Ships Service Level 17, 636 St Kilda Road Melbourne Vic 3004 AUSTRALIA
Tel: +61 3 9630 0900 Emergency 24hrs: +61 3 9630 0998
Wilhelmsen Ships Service INC 210 Edgewater Street US-10305 Staten Island New York United
States Telephone daytime: (+1) 718 815 1310 Fax: (+1) 718 233 3268
Wilhelmsen Ships Service INC 2200 W. Pacific Coast Highway US-90810 Long Beach California,
United States Tel (+1) 562 624 8888 Fax (+1) 562 624 1011
Wilhelmsen Ships Service INC 701 Ashland Ave. Ashland Center Two, Bay 12 US- 19032 Folcroft
Pennsylvania United States Tel (+1) 610 586 7801 Fax (+1) 215 701 0646
Wilhelmsen Ships Service INC. 9400 New Century Drive US-77507 Pasadena Texas United States
Telephone daytime: (+1) 281 867 2000 Fax: (+1) 281 867 2800
Wilhelmsen Ships Service Ltd. Unit 3A NewtonsCourt Crossways DA2 6QL Dartford, Kent United
Kingdom Tel (+44) 1322 282 412 Fax (+44) 1322 284 774
Wilhelmsen Ships Service Ltda Rua Bispo Lacerda nos.61/67 Del Catilho BR 21051120 Rio de
Janeiro Brazil Tel (+55) 21 25 82 8000 Fax (+55) 21 25 82 8001
Wilhelmsen Ships Service (S) Pte Ltd 186 Pandan Loop Singapore 128376 Tel (+65) 6395 4545
Wilhelmsen Ships Service Co., Ltd 12-31 Torihama-cho Kanazawa-ku Yokohama-shi JP-236 0002,
Japan Tel (+81) 45 775 0012 Fax (+81) 45 775 0070
Wilhelmsen Ships Service Hellas SA 100, D. Moutsopoulou & Serifou str GR-185 41 Piraeus
Greece
Tel (+ 30) 210 4239100 Fax (+ 30) 210 4212480
Wilhelmsen Ships Service AS U.A.E . Fl 24 Executive Heights, Tecom C Sheikh Zayed Road (East)
Dubai United Arab Emirates Tel (+971) 4 382 3888
Wilhelmsen Ships Service AS, Willem Barentszstraat 50 3165 AB Rotterdam-Albrandswaard,
the Netherlands. Tel (+31) 10 4877 777

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