MIRACEMA-NUODEX

INDÚSTRIA QUÍMICA LTDA.

Material Safety Data Sheet

Product: LlOSEC® HC COBALT 6 % Page: 1 / 5

Product Code: 5.15.0023.0 Version: 1.01 Date: August 23, 2015

01 – IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND THE COMPANY/UNDERTAKING

PRODUCT NAME LIOSEC® HC COBALT 6 %

SUPPLIER MIRACEMA-NUODEX INDÚSTRIA QUÍMICA LTDA.
Av. Ricardo Bassoli Cezare, 15 – Jd. São José - CEP 13050-080
P.O. Box 719 - CEP 13001-970
Campinas, SP, Brazil
Telephone: (55-19) 3728 1000 / 3227 9189
Telefax: (55-19) 3227 3821 / 3227 9189

02 – COMPOSITION / INFORMATION ON INGREDIENTS

CHEMICAL CHARACTERIZATION Cobalt carboxylate solution with 6 % of cobalt.

Components which contribute to hazards:

Chemical Name CAS number EINECS Risk Phrases Concentration
White spirit 64742-88-7 265-191-7 R 10 / R 65 40 – 50 %

03 – HAZARDS IDENTIFICATION

MOST IMPORTANT HAZARDS Inflammability

ENVIRONMENTAL EFFECTS -
PHYSICAL AND CHEMICAL HAZARDS Thermal decomposition giving flammable and toxic products.
SPECIFIC HAZARDS / EEC Inflammable liquid – UN number 1993

04 – FIRST AID MEASURES

GENERAL ADVICE -

INHALATION Move to fresh air.

Oxygen or artificial respiration if needed.
Keep under medical surveillance.

SKIN CONTACT Wash immediately and abundantly with soap and water.

EYE CONTACT Wash immediately, abundantly and thoroughly with water.

In case of troubles, consult an ophthalmologist.

INGESTION In case of troubles, consult a doctor. Do not induce vomiting.

MIRACEMA-NUODEX
INDÚSTRIA QUÍMICA LTDA.

Material Safety Data Sheet

Product: LlOSEC® HC COBALT 6 % Page: 2 / 5

Product Code: 5.15.0023.0 Version: 1.01 Date: August 23, 2015

05 – FIRE-FIGHTING MEASURES

SUITABLE EXTINGUISHING MEDIA Foam.

Water spray.
Dry powder.
Carbon dioxide (CO2).

SPECIFIC HAZARDS Inflammable liquid. Flash point (c.c.) : 40 °C typical

Thermal decomposition giving carbon monoxide and
cobalt oxides.

SPECIFIC METHODS Cool containers / tanks with water spray.

SPECIAL PROTECTIVE EQUIPMENT

FOR FIREFIGHTERS Wear self-contained breathing apparatus and protective suit.

06 – ACCIDENTAL RELEASE MEASURES

PERSONAL PROTECTION Avoid contact with skin and eyes and inhalation of vapours.
Wear personal protective equipment.
In case of insufficient ventilation wear respiratory equipment.
Evacuate non-essential staff and those not equipped with
individual protection apparatus.

ENVIRONMENTAL PROTECTION Should not be released into the environment.

Do not let product enter into drains.
Contain by damming.

METHODS FOR CLEANING UP

Recovery Pump into an inert labeled emergency container.

Absorb the remainder with an inert absorbent material.

Disposal Destroy the product by incineration at an approved

waste disposal site only.
MIRACEMA-NUODEX
INDÚSTRIA QUÍMICA LTDA.

Material Safety Data Sheet

Product: LlOSEC® HC COBALT 6 % Page: 3 / 5

Product Code: 5.15.0023.0 Version: 1.01 Date: August 23, 2015

07 – HANDLING AND STORAGE

HANDLING

Technical measures/Precautions Storage and handling precautions applicable to products:

Provide for appropriate exhaust ventilation at machinery.
Provide showers, eye-baths.
Provide self-contained breathing apparatus nearby.
Well ventilate empty vats and tanks before entering.

STORAGE

Technical measures/Storage conditions Keep containers tightly closed in a cool, well-ventilated place.
Avoid temperatures above 40 ºC.

Incompatible products Strong oxidizing agents and strong acids.

PACKAGING MATERIALS

Recommended Iron drums.

Stainless steel.
Joints: Polyethylene, Rilsan Polyamide, Polytetrafluoroethylene (PTFE).

Not recommended Plastic drums.

08 – EXPOSURE CONTROLS / PERSONAL PROTECTION

PROTECTIVE PROVISIONS Provide sufficient air exchange and/or exhaust in work areas.

PERSONAL PROTECTION EQUIPMENT

Respiratory protection In case of insufficient ventilation wear suitable respiratory equipment.

Hand protection PVC or Rubber gloves.

Eye protection Safety glasses.

Skin and body protection Protective clothing.

Specific hygiene measures Avoid contact with skin and eyes and inhalation of vapours.
Remove and wash contaminated clothing before re-use.
MIRACEMA-NUODEX
INDÚSTRIA QUÍMICA LTDA.

Material Safety Data Sheet

Product: LlOSEC® HC COBALT 6 % Page: 4 / 5

Product Code: 5.15.0023.0 Version: 1.01 Date: August 23, 2015

09 – PHYSICAL AND CHEMICAL PROPERTIES

PHYSICAL STATE (20°C) Brilliant liquid

COLOUR Blue
ODOUR Characteristic
BOILING POINT/RANGE No data
MELTING POINT/RANGE No data
DECOMPOSITION TEMPERATURE > 100°C
FLASH POINT Closed cup: 40°C typical (Standard : ASTM D-93/90)
DENSITY (25°C) : 0,900 typical g/cm3 (Standard : ASTM D-1298/85)
SOLUBILITY
Solubility in water Insoluble (25°C)
Solubility in organic solvents Soluble (25ºC)
OTHER DATA Viscosity Gardner (25 °C) : A typical (Standard : ASTM D-1545/89)

10 – STABILITY AND REACTIVITY

CONDITIONS TO AVOID To avoid thermal decomposition, do not overheat.

MATERIALS TO AVOID Strong-oxidizing agents.

HAZARDOUS DECOMPOSITION PRODUCTS Thermal decomposition giving carbon monoxide and cobalt oxides.

FURTHER INFORMATION The product is stable at ambient temperature.

11 – TOXICOLOGICAL INFORMATION

ACUTE TOXICITY
Inhalation No data.
Ingestion No data.
Skin-contact No data.

LOCAL EFFECTS
Skin-contact Slightly irritant if in contact for a long period.
Eye-contact Slightly irritant.

SENSITIZATION
Skin-contact No data.

SPECIFIC EFFECTS No data.

MIRACEMA-NUODEX
INDÚSTRIA QUÍMICA LTDA.

Material Safety Data Sheet

Product: LlOSEC® HC COBALT 6 % Page: 5 / 5

Product Code: 5.15.0023.0 Version: 1.01 Date: August 23, 2015

12 – ECOLOGICAL INFORMATION
PERSISTENCE/DEGRADABILITY
In water No data
ECOTOXICITY No data
AQUATIC TOXICITY No data
ACUTE TOXICITY No data

13 – DISPOSAL CONSIDERATIONS
DISPOSAL OF PRODUCT Obey relevant local, state and federal laws. Do not contaminate any
lakes, streams, ponds or underground water supply.

14 – TRANSPORT INFORMATION
ADR/RID-GGVS/E Class: 3 Flammable Substances.
Kemler Number: 30
UN-Number: 1993
Packaging group: III
Label 3
Designation of goods: FLAMMABLE, LIQUID, N.O.S.
COBALT CARBOXYLATE SOLUTION.
IMDG/GGV/Sea Class: 3 Flammable Substances.
UN-Number: 1993
Label 3
Packaging group: III
EMS Number: F-E,S-E
Correct technical name: FLAMMABLE, LIQUID, N.O.S.
COBALT CARBOXYLATE SOLUTION.
ICAO/IATA Class: 3
UN/ID Number: 1993
Label 3
Packaging group: III; PI 309, Y309, 310
Correct technical name: FLAMMABLE, LIQUID, N.O.S.
COBALT CARBOXYLATE SOLUTION.

15 – REGULATORY INFORMATION
EEC DIRECTIVE No data EEC
CLASSIFICATION / LABELLING No data
HAZARDOUS SUBSTANCES White spirit
EEC No. (EINECS) 265-191-7
CLASSIFICATION / LABELLING No data
INVENTORIES No data

16 – OTHER INFORMATION
RISK PHRASES OF THE PRODUCT : 10 Flammable product.
LEGEND FOR TABLE IN ITEM 02 : R 10 Flammable product.
R 65 Harmful: May cause lung damage if swallowed.
SHELF LIFE : 24 months when kept in original packaging and under normal storage
conditions.

NOTE
The data given here is based on current knowledge and experience. The purpose of this Safety Data Sheet is to
describe the products in terms of their safety requirements. The data does not signify any warranty with regard to
the products' properties.