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    Organic Chemistry

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    Kishore Kishore
    The document provides reference books for chemistry for the TIFR GS exam, organized by subject area: physical chemistry, organic chemistry, and inorganic chemistry. It also includes detailed syllabi for the topics covered in each subject area.

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    Organic Chemistry

    Uploaded by

    Kishore Kishore
    103 views6 pages
    The document provides reference books for chemistry for the TIFR GS exam, organized by subject area: physical chemistry, organic chemistry, and inorganic chemistry. It also includes detailed syllabi for the topics covered in each subject area.

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    Chemistry

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    Organic chemistry

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    The document provides reference books for chemistry for the TIFR GS exam, organized by subject area: physical chemistry, organic chemistry, and inorganic chemistry. It also includes detailed syllabi for the topics covered in each subject area.

    Copyright:

    © All Rights Reserved
    Download as PDF, TXT or read online from Scribd
    Download as pdf or txt
    103 views6 pages

    Organic Chemistry

    Uploaded by

    Kishore Kishore
    The document provides reference books for chemistry for the TIFR GS exam, organized by subject area: physical chemistry, organic chemistry, and inorganic chemistry. It also includes detailed syllabi for the topics covered in each subject area.

    Copyright:

    © All Rights Reserved
    Download as PDF, TXT or read online from Scribd
    Download as pdf or txt
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    Reference Books for Chemistry TIFR GS Exam:

    1. PHYSICAL CHEMISTRY

    a. Basic Mathematical Concept

    Differential Equation & Matrices–Shanti Narayan


    Engineering Mathematics–B.S. Grewal

    b. Atomic Structure

    Physical Chemistry–Peter W. Atkins


    Physical Chemistry–Puri, Sharma, Pathania

    c. Theory of Gases

    Physical Chemistry–Peter W. Atkins


    Physical Chemistry–Puri, Sharma, Pathania

    d. Chemical Thermodynamics

    Physical Chemistry–Thomas Engel & Phillip Reid


    Basic Physical Chemistry–Peter W. Atkins

    e. Chemical and Phase Equilibria

    Principals of Chemical Equilibrium & Phase Rule –K.G. Denbigh


    Phase Rule –Gurdeep Raj

    f. Electrochemistry

    An Introduction to Electrochemistry–Samuel Glasstone


    Electrochemistry–Philip H. Rieger
    A text book of Physical Chemistry (Vol-III)- K. L. Kapoor

    g. Chemical Kinetics

    Chemical Kinetics – Keith J. Laidler


    Physical Chemistry– Thomas Engel & Phillip Reid
    A text book of Physical Chemistry (Vol-V)- K. L. Kapoor
    h. Solid State

    Solid State–Peter W. Atkins


    Solid Slate Physics – R.K. Puri & V.K.Babbar

    i. Adsorption

    Surface Chemistry –A. Goel


    Introduction to Surface Chemistry & Catalysis – Gabor A. Somorjai

    2. ORGANIC CHEMISTRY

    a. Basic Concepts in Organic Chemistry and Stereochemistry

    Stereochemistry Conformation and Mechanism-P.S. Kalsi


    Stereochemistry of Organic Compound - E. L. Eliel

    b. Aromaticity and Huckel’s rule

    Organic Chemistry (Vol-I) - I. L. Finar

    c. Organic reaction Mechanism and synthetic applications

    Organic Chemistry-Clayden, Greeves, Warner and Wothers


    Organic Chemistry- T.W. Graham Solomons
    Organic Chemistry -Morrison & Boyd

    d. Natural Products Chemistry

    Organic Chemistry (Vol-II) - I. L. Finar

    e. Heterocyclic Chemistry

    Organic Chemistry (Vol-I) - I. L. Finar

    f. Qualitative organic Analysis

    Qualitative Organic Analysis - A. I. Vogel


    3. INORGANIC CHEMISTRY

    a. Periodic Table

    Concise Inorganic Chemistry - J. D. Lee


    Basic Inorganic Chemistry -F. A. Cotton & Wilkinson

    b. Chemical Bonding and Shapes of compounds

    Inorganic Chemistry - J. E. Huheey


    Inorganic Chemistry - Meissler & Tarr

    c. Main Group Elements (s and p blocks)

    Concise Inorganic Chemistry - J. D. Lee

    d. Transition Metal (d block)

    Concise Inorganic Chemistry - J. D. Lee


    Inorganic Chemistry -Meissler & Tarr

    e. Analytical Chemistry

    Quantitative Inorganic Analysis - A. I. Vogel

    f. Bioinorganic Chemistry

    Inorganic Chemistry – Shriver & Atkins


    Inorganic Chemistry – James E. Huheey, E.A. Keiter, R. L. Keiter, O. K. Medhi

    g. Instrumental Method of Analysis

    Instrumental method - Skoog, Holler & Crouch


    Detailed Syllabus for Chemistry:

    1. Physical Chemistry:

    a. Basic Mathematical Concepts: Functions, maxima and minima, integrals, ordinary differential
    equations, vectors and matrices, determinants, elementary statistics and probability theory.
    b. Atomic and Molecular Structure: Fundamental particles, Bohr’s theory of hydrogen-like
    atom; wave- particle duality; Uncertainty principle; Schrödinger’s wave equation; Quantum
    numbers, shapes of orbitals; Hund’s rule and Pauli’s exclusion principle, electronic
    configuration of simple homonuclear diatomic molecules.
    c. Theory of Gases: Equation of state of ideal and non-ideal (van der Waals) gases, Kinetic theory
    of gases. Maxwell-Boltzmann distribution law; equipartition of energy.
    d. Solid state: Crystals, crystal systems, X-rays, NaCl and KCl structures, close packing, atomic
    and ionic radii, radius ratio rules, lattice energy, Born-Haber cycle, isomorphism, heat capacity
    of solids.
    e. Chemical Thermodynamics: Reversible and irreversible processes; First law and its
    application to ideal and nonideal gases; Thermochemistry; Second law; Entropy and free
    energy, Criteria for spontaneity.
    f. Chemical and Phase Equilibria: Law of mass action; Kp, Kc, Kx and Kn; Effect of temperature
    on K; Ionic equilibria in solutions; pH and buffer solutions; Hydrolysis; Solubility product;
    Phase equilibria– Phase rule and its application to one-component and two-component
    systems; Colligative properties.
    g. Electrochemistry: Conductance and its applications; Transport number; Galvanic cells; EMF
    and Free energy; Concentration cells with and without transport; Polarography;
    Concentration cells with and without transport; Debey-Huckel-Onsagar theory of strong
    electrolytes.
    h. Chemical Kinetics: Reactions of various order, Arrhenius equation, Collision theory; Theory of
    absolute reaction rate; Chain reactions – Normal and branched chain reactions; Enzyme
    kinetics; photochemical processes; Catalysis.
    i. Adsorption: Gibbs adsorption equation, adsorption isotherm, types of adsorption, surface
    area of adsorbents, surface films on liquids.
    2. Organic Chemistry:

    a. Basic Concepts in Organic Chemistry and Stereochemistry: Electronic effect (resonance,


    inductive, hyperconjugation) and steric effects and its applications (acid/base property).
    Optical isomerism in compounds without any stereocenters (allenes, biphenyls),
    conformation of acyclic systems (substituted ethane/n-propane/n-butane) and cyclic systems
    (mono and di substituted cyclohexanes).
    b. Organic Reaction Mechanism and Synthetic Applications: Chemistry reactive intermediates,
    carbine, nitrene, benzyne, Hofmann-Curtius-Lossen rearrangement, Wolf rearrangement,
    Simmons-Smith reaction, Reimer-Tiemann reaction, Michael reaction, Darzens reaction,
    Witting reaction, McMurry reaction. Pinacol-pinacolone, Favorskii, benzilic acid
    rearrangement, dienonc-phenol rearrangement, Bayer-Villeger reaction. Oxidation and
    reduction reactions in organic chemistry. Organometallic reagents in organic synthesis
    (Grignard and organocopper). Diels-Alder reaction, Sigmatropic reactions.
    c. Qualitative Organic Analysis: Functional group interconversions, structural problems using
    chemical reactions, identification of functional groups by chemical tests, elementary 1H NMR
    and IR spectroscopy as a tool for structural elucidation.
    d. Natural Products Chemistry: Introductory chemistry of alkaloids, terpenes, carbohydrates,
    amino acids, peptides and nucleic acids. Heterocyclic Chemistry: Monocyclic compounds with
    one hetero atom.

    3. Inorganic Chemistry:

    a. Periodic Table: Periodic classification of elements and periodicity in properties; general


    methods of isolation and purification of elements.
    b. Chemical Bonding and Shapes of Compounds: Types of bonding; VSEPR theory and shapes of
    molecules; hybridization; dipole moment; ionic solids; structure of NaCl, CsCl, diamond and
    graphite; lattice energy.
    c. Main Group Elements (s and p blocks): Chemistry with emphasis on group relationship and
    gradation in properties; structure of electron deficient compounds of main group elements
    and application of main group elements.
    d. Transition Metals (d block): Characteristics of 3d elements; oxide, hydroxide and salts of first
    row metals; coordination complexes; VB and Crystal Field theoretical approaches for
    structure, color and magnetic properties of metal complexes. Organometallic compounds,
    metal carnonyls, nitrosyls and metallocenes, ligands with back bonding capabilities; MO
    theory approaches to explain bonding in metal- carbonyl, metal-nitrosyl and metalphosphine
    complexes.
    e. Bioinorganic Chemistry: Essentials and trace elements of life, basic reactions in the biological
    systems and the role of metal ions especially Fe2+, Fe3+, Cu2+ and Zn2+, function of
    hemoglobin and myoglobin.
    f. Instrumental Methods of Analysis: Basic principles, instrumentations and simple applications
    of conductometry, potentiometry, UV-vis spectrophotometry, analysis of water, air and soil
    samples.
    g. Analytical Chemistry: Principles of qualitative and quantitative analysis; acid-base, oxidation-
    reduction and EDTA and precipitation reactions; use of indicators; use of organic reagents in
    inorganic analysis; radioactivity; nuclear reactions; applications of isotopes.

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