Chemistry Project ON CHECKING HARDNESS OF WATER

SESSION: 2019-2020
SUBMITTED TO CBSE
CHEMISTRY PROJECT
TOPIC:
TESTING HARDNESS, PRESENCE OF IRON,

FLUORIDE & CHLORIDE IN DRINKING WATER
Under the Supervision of - Submitted By -

MRS. MANISHA SHARMA SHIWANG SHARMA
CONTENTS:
CERTIFICATE
ACKNOWLEDGEMENT
OBJECTIVE
INTRODUCTION
THEORY
APPARATUS
DETERMINING HARDNESS OF
WATER
PROCEDURE
TEST FOR IRON
TEST FOR CHLORIDE
TEST FOR FLUORIDE
RESULT
BIBLIOGRAPHY
ACKNOWLEDGEMENT
It gives me a great pleasure to acknowledge my
humble & sincere indebtedness to our Principal
MR.WILLIAM D’SOUZA for providing us excellent
facilities & encouragement despite of his multiple
responsibilities.
I wish to place one record my sense for respect &
gratitude to Mrs. MANISHA SHARMA for her keen
interest and tireless efforts at all stages of this
undertaking.
I owe this achievement to my respected parents & my
friends for their appreciation and help I received
during the course of my endeavors while working in
the project.
OBJECTIVE:
To determine the hardness, presence of iron,

fluoride & chloride depending upon the regional
variation in drinking water and study of causes of
presence of these ions.
INTRODUCTION:
Hardness of water is determined by concentration of
multivalent cations present in water.Hard water
contains Ca2+ , Mg2+ ions.Hardness of water can be
removed by adding sodium carbonate to hard
water.Sometimes salts are dangerous for human
health. Therefore, it is necessary to detect presence of
these ions and remove them to stay on safer side.
TYPES OF HARDNESS IN WATER:

1) Temporary hardness
2) Permanent hardness
TEMPORARY HARDNESS:
Temporary hardness is due to the presence of
bicarbonates of calcium and magnesium. It can be
easilyremoved by boiling.
PERMANENT HARDNESS:
Permanent hardness is due to the presence of chlorides
and sulphates of calcium and magnesium.This type of
hardness cannot be removed by boiling.
SALTS PRESENT IN WATER :

Sulphate in groundwater is caused by natural
deposits of magnesium sulphate, calcium sulphate
or sodium sulphate. Concentrations should be below
250 ppm. Higher concentrations are undesirable
because of their laxative effects.
Iron as it exists in natural groundwater is in the

soluble (ferrous) state but, when exposed to oxygen,
is converted into the insoluble (ferric) state with its
characteristic reddish brown or rusty color.
Chlorides in groundwater can be naturally occurring
in deep aquifers or caused by pollution from sea
water, brine, or industrial or domestic wastes.
Chloride concentration above 250 mg/l can produce
a distinct taste in drinking water.
Fluorinated water contains fluoride at a level that is
effective for preventing cavities; this can occur
naturally or by adding fluoride.
THEORY:
Hard water: Water with very high mineralcontent is
called hard water. Hard water iswhen water percolates
through deposits ofchalk and limestone. We know that
limestoneand chalk are made up of calcium and
magnesium carbonates.
Indicator of hardness in water:

Hardness in waterindicates an inability to form
lather with soapsolution. The effect of various
dissolved salts,containing several different cations
and anions, onthe formation on lather, is
investigated. Followingexample of hard water
containing calcium andmagnesium ions, shows
formation of insolubleprecipitate.
 2 C17H35COO− Na++ Ca2+ → (C17H35COO)2Ca + 2 Na+
 2 C17H35COO− Na++ Mg2+→(C17H35COO)2Mg + 2Na+

APPARATUS:
Test tubes
Pipette
Beakers
Stop watch
Corks
Test tube stand
CHEMICALS REQUIRED:
Soap solution
Calcium chloride solution
Sodium sulphate
Distilled water
Iron(II)sulphate solution
Sodium chloride
Potassium nitrate
Magnesium sulphate
DETERMINING HARDNESS OF WATER :
Take eight test tubes and label them as
1,2,3,4,5,6 and 7
Put about 10 drops of the following in
different test tubes:
Test tube 1-distilled or deionized water

Test tube 2-calcium chloride solution
Test tube 3-sodium sulphate solution
Test tube 4-Iron(II) sulphate solution
Test tube 5-Sodium chloride solution
Test tube 6-potassium nitrate solution
Test tube 7-magnesium sulphate
Take out 50 mL of soap solution in a

small beaker.
Pipette out about 5 mL soap solution in
each test tube.
Close the mouth of each test tube with
cork and shake it vigorously.
Note which tube contains a foamy
lather and which do not.
With the help of stopwatch measure

the time taken for disappearance of foam in
each test tube.
Time taken for

Test Lather formed
Solution disappearance
tubes or not
of foam
1 Distilled water Yes 35s
2 Calcium chloride No
-
3 Sodium sulphate Yes 28s
4 Sodium chloride Yes 31s
5 Potassium Yes 29s

nitrate
6 Magnesium No
sulphate
-
7 Iron(II) sulphate Yes 32s
PROCEDURE:
A. TESTING IRON IN WATER:

Take 5 mL water in a test tube. Add twodrops of
Dilute H2SO4..
Boil the contents and allow it to cool.
Now, add 2-3 drops of Potassium ferrocyanide.
OBSERVATION:
Appearance of blue ppt indicates the presence
of iron in water.
H2SO4 + H2O → H3O+ + HSO4
4FeCl3 + 3K4 [Fe(CN)6 ] → Fe4 [Fe(CN)6 ] 3 + 12KCl

B. TESTING CHLORIDE IN WATER:
Take 5 mL water in a test tube. Add 2drops

of concentrated HNO3 in it.
Boil the contents of the test tube and
allow it to cool.
Now, add 2-3 drops of AgNO3 solution toit.
OBSERVATION:
Appearance of curdy precipitate indicates the

presence of chloride in water.
HNO3(aq)+ H2O→ H+ (aq)+ NO3-(aq)
Ag + 2HNO3 → AgNO3 + NO2 + H2O

C.TESTING FLUORIDE IN WATER:
Take 5 mL water in a test tube.
Add water, silver nitrate and dilute nitric acid
to it.
OBSERVATION:
No precipitate indicates presence of fluoride

ion in water.
RESULT:
Presence of salt contents in different

source of water is detected experimentally.
The water sample contain iron, fluoride and
chloride in it.
BIBLIOGRAPHY:
ENVIRONMENTAL JOURNAL ON OXICOLOGY.

PUBLICATION BY DEPARTMENT OF PUBLIC
HEALTH.
HANDBOOK OF GROUND WATER
DEVELOPED BYROSCO MOSS.
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SESSION: 2019-2020

TESTING HARDNESS, PRESENCE OF IRON,

Under the Supervision of - Submitted By -

humble & sincere indebtedness to our Principal

MR.WILLIAM D’SOUZA for providing us excellent

facilities & encouragement despite of his multiple

I wish to place one record my sense for respect &

gratitude to Mrs. MANISHA SHARMA for her keen

interest and tireless efforts at all stages of this

I owe this achievement to my respected parents & my

friends for their appreciation and help I received

during the course of my endeavors while working in

To determine the hardness, presence of iron,

TYPES OF HARDNESS IN WATER:

SALTS PRESENT IN WATER :

Iron as it exists in natural groundwater is in the

Indicator of hardness in water:

 2 C17H35COO− Na++ Ca2+ → (C17H35COO)2Ca + 2 Na+

 2 C17H35COO− Na++ Mg2+→(C17H35COO)2Mg + 2Na+

Test tube 1-distilled or deionized water

Take out 50 mL of soap solution in a

With the help of stopwatch measure

Time taken for

4 Sodium chloride Yes 31s

5 Potassium Yes 29s

A. TESTING IRON IN WATER:

H2SO4 + H2O → H3O+ + HSO4

4FeCl3 + 3K4 [Fe(CN)6 ] → Fe4 [Fe(CN)6 ] 3 + 12KCl

Take 5 mL water in a test tube. Add 2drops

Appearance of curdy precipitate indicates the

HNO3(aq)+ H2O→ H+ (aq)+ NO3-(aq)

Ag + 2HNO3 → AgNO3 + NO2 + H2O

No precipitate indicates presence of fluoride

Presence of salt contents in different

ENVIRONMENTAL JOURNAL ON OXICOLOGY.

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