Fiitjee: Internal Test

IIT2019, RIT-1-CPM-1
FIITJEE INTERNAL TEST

RANK IMPROVEMENT TEST – I
Batches: All 719 batches
IIT- JEE 2019
QP CODE: 111515
Time: 3 hours Maximum Marks: 210
 Please read the instructions carefully. You are allotted 5 minutes specially for this purpose.
 You are not allowed to leave the examination hall before end of the test.
 Use Blue/Black Ball Point Pen only for writing particulars on Side–1 and Side–2 of the
Answer Sheet. Use to Pencil is strictly prohibited.
Instructions
Note:
1. The question paper contains 3 sections (Sec-1, Chemistry, Sec-II, Physics & Sec-III, Mathematics.)
2. Each section is divided into three parts, PART-A, PART-B and PART-C.
3. Rough spaces are provided for rough work inside the question paper. No additional sheets will be provided
for rough work.
4. Blank Papers, clip boards, log tables, slide rule, calculator, cellular phones, pagers and electronic devices, in
any form, are not allowed.
Filling of OMR Sheet
1. Ensure matching of OMR sheet with the Question paper before you start marking your answers on OMR
sheet.
2. On the OMR sheet, darken the appropriate bubble with Blue/Black Ball Point Pen for each character of
your Enrolment No. and write in ink your Name, Test Centre and other details at the designated places.
3. OMR sheet contains alphabets, numerals & special characters for marking answers.
Marking Scheme For All Three Parts.

1. PART – A (01 – 05) contains 5 Multiple Choice Questions which have Only One Correct answer. Each
question carries +3 marks for correct answer and –1 mark for wrong answer.
2. PART – A (06 – 13) contains 8 Multiple Choice Questions which have One or More Correct answer.
For each question in the group Q. 6 – 13 of PART – A you will be awarded
Full Marks: +4 If only the bubble(s) corresponding to all the correct options(s) is (are) darkened.
Partial Marks: +1 For darkening a bubble corresponding to each correct option, provided NO incorrect
option is darkened.
Zero Marks: 0 If none of the bubbles is darkened.
Negative Marks: 2 In all other cases.
For example, if (A), (C) and (D) are all the correct options for a question, darkening all these three will result
in +4 marks; darkening only (A) and (D) will result in +2 marks; and darkening (A) and (B) will result in 2
marks, as a wrong option is also darkened.
3. PART – B contains 2 Matrix Match Type Questions which have statements given in 2 columns. Statements
in the first column have to be matched with statements in the second column. There may be One or More
Than One Correct choices. Each question carries +4 marks for all correct answer however for each correct
row +1 marks will be awarded. No negative marks will be awarded in this section.
4. PART-C (01 – 05) contains 5 Numerical Based questions with Single Digit Integer as answer, ranging from 0
to 9 and each question carries +3 marks for correct answer. No negative marks will be awarded in this
section.
Name of the Candidate :
Enrolment Number :
FIITJEE Ltd., Punjabi Bagh Centre, 31, 32, 33 Central Market, West Avenue Road, Punjabi Bagh, New Delhi – 110026, Ph: 011 - 45634000
Section – I (Chemistry)
PART – A
(Single Correct Choice Type)
This section contains 5 multiple choice questions. Each question has four choices (A), (B), (C) and (D) out of which only
ONE option is be correct.
1. The second ionization energy of which atom can be determined by applying Bohr’s theory?
(A) He (B) Li
(C) Be (D) B
2. If chlorine is assumed to undergo hybridization in HCl, how many hybrid orbitals should it contain?
(A) 1 (B) 2
(C) 3 (D) 4
3. The incorrect statement regarding BeCl2 is

(A) In solid state, it exists as a one dimensional polymer
(B) In gas state, it exists as a monomer as well as dimmer
(C) In gas state one atom of Be can form a maximum of four covalent bonds.
(D) The monomer is a linear molecule
4. Which of the following can be used in washing powder as a brightener?

(A) NaOH (B) H2O2
(C) D2O (D) Na2S
 %s 
5. In which of the following covalent bond, the ratio of s-orbital to p-orbital character i.e.   has the
 %p 
lowest value?
(A) C-H bond in CH3Cl (B) C-F bond in CH3F
(C) C-H bond in CH3F (D) C-Cl bond in CH3Cl
(Multiple Correct Choice Type)

This section contains 8 multiple choice questions. Each question has four choices (A), (B), (C) and (D) out of which
ONE OR MORE may be correct.
6. Which of the following statement(s) is/are correct for the third orbit of hydrogen atom?
(A) It contains nine degenerate atomic orbitals
(B) No electron transition takes place between the s-orbital of third orbit and the s-orbital of the
second orbit
0
(C) The radius of this orbit is  9  0.529  A
1.5h
(D) The angular momentum of the electron in this orbit is

space for rough work
7. Which of the following species has non-zero spin value?

(A) O (B) O2

(C) O 2 (D) O 2
NaH 
H2 O
  A   B  

Cl2
Cold
  C   D   H2O
8.
Choose correct statement(s) regarding the unknown compounds A, B, C and D.
(A) (B) is produced when Cu reacts with HCl
(B) The difference between the molar masses of (C) and (D) is 16 g
(C) The decahydrate of (A) is called washing soda
(D) (B) is a component of water gas
9. Which of the following substance(s) can be oxidised by H2O2?

(A) KI (B) KNO2
(C) Na2CO3 (D) CaSO4
10. No change in colour of acidified KMnO4 solution takes place when ordinary dihydrogen gas is passed
through it. But addition of ‘Zn’ metal brings decolourization because
(A) Zn forms nascent hydrogen in the solution (B) Zn is reduced
(C) Zn is oxidized (D) Zn produce H2O2 in the solution
11. Which of the following compound(s) is/are more soluble than CaSO 4 in water?
(A) BeSO4 (B) MgSO4
(C) SrSO4 (D) BaSO4
12. Which of the following wave function(s) do/does not represent any atomic orbitals?
(A) 4,0,0 (B) 3,1,2
(C) 4,1,0 (D) 2,0,1
13. The correct statement(s) regarding the most thermally stable structure of SNF 3 is/are
(A) ‘S’ and ‘N’ are joined through multiple bonds
(B) The F  S  F angle is less than 109.5o
(C) All the three atoms N, S and F contain non-bonded electrons in their outermost orbits
(D) All the S-F bonds are identical having the same bond length
PART – B
(Matrix Match Type)
1. Match the ions mentioned in column-I with the overlapping pattern of some of their atomic orbitals and
other properties mentioned in column-II.
Column – I Column – II
(A) SO24 (P)
(B) PO34 (Q)
(C) CO32 (R)
(D) BO33 (S) Bond order is greater than 1.2
(T) Planar structure
2. Match the pair of compounds mentioned in column-I with their distinction tests mentioned in column-II.
(A) Li3N and KCl (P) Heating
(B) NaNO3 and LiNO3 (Q) Passing of chlorine gas through aqueous
solution
(C) NaOH and Mg(NO3)2 (R) Reaction with water
(D) Ca(NO3)2 and Li2CO3 (S) Passing CO2 through aqueous solution
(T) Reaction with dil.HCl
PART – C
This section contains 5 Numerical Based questions. The answer to each question is a single digit integer, ranging from 0
to 9 (both inclusive)
1. The atomic number of phosphorus is 15. How many maximum number of electrons of phosphorus
1
can have s   ,where ‘s’ is spin quantum number.
2
2. NH3, N(SiH3)3, N(C6H5)3, BF3, XeF4, SF4, O(CH3)2, XeO3, SF6

How many of the above molecule(s) has/have planar shape?
X  s   H2O 
 KOH  aq   Y  aq   Z  g 
PbSO 4 
PbS

MgCO3  s  
CO2
 R  s  
Mg

3.
If two moles of X(s) reacts with one mole of sulphur(S), compound ‘M’ is formed. If the oxidation
number of sulphur in compound ‘M’ is +x, the value of ‘x’ is
4. How many spectral lines(fine lines) is/are formed if electron transition takes place from third orbit to
second orbit in H– ions?
5. The set of quantum numbers of an atomic orbital is (4, 1, -1, +1/2). What is the sum of the numbers of
radial nodes and angular nodes associated with the orbital.
Section – II (Physics)
PART – A
1. The magnitude of a vector ' a ' is constant, but its direction is not constant then
da da
(A) and a are in same direction (B) is opposite to a
dt dt
da
(C) is perpendicular to a (D) none of these
dt
2. Velocity versus displacement curve of a particle moving in v(m/s)

straight line is shown in the figure. From a point P, a line is
drawn perpendicular to displacement axis and line PR is drawn P
normal to the curve at P. The magnitude of tangential
acceleration of the particle at point P is
Q R s(m)
(A) 1 m/s2
(2, 0) (3, 0)
(B) 2 m/s2
(C) 3 m/s2
(D) 2.5 m/s2
3. An insect crawls with constant speed ‘u’ along the radial spoke of a
wheel which is rotating with angular speed  in clockwise direction as y
shown in figure. Initially the insect was at the centre of the wheel and the
spoke on which the insect was crawling was along x-axis. If at an instant j
the position vector with respect to centre of wheel and velocity of the
insect are r and v respectively then
(A) v    r O 
x
i
(B) v  r  
(C) r  v  
(D) none of these
4. A particle is projected with speed u at an angle  (< 60°) with the horizontal. The time taken by it, so
that its velocity makes an angle 60° with the initial velocity.
3 u 1 3 u 1
(A) (B)
2 g sin(   60o ) 2 g sin(   30o )
3 u 1 3 u 1
(C) (D)
2 g sin(   30o ) 2 g sin(  60o )
v
5. A block is dragged on smooth curved plane with the help of a
rope which moves with a speed v as shown in figure. The speed
of block at this instant will be
V 
(A)
sin(  )
V
(B)
cos(   )
V
(C)
sin(  ) 
(D) none of the above
6. A man who can swim at a speed v relative to the water wants to cross a river of width d, flowing with a
speed u. The point opposite him across the river is P.
d
(A) The minimum time in which he can cross the river is .
v
d
(B) He can reach the point P in time .
v
d
(C) He can reach the point P in time
v  u2
2
(D) He cannot reach P if u > v.
7. A body is projected with velocity u at an angle of projection  with the horizontal. The body makes 30°
with the horizontal at t = 2 second and then after 1 second it reaches the maximum height. Then
(A) u  20 3 m/s (B)  = 60°
(C)  = 45° (D) u  20 / 3 m/s
8. A particle of mass m moved on the x-axis as follows: it starts from rest t = 0 from the point
x = 0, and comes to rest at t = 1 at the point x = 1. No other information is available about its motion
at intermediate times (0 < t < 1). If  denotes the instantaneous acceleration of the particle, then
(A)  cannot remain positive for all t in the interval 0  t  1
(B)  cannot exceed 2 at any point in its path
(C)  must be  4 at some point or points in its path
(D)  must change sign during the motion, but no other assertion can be made with the information
given
9. A particle is projected from origin with velocity

 
u  ˆj  2kˆ m/s. Horizontal surface lies in X – Y plane, Z  kˆ 
then (take g = 10 m/sec2)
2 Y  ˆj 
(A) Time of flight = sec
5
2
(B) horizontal range = m
5 0  
X î
1
(C) Maximum height m
10
1
(D) Maximum height = m
5
10. If r1  2iˆ  Jˆ & r2  î  2jˆ  3kˆ and angle between r1 & r2 is , then which of the following is correct?
(A)  = 0° (B)  = 90°
(C) r1  r2  0 (D) r1  r2  70
x t3
11. A particle moves along positive branch of the curve, y  , where x  , x and y are measured in
2 3
metres and t in seconds, then
1 1ˆ ˆ
(A) The velocity of particle at t  1s is î  ˆj ij
(B) The velocity of particle at t =1s is
2 2
(C) The acceleration of particle at t =1s is 2iˆ  ˆj (D) The acceleration of particle at t = 2 s is î  2ˆj
12. Two particles projected from the same point with same speed u at angles of projection  and  strike
the horizontal ground at the same point. If h1 and h2 are the maximum heights attained by the
projectiles, R is the range for both and t1 and t2 are their time of flights, respectively, then:

(A)     (B) R  4 h1h2
2
t1
(C)  tan  (D) tan   4 h1 / h2
t2
13. Let ar and at represent radial and tangential accelerations. The motion of a particle may be circular if:
(A) ar = at = 0 (B) ar = 0 and at  0
(C) ar  0 and at = 0 (D) ar  0 and at  0
PART – B
(Matrix Match Type)
1. Column-I indicates the type of motion and column-II indicates the different parameters of motion.
Match them for which change of parameters during the motion.
Column-I Column-II
(A) Projectile motion (neglect the air (P) speed
resistance)
(B) Projectile motion (consider the air (Q) velocity
resistance)
(C) Uniform circular motion (R) magnitude of acceleration
(D) Non-uniform circular motion (S) direction of acceleration
(T) Acceleration
m m
a3 a2
3 2
2. Three identical rings of mass m are placed 30 0
600
on a T shaped smooth rod as shown in
T2
figure. Ring (1) & (3) is joined through string T1
& ring (1) & (2) joined through string (take g
= 10 m/s2) then match the following
1 m g
a1
(A) Magnitude of acceleration of ring – (P) 3g
(1) a1
13
(B) Magnitude of acceleration of ring – (Q) g
(2) a2 3
13
(C) Magnitude of acceleration of ring – (R) 4 3
(3) a3 g
13
(D) Magnitude of acceleration of ring – (2) (S) g
w.r.t. ring (3) 3 3
13
PART – C
1. The resultant of two vectors A and B is perpendicular to the vector A and its magnitude is equal to half

the magnitude of vector B. The angle between A and B is x . Then the value of ‘x’ is
6
2. Two ports A and B are separated by a river of width D. Water in B
the river flows with speed VW. A boat crosses the river form port A
to port B. The speed of the boat relative to water is VB. Given
 Vw
VW  3 VB . if at angle  = ( in radian) with AB in which the D
n 
boat should start relative to water so that it moves along A, then 30
0
find the value of n A
3. A 2m wide truck is moving with a uniform speed v0 = 8 m/s along a

straight horizontal road. A pedestrian starts to cross the road with a
uniform speed v when the truck is 4 m away from him. The
minimum value of velocity so that he can cross the road safely is v 2m Truck v0 v
5 man
then the value of v is 4m
2
V0
0
4. In the given figure, the angle of inclination of the inclined 90
plane is 300. Find the horizontal velocity V0 (in m/s) so that H
the particle hits the inclined plane perpendicularly. Given,
H = 4m, g = 10 m/s2
0
30
V(m/s)
20
5. Referring to v –s diagram, find magnitude of acceleration of

the particle when its velocity becomes half of the initial velocity
s(m)
O 50
Section – III (Mathematics)

PART – A
1. If f  x   x  tan x and g  x  is the inverse of f  x  then g’(x) is equal to

1 1
(A) (B)
1 g x  x 2  g  x  x
2 2
1
(C) (D) none of these
2  g x  x
2
 
2.  
Let f  x   g f  x   f  x 
4 
, where f(x) and g(x) are real valued functions. For all possible values


of x.f g  x   
 x  1
(A) tan   (B) tan  x  1  tan  x  1
 x  1
f x  1 x/4
(C) (D)
f x  1 x/4
3. Range of f  x   log3 10  5  2sin x  cos x   5 is 

(A) 0,1 (B) 0,3
 1
(C)  , (D) none of these
 3 
x
4. If f : 0,    0,   and f  x   , then f is
1 x
(A) one – one and onto (B) one – one but not onto
(C) onto but not one – one (D) neither one – one nor onto
5 Let f :R  0,   be defined as f  x   log  

9x 2  12x    1 be an onto function, where x is a
real parameter belong to (0, 10). Find the greatest possible value of  .
(A) 4 (B) 5
(C) 6 (D) 7

6. If logkx  logk5  log5x k  1, k > 0, then x is equal to

1
(A) k (B)
5
(C) 5 (D) none the these
x 1
7. If 1   then x satisfies
1 x 2
 1 1
(A)  1,1 (B)   , 
 2 2
(C) (2, 3) (D)  1,5
 x2 
8. Let f :  10, 10   R where f  x   sin x    be an odd function. Then values which a can
 a 
take place is/are,  .  is G.I.F.
(A) 50 (B) 100
(C) 150 (D) 200
9. Which of the following pairs of function are not identical?

sin x cos x
(A) f  x    ;g  x   sin 2x
1  tan x 2
1  cot 2 x
(B) f  x   tan x cot x;g  x   sin x cosec x
sec x  cos ec x
(C) f  x   cos x  sin x ; g  x  
sec x cos ec x
2 tan x
(D) f  x   tan2x; g  x  
1  tan2 x
10. f graph of function f  x  which is defined in  1, 4 is shown in the adjacent figure then identify the
correct statement(s)
y
f (x)
1
–1
O x
0 1 2 4
–1

(A) domain of f x  1 is  5, 5   
(B) range of f x  1 is  0, 2
(C) range of f  x   is 1, 0 (D) domain of f x   is  3, 3

11.      
Consider, f  x   x  log2  2  x    x  log2 2  x 2   ......  x  log2  2  x10   . Identify
 
the correct statement(s).
(A)  f  e    7
(B) f     20  60
(C) the number of solution of the equation f  x   x is 9.
(D) the number of solutions of the equation f  x   x is 10.
[Note : {y} and [y] denotes the fractional part function and greatest integer function respectively.]
12. Let f be the greatest integer function and g be the modulus functions, then
 5
(A)  gof  fog    1 (B)  f  2g 1  1
 3
5
(C)  gof  fog    0 (D)  f  2g1  1
3
   
13. f  x   cos2 x  cos2   x   cos x cos   x  is
3  3 
(A) an odd function (B) an even function
(C) a periodic function (D) f  0   f 1
PART – B
(Matrix Match Type)
1. Match the following

Column-I Column-II
(A)   (P) one to one function
Function f : 0,   0,1 defined by f  x   sin x is
 3
(B) x3 (Q) many – one function
Function f : 1,    1,   defined by f  x   is
x 1
(C)   4  (R) into function
Function f :   ,    1, 1 defined by f  x   sin x is
 2 3 
(D) x2 (S) onto function
Function f :  2,    8,   defined by f  x   is
x2
2. Match the following

(A) 1 1 1 (P) 1
1log 10 x 1log 10 y a  b log 10 z
If y  10 , z  10 implies x  10 then a  b =
(B) log a N  log b N (Q) 2
If b  ac , a  0, c  0, b  1 and  k  log ca then k =
log b N  log c N
(C) 8x 2  3 (R) 1
lim
x  4x 2  x 2
(D) 1x  x (S) 100
2
0 x  1 dx
(T) 1
100
PART – C
sin1  sin x 
1. If domain of f  x   is  a,b    c,   , then find the value of a  b  3c .
 2x  1 
 log x  4  log2  

 2 
  3x 
2. If f  x  is a polynomial function satisfying f  x  f  y   f  x   f  y   f  xy   2 for all real x and y and

f  3   10, then f (4) is equal to p, where p – 9 is
 
3. The number of values of x satisfying the equaiton logx2  6x 8 log x 2  2x  0 is
 2x 2
 2x  3
( x  2)2013 ( x  4)2015 ( x  3)2014

4. Number of integers satisfying the inequality  0 is ___
( x  6)( x  1)2012 ( x  5)2017
3  3  3x  5 px  q
5. Let g :R     R    be defined as g  x   . If g2014  x   , where
2 2 2x  3 rx  s
 
g2014  x   g g  g ...   x  , then find the value of p  q  r  s  .
2014 times

Fiitjee: Internal Test

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IIT2019, RIT-1-CPM-1

FIITJEE INTERNAL TEST

Marking Scheme For All Three Parts.

Name of the Candidate :

3. The incorrect statement regarding BeCl2 is

4. Which of the following can be used in washing powder as a brightener?

(Multiple Correct Choice Type)

7. Which of the following species has non-zero spin value?

9. Which of the following substance(s) can be oxidised by H2O2?

(B) PO34 (Q)

(C) CO32 (R)

(D) BO33 (S) Bond order is greater than 1.2

(T) Planar structure

(T) Reaction with dil.HCl

space for rough work

2. NH3, N(SiH3)3, N(C6H5)3, BF3, XeF4, SF4, O(CH3)2, XeO3, SF6

2. Velocity versus displacement curve of a particle moving in v(m/s)

space for rough work

(D) He cannot reach P if u > v.

9. A particle is projected from origin with velocity

2. Two ports A and B are separated by a river of width D. Water in B

find the value of n A

3. A 2m wide truck is moving with a uniform speed v0 = 8 m/s along a

5. Referring to v –s diagram, find magnitude of acceleration of

space for rough work

Section – III (Mathematics)

1. If f  x   x  tan x and g  x  is the inverse of f  x  then g’(x) is equal to

3. Range of f  x   log3 10  5  2sin x  cos x   5 is 

5 Let f :R  0,   be defined as f  x   log  

(Multiple Correct Choice Type)

6. If logkx  logk5  log5x k  1, k > 0, then x is equal to

9. Which of the following pairs of function are not identical?

(C) range of f  x   is 1, 0 (D) domain of f x   is  3, 3

space for rough work

1. Match the following

2. Match the following

space for rough work

2. If f  x  is a polynomial function satisfying f  x  f  y   f  x   f  y   f  xy   2 for all real x and y and

( x  2)2013 ( x  4)2015 ( x  3)2014

space for rough work

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