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    Raoult's Law States That The Partial Pressure of A Component in A Vapor Phase

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    Raoult's Law states that the partial pressure of a vapor component is directly proportional to its mole fraction in the liquid phase. It was formulated by François-Marie Raoult in 1882 and takes into account ion dissociation. Henry's Law applies to dilute solutions and states the partial pressure is proportional to concentration. Unlike Raoult's Law, Henry's constant depends on both temperature and solvent. Dalton's Law from 1801 relates partial gas pressures to mole fractions for ideal gas mixtures. Modified Raoult's Law accounts for non-ideal behavior and more complex phase equilibrium calculations.

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    Raoult's Law States That The Partial Pressure of A Component in A Vapor Phase

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    niezajanepatna
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    Raoult's Law states that the partial pressure of a vapor component is directly proportional to its mole fraction in the liquid phase. It was formulated by François-Marie Raoult in 1882 and takes into account ion dissociation. Henry's Law applies to dilute solutions and states the partial pressure is proportional to concentration. Unlike Raoult's Law, Henry's constant depends on both temperature and solvent. Dalton's Law from 1801 relates partial gas pressures to mole fractions for ideal gas mixtures. Modified Raoult's Law accounts for non-ideal behavior and more complex phase equilibrium calculations.

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    Phase equilibrium

    Original Title

    Phase equilibrium

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    Raoult's Law states that the partial pressure of a vapor component is directly proportional to its mole fraction in the liquid phase. It was formulated by François-Marie Raoult in 1882 and takes into account ion dissociation. Henry's Law applies to dilute solutions and states the partial pressure is proportional to concentration. Unlike Raoult's Law, Henry's constant depends on both temperature and solvent. Dalton's Law from 1801 relates partial gas pressures to mole fractions for ideal gas mixtures. Modified Raoult's Law accounts for non-ideal behavior and more complex phase equilibrium calculations.

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    115 views2 pages

    Raoult's Law States That The Partial Pressure of A Component in A Vapor Phase

    Uploaded by

    niezajanepatna
    Raoult's Law states that the partial pressure of a vapor component is directly proportional to its mole fraction in the liquid phase. It was formulated by François-Marie Raoult in 1882 and takes into account ion dissociation. Henry's Law applies to dilute solutions and states the partial pressure is proportional to concentration. Unlike Raoult's Law, Henry's constant depends on both temperature and solvent. Dalton's Law from 1801 relates partial gas pressures to mole fractions for ideal gas mixtures. Modified Raoult's Law accounts for non-ideal behavior and more complex phase equilibrium calculations.

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    Nieza Jane Patna ChE 4206a

    BS ChE-5 July 10,2019

    Raoult's Law states that the partial pressure of a component in a vapor phase
    that is in equilibrium with a liquid is directly proportional to the mole fraction of
    the component in the liquid phase. This also takes into account things like ion
    dissociation in a solution [Van't Hoff factor]. It was formulated by a French
    chemist, François-Marie Raoult in the year 1882.

    Henry's Law, is especially useful for dilute solutions, and states that at very low
    concentrations, the partial pressure of the dilute component over a liquid
    mixture is proportional to the concentration. This law is very similar to Raoult's
    Law, except that the proportionality constant is not the pure-component vapor
    pressure but is empirically determined from VLE data. Like the pure-component
    vapor pressure, the Henry's constant is dependent on temperature and the
    nature of component A. Unlike the pure-component vapor pressure, it also
    depends on the solvent, so when utilizing tables of Henry's constants, make sure
    that the solvents match.

    The Dalton’s Law was formulated by an English chemist, John Dalton in the year
    1801 for gas mixtures. It relates the partial pressure of an individual component
    of the mixture to the total pressure of the mixture to its mole fraction. It is
    applicable only to the non – reacting, ideal gas mixtures.

    Modified Raoult’s Law deviates from solution ideality. It is function of T and liquid
    composition and based on experiments. As a result, bubble point and dew point
    calculations are more complex. It means: A boiling liquid of this composition
    produces a vapor of exactly the same composition as the liquid; therefore does
    not change in composition as it evaporate.

    REFERENCES:
    https://www.kau.edu.sa/Files/0002494/files/18921_handouts10.pdf

    https://en.wikibooks.org/wiki/Introduction_to_Chemical_Engineering_Processes/
    Vapor-Liquid_equilibrium

    https://nptel.ac.in/courses/112101004/downloads/(21-5-4)%20NPTEL%20-
    %20Gas%20Separation.pdf
    . Raoult’s Law has two major assumptions: The vapor phase is an ideal gas and
    The liquid phase is an ideal solution. It means that Raoult’s law can apply only
    for low to moderate pressures. Raoult’s law can apply only when the species
    that comprise the system are chemically similar

    Henry's Law constants are generally very small, and are most useful when the
    concentration is less than 10%. Henry’s law has important applications. For
    example, bubbles of CO2CO2 form as soon. Henry’s law: The partial pressure of
    the species in the vapor phase is directly proportional to its liquid phase mole
    fraction.

    NO SEPERATION of such a constant-boiling solution is possible by distillation. -


    Negative departure from linearity ≡ Stronger liquid phase intermolecular
    attractions between unlike than between like pairs of molecules. - Positive
    departure from linearity ≡ Stronger liquid phase intermolecular attractions
    between like than between unlike pairs of molecules

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