IUPAC 1

IUPAC
LDA-1

Theory Question
A. Convert given structure into bondline

1.

2.

3.

4.

5.

6.

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B. Convert given structure into normal dash structure

1.

2.

3.

4.

5.

6.

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IUPAC 3

C. Convert given structure into condensed structure

1.

2.

3.

4.

5.

0 0 0 0 0 0 0
D. Find the number of 1 , 2 3 and 4 carbon along with 1 , 2 , 3 H

1.

2. (CH3 ) 3 C CH2 CH (C 2H5 ) C (CH3 ) (C 2H5 ) CH(CH3 ) 2

3. CH3 CH (CH3 ) (CH2 ) 2 C (C 2H5 ) 2 CH3
4. (C 2H5 ) 4 C
5.

6.

7.

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4 IUPAC

LDA-2

A. Draw the structure of given compound in Bondline and

condensed structure
1. Isohexane
2. Neohexane
3. Neononane
4. Isooctane (b)

B. Draw the structure of following alkyl group.

1. tert-butyl
2. sec-pentyl
(c)
3. isopentyl
CH3  CH  CH2  CH3
4. neohexyl (d) |
5. isobutyl
3. Which of the following alkanes contains primary,
6. tert-pentyl
secondary, tertiary and quaternary carbon atoms
7. neo-heptyl
together?
C. Identify alkyl group – (a)  CH3  3 CH
(b)  C 2H5  3 CH
1.
(c)  CH3  3 CCH2CH  CH3  2
(d)  CH3  4 C
4. The minimum number of carbon atoms necessary for an
2.
alkane to form a branched structure is _____.
(a) 4 (b) 6
(c) 3 (d) 9
5. In isoalkanes, one of the carbon atom is attached to
_____ other carbon atom(s).
(a) One (b) Two
3. (c) Three (d) Four
6. The alkanes in which there are two single carbon
branches on the second carbon atom of the parent
chain are
4. called _____ alkanes.
(a) iso (b) neo
(c) clsoed (d) ring
7. ______ carbon atom us the one which is directly
attached to two other carbon atoms
D. MCQ’s From Tatva (a) Secondary (b) Tertiary
1. The number of tertiary carbon atoms in the compound (c) Primary (d) Quaternary
(CH3)2CHCH2C(CH3)3 is ______. 8. The number of primary, secondary, tertiary and
(a) 2 (b) 3 quaternary carbon atoms in the following alkanes are
(c) 1 (d) 4 respectively.
2. The structure of isobutyl group in an organic compound
is _______.
(a) CH3  CH2  CH2  CH2 

(a) 5, 2, 1 and 1 (b) 3, 3, 2 and 0

(c) 6, 1, 0 and 0 (d) 6, 1, 2 and 1

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IUPAC 5

LDA-3

Theory Question
A. Give IUPAC name of the following compound.

1. 3. Consider the following alkane and answer the

questions.
(CH3)2 CH CH2 CH (C2H5) CH (CH3) CH3

1. Write the complete structural formula of the

2. alkane.
2. What is its molecular formula?
3. Write its bond line formula and IUPAC name.
4. How many ethyl and isopropyl groups are
present in this alkane?
3. 5.
0 0 0
How many carbon atoms are 1 , 2 , 3 and 4 ?
0

D. Following are wrongly named. Write their correct IUPAC

names.

4. 1. 2-Ethylbutance
2. 4-Methyl pentane
3. 3, 5-Dimethylhexane
4. 5-Ethyl-4-Methyl heptane
5. 2, 3- Dimethyl-3-ethyl pentane
6. 1-Methyl pentane.
5.
Master key MCQ’s
1. A student named an alkane as 2-ethyl propane. The
correct IUPAC name of the alkane is
6.  CH3  3 C CH2 CH  CH3  2 (a) 2-Methylbutane
7.  C 2H5  2 CH CH2 C  CH3  3 (b) 2, 2-dimethylbutane
(c) 2, 3-dimethylbutane
(d) 2, 3-dimethylpentane
8.

B. Draw the structure of the following compound

1. 2, 2-Dimethyl butane
2. 3-Ethyl-2-5-dimethyl hexane
3. 4-Ethyl-3,5-dimethyl heptane (a) 2, 3-Diethyl-2, 3-dimethylbutane
4. 2, 2, 4- Trimethyl pentane (b) 2-Ethyl-2, 3, 3-trimethylpentane
5. 3, 3 - Diethyl pentane (c) 3, 3, 4, 4-Tetramethylhexane
(d) 2, 2, 3, 3-Tetramethylhexane
C. Master key Theory
1. Write the complete structural formula, condensed
structural formula and bond line formula of iso octane.
2. Write the condensed structural formual and
complete structural formula of following
alkane. Give its IUPAC name.

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6 IUPAC

3. Which of the following skeletal formulae represents

2-Methylpentane? 6. The given compound is _______.
(a)

(b)

(a) 3, 4, 4, 5-Tetramethylheptane
(b) 4,4,5-Trimethylheptane
(c) (c) 3,3,4,5-Tetramethylheptane
(d) 3,4,5-Trimethylheptane
7. Name the compound given below:

(d)

(a) 2,3-Diethylheptane
4. The IUPAC name of neohexane is _____. (b) 3-Methyl-4-ethyloctane
(a) 2-Methylpentane (c) 5-Ethyl-6-methylocatane
(b) 2,3-Dimethylhexane (d) 4-Ethyl-3-methylocatane
(c) 2,2-Dimethylbutane 8. Which one of the following contain isopropyl group?
(d) 2,3-Dimethlbutane (a) 2,2,3,3-Tetramethylpentane
5. The IUPAC name of following compound is _____. (b) 2-Methylpentane
(c) 2,2,3-Trimethylpentane
(d) 3,3-Dimethylpentane

(a) 2, 2, 4, 4-Tetramethylhexane
(b) 2, 4-Tetramethylhexane
(c) 2, 2, 4-Tetramethylhexane
(d) 4,4-Tetramethylhexane

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IUPAC 7

LDA-4

Theory Question
A. Give IUPAC name of following alkyl group.

1.

2.

3.

4.

5.

6.

B. Draw the structure of following alkyl group.

1. 1, 1-Dimethylbutyl
2. 1-Methylpropyl
3. 2-Ethylbutyl
4. 3,3-Dimethylbutyl

C. Write the structure of following alkane.

1. 5-(2-Ethylbutyl)-3,3-dimethyl decane
2. 5-Sec-Butyl- 4 – isopropyl decane
3. 4-tert-Butyl-3-methyl heptane
4. 5-(1,2-Dimethyl propyl) -2- methyl nonane

MCQ’s From Target

1. Which of the following is pent-1-ene?
(a) CH3 (CH2 ) 4 CH  CH2
(b) CH3 (CH2 )3 CH  CH2
(c) CH3 (CH2 )2 CH  CH2
(d) CH3CH2CH  CH2
2. Write the IUPAC name of the following compound.

(a) 5,6-Dimethylhepta-1,4,6-triene
(b) 5,6-Trimethylhepta-1,4,6-triene
(c) 3,4-Dimethylocta-1,3,6-triene
(d) 2,4-Dimethylhepta-1,3,6-triene
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IUPAC 9

3. Which of the following is 5-Methylhex-2-ene? (a) 3-Ethyl-4-methylpent-2-yne

(b) 3-Ethyl-4-methylpent-1-yne
(c) 2-Methyl-3-ethylpent-4-yne
(d) 3-Ethyl-4-methylpent-1-yne
8. The IUPAC name of isopropyl acetylene is ______.
(a) 3-Methylbut-1-yne (b) 2-Methylbut-1-yne
(c) But-1-yne (d) 3-Methylpent-1-yne
9. Write the IUPAC name of following compound.

(a) Oct-4-ene-2,6-diyne
(b) Hept-4-ene-2,6-diyne
(c) Hepta-2,6-diene-4-yne
(d) Octa-2,6-diene-4-yne
10. IUPAC name of the compound

4. Write IUPAC name of the following compound

(a) 3,4-Dimethylhex-2-en-5-yne
(a) 4-Ethyl-3-methylocta-2,4,7-triene (b) 3,4-Dimethylhex-4-en-1-yne
(b) 4-Ethyl-3-methylocta-2,4,8-triene (c) 3,4-Dimethylhex-2-en-5-diyne
(c) 5-Ethyl-6-methylocta-1,4,6-triene (d) 3,4-Dimethylhex-5-en-2-yne
(d) 4-Ethyl-3-methylocta-2,4,7-triene 11. Name of the following compound is ______.
5. The IUPAC name of the following molecule is ____ .

(a) 2,3-Diethylpent-1-en-4-yne
(a) 5,6-Dimethylhept-2-ene (b) 2,3-Dimethylpent-1-en-4-yne
(b) 2,3-Dimethylhept-5-ene (c) 3,4-Dimethylpent-4-en-1-yne
(c) 5,6-Dimethylhept-3-ene (d) 3,4-Methylpent-4-en-1-yne
(d) 5-Isopropylhex-2-ene
6. IUPAC name of following compound

(a) Hexa-1,5-diene (b) Hexa-1,5-diyne

(c) Hexa-2,6-diyne (d) Hexa-2,6-ene
7. Give the IUPAC name of the following compound.

Answer Key

MCQ’s From Target

1. (c) 2. (d) 3. (b) 4. (c) 5. (a) 6. (b) 7. (d) 8. (a) 9. (a) 10. (b)
11. (b)

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LDA-5
Theory Question
1. Give name of the following compounds
8.

9.

2.

10.

3.

11.

4.

12.

Theory Question
5. A. Write the structure of the following compounds.
1. 1,1,2,4 – Tetra Methyl cyclopentane
2. 1,2 - Diethyl cyclobutane
3. 2 - Cyclopropyl butane
4. 1 - Cyclobutyl butane
5. 2,3 – Dimethyl cyclopent - 1 – ene
6. 1,1 – Diethyl cyclopropane.
6. 7. 2 – Cyclobotyl – 4 – methyl cyclohex – 1 – ene.
8. 1 – Ethyl – 2 – methyl cyclohex – 1 – ene.
9. 4 – Ethyl – 1, 1-dimethyl cyclohexane.

7.

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IUPAC 11

Master key (a) carboxylic acid (b) ketone

1. Identify the functional group present in the following (c) aldehyde (d) ester
compounds: 4. Which of the following structure represents a ketones?
(i) n–propyl alcohol (ii) Acetylene
2. What is the structure of functional group in the following (a) CH3CH2  O  CH2CH3
classes of organic compounds? (b)
(i) Esters (ii) Carboxylic acids
3. Write the general representation (general formula) of the
following classes of organic compounds:
(i) Alcohols (ii) Ethers (iii) Esters (iv) Amines
4. Write name of the class of following organic compounds:
5. Write structure of an organic compound containing the
following functional groups: (c)
(i) Hydroxyl (ii) Nitrile
6. i) Write IUPAC names of the following alicylic compounds.
(d)

ii) Write IUPAC names for the following compound:

5. Which of the following is 1, 1- dimethylcyclohexane?

(a)

7. Name the following organic compounds. List the names of

the functional group in each compound.
(b)

(c)

B.MCQ Question
1. Which of the following is an ether? (d)
a) CH3  O  CH3
b) CH3  CH2  OH
c) CH3  CH2  CH2  OH
6. Which of the following structure represents a
d) CH3  O  H carboxylic acid?
2.
(a) CH3CH2  O  CH3
To which class of compound does belong ? (b)
(a) Amines (b) Amides
(c) Ketones (d) Aldehydes

3.

(c)

is a/an ______ .

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(d) (d)

7. The general formula for an ether is ______ .

(a) R  O  R' (b) R  CO  R'
(c) R  CO  OH (d) R  OH
8. Which of the following class of compounds does
NOT contain a C  O bond ?
(a) 14 units (b) 16 units
(c) 15 units (d) 13 units

9. Which of the following compound does NOT belong to

the same class of compounds ?

(a)

(b)

(c)

(d)

10. The bondline formula of cyclopentane is

(a)

(b)

(c)

Answer Key
MCQ’s From Tatva
1. (a) 2. (b) 3. (d) 4. (d) 5. (d) 6. (b) 7. (a) 8. (d) 9. (b) 10. (c)

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IUPAC 13

LDA-6
Give the IUPAC names of the following compounds.

1.

2.

3. CH3  CH  CH  CH2OH
4.

5.

6.

7. NC  CH  CH  CN
8. HOOC  CH  CH  COOH
9.

10.

11.

12.

13.

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14 IUPAC

14.

15.

16.

17.

18.

19.

20.

21.

22.

23. CH3CH2CH(CH3)CHO
24.

25.

26.

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IUPAC 15

27.

28.

29.

30.

31.

32. CH3 CH2 CH2 CN

33.

34.

35.

B. Give a correct IUPAC name of wrongly named IUPAC

1. 2,3- Dichloro propane
2. 3-Bromo-2-Methyl propane
3. 2-Hydroxy Pentane
4. 3-Chloro-2-ethyl-4-methyl Pentane
5. 3,5-Dimethyl-3-nitrohexane
6. 3-Ethyl-5-Chloro heptane
7. 3,4-Dimthyl Pentane-3,4-diol
8. 4-Amino-3-methyl Pentane.

C. Write the structure of the following compounds

1. 3-methyl butanoic acid
2. 2,3,4-Trimethyl hexan -3- ol
3. 3-Cyclohexyl butan-2-ol
4. 3-Ethyl-4-methyl hex-4-en-2-one
5. Cyclopropyl propanoate
6. Butanoyl chloride

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7. Hexanedial
8. 3-Methyl butanenitrile
9. 2-Bromo-4-Chloro-3ethyl hexane.
MCQ’s Master key
1. i) Give IUPAC names of the following compounds.

ii) Write IUPAC names of the following organic compounds.

2. Write complete structural formula and bond line formula

of the following compounds:
(i) 2 – Methylbutan – 2 – ol
(ii) l – Iodo – 2, 3 – dimethylpentane
(iii) 2 – Methylcyclohexa–1, 3–diene

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IUPAC 19

LDA-7
1. Write the IUPAC names of following compounds.

1.

2.

3.

4. CH3 CH2 O – CH2 – CHOH – CH3

5.

6.

7.

8.

9.

10.

11.

12.

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20 IUPAC

13.

14.

15.

16.

17.

18.

19.

20.

Write the structure of the following compounds

1. 5 – Chloro – 7 – hydroxy – 3 – methoxy oct – 5 – enal
2. 6 – Ethyl – 5 – methyl dec – 5 – enoic acid
3. 5, 6 – Dimethyl cyclohex – 2 – en – 1 – one
4. 5 – Ethyl – 4 – methyl non – 4 – enoic acid
5. 4 – Hydroxy pent – 3 – enoic acid
6. Ethyl – 2 – Cyano propanoate
7. Cyclohex – 3 – en – 1 – ol
8. But – 2 – enal
9. 4 – Hydroxy – 4 – methyl pentan – 2 – one
10. 4 – Cyclopropyl – 6 – methyl oct – 3 – enenitrile

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MCQ’s From Target MCQ’s From Drishti

1. The IUPAC name of the compound 1. The IUPAC name of the molecule

CH3COC(CH3)=C(CH3)COOH

(a) 4-oxo-2,3-dimethylpent-2-en-1-oic aicd

(a) 2–bromo–3–chloro–4–oxopentanoic acid (b) 2-carboxy-3-methylpent-2-en-3-one
(b) 4–oxo–3–chloro–2–bromopentanoic acid (c) 4-carboxy-3-methylpent-3-en-2-one
(c) 3–carboxy–2–bromo–3–chlorobutanone (d) 2,3-dimethyl-4-oxo-pent-2-en-1-oic acid
(d) 3–chloro–2–bromo–4–oxopentanoic acid
2. The IUPAC name of 2. The IUPAC name of

will be ______. (a) 3-(formyl methyl) hexane dail

(a) 4-hydroxy-1-methylpentanal (b) 3-methyl pentane dail
(b) 4-hydroxy-2-methylpentanal (c) 3-formyl methyl) butanal
(c) 3-hydroxy-2-methylpentanal (d) 2-(formyl methyl) butanal
(d) 3-hydroxy-3-methyl pentanal

Answer Key

MCQ’s From Target

1. (a) 2. (b)

MCQ’s From Drishti

1. (a) 2. (b)

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IUPAC 23

LDA-8

Give IUPAC names of the following compounds.

1.

2.

3.

4.

5.

6.

7.

8.

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9.

10.

11.

12.

13.

14.

15.

16.

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IUPAC 25

17.

18.

19.

20.

21.

22.

23.

24.

25.

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Theory Question : 5. In p-nitrotoluene, the two substituents are at ____

1. Write IUPAC names of the following compounds. positions.
2. Write the structural formula of the following (a) 1, 4 (b) 1, 2
derivatives of benzene. (c) 1, 3 (d) 1, 6
3. Give IUPAC names to the following compounds. 6. The IUPAC name of the compound

MCQ’s From Target

1. The common name of the given compound is _____.

(a) 2-bromo-1, 3-dinitrobenzene

(b) 1-bromo-2, 4-dinitrobenzene
(c) 4-bromo-1, 3-dinitrobenzene
(d) 1-bromo-2, 3-dinitrobenzene
(a) Anisole (b) Acetophenone
7. Write the IUPAC name of the following compound.
(c) Aniline (d) Toluene
2. The IUPAC name of the given compound is ____.

(a) 1–bromo–3–phenylpropane
(b) 2–bromo–4–phenylbutane (a) 2-Amino-4-hydroxybenzoic acid
(c) 1–bromo–4–phenylbutane (b) 6-Amino-4-hydroxybenzoic acid
(d) 1–bromobutylbenzene (c) 3-Amino-4-carboxyphenol
3. The CORRECT name for (d) 2-carboxy-5-hydroxyaniline
8. The IUPAC name of the given compound is ____.

(a) m-nitrobenzene
(b) m-hydroxynitrobenzene
(a) Trinitrophenol
(c) m-nitrophenol
(b) Phenyltrinitrobenzene
(d) nitrobenzene
(c) 2, 4, 6-trinitrophenol
4. The CORRECT name for 2-fluoro-4-methylanisole is ___.
(d) 1, 3, 6-trinitrophenol
(a) (b)

(c) (d)

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IUPAC 27

Answer Key

MCQ’s From Target

1. (b) 2. (c) 3. (c) 4. (d) 5. (a) 6. (b) 7. (a) 8. (c)

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