Quiz
Quiz
Quiz
QUIZZES
CHE 303 W17
QAQQCG
QUIZ #1 OAK
CH4 nC4H10
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QUIZ #2 OAK
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Quiz 3: Answer
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Q4 ANSWER
303W17f/p= 60.44295
QAW MW 18
T 773.15
H 3422.2
S 6.8803
H* 3488.1
S* 8.8342
H-H* -65.9
S-S* -1.9539 μ=G/n=h-Ts -1897.304
RTln(f/P*) 1444.758
R 8.314
RT 6427.969
* ln(f/P*) 4.045701
f/P* 57.15123
P*=1 bar
f= 57.15123 bar
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Quiz 5: Answer
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m, lb 157 P= 91.3073
MW1 39.94 Mx v= 0.23187
MW2 28.05
y1 0.75
y2 0.25
MW, Avg 36.9675
a11=a1 1.3618
b1 0.032289
a22=a2 4.56149
b2 0.057443
a12= 2.492355729
bm 0.0385775
am 1.985739024
Tc,1 271.8 oR
Pc,1 47.976308 atm
Tc,2 509.4 oR
Pc,2 50.54294176 atm
f10,bar 75.75
f20,bar 46.28
vdw-mx Find:
CALC.2 Fugacities in Mx
vdW Formula: ln(f1/y1P)= b1/(v-b)-2(x1*a11+x2*a12)/vRT-ln[P(v-b)/RT]
Fugacity, f1
b1/(v-b) 0.167047351
Fugacity, f2
b2/(v-b) 0.297181732
2(...)/vRT 1.047261284
ln[P(v-b)/RT] -0.34086317
sum= -0.40921639
f2/y1P 0.6641705
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QUIZ 8:
OBFPBO
QUIZ
8:
Rachford-
Rice for
Flash
K3 3.46 x5 0.465867
K4 2.285 fi x6 0.302424
K6 0.164 C4 0.169015
z3 0.2 C5 -0.16259
z4 0.2 C6 -0.25283
z6 0.2
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QUIZ 9:
OBFPBOQBJ
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QUIZ 10:
QBM
Not to
scale !
Quiz 10: For example, the final T-x-y should look like this !
QBM
409K
400K
390K
377K
Not to scale !
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Ans. Q11
yA = (100-ε)(350-2 ε) = 0.212
yB = (250-3ε)(350-2 ε) = 0.442
yC = 2ε/(350-2 ε) = 0.346
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• N2 + 3 H2 2 NH3
*2
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Find K,
Find yi !
Hints:
• N2 + 3H2 2 NH3
•
• t=0 (initial) ni0 : 1 3 0
• t’>0, extent -ɛ -3 ɛ 2ɛ
• of reaction
• t’>0, remaining 1- ɛ 3-3 ɛ 2ɛ
• moles nit
• Total moles nT at t’>0: nT = 1- ɛ + 3-3 ɛ+ 2 ɛ = 4 – 2 ɛ
• Mole frac:
• yi= (1- ɛ)/(4-2 ɛ), 3(1- ɛ)/(4-2 ɛ), 2 ɛ/(4-2 ɛ),
• Change in moles: Δv = 2-3-1 = -2
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1 *P-2
Excel:
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x yRatio
By
Goalseek 0.249749 0.3574 4x^2(4-2x)^2//27/(1-x)^4
Constraint: Ka 0.35738728
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HINTS:
ANSWERSUsing Solver!!!
[DATA] [CALC.]
T= 2600K
P= 1 atm I. Mole balances
Rxn A: CO2+ H2 ? CO + +
H2 O
t=0 3 6
0
Rxn B: CO2 ? CO ½ O2
Feed: t=0 1 0
Extent A .-x .-x .+x
.+x
Extent B: .-y .+y .+0.5y
total nT nT = 10+0.5y
= 6.3387
= 6.3387
= 0.060395
= 0.060395
From Table A27 Thus Table Value Calc. Value
ANSWERSUsing Solver!!!
[DATA] [CALC.]
T= 2600K
P= 1 atm I. Mole balances
Rxn A: CO2+ H2 ? CO + + H2 O
t=0 3 6
Rxn B: CO2 ? CO ½ O2 0
Feed: t=0 1 0
Extent A .-x .-x .+x
Extent B: .-y .+y .+0.5y
total nT nT = 10+0.5y
== 6.3387
6.3387
= 0.060395
= 0.060395
From Table A27 Thus Table Value Calc. Value
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Use Solver:
x= 0.682
y= 0.0087
nT= 10.00435
sum 1
QUIZ 16: Use van der Waals Eq. for Mixture Eq. for
fugacities: Find the fugacity coefficient,φ3, for NH3.
T, K= 773.2 R= 0.08314
P, bar= 300
3 1 2
a12 0.584063
a13 2.412986
a23 1.028713
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Excel Calculations:
ln(f1/y1P) 0.097235
am 0.810828
Φ-product Φ3^2/[Φ1*Φ2^3]
mx fugs ==> 0.583522
bm 0.030969
pur fugs ==> 0.48147
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