Chemical Reactor Technology: Department of Chemical Engineering Technology Government College University Faisalabad

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Chemical Reactor Technology

Department of Chemical Engineering Technology


Government College University Faisalabad
Recap Lecture 1: Reactor Simulation
The design of new reactors in the industry is today based on experiments and computer
simulations using Aspen, Matlab or CFD.
Reactor performance can be evaluated with process simulator such as Aspen.

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Recap-Lecture 2: Types of Chemical Reactors
Fixed bed reactor Fluidized bed reactor

Batch Reactor

Moving bed reactor Trickle bed reactor


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Recap Lecture 3: Types of Chemical Reactions
Reactions may be classified in a variety of ways. On the basis of mechanism they may be
1. Irreversible 2. Reversible Multiple Reactions

Based on operating conditions


1. Isothermal 2. Adiabatic 3. Nonisothermal

Based on phase involved


1. Homogeneous 2. Heterogeneous

Based on catalyst used


1. Catalytic 2. Non-Catalytic

Based on heat of reaction


1. Exothermic 2. Endothermic

Based on chemical bonds


1. Synthesis 2. Decomposition 3. Displacement 4. Combustion

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Chemical Reactors Nomenclature

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Modes of Operation

Batch Reactor Semi-Batch Reactor


Please read the notes for complete comparison and applications
Batch Continuous Semi-Batch

Advantages Disadvantage Advantages Disadvantage Advantages Disadvantage

Better for small Process control & Better Process Flexibility usually low Good for small-scale Operating cost may
production uniform product control & uniform production be relatively high
quality is difficult product quality compared to batch
Capital cost usually unsteady-state Operating cost Capital cost usually Better than batch Unsteady-operation
relatively low operation relatively low relatively high operation

Easy to shut down Steady-state Shut down for cleaning Easy adjustment Difficult to control
and clean operation very costly accordingly
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Theoretical background for Designing & Selecting a Reactor
Fluid Mechanics
• Pressure drop
• Flow characteristics
Chemical kinetics • Pump required? Heat Transfer
• How fast a reaction • Heat removal/addition
proceed to a reactor

Thermodynamics Mass Transfer


• Is reaction feasible • Diffusion of reactant and products
• How far a reaction can go molecules between catalyst surface
and reaction medium

Chemical
Stoichiometry Process Economics
• Quantitative relation between
Reactor • Is reaction/process feasible
reactants and products Selection economically?

and Design

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Pillars of Chemical Reactor Technology
 Many applications lies on these pillars
 These are the concepts required before designing, selecting or operating a chemical reactor

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Reactor Performance

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Predicting Reactor Behavior
To predict the reactor performance we need to know the kinetics, the contacting pattern
and the performance equation.

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