LECTURE 1 Kinds of Minerals
LECTURE 1 Kinds of Minerals
LECTURE 1 Kinds of Minerals
The silicate minerals make up the largest and most important class of rock-forming minerals,
constituting approximately 90 percent of the crust of the Earth. They are classified based on the
structure of their silicate group which contain different ratios of silicon and oxygen.
Nesosilicates or orthosilicates
Nesosilicates (from Greek νησος nēsos, island), or orthosilicates, have isolated (insular) [SiO4]4−
tetrahedra that are connected only by interstitial cations.
Phenakite group
o Phenakite - Be2SiO4
o Willemite - Zn2SiO4
Olivine group
o Forsterite - Mg2SiO4
o Fayalite - Fe2SiO4
o Tephroite - Mn2SiO4
Garnet group
o Pyrope - Mg3Al2(SiO4)3
o Almandine - Fe3Al2(SiO4)3
o Spessartine - Mn3Al2(SiO4)3
o Grossular - Ca3Al2(SiO4)3
o Andradite - Ca3Fe2(SiO4)3
o Uvarovite - Ca3Cr2(SiO4)3
o Hydrogrossular - Ca3Al2Si2O8(SiO4)3-m(OH)4m
Zircon group
o Zircon - ZrSiO4
o Thorite - (Th,U)SiO4
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Al2SiO5 group
o Andalusite - Al2SiO5
o Kyanite - Al2SiO5
o Sillimanite - Al2SiO5
o Dumortierite - Al6.5-7BO3(SiO4)3(O,OH)3
o Topaz - Al2SiO4(F,OH)2
o Staurolite - Fe2Al9(SiO4)4(O,OH)2
Humite group - (Mg,Fe)7(SiO4)3(F,OH)2
o Norbergite - Mg3(SiO4)(F,OH)2
o Chondrodite - Mg5(SiO4)2(F,OH)2
o Humite - Mg7(SiO4)3(F,OH)2
o Clinohumite - Mg9(SiO4)4(F,OH)2
Datolite - CaBSiO4(OH)
Titanite - CaTiSiO5
Chloritoid - (Fe,Mg,Mn)2Al4Si2O10(OH)4
Mullite (aka Porcelainite) - Al6Si2O13
Sorosilicates
Sorosilicates (from Greek σωρός sōros, heap, mound) have isolated double tetrahedra
groups with (Si2O7)6− or a ratio of 2:7.
Hemimorphite (calamine) - Zn4(Si2O7)(OH)2·H2O
Lawsonite - CaAl2(Si2O7)(OH)2·H2O
Ilvaite - CaFe2+2Fe3+O(Si2O7)(OH)
Epidote group (has both (SiO4)4− and (Si2O7)6− groups)
o Epidote - Ca2(Al,Fe)3O(SiO4)(Si2O7)(OH)
o Zoisite - Ca2Al3O(SiO4)(Si2O7)(OH)
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o Clinozoisite - Ca2Al3O(SiO4)(Si2O7)(OH)
o Tanzanite - Ca2Al3O(SiO4)(Si2O7)(OH)
o Allanite - Ca(Ce,La,Y,Ca)Al2(Fe2+,Fe3+)O(SiO4)(Si2O7)(OH)
o Dollaseite-(Ce) - CaCeMg2AlSi3O11F(OH)
Vesuvianite (idocrase) - Ca10(Mg,Fe)2Al4(SiO4)5(Si2O7)2(OH)4
Cyclosilicates
Cyclosilicates (from Greek κύκλος kuklos, circle), or ring silicates, have linked tetrahedra
with (TxO3x)2x- or a ratio of 1:3. These exist as 3-member (T3O9)6- and 6-member
(T6O18)12- rings, where T stands for a tetrahedrally coordinated cation. Nickel-Strunz
classification: 09.C
3-member ring
o Benitoite - BaTi(Si3O9)
6-member ring
o Axinite - (Ca,Fe,Mn)3Al2(BO3)(Si4O12)(OH)
o Beryl/Emerald - Be3Al2(Si6O18)
o Cordierite - (Mg,Fe)2Al3(Si5AlO18)
o Tourmaline - (Na,Ca)(Al,Li,Mg)3-(Al,Fe,Mn)6(Si6O18(BO3)3(OH)4
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Inosilicates
Inosilicates (from Greek ις is [genitive: ινος inos], fibre), or chain silicates, have
interlocking chains of silicate tetrahedra with either SiO3, 1:3 ratio, for single chains or
Si4O11, 4:11 ratio, for double chains. Nickel-Strunz classification: 09.D
Single chain inosilicates
Pyroxene group
o Enstatite - orthoferrosilite series
Enstatite - MgSiO3
Ferrosilite - FeSiO3
o Pigeonite - Ca0.25(Mg,Fe)1.75Si2O6
o Diopside - hedenbergite series
Diopside - CaMgSi2O6
Hedenbergite - CaFeSi2O6
Augite - (Ca,Na)(Mg,Fe,Al)(Si,Al)2O6
o Sodium pyroxene series
Jadeite - NaAlSi2O6
Aegirine (Acmite) - NaFe3+Si2O6
o Spodumene - LiAlSi2O6
Pyroxenoid group
o Wollastonite - CaSiO3
o Rhodonite - MnSiO3
o Pectolite - NaCa2(Si3O8)(OH)
Double chain inosilicates
Amphibole group
o Anthophyllite - (Mg,Fe)7Si8O22(OH)2
o Cumingtonite series
Cummingtonite - Fe2Mg5Si8O22(OH)2
Grunerite - Fe7Si8O22(OH)2
o Tremolite series
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Tremolite - Ca2Mg5Si8O22(OH)2
Actinolite - Ca2(Mg,Fe)5Si8O22(OH)2
o Hornblende - (Ca,Na)2-3(Mg,Fe,Al)5Si6(Al,Si)2O22(OH)2
o Sodium amphibole group
Glaucophane - Na2Mg3Al2Si8O22(OH)2
Riebeckite (asbestos) - Na2Fe2+3Fe3+2Si8O22(OH)2
Arfvedsonite - Na3(Fe,Mg)4FeSi8O22(OH)2
Phyllosilicates
Phyllosilicates (from Greek φύλλον phyllon, leaf), or sheet silicates, form parallel sheets
of silicate tetrahedra with Si2O5 or a 2:5 ratio. Nickel-Strunz classification: 09.E. All
phyllosilicate minerals are hydrated, with either water or hydroxyl groups attached.
Serpentine group
o Antigorite - Mg3Si2O5(OH)4
o Chrysotile - Mg3Si2O5(OH)4
o Lizardite - Mg3Si2O5(OH)4
Clay mineral group
o Halloysite - Al2Si2O5(OH)4
o Kaolinite - Al2Si2O5(OH)4
o Illite - (K,H3O)(Al,Mg,Fe)2(Si,Al)4O10[(OH)2,(H2O)]
o Montmorillonite - (Na,Ca)0.33(Al,Mg)2Si4O10(OH)2·nH2O
o Vermiculite - (MgFe,Al)3(Al,Si)4O10(OH)2·4H2O
o Talc - Mg3Si4O10(OH)2
o Palygorskite - (Mg,Al)2Si4O10(OH)·4(H2O)
o Pyrophyllite - Al2Si4O10(OH)2
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Mica group
o Biotite - K(Mg,Fe)3(AlSi3)O10(OH)2
o Muscovite - KAl2(AlSi3)O10(OH)2
o Phlogopite - KMg3(AlSi3)O10(OH)2
o Lepidolite - K(Li,Al)2-3(AlSi3)O10(OH)2
o Margarite - CaAl2(Al2Si2)O10(OH)2
o Glauconite - (K,Na)(Al,Mg,Fe)2(Si,Al)4O10(OH)2
Chlorite group
o Chlorite - (Mg,Fe)3(Si,Al)4O10(OH)2•(Mg,Fe)3(OH)6
Tectosilicates
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Oligoclase - (Na,Ca)(Si,Al)4O8 (Na:Ca 4:1)
Andesine - (Na,Ca)(Si,Al)4O8 (Na:Ca 3:2)
Labradorite - (Na,Ca)(Si,Al)4O8 (Na:Ca 2:3)
Bytownite - (Na,Ca)(Si,Al)4O8 (Na:Ca 1:4)
Anorthite - CaAl2Si2O8
Feldspathoid family
o Nosean - Na8Al6Si6O24(SO4)
o Cancrinite - Na6Ca2(CO3,Al6Si6O24).2H2O
o Leucite - KAlSi2O6
o Nepheline - (Na,K)AlSiO4
o Sodalite - Na8(AlSiO4)6Cl2
Hauyne - (Na,Ca)4-8Al6Si6(O,S)24(SO4,Cl)1-2
o Lazurite - (Na,Ca)8(AlSiO4)6(SO4,S,Cl)2
Petalite - LiAlSi4O10
Scapolite group
o Marialite - Na4(AlSi3O8)3(Cl2,CO3,SO4)
o Meionite - Ca4(Al2Si2O8)3(Cl2CO3,SO4)
Analcime - NaAlSi2O6•H2O
Zeolite family
o Natrolite - Na2Al2Si3O10•2H2O
o Chabazite - CaAl2Si4O12•6H2O
o Heulandite - CaAl2Si7O18•6H2O
o Stilbite - NaCa2Al5Si13O36•17H2O
o Scolecite - CaAl2Si3O10.3H2O
o Mordenite - (Ca,Na2,K2)Al2Si10O24•7H2O
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o PYROXENE GROUP OF MINERALS