Technical Brief

UV Protection of Coated Line Pipe

Background UV Exposure – Chalking

Fusion bonded epoxy (FBE) is a one part powdered epoxy Due to the presence of the aromatic group, epoxy resins
coating that is sprayed onto the hot metal substrate where it generally absorb at about 300 nm and will degrade in the
melts, flows and cures to give a corrosion resistant coating. presence of UV light and humidity via photoinitiated free-
The first line pipe coated with FBE was placed into service radical degradation. This polymer degradation is known as
in 19601. Since that time, FBE coatings have become the chalking and results in the formation of a loose powdery
most commonly used coating for new pipeline construction residue on the pigmented coating surface. The residue on
in North America. FBE coatings are formulated to meet the polymer surface protects against further degradation
both the requirements of the applicator who will apply the unless it is removed. Removal of this protective barrier
coating and the performance requirements of the end user (either by natural or mechanical means) exposes a fresh
(pipeline owner). surface which is then subject to further UV exposure
and degradation.
The primary raw materials used to formulate FBE coatings
include epoxy resins, curing agents (hardeners), catalysts, Numerous studies have been conducted to investigate the
pigments and fillers. Other additives may be used to control UV degradation of epoxy resins 2-5. One study investigated
the flow characteristics, improve adhesion performance several possible weak links in amine cured epoxy systems
and provide other useful benefits. While there are several and reported that the presence of the aromatic bisphenol
types of epoxy resins commercially available, those based moiety is primarily responsible for the absorption of UV
on diglycidyl ether of bisphenol A (DGEBA) or novolac light6. Modification of the polymer backbone by changing
chemistry are the two epoxy resin types most frequently the chemistry (use of alternate diglycidyl ethers such as
used in FBE coatings. While these epoxy resins can be used diglycidyl ether of bisphenol F and/or varying the curing
to make polymers with a wide range of properties and are agent) can have some impact on the degree chalking but
very versatile in many ways, they are aromatic and thus does not eliminate the phenomena. In other words, all
have poor ultraviolet (UV) light resistance limiting their use in FBE pipeline coatings based on aromatic epoxy resins will
exterior applications. chalk but there may be some difference in the degree of
chalking due to slight differences in the chemistry of the
various formulations.

Efforts have been made to improve the UV stability of epoxy

products; however, to date commercial success of epoxy
resins with improved weatherability has been limited 7-9.
These resins are much higher in price and end users have
other ways to limit UV exposure as will be discussed later in
this paper.

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In addition to the susceptibility of specific FBE formulations As long as thickness has not been substantially reduced,
to UV attack, the degree of chalking also depends on weathering appears to have only minimal effects on the
direct exposure to UV, the intensity and duration of the performance of FBE coatings. One published study of pipe
UV radiation, and the availability of water on the coating coated in the US and installed in the Middle East showed
surface 1. A pipe stored above ground experiences the no significant reduction in either flexibility or short-term
most chalking on the top (12 o’clock position), less on the cathodic disbondment tests (65°C, 3% NaCl, and 48 hour
sides (3 and 9 o’clock positions) and little or none on the duration) after 3 years in a stockpile11. The Cetiner study,
bottom (6 o’clock position). Since the degree of chalking is which evaluated pipe that had been stored for approximately
dependant on the intensity and duration of the UV radiation one year, showed no measurable reduction in performance
and the presence of moisture, it is not surprising that in either the 48-hour cathodic disbondment test or hot
variations in the degree of chalking observed in the field water adhesion tests. There was however a measurable
appear to be geographic-location specific. reduction in flexibility as measured by the CSA FBE flexibility
test method at -30°C12. Based on this work, Cetiner and
Effects of Chalking on coworkers recommended that pipe stored for longer than
Coating Performance one year should be protected from UV radiation.
The chalking process is polymer degradation and thus
thickness loss is an obvious concern. Thickness loss is Again, it is important to keep in mind that the rate of
caused by alternate chalking and removal of this loose chalking/thickness loss can vary considerably and is
surface material by wind, rain, tidal splash or blowing dependant on the susceptibility of the specific FBE
particulate. The rate of thickness loss depends on the rate formulation to UV attack, the intensity and duration of the UV
of removal of the protective layer as well as the factors that exposure, the availability of moisture, as well as the rate at
determine the degree of chalking reviewed in the previous which the protective chalk layer is removed.
section. Field experience suggests that there is considerable
variance in the rate of thickness loss which tends to relate to
Common Industry Solutions
Many different methods have been used throughout the
location/geography. The chalking process takes some time
industry to protect coated pipe from UV radiation. As a
to get started. One study reported a thickness reduction
preventative measure, many applicators apply additional
in the 12 o’clock position of about 20 μm (3/4 mil) after
coating thickness at the time the FBE coating is applied in
approximately a year of storage in northern US and southern
order to compensate for any thickness loss that may occur
Canada10. Historical observation suggests that measurable
during the time between when the pipe is coated and when
thickness loss typically begins within 9 to 18 months1. Once
the pipe is actually installed. The typical procedure in most
started, the typical rate of loss is in the range of 10 to 40 μm
cases is to provide a barrier between the sun and the coated
(0.375 to 1.5 mil) per year.
pipe. The barrier could include any of the following:

1. Covering pipe stock piles with tarps.

2. Applying white wash to the UV exposed upper layer of
the stock pile.
3. Applying an overcoat of an aliphatic polyurethane to the
entire coated surface
4. Applying an overcoat of polyester powder coating.
(Separate spray booths are required due to the
incompatibility of epoxy and polyester systems)
Selection of the barrier is dependant on the length of time References
the UV exposure is expected. In the short term, a water 1
Alan J. Kehr, “Fusion Bonded Epoxy (FBE): A Foundation
permeable paint such as latex is sufficient. For longer term for Pipeline Corrosion Protection”, NACE International
storage or permanent above ground usage, selection of the Publication, 2003.
barrier coating and surface preparation are crucial. Prior to
use, any UV-barrier coating should be evaluated for their
2
P. G. Kelleher, B. D. Gesner, J. Appl. Polym. Sci., 13 (1969)
ability to adhere to the FBE coating. Any residual chalking 9–15.
must be removed before application of a UV-barrier coating. 3
B. D. Gesner, P. G. Kelleher, J. Appl. Polym. Sci., 13 (1969)
The long-term adhesion performance of the UV-barrier
2183–2191.
coating can be improved by roughening the FBE coating
surface with sandpaper or a light abrasive blast. For storage 4
A. Rivaton, L. Moreau, J.-L. Gardette, Polym. Degrad. Stab.
over two years; a weldable primer should be applied to the 58 (1997) 321–332.
cutback area. This helps prevent corrosion in the cutback 5
A. Rivaton, L. Moreau, J.-L. Gardette, Polym. Degrad. Stab.
area and undercreep of the FBE coating.
58 (1997) 333–339.
6
V. C. Malshe, G. Waghoo, Prog. Org. Coat. 51 (2004)
267–272.
7
H. Q. Pham, M. J. Marks, “Epoxy Resins” Ullmann’s
Encyclopedia of Industrial Chemistry
8
V. C. Malshe, G. Waghoo, Prog. Org. Coat. 51 (2004)
172–180.
9
V. C. Malshe, G. Waghoo, Prog. Org. Coat. 56 (2006)
131–134.
10
M. Cetiner, P. Singh, J. Abes, Oil Gas J. 99 (2001) 58–60.
11 
Surfcote Bulletin, “Case History of Fusion Bonded Coated
Pipe Shipped to Middle East” Houston, TX Winter 1979/80.
12 
CSA Z245.20-98, “External Fusion Bonded Epoxy Coating
for Steel Pipe,” (Etobicoke, Ontario, Canada: Canadian
Standards Association, April 1998).
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