Nama: Khoirunnisa Nim: 16612132: Lnkvs1/T

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Nama : Khoirunnisa

NIM : 16612132

1.)

k (1/M.s) T (K) ln K 1/T


0,000000524 303 -14,46177415 0,00330033
0,00000244 328 -12,92351252 0,00304878
0,0000835 354 -9,390663926 0,002824859
0,000637 373 -7,358740902 0,002680965
0,00396 399 -5,531511254 0,002506266

ln K VS 1/T
0
0 0.0005 0.001 0.0015 0.002 0.0025 0.003 0.0035
-2

-4

-6 y = -11869x + 24.157
R² = 0.9784
ln K

-8

-10

-12

-14

-16
1/T

Ea = slope x (-R) , R = 8,314 J/mol


Ea = -11869 x (-8,314 J/mol)
Ea = 98678,866 J/mol

2.) Diketahui : reaksi ber orde 1


k = 3,46 x 10-2 pada T = 30◦C = 303K
Ea = 55,2 kJ/mol
Ditanya : k pada T = 80◦C = 353K
Jawab :
ln K = ln A – (Ea/R) x (1/T)
-3,3639 = ln A – (55200 J/mol / 8,314 J/mol) x (1/303K)
-3,3639 + (55200 J/mol / 8,314 J/mol) x (1/303K) = ln A
18,54832249 = ln A

K pada 80◦C

ln K = ln A – (Ea/R) x (1/T)
ln K = 18,54832249 – (55200 J/mol / 8,314 J/mol) x (1/353K)
ln K = -0,260185766
k = 0,770908364 1/M.s

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