N5

T=136 C
700 kmol/h

S + O2 ----> SO2
N6
O2
N2

DATA
Komponen

T= 70 C
1050 kmol/h
9000 kmol/h

Fase

T 1=
T2=
T3=
S=

409 K
343 K
1273 K
a

2.003
O2=

0.12002
b

29.526
SO2=

c
0.034735

b
2.9342E+01

-3.5395E-03

-18777.1286 J/mol K
-20296.8991 J/mol K
0 J/mol K

cp N2=

28432.58309 J/mol K

komponen

e
-3.2629E-08

d
9.2903E-06

cp S =
cpO2=
cp SO2 =

dq/dt=

-0.0088999 -0.000038083

29.637
N2=

-0.00016202

e
-2.9885E-08

d
1.0076E-05

8.8607E-12

1.0937E-11
e

-4.3116E-09

-2.5935E-13

-18.77712864

r. HR(360 K) + N in ME Cp ME dT + N in N2

2.48886E+11 J/mol.K
248886395.8 KJ/mol.K

43633216036

S
O2
SO2
N2
SO3
metanol
NaOH
H2O2

2.0030E+00
2.9526E+01
29.637
2.9342E+01
22.4
40.152
51.234
-15.248

1.2002E-01
-8.8999E-03
0.034735
-3.5395E-03
0.11981
0.31046
0.013088
0.67693

-1.6202E-04
-3.8083E-05
9.2903E-06
1.0076E-05
-0.000090842
-0.0010291
2.33559E-05
-0.0014948

-3.2629E-08
-2.9885E-08
-4.3116E-09
2.5503E-08
1.4598E-06
1.2018E-06

8.8607E-12
1.0937E-11
-2.5935E-13
-7.9208E-13
-

Burner
T = 1000 C
N4
SO2
O2
N2

N in S=
N in O2=
N in N2=
r=
HR(298 K)=

700000
1050000
9000000
700000
-0.29683

10050
700
350
9000
0.069652
0.034826
0.895522

mol/h
mol/h
mol/h
mol/h
j/mol

CP inlet
-18777.1286 -18777.1286 -13143990
8530.452296 891.2412847
28432.58309 25462.0147
26353.25599 264850223
2.79155E+11 J/Mol
279155114.7 Kj/mol K

S
O2
kmol/h
kmol/h
kmol/h
kmol/h

cp s=
cp O2=
cp SO2 =

10324.79862 j/mol
8530.452296 j/mol
41007.33185 j/mol

HR(1273 K)=

39212.6887 j/mol
39.2126887

700
1050
9000

E Cp ME dT + N in N2 Cp N2 dT +N in inter 3 Cp inter 3 dT + N in H2O Cp H2O dT

N4

T=450 C

SO2
O2
N2
r=

350 kmol/h

T 298 K
T1=
T2=
HR(298 K)=
SO2=
O2=

2SO2 + O2 ----> 2SO3

1000 kmol/h
350 kmol/h
9000 kmol/h
10350

25
450
40
-98.89
-0.09889
a
a

N2=

SO3

c
c
c
j/mol

b
29.637 0.034735
b
29.526
-0.0089
b
29.342 -0.00354
b
22.4
0.11981

298
723 K
313 K

d
9.29E-06

e
-3E-08

d
-3.8E-05

1.09E-11
e

-3.3E-08
d

8.86E-12
e

1.01E-05

-4.3E-09 -2.6E-13
d
e
-9.1E-05 2.55E-08 -7.9E-13

SO2
O2
N2
dq/dt =

T 313K - 723 K
cp SO2 =
cpO2=
cp N2 =
cp SO3 =
HR(313 K)=
dq/dt=

-19059.3859 J/mol K
-4001.28779 J/mol K
-12150.5838 J/mol K
-25763.8494
2604.285762
-1.2982E+11 j/mol.K
-129824108 Kj/mol.K

298 K
CP SO2 =
0 j/mol K
CPO2 =
335.9768 J/mol K
CP N2 =
436.14

T=40 c
N2 =
SO3 =
SO2
N2

N in
SO2
O2
N2
r

1000 kmol/h
350 kmol/h
9000 kmol/h

Cp inlet
-19059.38588 J/mol
-4001.28779 J/mol
-12150.58376 J/mol
-1.29814E+11 J/mol
-129814179 Kj/mol

0.096618
0.033816
0.869565

1000000
350000
9000000
350

-1841.49
-135.309
-10565.7
-12542.5

mol/h
mol/h
mol/h
mol/h

-1.30E+08

N1 =
ME =
H2O =
400 C

N1 T=

ME + 2SO3

N2 =
SO3 =
SO2
N2

400 C

N2 T=

Tstandar=
T1=
T2=
Cp ME=
CpSO3=
CpN2=
cpSO2=
Cp III=
CP III =
SO3
SO2
N2
HR(298 K)=

298 K
313 K
348 K
590.01
768.64
1019.011993
1441.369316
824.86

J/mol K
J/mol K
J/mol K
J/mol K
J/mol K

28870.1 J/mol K
22.4
0.11981
-9.084E-05 2.5503E-08
29.637
0.034735
9.29E-06 -2.9885E-08
2.9342E+01
-3.5395E-03 1.0076E-05 -4.3116E-09
-38338.4 j/mol

HR(348)=

23278208.11 j/mol

dQ/dT=

2.01944E+28 j/mol.K
2.01944E+25 kj/mol.K

Nin ME=
Nin H2O=
NinSO3=
Nin SO2=
Nin N2=
r=
-7.9208E-13
1.0937E-11
-2.5935E-13

ME
H2O
SO3
SO2
N2
dq/dt =

T1=
T2=
T3=

T=

313 H2O=
298
348 Cp H2O=

b
c
1.82964 0.472118 -0.00134
5068254257 J/mol K

75 C

+ 2SO3 ----> (III)

10469.4751
468.070879
1.40421264
700
300
9000
350

Cp Inlet
205046.47
5068254257
11482096.9
11481300.8
11480875.5
1.3017E+14

kmol/h
kmol/h
kmol/h
kmol/h
kmol/h
kmol/h

468070.9
1404.213
700000
300000
9000000
350000

mol/h
mol/h
mol/h
mol/h
mol/h
mol/h

0.044708
0.000134
0.066861
0.028655
0.859642

d
1.31E-06

N3

T= 75 C

ME
N2
Int III
H2O

T standar =
T1=
T2=
a

25
75
87
b

SO3
N2
SO2
H2O
Data
Cp ME =
Cp SO3 =
Cp N2 dT=
Cp inter3=
Cp SO2 dT=
Cp MESA =

22.4
2.9342E+01
29.637
1.82964

Cp ME dT=
Cp inter 3 dT=
Cp MESA dT=
Cp SO3 dT=
Cp H2O dT=

7080.12
584000.88
260655.31
3277.467206
713.9001237

590.01
654.5632008
349.877054
824.86
503.3189278
725.09

0.11981
-3.5395E-03
0.034735
0.472118
J/mol K
J/mol K
J/mol K
J/mol K
J/mol K

116.667
9000
350
1.404

kmol/h
kmol/h
kmol/h
kmol/h

298 K
348 K
360 K
c
d
-9.0842E-05 2.5503E-08
1.0076E-05 -4.3116E-09
9.2903E-06 -2.9885E-08
-0.00133878 1.31424E-06

N in
ME
N2
Int III
H2O
r
HR(298 K)=
HR(360 K)=

e
-7.921E-13
-2.5935E-13
1.0937E-11

116.667
9000
350
1.404
280
2379.74
-317688.36

dQ/dt=

r. HR(360 K) + N in ME Cp ME dT + N in N2 Cp N2 dT +N in inter 3 Cp inter 3 d

Digesrter
ME
N2
Int III
H2O

Cp inlet
7080.12
349.877054
584000.88
713.9001237

J/mol K
J/mol K
J/mol K
J/mol K

dq/dt

2.08287E+11 J/mol K
208287267.4 Kj/mol K

T = 87 C

N7

Inter III ----> MESA + SO3

kmol/h
kmol/h
kmol/h
kmol/h
kmol/h

116667
9000000
350000
1404
280000

mol/h
mol/h
mol/h
mol/h
mol/h

Hf inter 3 =
Hf MESA =
Hf SO3 =

-1348.39 J/mol
1125.82 J/mol
-94.47 J/mol

J/mol

in inter 3 Cp inter 3 dT + N in H2O Cp H2O dT

ME
N2
Int III
H2O

9468.071
116.667
9000
350
1.404

kmol/h
kmol/h
kmol/h
kmol/h

0.012322151
0.950563214
0.036966347
0.000148288

87.242307
332.58026
21588.379
0.1058627
2.20E+04

2.08E+08

T3 =

25 C
298 K

N9
H2O2
H2O

7280 kg/h
3640 kg/h
3640 kg/h
#REF!
918.75 kmol/h

N8

T2 =

25 C
298 K
T1 =

T standar

CH3OH
H2O

87 C
N7
9468.071
ME
116.6667
N2
9000
III
70
H2O
1.404213
MESA
280

III + CH3OH + 2H2O2 ---> MESA + HMS +

918.75
894.5325 kmol/h
24.21746 kmol/h
360 K
kmol/h
411625.3 kg/h
kmol/h
31500 kg/h
kmol/h
252000 kg/h
kmol/h
30100 kg/h
kmol/h
25.27583 kg/h
kmol/h
98000 kg/h

0.0123221
0.9505632
0.0073933
0.0001483
0.0295731

298 K

CP ME =
Cp ME =
Cp N2 =
Cp inter3=
Cp inter 3 =
Cp MESA =
Cp MESA =
CP impurities=
Cp CH3OH =
Cp H2O =
Cp H2O2 =
Cp H2O =

590.01
7080.12
350.16363
824.86
9898.32
725.09
269368.39
716.67465
6197.2746
4376.784
6572.7376
4376.784

J/mol K
J/mol K
J/mol K
J/mol K
J/mol K
J/mol K
J/mol K

CP HMS =
Cp HMS =
Cp O2 =

214.86 J/mol K
15899.64
1554.8604

dQ/dt=

2.092E+10 J/mol.K
20922630 Kj/mol.K

T 372 --T 298K

N in
ME
N2
Int III
H2O
MESA
r

116.667
9000
70
1.4042
280
49.19929

HR(298 K)=
HR(372 K)=

-1422568
-1206479

a
SO3
N2
SO2
CH3OH
H2O
H2O2
O2

> MESA + HMS +

0.973641 6033.91978 6149.288 T4 =

7.270172 368.3135
332.8527
6.098412
0.649122
21.44314

kmol/jam
kmol/jam
kmol/jam
kmol/jam
kmol/jam
kmol/jam

116667
9000000
70000
1404.2
280000
49199.29

3.49E+06

mol/jam
mol/jam
mol/jam
mol/jam
mol/jam
mol/jam

22.4
29.342
29.637
40.152
1.82964
-15.248
2.9526E+01

c
0.11981
-0.0035395
0.034735
0.31046
0.472118
0.67693
-8.8999E-03

-9.084E-05
1.0076E-05
9.2903E-06
-0.0010291
-0.0013388
-0.0014948
-3.8083E-05

99 C
N10
ME
N2
III
H2O
MESA
CH3OH
H2O2
HMS
O2

372
10696.10193
116.6666667
9000
20.80071046
326.2424769
329.1992895
845.3332475
8.660244452
49.19928954
49.19928954

H2o2
H2O

309.281046
107.058824 kmol/h
202.222222 kmol/h

CH3OH
H2O

28625.0412 kmol/jam
435.914333 kmol/jam

kmol/h
kmol/h
kmol/h
kmol/h
kmol/h
kmol/h
kmol/h
kmol/h
kmol/h
kmol/h

0.34615385
0.65384615

e
2.5503E-08 -7.9E-13
-4.3116E-09 -2.6E-13
-2.9885E-08 1.09E-11
1.4598E-06
1.31424E-06
1.2018E-06
-3.2629E-08 8.86E-12

K
447966.2313
31500
252000
8944.305498
5872.364584
115219.7513
27050.66392
294.4483114
5510.320428
1574.377265

kg/h
kg/h
kg/h
kg/h
kg/h
kg/h
kg/h
kg/h
kg/h
kg/h

1515.040632 4376.784 1.35E+06

T
N9
H2O
T

Nin H2O=
Nin SO3=

T1=
T2=
T3=
T standar=
integral
integral
integral

130

H2O + SO3 --> H2SO4

448000
mol/h
102 C

N10
H2SO4
SO3
H2O

448000 mol/h
280000 mol/h

N9
SO3
T

280
120 C

375
393
403
298

CpH2O=
1.17E+06 j/mol
CpSO3=
7.83E+04 j/mol
Cp H2SO4= -39802815 j/mol
r=
279.86

5.23E+08
2.19E+07
279860 mol/h

HR ( 298 K ) =
HR ( 403 K ) =

-1332.47
38713126

b
c
d
1.82964 0.472118 -0.00134
1.31424E-06
Cp H2O=
15150.86
integral Cp=
1166616.4
H2SO4
a
b
26.004
0.70337
Cp=
-379074.4297
279860 mol/h
integral Cp=
-39802815
140 mol/h
168140 mol/h

279.86
0.14
168.14

280000 mol/h

Hf SO3=
Hf H2O=
j/mol
j/mol

-94.47
220

Hf H2SO4=

dQ/dT=

1458

1.13788E+13 j/mol.K
11378812187 Kj/mol.K

d
-0.37585 0.000010342

T1=
N12
NaOH
H2O
N10
ME
III
H2O
MESA
CH3OH
H2O2
HMS

99 0C
1261.826801
391.6014209 kmol/h
870.2253798 kmol/h
T2=
25 0C
1696.101925
116.6666667 kmol/h
20.80071046 kmol/h
326.2424769 kmol/h
329.1992895 kmol/h
845.3332475 kmol/h
8.660244452 kmol/h
49.19928954 kmol/h

T1=
T25=
T2=
Tstandar=

0.310344828 626.6382
0.689655172 2425.24

0.068785174
0.012263833
0.192348391
0.19409169
0.49839767
0.005105969
0.029007272

590.01 J/mol K

HR 1(298 K)=
HR 2(298 K)=

1.04E+07

Nin NaoH=
Nin H2O=
Nin ME=
Nin III
Nin H2O
Nin MESA
Nin CH3OH
Nin H2O2
Nin HMS
r1=
r2=

372
298
333
298

Cp NaOH=
Cp H2O=
Cp ME=
CpIII=
Cp H2O=
Cp MESA=
Cp CH3OH=
Cp H2O2=
Cp HMS=

40.58394
10.12821
676.4119
140.7339
5529.777
-17.9702
-243.068
6136.597

3051.878102
3.85E+06

integral Cp=

152.6454814
-2031.71185

391.6014
870.2254
116.6667
20.80071
326.2425
329.1993
845.3332
8.660244
49.19929
20.80071
329.1993

2019.167513
-4031.78702
-23010.39
825.86
3516.597867
725.09
11095.11
-3519.45508
-8379.54

j/mol
j/mol
j/mol
j/mol
j/mol
j/mol
j/mol
j/mol
j/mol

HR 1(333 K)=
HR 2(333 K)=

17393.56584
-1967.84951

dQ/dT=

2952587101 j/mol.K
2952587.101 kj/mol.K

T=

60 0C
III + 3NaOH ---> disalt
N11+ 2H2O + SMS
MESA + NaOH ---> MES + H2O
372
ME
H2O
CH3OH
H2O2
HMS
disalt
MES
SMS

kmol/h
kmol/h
kmol/h
kmol/h
kmol/h
kmol/h
kmol/h
kmol/h
kmol/h
kmol/h
kmol/h

116.6666667
1567.268567
845.3332475
8.660244452
49.19928954
20.80071046
329.1992895
20.80071046

kmol/h
kmol/h
kmol/h
kmol/h
kmol/h
kmol/h
kmol/h
kmol/h

Cp r1=
CpIII=
Cp NaOH=
Cp disalt=
Cp H2O=
Cp SMS=

825.86
2019.167513
22522.5
3516.597867
5953.15

j/mol
j/mol
j/mol
j/mol
j/mol

Cp r2=
CpMESA=
Cp NaOH=
Cp HMS=
Cp H2O=

725.09
2019.167513
680.32
-4031.78702

j/mol
j/mol
j/mol
j/mol

391601.4
870225.4
116666.7
20800.71
326242.5
329199.3
845333.2
8660.244
49199.29
20800.71
329199.3

mol/h
mol/h
mol/h
mol/h
mol/h
mol/h
mol/h
mol/h
mol/h
mol/h
mol/h

T = 1000 C

mol/h
mol/h
mol/h

700000
350000
9000000

10050
700
350
9000

N4
SO2
O2
N2

T1=
T2=
Tstandar=

0.069651741
0.034825871
0.895522388

-26815920.4
-6703980.1
-4432835821
-4.47E+09
-4.48869E+13

1273
723
298

Cp SO2=
CpO2=
CpN2=

-385000000
-192500000
-4950000000

dQ/dT=

-4.48869E+16 j/mol.K
-4.48869E+13 kj/mol.K

Cooler

T=450 c

SO2
O2
N2

1000
350
9000

N10
SO3
T=

N9
SO3
T=
T1=
T2=
Cp SO3=

280

280000

280

280000 mol/h

120 C

87 C
360
393
9.24E+06 2.59E+09 dQ/dT=

2.5872E+12 j/mol.K
2587200000 kj/mol.K

ME
H2O
cH3Oh
MES
disalt

T=

60 C

N15
MES
ME
disalt

T1=
T2=
T3=

333
418
418

Cp H2O=
788336089.3
CpCH3OH= 425202623.5
dQ/dT=

1.64614E+15 j/mol.K
1.64614E+12 kJ/mol.K

t=

T standar=

CpME=
CpMES=

298

48766752
137605388

145 c

Nin H2O=
Nin CH3OH=
Nin ME=
Nin MES=
Nin disalt=
cp disalt=
8694781.973

T=

145 C
h2o
ch3oh

2879.268
1567.269
845.3332
116.6667
329.1993
20.80071

1567269
845333.2
116666.7
329199.3
20800.71

mol/h
mol/h
mol/h
mol/h
mol/h

0.544329
0.293593
0.04052
0.114334
0.007224

429113985.4
124836539.9
1976006.891
15733022.56
62813.74714
5.72E+08
1.64614E+12

N15
CH3OH
T=

T=

H2O
CH3OH

T1=
T2=
T3=

145 C

1567.268567 1567269 j/mol

418
333
333

Cp H2O=
388682604.7
CpCH3OH= 209642645.4
dQ/dT=

7.86388E+14 j/mol.K
7.86388E+11 kj/mol.K

N16
H2O

66 C

N14
H2O
CH3OH

55261.5 kg/h
28210.83 kg/h
27050.66 kg/h

2412.602 kmol/h
1567.269 kmol/h
845.3332 kmol/h

0.510497
0.489503

198421340
102620684
3.01E+08
1.66E+13

T=

66 C

N16
CH3OH
H2O

49.1992895
24.2174629

T=

T=

N8
CH3Oh
H2O

40 C
T1=
T2=
T3=

Cp CH3OH=
Cp H2O=

49199.29 mol/h
24217.463

25 C

N15
CH3OH

845.3332

845333.2 mol/h

339
298
313

3.17E+08 2.68E+11 dQ/dT=

2.83267E+14 j/mol.K
2.83267E+11 kJ/mol.K

N12
NaOH
H2O

T= 99 C

T=
F10
NaOH
H2O

25 C

76.37335 76373.35 mol/h

T1=
T2=
T3=

298
339
372

391.6014
870.2254

391601.4 mol/h
870225.4 mol/h

T=

66 C

N16
H2O

Cp H2O=
CpNaOH=

5.20E+08 8.15E+11
28410844.04

dQ/dT=

8.19036E+14 j/mol.K
8.19036E+11 kj/mol.K

1567.269

1567269

25-70
n2
o2

T= 25 C

T= 70

700000

T1=
T2=
Cp S=
dQ/dT=

298
343
3.15E+07
2.205E+13
22050000000 kj/jam

2.21E+10

700

700000 j/mol