Ammonia Refrigeration Bk1 PDF en
Ammonia Refrigeration Bk1 PDF en
Ammonia Refrigeration Bk1 PDF en
Refrigeration
Systems
About WorkSafeBC
WorkSafeBC (the Workers’ Compensation Board) is an independent provincial statutory agency
governed by a Board of Directors. It is funded by insurance premiums paid by registered employers and
by investment returns. In administering the Workers Compensation Act, WorkSafeBC remains separate
and distinct from government; however, it is accountable to the public through government in its role of
protecting and maintaining the overall well-being of the workers’ compensation system.
WorkSafeBC was born out of a compromise between B.C.’s workers and employers in 1917 where
workers gave up the right to sue their employers or fellow workers for injuries on the job in return for a
no-fault insurance program fully paid for by employers. WorkSafeBC is committed to a safe and healthy
workplace, and to providing return-to-work rehabilitation and legislated compensation benefits to
workers injured as a result of their employment.
Phone 604 276-3100 in the Lower Mainland, or call 1 888 621-7233 (621-SAFE) toll-free in British Columbia.
To report after-hours and weekend accidents and emergencies, call 604 273-7711 in the Lower Mainland,
or call 1 866 922-4357 (WCB-HELP) toll-free in British Columbia.
Phone 604 660-6286 in the Lower Mainland, or call 1 866 566-7233 (566-SAFE) toll-free in British Columbia.
Ammonia in
Refrigeration
Systems
WorkSafeBC Publications
Many publications are available on the WorkSafeBC web site. The Occupational Health and Safety
Regulation and associated policies and guidelines, as well as excerpts and summaries of the Workers
Compensation Act, are also available on the web site: WorkSafeBC.com
Online ordering: WorkSafeBC.com and click on Publications; follow the links for ordering
© 2007 Workers’ Compensation Board of British Columbia. All rights reserved. The Workers’
Compensation Board of B.C. encourages the copying, reproduction, and distribution of this document
to promote health and safety in the workplace, provided that the Workers’ Compensation Board of B.C.
is acknowledged. However, no part of this publication may be copied, reproduced, or distributed for
profit or other commercial enterprise, nor may any part be incorporated into any other publication,
without written permission of the Workers’ Compensation Board of B.C.
Previously published 1988 under title: Ammonia in refrigeration systems : manual of standard practice.
Publisher’s original name, Workers’ Compensation Board of British Columbia, also appears on
publication.
ISBN 978-0-7726-5881-4
1. Ammonia - Safety regulations - British Columbia - Handbooks, manuals, etc. 2. Liquid ammonia
- Safety regulations - British Columbia - Handbooks, manuals, etc. 3. Refrigeration and refrigerating
machinery - Safety regulations - British Columbia - Handbooks, manuals, etc. 4. Refrigeration and
refrigerating machinery - Maintenance and repair - Safety regulations - British Columbia - Handbooks,
manuals, etc. 5. Industrial safety - British Columbia. I. WorkSafeBC. II. Workers’ Compensation Board
of British Columbia. III. Title: Ammonia in refrigeration systems : manual of standard practice.
WorkSafeBC wishes to thank the following organizations and their representatives for their assistance
in preparing this manual:
British Columbia Safety Authority
Recreational Facilities Association of British Columbia
City of New Westminster
City of Vancouver
City of Coquitlam
City of Richmond
Canadian Fishing Company Ltd.
D & C Refrigeration Ltd.
ICI Canada
Introduction.................................................................................................................. 1
What is ammonia?......................................................................................................... 3
Hazards of ammonia..................................................................................................... 4
Health.............................................................................................................................................................4
Fire.................................................................................................................................................................5
Corrosive action.............................................................................................................................................5
Employer responsibilities............................................................................................. 6
Health and safety program............................................................................................................................6
Written safe work procedures........................................................................................................................6
WHMIS program......................................................................................................................................7
Exposure control plan...............................................................................................................................7
Respirator program (personal protective equipment)...............................................................................7
Written emergency procedures.................................................................................................................8
Written preventive maintenance procedures............................................................................................8
Checking on a worker working alone.......................................................................................................8
Training, instruction, and supervision..........................................................................................................9
Investigating accidents.............................................................................................. 16
First aid.................................................................................................... 29
Ammonia inhalation........................................................................................................................... 29
Skin contact......................................................................................................................................... 29
Eye contact........................................................................................................................................... 30
This manual is mainly for two groups: employers whose business includes the
use of ammonia as a refrigerant (in ice rinks or ice-manufacturing plants, for
example), and workers who work with or around ammonia, including those
who repair or maintain ammonia systems. Employers will find information
on what they need to do to comply with the Occupational Health and Safety
Regulation and to ensure a safe environment both for workers and for
communities around facilities in which ammonia is stored or used. Workers
will find information that will help them work safely around ammonia.
Engineers and architects will also find information on building design for
facilities in which ammonia is to be used or stored.
This manual does not replace the Occupational Health and Safety
Regulation. It complements the Regulation and is a tool to help industry
work safely. In this manual, the word must means that a particular safety
step is specified in the Occupational Health and Safety Regulation. The
word should indicates that a particular action, although not specified in
the Regulation, will improve safety in the workplace. Please note also that
the word worker includes supervisors, managers, and workers.
Health
Hazard alert: Do
not heat ammonia Ammonia gas is very irritating to the eyes, nose, and respiratory system,
systems which makes it easy to detect low concentrations in the air. Because the
gas is physically irritating, it is unlikely that any person will remain in an
Never apply heat to area contaminated with a detectable concentration of ammonia, unless the
any part of an ammonia
person is trapped or unconscious.
system containing
liquid ammonia. The If you have been exposed to ammonia repeatedly, however, your ability
immediate increase in
to smell it may be significantly reduced. Workers who have worked
pressure can rupture
the tank or pipe. regularly with ammonia have shown decreased ability to detect its odour
at concentrations immediately dangerous to life and health (IDLH).
Note The IDLH exposure level is the point at which a person without
appropriate respiratory protection could be fatally injured or could suffer
irreversible or incapacitating health effects.
Ammonia concentration
(parts per million) Effect
2–55 ppm Normal range of odour threshold*
Written exposure control plans explain the work procedures and other
controls that will be used to reduce workers’ risk of exposure to ammonia.
Strict adherence to ammonia exposure limits and appropriate respiratory
and skin protection are essential elements of such a plan. Employers must
also ensure that qualified persons perform a formal risk assessment to
determine which workers may be affected by exposure to ammonia and
the extent of any exposure. For more information about the elements of
exposure control plans, see Section 5.54 of the Regulation.
Employers must ensure that workers are trained in proper use and care of
respirators. Employers must also provide fit-testing (using a WorkSafeBC-
accepted protocol, such as described in CSA Standard Z94.4-02) when a
worker is first fitted with a respirator, and once a year thereafter. (One
type of test, the qualitative fit-test, determines if the worker can detect
any amount of a test compound leaking through the respirator.) Employers
must keep records of the fit-test program. Fit-test kits are available from
respirator suppliers.
Employers must also include plans for testing and replacing, where
required, all ancillary (secondary) safety equipment, such as monitors and
alarm systems, detection equipment, radios, eye washes, respiratory and
skin protection equipment, and first aid kits. To ensure that nothing is
missed, employers may find it useful to develop checklists for inspecting
and testing equipment. All use and maintenance of safety equipment
must be recorded in a suitable log book.
Some tasks that require written safe work procedures include (but are not
Hazard alert: limited to):
Lack of written •• Cylinder hookup
procedure results in •• Leak detection and control
ammonia leak •• Draining the chiller
A heavy buildup •• Checking on a worker working alone
of ice had formed •• Respirator program
on the outside of •• Disposal of damaged containers
the main ammonia •• System shut-down procedure
feed-line. One of the •• Routine maintenance of equipment (such as pumps and piping)
maintenance staff
was told to remove Written safe work procedures must be detailed and complete, and must
the ice. There was not assume that the worker will know or remember any unlisted tasks.
no written safe work The following examples demonstrate the amount of detail required.
procedure, so the
employee attempted These examples will not apply to all worksites. Employers must create
to break the ice away their own detailed, written safe work procedures to suit each individual
with an axe. He hit a worksite.
pipe elbow, snapping
it off and releasing
liquid ammonia into the Example 1: Leak detection and control
area. The emergency
procedures had to be Situation 1: A minor leak occurs during routine operation (with an alarm system
activated, and the plant in place).
was evacuated. •• If the alarm has been activated, leave the area and follow emergency
procedures.
•• If the alarm has not been activated (for example, when ammonia
concentration is less than 35 ppm), follow these steps:
1. Moisten a strip of indicator paper with water (see notes on next
page), then check for the approximate area of the leak.
2. After locating the approximate area of the leak, use fresh strips of
indicator paper to determine the exact source of the leak.
3. Do not attempt to stop the leak until a second worker is present.
4. Put on appropriate respiratory protection (see the respirator
selection table, page 27).
5. Perform minor maintenance to stop the leak (for example, tighten
the flange).
6. Wait a few minutes, then re-test the leak with indicator paper.
7. If minor procedures do not stop the leak, initiate the shutdown
procedure to prepare for repair.
Situation 2: A minor leak occurs during routine operation (with no alarm system
in place).
1. If you smell ammonia and/or feel eye irritation, leave the area.
2. Notify the supervisor.
3. Wearing appropriate respiratory protection (see the respirator
selection table, page 27), measure the airborne ammonia
concentration using a detector tube.
4. Moisten a strip of indicator paper with water (see notes below),
then check for the approximate area of the leak.
5. After locating the approximate area of the leak, use fresh strips of
indicator paper to determine the exact source of the leak.
6. Perform minor maintenance to stop the leak.
7. Wait a few minutes, then re-test the leak with indicator paper.
8. If minor procedures do not stop the leak, initiate the shutdown
procedure to prepare for repair.
Notes
1. The indicator paper contains phenolphthalein — do not attempt to
moisten the strip using your mouth.
2. Indicator paper can be used only for detecting leaks, not for measuring
airborne ammonia concentrations. The indicator paper changes colour
to pink when near ammonia. The colour change is slow at 6 ppm and
moderately quick at 15 ppm.
3. Do not store indicator paper in the machine room.
4. If the exhaust ventilation is not automatically triggered (see Ventilation,
page 22), the designated supervisor will determine when it is safe to
ventilate the contaminated area.
Preparing for emergencies includes planning for ammonia spills that may
require procedures such as evacuation and notification of local emergency
response units. The preparation required for these types of emergencies is
detailed below under Written emergency procedures.
As soon as the written emergency procedures are created, the employer must:
•• Provide each worker with a copy of the plan, and provide enough
training to ensure that workers clearly understand the procedures
•• Post the procedures and other relevant information (such as telephone
numbers) in appropriate, conspicuous locations
•• Conduct regular tests of the procedures, including drills
•• Notify the fire department and other emergency response units of any
specialized information
Employers must follow these requirements for eye wash and shower facilities:
•• Ensure that the facilities have a supply of tempered water — not running
cold water. Ensure that workers cannot mistakenly turn on hot water alone.
•• Determine the most appropriate location for emergency equipment. It
is not appropriate, for example, to install emergency equipment in the
machinery room.
•• Take into account the geographical location of the facility when deciding
whether or not an outdoor location will be practicable during the winter.
•• Do not locate emergency equipment where the public may access and
possibly damage it.
Workers must have immediate access to an appropriate first aid kit at each
ammonia location. To determine the appropriate first aid kit required for
a particular worksite, see Part 3 of the Occupational Health and Safety
Regulation.
Any time enough ammonia is released to set off the alarm, the employer
must conduct a formal investigation to discover the causes of the accident.
This investigation must also examine measures that will prevent similar
situations in the future. Employers must forward copies of the investigation
report to their occupational health and safety committee and to WorkSafeBC.
This section will be useful to anyone who works with or around ammonia.
It includes information on storing ammonia, handling ammonia, and
repair and maintenance of ammonia systems.
Storing ammonia
Liquid ammonia is stored in a variety of containers: cylinders, pressure
vessels, and tank trucks. This section describes what you must and must
not do when storing ammonia.
Note All ammonia and refrigeration equipment must meet the requirements
of the Safety Standards Act, the Electrical Safety Regulation, the Power
Engineers, Boiler, Pressure Vessel and Refrigeration Safety Regulation (PEBPV
and RSR), and applicable CSA standards (such as B52-05 and B339-02).
Signage
•• Use signs to clearly identify all ammonia storage areas. Only qualified
personnel are permitted to enter an ammonia storage area.
•• Indicate the total weight of ammonia contained in the system using a
readable, accessible sign.
•• Do not allow the amount of stored ammonia to exceed 136 kg (300 lb.)
or 20 percent of the normal ammonia charge (total amount in system),
whichever is less.
•• Store ammonia cylinders and containers in a cool, dry, and relatively
isolated area, protected from weather and extreme temperatures. If
cylinders and containers are stored outside, shield them from direct
sunlight unless they are specifically designed for unshaded, outdoor
storage.
Note Never apply heat to containers or their valves.
•• When storing inside, store ammonia cylinders and containers in a
well-ventilated building, away from any heat sources. Never allow
cylinders and containers to reach 50°C.
Housekeeping
•• Do not store materials that may react violently with ammonia (for
example, iodine, bromine, chlorine, calcium, gold, mercury, silver, and
hypochlorite bleaches) in the same room as ammonia.
•• Do not block access to emergency equipment and doors.
•• Use cylinders on a “first-in, first-out” basis.
Empty cylinders
•• Clearly tag or mark empty cylinders, and separate them from full
cylinders.
•• Do not consider cylinders or other ammonia system containers empty
and safe until they have been thoroughly purged with nitrogen, steam,
or water.
Fire precautions
Handling ammonia
This section describes what you must and must not do when handling
ammonia.
Moving cylinders
Valves
•• Ensure that cylinders have valve protection hoods in place when not
connected to a system.
Machine rooms
Consider the following points for Class “T” ammonia machine rooms:
•• The room must not contain any permanently installed flame-
producing devices or hot surfaces over 427°C.
•• The room’s walls, floor, and ceiling must be sealed from the rest of
the building and must be constructed to have at least a one-hour
fire-resistance rating. All pipe openings must also be sealed.
•• At least one exit door must open to the outside of the building. Any
exit to another area in the building must be through a vestibule
equipped with approved self-closing, tight-fitting fire doors.
•• Exterior openings must not be under any fire escape or open stairway.
•• Emergency controls to shut down the mechanical equipment must be
located outside the machine room.
Ventilation
A suitable fan must ventilate the machine room and storage rooms. All
ventilating fans must provide at least 15 air changes per hour, and must have
switches outside the machine room even when an inside switch is installed.
Because ammonia gas is lighter than air and tends to collect at ceiling
level, the suction of ventilating fans must be at or near ceiling level. Air
inlets must be located to provide cross-ventilation using outside air.
Ammonia must not be discharged into areas where it may cause damage
or injury, such as schools, worksites, private homes, or shopping centres.
Ventilation exhaust must not be positioned where it can be captured by
the air intake system of the same or another building.
Administrative control
Monitoring/alarm systems
The continuous monitor needs to have a direct readout that can be seen from
outside the enclosed hazard area. A digital readout is preferable, but a needle/
scale is acceptable. The readout ensures that emergency response personnel
know the actual concentration inside the enclosure. Knowing that the leak has
developed an atmosphere below 35 ppm, between 35 and 300 ppm, or above
300 ppm allows emergency response personnel to make an informed decision
with respect to the proper respiratory protection to be worn.
Without a direct readout from the monitor, every leak must be considered
IDLH, as the ammonia concentration is unknown. This requires SCBA to
be worn, with emergency backup, as outlined in the detailed emergency
response procedures.
It is also important to determine what other gases may activate the alarm.
You may need a more selective system if interfering compounds may be
present in the facility. Equipment suppliers and other alarm system users
can provide more information.
– The system must include a visible and audible alarm at the ammonia
location, preferably connected to a radio or telephone system to alert the
operator in case of an emergency.
Detector tubes
Eye protection
Skin protection
Workers who are controlling any liquid ammonia leak must have access
to full-body protective suits. This equipment must also be available to
workers exposed to airborne ammonia concentrations above 300 ppm for
more than a few minutes, which causes immediate irritation of moist body
areas. (Ammonia reacts instantly with moisture.)
Respiratory protection
This section outlines the types of respirators available to protect workers from
exposure to ammonia, and the limitations of each respirator. Choosing the
right respirator must be based on both the needs of each individual worksite
and the requirements of the employer’s written safe work procedures.
Notes
1. If the concentration of ammonia is greater than 300 ppm, cartridges
or canisters cannot be worn, and a self-contained breathing apparatus
(SCBA) must be used.
2. Canisters with an indicator window must be replaced when the
material in the window has changed colour. Canisters or cartridges
without an indicator window must be replaced after each use. In either
case, canisters must never be used after the expiration date stamped
on the label.
Escape respirators
Two types of escape respirators are acceptable: bite-block respirators and
half facepiece cartridge respirators. Bite-block respirators must be worn
with a nose plug. Anyone entering an ammonia enclosure for any reason
must carry an escape respirator and keep it within arm’s reach at all times.
Person-check radio/telephone
Emergency equipment includes eye wash and shower facilities and first
aid kits. Workers must have immediate access to each of these items and
must know how to use them in case of emergency. Emergency equipment
is covered in more detail on page 14. For first aid information, see page 29.
Ammonia inhalation
Someone who has inhaled ammonia may be unconscious, and may have
difficulty breathing or may have stopped breathing completely. Follow
these steps when treating a victim of ammonia inhalation: Unconscious patients
1. Assess the victim’s breathing: As soon as they
• If breathing has stopped, begin artificial respiration and continue resume breathing,
until the victim resumes breathing. (Mouth-to-mouth and pocket always place
masks are the most effective methods of artificial respiration.) unconscious patients
• If the victim is having difficulty breathing (gasping, coughing), place in the drainage
the victim in the most comfortable position, usually semi-sitting. position (on their side,
2. If an oxygen therapy unit and trained personnel are available, so fluids can drain
from the mouth and
administer oxygen at a 10-litre flow.
airways). Never give
3. Ensure that the victim is transported to hospital in case the victim an unconscious patient
suffers a delayed reaction in the form of pulmonary edema. Any anything by mouth.
physical exertion, excitement, or apprehension increases the chances
and severity of a delayed reaction. Keep the victim warm and
completely at rest. Reassure the victim while waiting for assistance
and transportation to hospital by ambulance.
Skin contact
Skin contact with ammonia can result in severe — even fatal — burns.
Before attempting to flush a victim’s contaminated skin, make sure the
victim is breathing properly. Follow these steps:
1. Assess the victim’s breathing:
• If breathing has stopped, begin artificial respiration and continue
until the victim resumes breathing. (Pocket masks are recommended
for artificial respiration, although the mouth-to-mouth method may
also be used.)
Notes
1. Do not attempt to neutralize the ammonia with other chemicals.
2. Do not apply salves, ointments, or medications unless prescribed by a
doctor.
3. Skin contact with liquid ammonia or an ammonia gas stream leaking
under high pressure can cause frostbite. Pure liquid ammonia can
cause severe burns.
Eye contact
Eye contact with liquid ammonia for even a short period can cause
permanent disability such as blindness. Flushing must begin within 10
seconds. Follow these steps:
1. Flush the eyes immediately with large amounts of running water
(preferably lukewarm) if:
• Any amount of liquid ammonia has entered the eyes
• Exposure to gaseous ammonia causes persistent eye irritation
2. Hold the eyelids apart forcibly to ensure full flushing of the eyes and
eyelids.
3. After flushing has removed all traces of ammonia, cover both eyes with
moistened sterile gauze pads and bandage enough to keep light out.
4. Apply insulated cold packs to help reduce pain.
5. Call for an ambulance to take the victim to a hospital.
Notes
1. Do not attempt to neutralize the ammonia with other chemicals.
2. Do not apply oils, ointments, or medications to the eyes.
Coquitlam Surrey
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Phone 604 276-3100 Phone 604 276-3100
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