L4 Entropy

CHEMISTRY 163 EXPERIMENT NO.
4 LAB OF “GREATER” DISORDER
ENTHALPY, GIBBS ENERGY, & ENTROPY!

(A very disorderly lab)
Introduction:
Reactions in nature are driven by two forces, which in combination determine whether or not the reaction will
be spontaneous. Recall, reactions that are exothermic (give off heat) are generally favored by nature.
However, some endothermic reactions, such as the melting of ice, are spontaneous and thus favored by
nature. The second driving force that also determines whether or not a reaction will occur is entropy.
Entropy can be defined as a measure of the degree of randomness of the particles, such as molecules, in a
system. Nature favors an increase in entropy. In other words, reactions that increase the disorder of the
system tend to be spontaneous. The amount of entropy of a system is best understood by considering the
three principle states of matter. In a solid, the particles vibrate in place and are not free to switch places
with each other. As such, solids are considered to have very low entropy because very little randomness
exists in them. Liquids, in general, are more disorderly than solids, and thus have higher entropy. Gases, the
most disorderly of the three states possesses the highest entropy. These are general guideline as some
liquids (mercury, for instance) have lower entropy than certain solids. In general, the dissolution process
increases the entropy of a system. Entropy of substances can be determined quantitatively in the lab and are
measured in molar values with units kJ/(mol·K). We will be most concerned with the change in entropy of
a system, denoted as S.
Gibbs Free Energy

Reactions in nature tend toward decreasing enthalpy and increasing entropy. A reaction that is exothermic and
increases entropy will always be spontaneous. An endothermic reaction decreases the randomness of the system
will never be spontaneous. Consider reactions that decrease enthalpy but decrease entropy, or increase entropy
but increase enthalpy? Will these reaction be spontaneous? That depends on the temperature. To predict this, we
must look at Gibbs Free Energy. Mathematically, Gibbs free energy relates the enthalpy and entropy changes of
a reaction: G = H - TS
0 0 0
If the Gibbs Free Energy of a reaction is negative, then the reaction will be spontaneous, if positive, then the
reaction will not be spontaneous.
Objectives: 1. To measure enthalpy 2. To calculate entropy 3. To calculate Gibbs Energy

4. To study reactions and determine the driving forces behind the reactions
Lab Hints
We will define our system as the solid crystalline compound that will be dissolving. Then, our surroundings
become the water, which we record the temperature changes during the process. If the temperature of the
water increases, this means the system released heat (-q) to the water, so, the reaction is exothermic.
If the temperature of the water decreases, this means the system absorbed heat (+q) from the water, so, the
reaction is endothermic.
Define in this experiment, what is the system? _____________________
, what is the surroundings? ___________________

PROCEDURE – Disorder
ALL TEMPERATURE MEASUREMENTS SHOULD BE TAKEN WITH THE UTMOST CARE
Set up Lab Quest with Temperature Probe

LabQuest Set – Up
1. Assembly LabQuest with AC power source, turn on
2. Connect temperature probe in a top channel, flash drive in USB drive
3. Set “length” to 600 sec. or longer. “OK”
Reaction 1
1. Measure 60.0-mL of distilled water and place into the calorimeter. Place the temperature probe into the
calorimeter to obtain a constant temperature. Record this as the initial temperature
2. Weigh 10.000 g ammonium nitrate solid. Record exact weight
3. Start LabQuest when temperature in calorimeter is constant; next add the solid crystals to the calorimeter
4. Gently mix till all solid crystals are dissolved completely
5. Keep recording the temperature curve till the temperature stabilizes. Record as the final temperature
6. In calculations, assume that the calorimeter loses only a negligible quantity of heat, density of the solution is
1.00 g/mL. Since adding the crystals doesn’t change the volume noticeably, assume the mass of solution to be
equal to the volume of water
7. Record and save the temperature graph on the flash drive. Print out graph using LoggerPro program
Reaction 2
1. Measure 60.0-mL of distilled water and place into the calorimeter. Place the temperature probe into the
calorimeter to obtain a constant temperature. Record this as the initial temperature
2. Weigh 5.000 g sodium hydroxide pettets. Record exact weight
3. Start Lab Quest when temperature in calorimeter is constant, then add the solid to the calorimeter
4. Gently mix till all solid pellets are dissolved completely
5. Keep recording the temperature curve till the temperature stabilizes. Record as the final temperature
6. In calculations, assume that the calorimeter loses only a negligible quantity of hear, density of the solution is
1.00 g/mL. Since adding the crystals doesn’t change the volume noticeably, assume the mass of solution to be
equal to the volume of water
7. Record and save the temperature graph on the flash drive. Print out graph using LoggerPro program
NAMES _____________________________________ Chem. 163 Spr ’16 Lab. #4
DATA TABLE – Entropy, Gibbs
REACTION 1
Initial Temp _________ Change in Temp _________ Mass of Water _________
Final Temp __________ Mass of Solid _________ Mass of Solution _________
Write the thermochemical equation for the reaction:
CALCULATIONS pay attention to the required label
Step 1: H Calculate Heat produced in the reaction
____________ kJ
Step 2: Calculate the number of moles of solid used
____________ moles
Step 3: Calculate Heat produced per 1 mole of solid
____________ kJ/mol
Step 4: Rewrite thermochemical equation with correct H value and sign expressed
Step 5: Calculate S, use standard entropy values

Rxn Species Entropy Value
Reactant
Product
Product
S ___________ J/molK S ___________ kJ/molK

Step 6: G Calculate Gibbs Energy
G ___________ kJ/mol
REACTION 2
Initial Temp _________ Change in Temp _________ Mass of Water _________
Final Temp __________ Mass of Solid _________ Mass of Solution _________
Write the thermochemical equation for the reaction:
CALCULATIONS pay attention to the required label
Step 1: H Calculate Heat produced in the reaction
____________ kJ
Step 2: Calculate the number of moles of solid used
____________ moles
Step 3: Calculate Heat produced per 1 mole of solid
____________ kJ/mol
Step 4: Rewrite thermochemical equation with correct H value and sign expressed
Step 5: Calculate S, use standard entropy values

Rxn Species Entropy Value
Reactant
Product
Product
S ___________ J/molK S ___________ kJ/molK

Step 6: G Calculate Gibbs Energy
G ___________ kJ/mol
CONCLUSION: for each reaction NH4NO3 Rxn NaOH Rxn
1. Is process exothermic or endothermic? Rxn 1___________ Rxn 2 ____________
2. Does entropy decrease or increase? Rxn 1___________ Rxn 2____________
3. Is Gibbs Energy positive or negative? Rxn 1___________ Rxn 2 ____________
4. Is this process spontaneous or nonspontaneous? Rxn 1 ___________ Rxn 2 ____________
5. Use Standard Thermodynamic Values to calculate Gibbs Free Energy for the reaction of dissolving potassium
sulfate in water at 25OC. Do the calculations in 2 ways. Remember to include the correct number of potassium
ions present in solution
Fill in chart with Reaction Species & Standard Thermodynamic Values

Species G kJ/mol H kJ/mol S J/mol-K S kJ/mol-K
Reactant
Product
Product
a) Use standard enthalpy of formation, H & S, and use the same formula as in the reactions, G = H - TS
H =
S =
after you have calculated both H & S, use those values to calculate G
G =
b) Use standard free energies of formation and equation, G = Gpdts - Greacts
G =
6. Print out temperature curves from LoggerPro and attach to finished lab report

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CHEMISTRY 163 EXPERIMENT NO.

4 LAB OF “GREATER” DISORDER

ENTHALPY, GIBBS ENERGY, & ENTROPY!

Gibbs Free Energy

Objectives: 1. To measure enthalpy 2. To calculate entropy 3. To calculate Gibbs Energy

Define in this experiment, what is the system? _____________________

, what is the surroundings? ___________________

Set up Lab Quest with Temperature Probe

Initial Temp _________ Change in Temp _________ Mass of Water _________

Final Temp __________ Mass of Solid _________ Mass of Solution _________

Write the thermochemical equation for the reaction:

CALCULATIONS pay attention to the required label

Step 1: H Calculate Heat produced in the reaction

Step 5: Calculate S, use standard entropy values

S ___________ J/molK S ___________ kJ/molK

Initial Temp _________ Change in Temp _________ Mass of Water _________

Final Temp __________ Mass of Solid _________ Mass of Solution _________

Write the thermochemical equation for the reaction:

CALCULATIONS pay attention to the required label

Step 1: H Calculate Heat produced in the reaction

Step 5: Calculate S, use standard entropy values

S ___________ J/molK S ___________ kJ/molK

1. Is process exothermic or endothermic? Rxn 1___________ Rxn 2 ____________

2. Does entropy decrease or increase? Rxn 1___________ Rxn 2____________

3. Is Gibbs Energy positive or negative? Rxn 1___________ Rxn 2 ____________

4. Is this process spontaneous or nonspontaneous? Rxn 1 ___________ Rxn 2 ____________

Fill in chart with Reaction Species & Standard Thermodynamic Values

b) Use standard free energies of formation and equation, G = Gpdts - Greacts

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Initial Temp _____ Change in Temp _ Mass of Water _____

Final Temp ______ Mass of Solid _ Mass of Solution _____

S _ J/molK S _ kJ/molK

Initial Temp _____ Change in Temp _ Mass of Water _____

Final Temp ______ Mass of Solid _ Mass of Solution _____

S _ J/molK S _ kJ/molK

1. Is process exothermic or endothermic? Rxn 1_ Rxn 2 __

2. Does entropy decrease or increase? Rxn 1_ Rxn 2__

3. Is Gibbs Energy positive or negative? Rxn 1_ Rxn 2 __

4. Is this process spontaneous or nonspontaneous? Rxn 1 _ Rxn 2 __