Anod Magneziu Hot Water Heater Anodes and Rust Protection

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The key takeaways are that sacrificial anodes are critical for protecting water heaters from corrosion and extending their lifespan. However, few people are aware of what they are and how they work.

A sacrificial anode is a rod made of magnesium or aluminum that is screwed into the top of a water heater tank. It protects the steel of the water heater tank from corroding through an electrochemical process where the anode corrodes instead of the steel tank.

The lifespan of a sacrificial anode depends on factors like water quality, amount of water heater use, water temperature, and water heater construction quality. Softer water and greater water heater use cause anodes to corrode more quickly.

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What you'll find on this page: Most people have never heard of
sacrificial anodes, even though they have been a key to water
heater longevity for decades. This may be the single most
important page on this site. It won't take you too long, so read
these words even if you skip everything else!

The single most important factor in whether a water heater lives or dies is
the condition of its sacrificial anode. For more than 60 years, it has been used
as a key part of the rust protection of a tank, although few people know it's
there.

This is a rod made of magnesium or aluminum that's formed around a steel


core wire and is screwed into the top of the tank. A six-year-warranty
residential tank will have one, while a 12-year-warranty tank will have two, or
an extra-large primary anode. Commercial tanks have from one to five.
Special aluminum/zinc sacrificial anodes or powered (impressed-current)
anodes can be used to resolve odor problems caused by bacteria in some
water. But if you have a vacation home where the water heater sits idle for
long periods of time, using them may not be a solution. Click here if that is an

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issue.

When the tank is filled with water, an


electrochemical process begins whereby sacrificial
anodes are consumed to protect a small amount of
exposed steel. Powered anodes replace that process
with electricity and are not consumed.

When two metals are physically connected in


water, one will corrode away to protect the other.
Sometimes that's bad, but often it's good. Although
few people have heard of this, the principle is used
all over the place -- anywhere that someone wants to
protect metal exposed to water. In marine
applications, anodes are known as "zincs" and are
usually made of that metal.

All metals fall somewhere on the galvanic scale of reactivity. When two are
placed together in water, the "nobler" -- or less reactive -- one will remain
intact while the more reactive one corrodes. When steel and copper are
together, steel will be the one that corrodes. Indeed, steel is more likely to rust
in the presence of copper than it would have been by itself. That's why
dielectric separation is necessary on items like copper flex lines when they're
connected to steel nipples.

Magnesium and aluminum are less noble than steel, which is why they're
used for anode rods.

Remember, the anode is screwed into the tank. That means it can be
unscrewed and replaced.

A sacrificial anode's life depends on the quality of the water, the amount of
use the tank gets, the water temperature, and the quality of the tank --
meaning how well it was constructed. When salt is added to the water (as in
softened water), anodes corrode more quickly. Water softeners help reduce
sediment, but anodes can corrode in as little as six months if the water is
over-softened. Do not soften to zero. Leave 50-120 ppm of hardness. This may
require some plumbing to add unsoftened water to softened water.

People occasionally ask us if pipe-seal tape applied to the threads of the


anode blocks the electrolytical reaction. Tanks we've serviced repeatedly
usually have corroded anodes. We've tested with a multimeter and found
continuity between the anode and the tank, despite the tape.

While we generally advocate putting two anodes in a tank, that may not be a
good idea if you have odor problems. Doubling the anode surface area may
worsen odor even when special aluminum/zinc anodes are used that reduce
or eliminate the odor.

If you have odor and soften, or for that matter, merely if you soften, consider
getting a powered anode that replaces the sacrificial reaction with electric
current and isn't consumed through use.

If you contemplate adding an anode to a new tank, make sure both rods are

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of the same metal. Otherwise, the


magnesium rod will be consumed more
rapidly in the presence of an aluminum one
and you won't get as long a life. How do you
tell them apart? In nearly all cases, an
aluminum hex head will be flat on top, while
a magnesium rod will have a bump, as in the
photo at right. The size of the bump may
vary, but bump, magnesium; no bump, probably aluminum. And all that said,
the latest shipment of aluminum/zinc anodes we bought had hex heads with
bumps! We thought we'd been sent the wrong stuff, but verified that it's really
aluminum/zinc.

The exception to that is Rheem and its sub-brands, Ruud/Richmond and


General Electrics made before 2015. As far as we know, Rheem always uses
magnesium even though there is no bump on top of its anodes. On the other
hand, if the tank is five years old or more, having dissimilar metals is less of
an issue, since the original one will likely be largely consumed. Rheem made
GE water heaters under license for a long time, but the rights to the brand
have been sold to a Chinese company, and it's not clear how much that has
changed things.

And there is no way to tell metal type if a tank has a combo rod, but you're
probably going to be replacing it anyway.

As to other brands, as far as we know, American/Whirlpool/Maytag always


uses aluminum anodes. Bradford White may use either aluminum or
magnesium, and many of their tanks have one combo rod in the hot port.
Giant uses magnesium, as does Bock. Heaters made by American Standard
also have magnesium anodes.

Older State/Reliance/Kenmore have had both combo rod tanks and tanks
with a hex anode. More recently, they all seem to have hex anodes. Aluminum
is usually used, but in the past, high-end models have come with magnesium.
Today, some of those also offer powered anodes.

There is one important exception to the anode equation: all Smith, State and
sub-brand ultra low-NOX heaters come with aluminum anodes.

It's common for people to ask us to choose for them. We won't do it; there
are too many variables and many of them are buyer-specific. Occasionally,
also, we're asked to pick a tank that will permit the addition of the parts we
sell that will extend life. Even that has gotten harder because the
manufacturers are rolling out models that meet the April 2015 energy rules.
We may be able to tell you more later, as we see what has changed.

If you decide to remove and check your anode, we'll tell you some of the
possibilities and what they mean.

If there is rough, seemingly chewed-up metal all up and down the rod, that's
normal. It's doing what it's supposed to do. If you can see six inches of the
steel core wire, replace the rod. If all you have IS the steel core wire -- or less
-- then extending the life of the tank by replacing the anode becomes more
iffy. You might still get several more years out of the next anode. Or the tank

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might fail shortly after. It all depends on factors that exist where none of us
can see them.

Passivation: If the rod looks perfectly intact, with no sign of corrosion,


about like the whole one in the picture at the top of the page, then it has
passivated. That means it has sort of gone to sleep. It might not be doing its
job. It's a wild-card situation. We've seen tanks with passivated rods last a
long time. We've seen them break. We're never sure what will happen next,
and apparently none of the experts in this field whom you think might know
are any more certain than we are. Some of the theories have been that it
happens in naturally soft water or that it's because of improperly formulated
anodes. We've seen scenarios that contradict each of these theories. About all
you can do is replace the rod and hope for the best. Or leave it and hope for
the best. Wild-card situation.

There are two configurations of anodes. The first kind is


called a hex-head anode and you can see a couple at the top of
this page. They are found in their own port on top of the tank.
With some brands, the hex head is exposed. On many, it may
be under a plastic cap about halfway in toward the center from
the edge. If there are caps on the edge, they were used to insert
the foam insulation. On some older tanks, it may be hidden
under the sheet-metal top.

The other kind is called a combo or outlet anode, like the one
in the picture at right. It is an anode/hot-water
outlet/plastic-lined steel nipple and is used in the hot-water
port. Often longer-warranty tanks have one hex-head and one
combo rod, although a couple of manufacturers make tanks that have just one
combo rod, with no place for a second one.

If you're adding a combo rod to a Rheem/Ruud/Richmond/GE tank made in


2005 or later, you'll need a special half-length one that is only available from a
plumber affiliated with Rheem. It may be pricey. We were able to stock
full-length ones for awhile, but our source dried up. Do not try to install a
standard combo anode, or you may not have water pressure, due to a redesign
of the tank's hot-water port in 2005.

The test, on older heaters, of whether you have a combo anode or not is to
unscrew the nipple and see if there is an anode connected to it.

Anode rods of all types can be purchased on our Product Page.

Water heaters always come with sacrificial anodes, and that is the most
common type. But not the only type. A powered anode can be a permanent
replacement for a sacrificial one. It replaces the sacrificial reaction by feeding
electrical current into the tank by way of an electrode. The device plugs into a
wall socket. However, it costs several times more than a sacrificial anode. We
often recommend them for smelly water situations where sacrificial anodes
may not help. To learn more about them, go to the Powered Anode Page.

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Water heaters typically come with magnesium or aluminum anodes. We


prefer magnesium. We dislike aluminum for a bunch of reasons. Those are:

First off, aluminum, being lower on the Galvanic Scale than


magnesium, produces less driving current between anode and cathode
(in this case, the tank is the cathode). We think that means it doesn't do
as good a job of protecting the tank, especially in softer waters.
Second, it produces about a thousand times its original volume in
corrosion byproduct, most of which falls into the bottom of the tank as a
sort of jelly, and adds to sediment buildup there.
Third, that gunk also occasionally floats out the hot-water port,
appearing as a cottage cheese-like substance clogging aerators and
filters.
Fourth, the rod actually expands as it corrodes so that it is hard, or
maybe impossible, to remove one a few months after installation
because its diameter is bigger than when it was installed.
Fifth, along with that, it has a tendency to split off from the core wire,
so that chunks fall into the bottom of the water heater, where they stop
being anode and start being junk. That also means that if you try to take
one out at that point, it may split away from the core wire and snag the
underside of the top of the tank, like a fish hook.
Sixth, the build-up of sediment on the bottom of gas heaters
encourages noisy operation, and some people can hear their water
heaters loud and clear at night, which is not helpful for those wishing to
sleep.
Seventh. There is a little booklet "The Danger of Food Contamination
by Aluminum" by Dr. R.M. Le Hunte Cooper. It details the nasty things
aluminum does to the body. The liver, brain, kidneys and spleen seem to
be the main repositories, with nervous tissues holding the most by
weight. It was written in 1932. Modern plumbing allows some water that
came from the heater to be used as cold water. This doesn't matter if
magnesium is used in the heater.
Eighth. If you find yourself ground zero in a disaster, and the water
main is broken, about the last thing you want is to be drinking heavily-
aluminum-laden water from the bottom of your water heater -- the
source of last resort. It could make you sick in dreadful ways: trash your
stomach and intestines, create instant arthritis in your joints. No fun!

But all that said, an aluminum/zinc anode is mostly aluminum, although it


tends to corrode more slowly than pure aluminum. It is the most economical
solution to odor problems if no water-softener is being used. Everything
stated here applies to it. So we suggest that those using that anode, or who
have bought a heater with a pure aluminum anode, especially if they have a
single-control faucet, simply let the cold water run for a few seconds to purge
the line of any cooled-off water from the water heater. That's all it takes.

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