Safe Disposal of Hazardous Wastes Vol I

Public Disclosure Authorized
WORLD BANK TECHNICAL PAPER NUMBER 93
The Safe Disposal of Hazardous Wastes

The Special Needs and Problems of Developing Countries
Volume I ;
Roger Batstone, James E. Smith, Jr., and David Wilson, editors

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A joint study sponsored by the )Vorld Bank,the World Health Organization (WHO),
and the United Nations EnvironmnentProgramme (UNEP).
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The Safe Disposal of Hazardous Wastes

Volume I
A Joint Study
The World Bank World Health United Nations

Organization Environment Programme
WORLD BANK TECHNICAL PAPER NUMBER 93
The Safe Disposal of HazardousWastes

Volume I
Roger Batstone, James E. Smith, Jr., and David Wilson, editors
The World Bank

Washington, D.C.
Copyright Co 1989
The International Bank for Reconstruction
and Development/THE WORLD BANK
1818 H Street, N.W.
Washington, D.C. 20433, U.S.A.
All rights reserved

Manufactured in the United States of America
First printing April 1989
Technical Papers are not formal publications of the World Bank, and are circulated to encourage
discussion and comment and to communicate the results of the Bank's work quickly to the
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Roger Batstone is an industrial risk management specialist in the World Bank's Environment
Department. James E. Smith, Jr., a technical adviser to the World Health Organization, is a senior
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Library of Congress Cataloging-in-Publication Data

The Safe disposal of hazardous wastes.
World Bank technicalpaper, 0253-7494; no. 93)

"A joint study sponsored by the World Bank, the
World Health Organization (WHO), and the United
Nations Envirorment Progranre (UNEP)"
Bibliography: p.
1. Hazardous wastes--Developing countries--Management.
I. Batstone, Roger, 1940- . II. Smith, Janms E.,
1941- . III. Wilson, David, 1952- . iv. world
Bank. V. World Health Organization. VI. United Nations
Environment Prograimne. VII. Series.
TD1045.D44S24 1989 363.7'28 89-5670
ISEN 0-8213-1144-1
v
ABSTRACT
The World Bank, World Health Organization,and United Nations Environment

Programme have cooperated in the preparationand issuance of The Safe Disposal
of Hazardous Wastes. This three-volumemanual is intended for administrators
and technical staff, primarily in developingcountries,who have
responsibilitiesfor waste management, public health and environmental
protection. Informationpresented in this publication includes the
classificationof hazardous waste, its effects on health and the environment,
the planning and implementationof programs in hazardous waste management,
hazardous waste treatment,and disposal technologies,including economic and
institutionalconsiderations.
The main emphasis of this manual is on the management aspects and on the
technologiesthat may be appropriate for implementinga region-widehazardous
waste management program. Case studies from developingcountries have been
incorporatedinto the main text for the purpose of practical illustration.
Sufficient informationfor at least a pre-feasibilityassessmentof various
options for a hazardous waste management program is provided.
A particularlyuseful section of this manual includes the examples of

various operating systems for hazardous waste tracking and disposal,waste
survey questionnairesand techniques, and landfill design and management
practices.
vii
CONTENTS
VOLUME 1
Preface xv
CHAPTER 1. Introduction 1
1.1 What are Hazardous Wastes7 1

1.2 Why are We Concerned with Hazardous Wastes? 1
1.3 Aspects of a Control System for Hazardous Wastes 3
1.4 Previous InternationalEfforts on Hazardous Waste Management 4
1.5 Quantities of Hazardous Waste 5
1.6 Progress in Controlling Hazardous Wastes 5
1.7 Specific Problems of Developing Countries 7
1.8 Purpose of this Manual 8
1.9 Guide to this Manual 9
1.10 References 1.1 - 1.9 10
CHAPTER 2. The Health and EnvironmentalEffects of HazardousWastes 11
2.1 Introduction 11
2.2 Working Definitions 11
2.2.1 Inclusions and Exclusions from the Definition 12
2.3 Identification and Classification of Hazardous Wastes 13
2.4 Proposed Classification Scheme -- Notation of Health/Ecological
Concerns 19
2.5 Potential Pathways of Release to the Environment 24
2.5.1 GroundwaterMovement and Contamination 24
2.5.2 Surface Water Contamination 24
2.5.3 Other Pathways of Release 26
2.6 Factors Affecting the Environmental Behavior of Chemicals 26
2.6.1 Physical and Chemical Factors 27
2.6.2 Degradation of Chemicals 28
2.7 Effects of Hazardous Wastes on Health and the Environment 31
2.7.1 Hazard Identification and Risk Assessment 32
2.8 Degree of Hazard Concept 41
2.9 Environmental Effects of Hazardous Waste Disposal 42
2.9.1 Effects on the Terrestrial Environment 43
2.9.2 Effects on the Aquatic Environment 43
2.10 Summary 43
2.11 References 2.1 - 2.10 44
Annex 2 Waste Types for Proposed ClassificationScheme 45
CHAPTER 3. Planning for Hazardous Waste Management 60
3.1 Introduction 60
viii
3.2 A Framework for Planning 60

3.3 Scope of the Plan (Step 1) 63
3.3.1 Basic Elements to be Considered 63
3.3.2 Types of Waste 63
3.3.3 Components of the System to be Included in the Plan 63
3.3.4 Geographical Limits 65
3.3.5 Choice of Timescale for Plann.ing 65
3.3.6 Government and Industry Responsibilities 66
3.4 Objectives and Constraints (St:ep2) 67
3.4.1 Objectives and Technical Assessment Criteria 67
3.4.2 Constraints 68
3.5 The Key Questions (Step 3) 69
3.6 Information Requirements (Step 4) 70
3.6.1 Introduction 70
3.6.2 Information on Waste Generators 71
3.6.3 Forecasts of Future Waste Generation 75
3.6.4 Information on Existing Treatment and Disposal Methods 75
3.6.5 Information on Potential Options for Recycling, Treatment and
Disposal 77
3.6.6 Market Survey 77
3.7 Review of the Existing Situation (Step 5) 78
3.7.1 Economic Considerations 78
3.7.2 Financial Considerations 79
3.7.3 Institutional Considerations 90
3.7.4 Staffing and Training 96
3.8 Evaluation of Options (Step 6) 96
3.8.2 The Hierarchy of Options 97
3.8.3 Practicable Options 97
3.8.4 Identifying Suitable Options for Particular Types of Waste 98
3.8.5 Evaluation of Options 98
3.9 Site Selection (Step 7) 108
3.9.1 General Principles 108
3.9.2 Siting Factors 108
3.9.3 A Phased Approach to Site Selection 111
3.10 Review and Feedback (Step 8) 111
3.11 Generating and Evaluating Alternative Plans (Step 9) 112
3.12 Selecting and Implementing the Preferred Plan (Step 10 and 11) 113
3.13 References 3.1 - 3.12 114
3.14 Bibliography 3.1 - 3.12 114
Annex 3A A Typical Wastes Generation Questionnaire For Use

As Part of a Waste Disposal Survey 116
Annex 3B The Siting of a Hazardous Waste Management Facility
in the Province of Ontario, Canada. A Case Study 122
Annex 3C Development of Methodologies for Industrial Hazardous
Waste Inventories. Experience in Mexico and Italy 147
ix
CHAPTER 4. Waste Minimization - A Key Strategy in Hazardous Waste

Management 161
4.1 Introduction 161

4.2 Waste Minimization Programs 162
4.2.1 Definition 162
4.2.2 Source Reduction 162
4.2.3 Recycling 169
4.2.4 Treatment 173
4.3 Incentives and Disincentives for Waste Minimization in
Developing Countries 173
4.4 Waste Minimization Audits 174
4.5 Evaluating Waste Minimization Project Costs and Benefits 175
4.6 Requesting Approval for Funding of Waste Management Projects. 180
4.8 Measurement of Waste Reduction 184
4.9 References 4.1 - 4.8 184
4.10 Bibliography 4.1 - 4.8 185
Annex 4A Cost/Benefit Analyses of Waste Minimization 186

Annex 4B Examples of Successful Waste Minimization Programs 198
Annex 4C Bringing About Change in Hazardous Waste Management 206
CHAPTER 5. Infrastructure of Hazardous Waste Management Systems 230
5.2 Storage upon Generation 230

5.2.1 Containers 230
5.2.2 Tanks 231
5.3 Collection/Transportation 231

5.3.1 Packaging/Labelling 231
5.3.2 Paperwork Tracking System 231
5.3.3 Direct Transfer/Collection Station 231
5.3.4 Transportation 234
5.4 Management Plans and Programs 237

5.4.1 Waste Characterization 237
5.4.2 Site Security 238
5.4.3 Equipment Inspection/Maintenance 238
5.4.4 Employee Training 238
5.4.5 Operating Record 239
5.4.6 Incident Prevention and Preparedness 239
5.4.7 Emergency Planning 239
5.4.8 Closure Planning 239
5.5 Example: Central Waste Treatment Plant 240

5.5.1 Basic Concepts 240
x
5.5.2 Siting 240

5.5.3 Design Philosophy 242
5.5.4 Process Descriptions 242
5.5.5 Plant Layout 245
5.5.6 Administrative Procedures 246
5.6 Site Safety Analysis 251

5.6.2 Safety Goals 255
5.6.3 Basic Approach 255
5.6.4 Identification of Failure Cases 255
5.6.5 Fault-tree Analysis 256
5.6.6 Event-tree Analysis 256
5.6.7 Calculation of Consequences an.dAssessment of Risk 256
5.6.8 Recommendations 256
5.6.9 Site Safety 257
5.7 Measurements to be Taken in Case of Unintentional Exposure to

Hazardous Waste 258
5.7.1 Health and Safety of Personnel Handling Hazardous Waste 258
5.8 Economic, Institutional and Financial Considerations 263

5.8.1 Cost 263
5.8.2 Complexity and Uncertainty 263
5.8.3 Liability 264
5.8.4 Relation to Emergency Response, Occupational Health and Safety,
Consumers and Toxic Substances Control 265
5.9 Economic Considerations 265
5.10 Direct Regulation 266
5.11 Economic Incentives 266
5.12 References 5.0 - 5.11 268
VOLUME 2
CHAPTER 6. Hazardous Waste Treatment Technologies 270
6.2 Discussion of Typical Treatment Technologies 270

6.2.1 Physical Treatment 272
6.2.2 Sludge Processing 272
6.2.3 Chemical Treatment 273
6.2.4 Biological Treatment 275
6.3 Treatment Technology Considerations 276

xi
6.4 Precipitation/Flocculation 277

6.4.1 Applications/Limitations 280
6.4.2 Design Considerations 282
6.4.3 Design Criteria 282
6.4.4 Technology/Selection/Evaluation 286
6.4.5 Costs 287
6.5 Sedimentation 287

6.5.2 Design Considerations 293
6.5.5 Costs 294
6.6 Oily Wastes 297

6.6.2 Design Considerations - Emulsion Breaking 297
6.6.4 Performance 301
6.6.5 Design Considerations - Skimming 301
6.6.7 Technical Selection/Evaluation 303
6.6.9 Costs 303
6.6.10 Case History 309
6.7 Chemical Oxidation 311

6.7.1 Description 311
6.7.2 Representative Types and Modifications 313
6.7.3 Technology Status 318
6.7.4 Applications 318
6.7.5 Advantages and Limitations 319
6.7.6 Reliability 320
6.7.7 Chemicals Required 320
6.7.8 Residuals Generated 320
6.7.11 Costs for Chlorine Oxidation of Cyanide 321
6.8 Stabilization/Solidification 331

6.8.2 Processes 333
6.8.3 Applicability 338
6.8.4 Process Evaluation 343
6.8.6 Process Considerations 353
6.8.7 Economic Considerations 355
6.8.8 Encapsulation 357
6.9 Neutralization 358

X ii

6.9.11 Cost of Neutralization 363
6.10 Solvent Extraction 377

6.11 Sludge Processing 383

6.11.1 Conditioning 387
6.11.2 Digestion 389
6.11.3 Composting 398
6.11.4 Thickening 408
6.11.5 Dewatering 416
6.12 References 6.1 - 6.11.5 439
CHAPTER 7. Technical Requirements for the Safe Disposal of Hazardous

Wastes 443
7.1 Landfills 448

7.1.2 Site Selection 451
7.1.3 Soil Properties and Contaminant Control Mechanisms 462
7.1.4 Water Quality Protection 469
7.1.5 Landfill Site Development. 482
7.1.6 The Disposal of Hazardous Wastes 499
7.1.7 Leachate Collection and Treatment 529
7.1.8 Treatment of Landfill Gas 536
7.1.9 Closure and Restoration of Site 541
7.1.10 Issues Regarding Codisposal of Municipal and Hazardous Waste 547
7.1.11 References 7.1 - 7.1.10 551
xiii
VOLUME 3
Annex 7.1A Leachate from a Hazardous Waste Landfill--Technical

and Economical Comparison of Treatment Process 552
Annex 7.1B Disposal and Management of Pesticide

Waste and Containers 589
7.2 Land Treatment 606

7.2.2 Treatment Demonstrations 608
7.2.3 General Operating Requirements 611
7.2.4 Surface Vegetation 613
7.2.5 Monitoring 613
7.2.6 Conceptual Design 614
7.2.7 System Design and Management 623
7.2.8 Site Conditions 623
7.2.9 Water Control 625
7.2.10 Application Methods 625
7.2.11 Closure and Post-Closure 627
7.2.12 Practical Application 628
7.2.13 References 7.2 - 7.2.12 630
7.3 Other Land Disposal Processes and Monitoring 632

7.3.1 Surface Impoundments 632
7.3.2 Deep Well Injection 637
7.3.4 References 7.3.1 - 7.3.3 652
7.4 Incineration 653

7.4.2 How Incineration Works 655
7.4.3 The Principles of Incinerator Design 657
7.4.4 Co-Incineration in Existing Industrial Facilities 658
7.4.5 Co-Incineration: Existing Incinerators 674
7.4.6 Small Scale Purpose-Built Incinerators 679
7.4.7 Large Scale Purpose-Built Incinerators 685
7.4.8 Energy Recovery 693
7.4.9 Gas Cleaning 695
7.4.10 Operation and Control 700
7.4.11 Incineration at Sea 719
7.4.12 Design Parameters for Incineration Facilities 721
7.4.13 Costs for Incineration Facilities 723
7.4.14 Concluding Remarks 732
7.4.15 References 7.4 - 7.4.14 734
Annex 7.4 Biomedical Waste 736
7.5 Ocean Disposal 754

7.5.2 International Conventions 754
xiv
7.5.3 Categorization of Wastes 755

7.5.4 Shallow Versus Deep-Sea Disposal 763
7.5.5 Permits for Dumping at Sea 764
7.5.6 Quantities Dumped At Sea 768
7.5.7 Fate of Dumped Wastes 771
7.5.9 Technical Assistance 775
7.5.10 References 7.5 - 7.5.9 783
Annex 7.5 Guidelines for the Implementation and Uniform

Interpretation of Annex III to the London Dumping
Convention 785
Glossary of Terms 795

xv
PREFACE
The inappropriateand often careless handling of municipal and industrial

wastes, including those that are hazardous,has all too often created problems
worldwide for human health and the environment. Effective control of
hazardous wastes is of paramount importancefor proper health and
environmentalprotection and natural resourcemanagement. Developing
countries, as they experiencerapid industrialgrowth, have a particular and
urgent need to initiate programmes for hazardouswaste management. To assist
them in this task, the World Bank, the World Health Organizationand the
United Nations Environment Programme joined forces to prepare and issue these
guidelines.
This three-volumemanual is intended for administratorsand technical staff

primarily in developingcountrieswho have responsibilitiesfor waste
management and for public health and environmentalprotection in general. The
document should also prove to be a useful reference for similar officials in
the industrializedcountries,particularlyat the regional and municipal
levels. Chapters 1-5 contain informationon the classificationof hazardous
waste, their effects on health and the environment,and the planning and
implementationof programmes for hazardouswaste management. Chapters 6 and 7
deal primarily with the hazardous waste treatment and disposal technologies,
including economic and institutionalconsiderations.
The publication provides a framework for evaluatingoptions such as waste

minimization,recycling and waste reduction,and for making decisions on
whether a waste generator should handle wastes alone or in combinationwith
other generators at a centralizedfacility. The full array of treatment and
disposal options is presented along with the advantagesand disadvantagesof
each. The user will find a framework for making decisions on the combination
of waste handling processes appropriateto local conditions,as well as
explicit directions on estimatingcost and developingfinancing for waste
handling facilities.
The publication of this manual will add to the guidelinematerial already

available from sponsoringorganizationson the subject of hazardouswastes.
In 1983, the WHO Regional Office for Europe and UNEP jointly issued a
guideline document which sets out the principlesof formulating and
implementinga hazardous waste management policy. In 1985, an ad hoc working
group, organized by UNEP, on environmentallysound management of hazardous
wastes, adopted the Cairo guidelineson policies and legislationregarding
hazardous wastes. Also in 1985, UNEP's InternationalRegister of Potentially
Toxic Chemicals (IRPTC) published a Waste Management File, which contains
information on treatment and disposal options for wastes containingspecific
chemicals. Finally, the UNEP Industry and EnvironmentReview publishes
articles on hazardous waste management regularly.
The preparation of this manual involved the active participationof over 30

scientists and waste management specialistsfrom 12 countries. The work of
these institutionsand scientistswas central to the successfulcompletion of
xvi
this manual, and is greatly appreciated. Also, it should be noted that the
manual, once its draft was prepared, was distributed to well over 35 experts
worldwide for in-depth review, and their comments were carefully considered
when finalizing the manual. The help of these reviewers is also gratefully
acknowledged.
CONTRIBUTORS
Many individuals and organizations have contributed to the preparation of this

technical manual.
Project Coordinators
Dr. R. J. Batstone, The World Bank, Office of Environmental & Scientific

Affairs, Washington, D.C.
Dr. M. Gajraj, Programme Officer, Industry and Environment Office, UNEP,

Paris, France
Mr. G. Ozolins, World Health Organization, Division of Environmental Health,

Geneva, Switzerland
Dr. J. E. Smith, Jr., USEPA-CERI, (Technical Advisor for WHO), Cincinnati,

Ohio
Dr. D. C. Wilson, Environmental Resources, Ltd. (ERL), London - World

Bank/UNEP Consultant
The following from the International Environmental Bureau (IEB) assisted in

review of draft material and its revision:
Dr. A. E. Fry, IEB, Geneva, Swit:zerland
Mr. G. Crouth, Aluminum Company of America, Pittsburgh, Pennsylvania (on

behalf of IEB)
Dr. U. Guyer, CIBA-GEIGY, Switzerland (on behalf of IEB)
Authors
Dr. D. C. Wilson, ERL, London, England
Dr. C. R. Krishna Murti, New Delhi, India
Drs. M. Berlin, M. Hutton, and S. Batt, Monitoring and Assessment Research

Centre (MARC), King's College London, England
Mr. M. A. Scott, ERL

xvii
Dr. J. E. Smith, USEPA-CERI, Cincinnati,Ohio
Mr. E. F. Harris, USEPA-HWERL,Cincinnati,Ohio
Dr. G. H. Eduljee, ERL, London
Dr. R. J. Batstone, World Bank, Washington,D.C.
Mr. G. A. Garland, EPA, Washington,D.C.
Prof. V. Freed, Oregon State University, Oregon, USA
Prof. R. C. Loehr, University of Texas at Austin, USA
Dr. U. Guyer, CIBA GEIGY, Switzerland
Dr. G. Olivetti, Dagh Watson, Italy
Mr. R. Barnard, Ashact, Ltd., U.K.
Fichtner ConsultingEngineers, Stuttgart,Germany
Dr. Howard Hatamuya, CaliforniaDepartmentof Health Services, Berkeley,USA
Prof. J. Kohl, North Carolina State University,Raleigh, North Carolina,
Jacobs Engineering Group, Inc., Washington,D.C.
Trecan CombustionLimited, Mississauga,Ontario, Canada
Ministry of the Environment,Toronto, Ontario, Canada
Ontario Waste Management Corporation,Toronto, Ontario, Canada
Reviewers
1. M.L. Bouguerra,Faculte des Sciences, Campus Universitaire,Tunis,

Tunisia
2. S. Hope, IPIECA, London
3. Prof. G. Anandalingan,Universityof Virginia, Charlottesville,
Virginia, USA
4. Amanda Horwath, National Institute of Hygiene, Budapest, Hungary
5. Dr. E. F. Thairs, CBI, London
6. Hassan E.-Baroudi,Haledon, New Jersey, USA
7. Prof. David Barnes, Universityof New South Wales, Kensington,New South
Wales, Australia
8. Norman F. Sather, Argonne National Laboratory,Argonne, Illinois,USA
9. Howard K. Hatayuma, CaliforniaDepartmentof Health Services, Berkeley,
California,USA
10. Dr. G. Sierig, Berliner Stadtreinigungs-Betriebe, Berlin, FRG
11. A. Q. Khan, South Yorkshire Joint Hazardous Waste Unit, Rotherham,
England
Xviii
12. Tsunemi Matsuda, International Iron and Steel Institute, Brussels,

Belgium
13. Prof. J. M. Dave, Jawaharlal Nehru University, New Delhi, India
14. Tan Gee Paw, Director EED, Ministry of Environment, Republic of
Singapore
15. Mrs. S. Soewasti Soesanto, National Institute of Health Research and
Development, Jakarta, Indonesia
16. Nelson Walter, E. C. Jordan Co., Portland, Maine
17. Somnuek Unakul, WHO-PEPAS, Kuala Lumpur, Malaysia
18. N. G. Thom, National Environmental Chemistry and Acoustics Laboratory,
Auckland, New Zealand
19. S. P. Maltezou, UNIDO, Vienna, Austria
20. Prof. Edward S. Kempa, Inst:itute of Sanitary Engineering, Zielona-Gora,
Poland
21. Tom de Brui , Institute of Waste Management, Cape Town, South Africa
22. Dr. Mohamed Raouf Hamid, National Organization for Drug Research, Cairo,
Egypt
23. Marcia E. Williams, USEPA, Office of Solid Waste, Washington, D.C.
24. Chiang Kok Meng, Ministry oE Environment, Republic of Singapore
25. K. J. Simpson, Alberta Special Waste Management Corp., Edmonton,
Alberta, Canada
26. Dr. Owona Rummel-Bulska, Environmental Law and Machinery, UNEP, Nairobi,
Kenya
27. Dr. Z. Hamzeh, Ministry of Health, Amman, Jordan
28. Dr. Suma'mur P. K., National Centre of Industrial Hygiene and
Occupational Health, Jakarta, IndLonesia
29. P. K. Ray, Industrial Toxicology Research Centre, Lucknow, U. P., India
30. Peter Martyn, International Prima,ryAluminium Institute, London, United
Kingdom
31. Dr. John H. Skinner, USEPA, Office of Environmental Engineering and
Technology Demonstration, Washington, D.C.
32. C. Bartone, Fred Wright, and Ed Quicke, WUJDAT,World Bank, Washington,
D.C.
33. Christopher M. Timm, Jacobs Engineering Group, Inc., Washington, D.C.
34. Dr. P. Anton and Mr. Grabenbauer, Fichtner Engineers, Stuttgart, FRG
35. Mike Scott, ERL, London
36. Lawrence J. Doucet, Doucet & Mainika Consulting Engineers, Peekskill, New
York, USA.
37. E. E. Finnecy, Harwell Laboratory, UK Atomic Energy Authority,
Oxfordshire, United Kingdom
38. Steven M. Erlanson, ENRECO, Balt:imore,Maryland, USA
39. F. Veen, TAUW Infra. Consultant, B. V., Al Denventer, Netherlands
Technical Editor: Donald Hinrichsen
Production Editor: Katherine Hoskins Mackey

CHAPTER 1 - Introduction
1.1 What are Hazardous Wastes?
This manual presents systems for the control, reduction,storage,

treatment and disposal of those wastes that contain highly persistent
elements, chemicals and compoundswith attendantchronic and acute impacts
on human health and the environment.
Hazardous wastes are generated from a wide range of industrial,

commercial,agriculturaland even domestic activities (Chapter2). Table
1-1 illustratesthe widespread distributionof hazardous wastes.
Hazardous wastes may take the form of solids, liquids or sludges. Most
definitionsexclude domestic solid wastes and aqueous effluents;however,
a major source of hazardous wastes is from the pretreatmentof effluents
in order to meet water pollution controls, an example being heavy metal
sludges from electroplating,sludges from treating tannery wastes, etc.
The degree of hazard posed by hazardouswastes varies widely. A useful

distinction is between those wastes which pose a potentiallyhigh risk to
human health and those wastes where the hazard is much less, but the
quantitiesare perhaps much greater. Typical wastes in the first category
might include low flashpointflammable solvents,highly toxic pesticides
or persistent chlorinatedmaterials such as PCBs, while the latter
includes such large volume mineral wastes as metaliferous slags, mine
tailings,phosphogypsumor lime sludges. These distinctionsare discussed
further in Chapter 2.
1.2 Why are we Concernedwith HazardousWastes?
Hazardous wastes have only come to be recognizedas a priority problem

over the past 10-15 years. Action to control hazardous wastes has too
often been precipitatedby an actual or potential environmentaldisaster.
O Japan was one of the first countries to introduce comprehensive

hazardous waste controls, followingthe Minamata incident in the late
1960s when many people died from eating fish contaminatedwith mercury
which had been dischargedto the sea.
o In the UK, a high level committee had been investigatingthe problem of

hazardous wastes for a number of years when, in February 1972, public
outrage arose over the discoveryof drums containingheat treatment
cyanide salts on vacant land where childrenwere playing. Ten days
later legislationwas enacted.
o The rigid control system on hazardouswastes in the United States which

has evolved since 1976 has been driven largely by public outcry over
the widespread discovery of pollution caused by past uncontrolled
dumping of hazardouswastes.
- 2 -
TABLE]1-1
Some Illustrative ExampLes of Hazardous Wastes
Sector Source Hazardous Waste
Commerce & Vehicle servicing Waste oils

Agriculture Airports Oils, hydraulic fluids etc.
Dry cleaning Halogenated solvents
Electrical transformers Polychlorinated Bipheryls
(PCBs)
Hospitals Pathogenic/infectious
wastes
Farms/Municipal parks Unused pesticides, "empty"
etc. containers
Small-scale Metal treating (elect:ro- Acids, heavy metals

industry plating, etching,
anodizing, galvanizing)
Photofinishing Solvents, acids, silver
Textile processing Cadmium, mineral acids
Printing Solvents, inks and dyes
Leather tanning Solvents, chromium
Large-scale Bauxite processing Red muds

industry Oil refining Spent catalysts
(Petrochemical manufacture) Oily wastes
Chemical/pharmaceutical Tarry residues, solvent
manufacture
Chlorine production Mercury
Note: A classification system for hazardous wastes is introduced in Chapter 2.

Hazardous wastes can cause immediate,short-term,public health problems
as well as long-term environmentalpollution. Proper control of hazardous
wastes does cost money, but experiencein a number of developed countries
suggests that cleaningup the 'sins of the past' is much more expensive in
the long term. For instance, in the United States clean up of improperly
managed wastes has been estimated to cost 10-100 times as much as proper
early management. It is therefore important that all developingcountries
institute controls over hazardous wastes to avoid such excessive costs in
the future.
Even though the definitionof hazardous waste excludes domesticwastes, in

many countries it may be difficult to totally separate industrialand
domesticwastes. Developing countrieswill need some strategy to identify
and quantify the risks posed by hazardous wastes in order to arrive at a
list of priorities for action within their limited resources. Some
factors affecting the degree of risk are:
o reactivity (fire, explosion,leaching);
o biological effect (toxicity,short and long, exotoxicity);
o persistence (fate in environment,detoxificationpotential,multiple

factors);
o indirecthealth risks (pathogens,vectors); and
o actual amounts and local conditions (temperature,soil, water,

humidity, light, receiving systems,their use pattern, etc.).
1.3 Aspects of a Control System for Hazardous Wastes
Every country needs a national control system for hazardous waste

management. Such a system must provide four vital componentsif it is to
be successful:
o legislationand regulations;
o proper implementationand enforcementprocedures;
o the provision of adequate facilitiesfor hazardous waste recycling,

treatment and disposal and measures to encourage their use;
o introductionof training schemes for governmentenforcementofficers

and plant operators and managers and/or public awareness educational
programs.
All four aspects are vital to the proper working of a national control
system. No matter how perfect a system may appear on paper, it is
worthless if it is not enforced. Similarly,control cannot be enforced if
adequate facilities are not available or if enforcementofficers are not
adequately trained. Thus developmentof legislationand provision of
adequate facilitiesmust proceed in parallel. A few general points may be
made regarding the introductionof a control system:
- 4 -
o Good informationon present quantitiesof waste and on present

practices is essential so that prioritiesmay be identified.
O A national strategy for hazardouswaste managementneeds to be

developed including a plan for the provision of facilities.
o A control system should encompass all aspects of hazardous waste

management, from generationthrough storage, transport and treatment to
disposal.
o All parties involved -- generators,transporters,disposers, and

government -- have their role and responsibilities.
1.4 Previous InternationalEfforts on HazardousWaste Management
A number of internationalorganizationshave taken an interest in

hazardous waste management.
o In 1983, the World Health Organization(WHO) and the United Nations

EnvironmentProgram (UNEP) published policy guidelinesand a code of
practice,which sets out the principles of formulatingand implementing
a hazardous waste managementpolicy. (Suess and Huismans 1983)
o In late 1985, an ad hoc working group on environmentallysound

management of hazardous wastes mseting under the auspices of UNEP
adopted the 'Cairo guidelines'on policies and legislation. (UNEP
1985)
o UNEP's InternationalRegister of PotentiallyToxic Chemicals (IRPTC)

published a Waste Management File in 1985, which contains information
on treatment and disposal options for wastes containing specific
chemicals. (IRPTC 1985)
o A workshop in May 1986 organized by ASEAN, UNEP and CDG developed

guidelines for establishingpolicies and strategiesfor hazardous waste
management in Asia and the Pacif:Lc. (UNEP 1986)
o The Organizationfor Economic Cooperation and Development (OECD) and

the Commission of the European Communities (CEC) have been preparing an
internationalconventionon the transfrontiermovement of hazardous
wastes. Much work has focused on standardizinga list of hazardous
wastes. (OECD 1988)
o The UN Economic Commission for Europe (ECE) and the Council for Mutual
Economic Assistance (CMEA) have focused in particular on low-waste and
non-waste technologies. (ECE 1979-1987)
Where these efforts have been of particularrelevance to developing

countries, the focus has generally teen on formulatingpolicies and
strategiesand developing legislaticn(ECE 1979-1987). Recently,
increasingfocus is being given to the dumping of hazardouswastes in
developing countrieswhere there are inadequatecontrols to ensure the
safe disposal of their wastes.
- 5-
1.5 Quantities of Hazardous Waste
Obtaining reliable informationon the quantitiesor types of hazardous

wastes produced by any country is very difficult. International
comparisons are almost impossiblebecause of differencesin the
classificationand definitionof hazardouswastes from country to country.
An attempt has been made to estimate the quantitiesof hazardous waste

produced in different countries (Yakowitz1985). It was estimated that
for a number of western European countries,hazardous waste production is
about 5,000 tons per billion US$ of gross domesticproducts (GDP). The
figure for the USA is approximately75,000 tons; the figure for the USA is
higher because certain high volume waste water streams are included in the
calculations. The correspondingfigure for Canada is 10,000 tons.
On the basis of very limited data, it was assumed that waste production in
the USSR could be estimated at 10,000 tons per billion US$ GDP, that in
other countries with mature industry at 5,000 tons, in newly
industrializedcountries 2,000 tons and in developingcountries 1,000
tons.
Such estimates can at best indicate relative orders of magnitude of

hazardous waste productionin different countries. Figure 1-1 summarizes
the numbers of countrieswithin each of four "bands" of likely hazardous
waste production,namely less than 10,000 tons per annum (tpa) 10-100,000
tpa, 100,000 - 1 million tpa and more than 1 million tpa.
From these estimates it appears that around two-thirdsof all countries

produce less than 10,000 tpa of hazardouswastes. For many developing
countries the estimates are in the range of a few hundred or a few
thousand tons. While this puts the overall problem in context, it should
be rememberedthat a single heavy industrialplant can produce hundreds of
thousands of tons per annum of bulk wastes, althoughmost of these are in
the 'grey' region between hazardous and non-hazardouswastes.
1.6 Progress in ControllingHazardous Wastes
Considerableprogress has been made over the last 10 years in controlling

hazardous wastes in a number of developed countries (Foresterand Skinner
1987). Progress varies considerablyfrom country to country,but in some
countries:
o effective legislationis in place;
o effective manifest systems are being introducedto control waste

transport;
o an increasingpercentageof operators of hazardous waste treatment and

disposal facilitieshave been licensed;
o in some cases, well engineeredand well managed facilitieshave been

provided for hazardous waste treatment,incineration,and landfill is
controlled;
- 6-
FIGURE1-1
Order of Magnitude of Hazardous Wasl:eProductionin IndividualCountries
Numberof
Countries
120
100
80
60
40
20
0 104 105 106 109
Estimated
rangeof hazardous
wasteproduction
-7-
o in a few cases, good collectionand transfer systems have been

established.
Hazardous waste disposal is a dynamic problem, and there is on-going work

in these countries on standards and licensingprocedures. Present
prioritiesvary depending on the stage of developmentand implementation
of the control systems.
o In those cases where the process is only just beginning,an effective

system is a priority (1.8).
o In other places, continuingimplementationof regulationsand provision

of adequate facilities,either for landfill or for treatment of
hazardous wastes, or both, are seen as high priorities.
o In a number of countries it is not the absence of facilitiesthat

presents a problem, but rather competitionbetween landfill and
treatment facilities. Landfill tends to be less expensive than waste
treatment, so that given a free market, landfills tend to predominate,
even though treatmentwould be better for environmentalreasons. In
these cases governmentcontrol of competition is necessary.
o Almost all countries see a need to improve enforcement of and

compliancewith the regulationsthat are in place.
1.7 Specific Problems of DevelopingCountries
Developingcountries face a number of specificproblems in tackling

hazardous wastes.
(i) General control over pollution and waste disposal is often poor
In many countries open dumps predominate,and in the absence of controls

hazardous wastes continue to find their way into such dumps. Scavengers
may live and work among the wastes, and many dumps are already causing
water pollution. Proper management of dumpsites is a high priority in
developing countries.
Controls over water and air pollution are often poor, and when such
controls are implemented,the treatment sludges and dusts are often
hazardous wastes.
Isolated efforts to control specifichazardous wastes are often

ineffectivewithout an overall upgrading of waste management practices.
Coordinationof controls over air and water pollution and hazardous waste
is particularlyimportant.
(ii) Generatorsmay be unaware of the hazard of their waste
Ignorance of the potential harm of hazardouswastes is encountered in all

countries,but it is a particularproblem among small generators in
developingcountries. Even though the quantitiesthey produce may be
small, the potential problems are not insignificant. For example, the
-8-
improper disposal of surplus pesticides or pesticide containersmay poison

humans or pollute sensitive ground water resources. (See Annex 7.1B)
(iii) Stockpilesof waste awaiting treatmentor disposal
In some countries,new industriesmay stockpiletheir waste on site in the

absence of proper facilitiesfor treatmentor disposal. After 5, 10 or 15
years space begins to run out or pollution problems arise, and suddenly
the problem becomes urgent.
(iv) Limited resources
Some developingcountries lack the financial resourcesand skilled

manpower to adequatelydispose of hazardouswaste. Restrictionson
foreign exchange and limited access to hard currenciesmake it difficult
to finance such facilities. A shortageof skilledmanpower will impede
planning, management, operation and maintenance of facilities,and
enforcement of regulations.
(v) Socio-politicalreasons
Without public education on the issues and a general awareness of the

dangers of improper disposal of hazardouswaste there is too often
insufficientpublic demand for action. Developingcountries may focus on
other very real and seeminglymore urgent problems and not see hazardous
waste disposal as a pressingneed and immediatepolitical goal.
Developing countriesneed to set priorities in controllinghazardous

wastes. The available resourcesmust be focused on the most significant
problems and short-term solutionsimplementedto bring immediateproblems
under control.
It may be necessary to distinguish between long-term solutions,which may

involve the establishmentof centralizedtreatment/disposalfacilitiesand
short-termsolutionswhich aim to eliminate the worst current practices.
Even in the longer term, there will be a need to develop solutionswhich

are compatiblewith the limited resources available. Such 'appropriate'
solutions are required particularlyfor small quantitiesof waste or for
those wastes which would appear on the agenda for action.
1.8 Purpose of this Manual
The World Bank, WHO and UNEP have each identifiedthe need for guidance on
the assessment and planning aspects of hazardous waste management,with
specific reference to developingcountries. Among the topics discussed in
this manual are the following:
o setting priorities for control;
o establishingan appropriatedefinitionand classificationscheme;

-9
o developing a plan to provide the necessary facilitiesfor waste

treatment and disposal;
o choosing a short-listof options for treatmentand disposal appropriate

to the needs of specific countries;
o the economics and financing of facilities.
The manual is aimed at meeting the needs of three distinctbut overlapping

target audiences.
(i) The first is the most senior technical level within governmentand
industry in developingcountries. The aim is to provide sufficient
information to enable them to undertake a study of the needs and
requirementsof their own country, region or community,and to select a
short list of potential options for more detailed examination.
(ii) Within funding organizations,the manual will be used to assist in

the identification,preparation and appraisal of countrywidehazardous
waste management programs and 'stand alone' projects.
(iii) It is envisaged that the manual will form the basis for national
and internationaltraining courses aimed both at senior and middle
management levels within governmentand industry in developingcountries.
1.9 Guide to this Manual
The remaining chapters in the manual are outlinedbriefly below.
o Chapter 2 gives a review of health and environmentaleffects,which

aims to give guidance on setting of priorities,and examines the
difficult questions of defining and classifyinghazardous wastes. A
practical classificationscheme, which can be adapted to the needs of a
particular country, is outlined.
O Chapter 3 provides a framework for developinga national, regional or

local plan to provide the necessary facilitiesfor recycling,treating
or disposing of hazardous wastes.
o Chapter 4 examinesmethods for waste avoidance,reduction at source,

recovery, recycling and reuse.
o Chapter 5 gives details of the infrastructurerequired for establishing

a hazardous waste management system as well as addressingeconomic,
financial and institutionalarrangements.
o Chapter 6 includes a discussionof the choice of appropriaterecycling

and treatment technologies.
o Chapter 7 provides informationon final disposal options.

- 10 -
1.10 References 1.1 - 1.9
Economic Commission for Europe. 1979-1987.161 Monographs on low-and

non-waste technologies. Geneva: InternationalEnvironment Bureau.
Forester, W. S., and J. H. Skinner, eds. 1987. InternationalPerspectives

on Hazardous Waste Management. London: Academic Press.
InternationalRegister of PotentiallyToxic Chemicals. 1985. Treatment

and Disposal Methods for Waste Themicals. Geneva: United Nations
Publications,Palais des Nations.
Organizationfor Economic Cooperationand Development (OECD). 1988.

Decision of the Council of TransfrontierMovements of Hazardous Wastes.
Document C (88) 90. Paris.
Suess M. J., and J. W. Huismans, eds. 1983. Management of Hazardous Waste

- - Policy Guidelines and Code Df Practice. European Series No. 14.
Washington, D. C.: WHO Regional Publications. (Availablein English,
French, Russian, Spanish, Chinese and Italian.)
United Nations EnvironmentProgra&nme(UNEP).1985. Principles for the

EnvironmentallySound Management of Hazardous Wastes ("The Cairo
Guidelines"). Nairobi: UNEP
UNEP. 1986. Guidelinesfor EstablishingPolicies and Strategiesfor

Hazardous Waste Management in Asia and the Pacific. Bangkok: UNEP
Regional Office.
Yakowitz, H. 1985. Backgroundinformationconcerninghazardous wastes in

non-OECD countries,unpublished.Paris: OECD.
- 11 -
CHAPTER 2 - The Health and EnvironmentalEffects of Hazardous Wastes
2.1 Introduction
In the last few years, considerableattention has focused on the question

of what constitutes a "hazardouswaste." National systems differ both in
the methods used for definingwastes and the type of wastes included.
These differences arise partly from variations in the institutionaland
legal frameworksof different countries.
Internationalorganizationslike the OECD and CEC are currently attempting

to establish a cross-referencelist of hazardous wastes, as a first step
towards harmonizationof definitions. The main concern, at present, is to
implement stricter controls over the transfrontiermovement of hazardous
wastes.
For the purpose of this manual, however, we are more concernedwith

evolving a practical definitionof hazardouswaste, which can then be
adapted to the legal system of any particular country.
Equally important,the possible health and environmentaleffects of

hazardous wastes must be understood and dealt with. In order to do this,
we need to understand the chemical and physical propertiesof hazardous
wastes and their potential pathways through ecosystemsto man.
Subsequent sections of this chapter consider the following:
o a working definitionof the terms "waste" and "hazardouswaste";

o broad types of waste which should be includedwithin the scope of
"hazardouswastes," and those which should be excluded;
o approaches to the identificationand classificationof hazardous
wastes, which can be used to give a proper working definition;
o details of our proposed classificationscheme;
o factors affecting the environmentalbehavior of chemicals;
o a detailed discussionof the effect of hazardous wastes on human
health;
o categorizinghazardous wastes by degree of hazard; and
o environmentaleffects of hazardous waste disposal.
2.2 Working Definitions
Typically, the concept of "waste" refers to somethingwhich no longer has

any further value or use.
This definition,however, has been complicatedby the issue of wastes

versus products; in other words, if a waste can be recycled or can be used
in some way, it has acquiredvalue and is no longer considereda waste.
This, in turn, requires a definitionof what is recyclable. There is some
evidence that relaxationof controls for recyclablewastes may increase
the risk of environmentaldamage resulting from the mismanagementof
recyclablewastes. Examples of such mismanagementabound and include the
use of contaminatedwaste oil for dust control; the long-term,
uncontrolled storage of materials pending recycling;using metaliferous
- 1.2-
wastes as building or road constructionmaterials; or using wastes as fuel

substitutes,burning them under uncontrolledconditions.
For these reasons, the definitionof waste adopted in this manual makes
little reference to recycling and does not suggest that any relaxationof
controls be consideredfor recyclablewastes.
A waste is thus defined as a moveable object which has no direct use and
is discardedpermanently.
All wastes must receive proper treatment and disposal so as to protect the
environimentand enhance the quality of life. Hazardous wastes are a
special category of wastes which, due to their toxicity, persistence,
mobility, flammability,etc., require more stringent regulatoryand
technical controlswhen compared to wastes such as municipal refuse.
Later in this chapter, the range of possiblehealth and environmental
problems that can arise because of the impropermanagement of hazardous
wastes are discussed.
The following definitionof hazardous wastes was prepared under UNEP

auspicesby the Ad Hoc Working Group of Experts on the Environmentally
Sound Management of HazardousWast:esin December 1985:
"Hazardouswastes means wastes other than radioactivewastes which by

reason of their chemical reactivityor toxic, explosive,corrosive or
other characteristicscausing danger or likely to cause danger to health
or the environment,whether alone or when coming into contact with other
wastes, are legally defined as hazardous in the State in which they are
generated or in which they are disposed of or through which they are
transported."
2.2.1 Inclusionsand Exclusions from the Definition
Thus defined,hazardous wastes can include solids, liquids, gases,

sludges, containerizedgases or contaminatedcontainers,and can originate
from a wide range of commercial,agricultural,and industrial sources. In
general, hazardous wastes cannot be handled safely and effectivelyby the
existing wastewater treatment or clomestic
waste disposal systems.
A number of specific exclusionsare mentioned within the definition:
o Radioactivewastes are consideredhazardous,but are excluded from the

definition, since most countries control and manage these material in a
separate organizationalframework;
o Domestic refuse can cause signi.ficantenvironmentalpollution and may

also contain small quantitiesof hazardous substances (e.g.,mercury
from dry cell batteries, solvents from paint residues, etc.). Again,
these wastes are normally controlledby a separate, though
interrelated,organizationalframework. However, some countrieswith
well developed control systems are now turning attention to separating
and/or eliminating the hazardous componentsin domesticwaste.
- 13 -
The UNEP Working Group also gave considerationto the quantity of waste:
o For small quantities,all countrieshave chosen to exclude "hazardous

wastes" from household waste. At the same time, some countries also
exclude small generatorsof hazardouswaste as well. The cutoff point
for regulation is important. The United States, for example, recently
reduced the threshold for control from 1000 kg/month to 100 kg/month,
thereby increasingthe number of regulated generatorsof hazardous
waste by tenfold;
o For large quantities, regulatorsmay wish to control wastes containing

relatively low concentrationsof pollutants, since the volume will
still render them hazardous to the environment. However, because of
the practical problems in implementingcontrols over such wastes, some
countries exclude certain large volume wastes, such as mining or
agriculturalwastes, from control under hazardous waste legislation.
As mentioned above, most countries choose to control waste-water effluents

separately from hazardous wastes. However, in the United States,
wastewater stored or treated in surface impoundments,settling ponds,
lagoons, etc. is controlledwithin the regulationsgoverning the
management and handling of hazardous wastes. The reason for this is
simple: there is growing concern that such effluents contain hazardous
substancesthat can leave with the wastewater stream percolating into
groundwater reservoirsor appearing in sludge which may later be
landfilled in municipal dumps or other areas not equipped to handle
potentially toxic or hazardous material. This is another factor
contributingto the large amounts of toxic waste reported for the US (See
Chapter 1, Section 1.5).
Wastes listed in Annex 2 are consideredhazardous according to current

standards and knowledge. This list, however, is not static and has
evolved over time, as more toxicological,and other data, have been
gathered on the health effects of various wastes, particularlychemical
wastes.
2.3 Identificationand Classificationof HazardousWastes
In developingan organized approach to hazardouswaste assessment and

management, a system of waste identificationand classificationmust be
formulated (see Table 2-1). In many countries,such a system is an
integral part of a legal definitionof hazardouswaste. Most countries
have used a definitionbased on an inclusive listing of the following
factors:
o particular types of hazardouswastes;

o industrialprocesses from which the wastes are defined as hazardous;
and
o substances,either specificor classes, the presence of which is
indicativeof a potential human health and or environmentalhazard.
TABLE 2-1
A ProposedWaste ClassificationScheme
Groups
Industrial/Waste Agriculture Mineral Energy Metal Manufacture Chemical Metal
Forestry Extraction Generation Manufacture of Non-metal A Related Goods
and Food Mineral Industries Engineering
Production Products and Vehicle
A B C D E F G-
I InorganicWastes
Acids and Alkalis x x x x x
CyanideWastes x
Heavy Metal Sludges x x x x
and Solutions
AsbestosWastes x x
Solid Residuesn.o.s. x x x
IT Oily Wastes
III OrganicWastes
Spent HnaogenatedSolvents x x
Non-halogenated x x x
SolventWastes
PCB Wastes x x
Paint and Resin Wastes x x
Biocide Wastes x x x x
Organic ChemicalResidues x x x
IV PutrescibleOrganic Wastes x x
V High Volume/Low
Hazard Wastes x x x
VI MiscellaneousWastes
InfectiousWastes x
LaboratoryWastes x
ExplosivesWastes x x
Note: n.o.s. = not otherwisespecified

TABLE2-1 (continued)
A ProposedWaste ClassificationScheme
TextileLeather Manufacture Medical and Commercial

Industrial/WasteGroups
and Timber of Paper Other Health Personal
Industrios Printing and Services Services
Publishing
H J K L
I InorganicWastes
Acids and Alkalis x x
Cyanide Wastes
Heavy Metal Sludges
and Solutions x
Asbestos Wastes
Solid Residues n.o.s.
II Oily Wastes x
III OrganicWastes
Spent
x x
HalogenatedSolvents
Non-halogenated
Solvent Wastes x x
PCB Wastes
Paints and Resin Wastes x x
Biocide Wastes x x
OrganicChemical
Residues n.o.s.
IV PutrescibleOrganic
wastes x
V High Volume/LowHazard
Wastes
VI MiscellaneousWastes
InfectiousWastes x
LaboratoryWastes x
x
ExplosivesWastes
Note: n.o.s. = not otherwisespecified

- 16 -
In some cases, a listing of one or more of these criteria is used as a

definition. In other cases, reference is also made to a particular
concentrationlevel for each hazardous substance.
Other criteria may include the toxicity of an extract of the waste,

usually obtained by means of a specific leaching test. Toxicity is
generally defined by reference to concentrationsof specific substancesin
the extract:
o the ignitabilityor flammabilityof the waste;

o the corrosivenessof the waste; and
o the reactivityof the waste.
Each of these approacheshave their advantagesand disadvantages. The use

of inclusive lists provides a relativelysimple approach, requiringno
testing and also give a certain flexibilityto the waste controlling
authorities in making qualitativejudgementswith respect to an individual
waste disposal option. It has the disadvantage,however, of placing the
burden of decision on the waste controllingauthoritiesas to which of the
industrialprocess wastes shouLd be controlled.
Supplementing(or replacing)such lists with testing procedures and/or

concentrationlimits has the advantage of presenting a clear and accurate
descriptionof wastes, theoreticallyleaving no doubt as to whether the
waste should be classifiedas hazardous or not. These precise
definitions,however, require detailed testing protocols and a
surveillancesystem which, in practice, may pose problems as regards
manpower, laboratory facilities,etc. for both waste generatorsand
controllingauthorities.
The U.S. Toxicity CharacteristicLeaching Procedure (TCLP) is designed to

identifywastes likely to leach hazardous concentrationsof toxic
constituents into the groundwateras a result of impropermanagement.
During the procedure,constituentsare extracted from the waste in a
manner designed to simulate the leachingactions that occur in landfills.
The extract is then analyzed to determine if it possesses any of the toxic
contaminantslisted in Table 2-2. If the concentrationsof a particular
toxic constituentexceeds the level listed in Table 2-2, the waste is
classified as hazardous.
0
In the TCLP test (FederalRegister 1.986), a 100 gm sample is employed.

For wastes containing less than 0.5% solids, the waste--after filtration
through a 0.6-0.8 um glass fiber filter, is defined as the TCLP extract.
Separationis accomplishedwith pressures of up to 50 psi. The particle
size of the solid phase is reduced, if necessary,to a size of about 9.5
mm. The sample is then weighed and extractedwith an amount of extraction
fluid equal to 20 times the weight of the solid phase. The extraction
fluid employed is a functionof the alkalinityof the solid phase of the
waste. If the sample after mixing with distilled deionizedwater has a pH
<5.0, the extraction fluid is made by adding 5.7 ml of 1.0 N Glacial
acetic acid to 500 ml of distilled dIeionizedwater, adding 64.3 ml of 1.0
N NaOH and diluting to a liter. If the sample after mixing with distilled
deionized water has a pH >5.0, add l.5ml 1.0 N HC1, slurry for 30
- 17 -
TABLE 2-2
Toxicity Criteria
Contaminant MCL (ppm)
Arsenic 5.0
Barium 100.0
Cadmium 1.0
Chromium (total) 5.0
Lead 5.0
Mercury 0.2
Selenium 1.0
Silver 5.0
Endrin 0.02
Lindane 0.4
Methoxychlor 10.0
Toxaphene 0.5
2,4-D 10.0
2,4,5-TP Silvex 1.0
- 18 -
seconds, cover with a watchglass,heat to 50 degrees C and hold for 10

minutes. If the sample after cooling has a pH <5.0, the extraction fluid
previously described is used. If the pH is >5.0, the fluid is made by
diluting 5.7 ml glacial acetic acid with distilled deionizedwater to a
volume of 1 liter. A special extract:or vessel is used when testing for
volatiles. Following extraction, the liquid extract is separated from the
solid phase by 0.6-0.8 um glass fiber filter filtration.
If compatible,the initial liquid phase of the waste is added to the

liquid extract and these liquids are analyzed together.
The characteristicof ignitability/flammability is a concern because these

wastes could cause fires during transport, storage or disposal. Typical
examples are waste oils and used solvents. These wastes often have the
properties of:
(a) being a liquid, except for aqueous solutions containingless than 24Z
alcohol, that has a flash point less than 60 degrees C;
(b) a non-liquid capable, under normal conditions, of spontaneousand

sustained combustion;
(c) an ignitable compressedgas; or
(d) an oxidizer.
Materials that might be consideredhazardous because of corrosivityare:

an aqueous material with pH <2.0 or FH >12.5; or a liquid that corrodes
steel at a rate greater than one-quarterinch per year at a temperatureof
550C. Wastes with high or low pH can.react dangerouslywith other wastes
or cause toxic contaminantsto migrate from certain wastes. Wastes
capable of corroding steel can escape from their containers and liberate
other wastes. Examples of such corrcsivewastes include acidic wastes and
used pickle liquor.
A reactivewaste might be expected to have one or more of the following

properties:
(a) normally unstable and reacts violently without detonating;
(b) reacts violently with water;
(c) forms an explosivemixture with water;
(d) generates toxic gases, vapors or fumes when mixed with water;
(e) contains cyanide or sulfide and generates toxic gases, vapors, or

fumes at a pH of between 2 and 12.5;
(f) is capable of detonationif heated under confined conditions or

subjected to a strong initiatingforce; and
- 19 -
(g) capable of detonationat standard temperatureand pressure. Examples

of reactivewastes include water from TNT operationsand used cyanide
solvents.
The choice of the most appropriatesystem depends upon the use to which
the classificationsystem will ultimately be put. For the purpose of this
manual, three objectivesare consideredof particular importance:
o to allow the waste controllingauthority to use its knowledge of

industry to draw up a short-listof wastes;
o to identifywastes in a way that is consistentwith the discussionof

technologiesfor recovery, treatment and disposal; and
o to provide the waste controllingauthoritywith a framework appropriate

for establishingtheir own hazardouswaste control system.
To achieve these objectives, the classificationscheme proposed here is a

qualitative listing, using a combinationof some specific types of waste
with classes of substancesspecific substancesand industrialprocesses to
identifywaste types.
2.4 Proposed C_a sification Scheme--Notationof Health/EcologicalConcerns
A proposed waste classificationscheme linkingwaste types to industrial

categories is shown in Annex 2. The purpose of the annex is to enable
planners to identify the major types of wastes associatedwith broad
industrial groups. The industrialgroups used for the waste
classificationscheme are defined in Table 2-3.
Further details of each waste type including examples of particularwaste

streams are included in Table 2-1. These listings are examples of the
most importantwaste streams likely to be encountered.
A brief descriptionof each waste type includingmajor subcategoriesand

sources of generation,is given below.
(A) Inorganic Wastes
Acids and alkalis are among the major componentsof the total amount of
hazardous waste generated. They occur in many sectors of industry,
although in termsiof quantity, acid wastes come mainly from the surface
preparation and finishingof metals.
The major hazard with acids and alkalis is their corrosive action,
complicated--insome cases--by the presence of toxic constituents.
Cyanide wastes are generated primarily in the metal finishing industry and
in the heat treatment of certain steels.
The principal hazard associatedwith cyanide waste is their acute

toxicity.
- 20 -
TAB]E 2-3
IndustrialGroups
A Agriculture,Forestr-yand Food Production
o agriculture,forest management, fisheries;

o animal and vegetable products from the food sector;
o drink industry;
o manufacture of animal feed.
B Mineral Extraction (excludingHydrocarbons)
o mining and quarrying of non-metallicminerals;

o mining and quarrying of metallic minerals.
C Energy
o coal industry, includingmineral extraction,gasworks and

coking;
o petroleum and gas industry includingoil and gas
extraction,and refined products;
o productionof electricity;
o production of water;
o distributionof energy.
D Metal Manufacture
o ferrous metallurgy;
o non-ferrousmetallurgy;
o foundry and metal working operations.
E Manufacture of Non-Metal Mineral Products
o constructionmaterials, ceramics and glass;

o salt refining;
o asbestos goods;
o abrasiveproducts.
F Chemical and Related Industries
o petrochemicals;
o production of primary chemicals and chemical feedstocks;
o production of inks, varnish, paints and glues;
o fabricationof photographicproducts;
o perfume industryand fabricationof soap and detergent
products
o finished rubber and plastic materials;
o productionof powders and explosives;
o productionof biocides.
- 21 -
TABLE 2-3 (continued)
IndustrialGroups
G Metal Goods, Engineeringand Vehicle Industries
o mechanical engineering;
o manufacture of office machinery and data processingof
equipment;
o electronicand electricalengineering;
o manufacture of motor vehicle and parts;
o manufacture of other transport equipment;
o instrumentengineering;
o other metal good manufacturingindustriesn.o.s.
H Textile, Leather, Timber and Wood Industries
o textile, clothing and footware industry;

o hide and leather industry;
o timber, wood and furniture industry;
o other non-metallicmanufacturingindustriesn.o.s.
J Manufacture of Paper and Products, Printing and Publishing
o paper and cardboard industry;

o printing, publishing and photographiclaboratories.
. Medical, Sanitary and other Health Services
o health; hospitals,medical centres and laboratories;

o veterinary services.
L Commercialand Personal Services
o laundries,dyers and dry cleaners;

o domestic services;
o cosmetic institutions(e.g., hairdressers);
o other personal servicesn.o.s.
- 22 -
Heavy metal sludges and solutionsof most concern are those containingthe
toxic metals, arsenic, cadmium, hexavalentchromium, lead, mercury,
nickel, zinc, and copper. These wastes are generated from a wide range of
manufacturingprocesses, includingchlorine production,pigment
production,wood preserving,battery production,textiles, metal plating
and tanning.
Asbestos wastes normally arise from lagging wastes, power stations,

industrialmanufacturingplants, gas works, dock yards, hospitals and
educational establishments. Materials containingasbestos may also appear
as waste from the demolitionor rebuildingof locomotivesand railway
carriages, and from building and demolition sites.
The health hazards associatedwith inhalationof asbestos fibers and dust

stem from the carcinogenicpotential of the material. Asbestos cement
pipes and sheets are typicallymuch less of a problem than loose fibers or
dust.
Other solid residues are generated from a variety of sources of which the
most significant is the smelting and refiningof metals. Dusts and
sludges generated from these processes typicallycontain toxic metals
including nickel, arsenic, zinc, mercury, cadmium and lead.
(B) Oily Wastes
Oily wastes are generated primarily Erom the processing,use and storage
of mineral oils. Examples include waste lubricationand hydraulic fluids,
bottom sludges from oil storage tanks, waste cutting oils and interceptor
waste. In some cases, these materiaLsmay be contaminatedwith toxic
metals (e.g. sludges from leaded pet.ol storage tanks, etc.).
(C) Organic Wastes
Halogenated solvents are generated primarily from dry cleaning operations,

metal cleaning in the engineeringindustry and, to a much smaller extent,
from degreasingand deoiling processes in the textile and leather
industries. The hazards associatedwith these wastes are a result of
their toxicity,mobility, and relativelyhigh persistencein the
environment.
Non-halogenatedsolvent wastes include a large number of hydrocarbonsand

oxygenatedhydrocarbons,of which some of the most commonly used are white
spirit, toluene, methanol, isopropanol,and ethanol. They find wide
application throughoutindustry in the production of paints, inks,
adhesives, resins, solvent-basedwood preservatives,toiletries,food
flavorings,cosmetics,and also for plant and equipment cleaning and as
thinners. They are also used as degreasants in the engineeringand
vehicle manufacturingindustriesand are used for the extractionof
natural products from animal and vegetable sources.
The toxicity of these materials varies greatly, and in many cases the
major hazard posed is flammability.
- 23 -
PCB wastes are generated from the manufacture of PCBs and from the
decommissioningof equipment in which PCBs are used, principallyas
dielectricfluids in transformersand capacitors,and also as hydraulic
fluids and heat transfer fluids. The major concernswith PCBs is
associatedwith their high persistenceand bioaccumulationpotential.
Paint and resin wastes are generated from a variety of formulationand

other tertiary chemical processes,and also in the application of paints
and resins to finished products. They are typically combinationsof
solvents and polymeric materials including, in some cases, toxic metals.
Biocide wastes are generated both in the manufacture and formulationof

biocides and in the use of these compounds in agriculture,horticulture
and a variety of other industries. The range of biocides used runs into
several thousand compounds. (For informationon their classification,see
Annex 2).
In addition to the concentratedorganic waste streams described above,

organic chemical residues are also generated from coal carbonizationand
by-products operations;and from the manufacture or primary, secondary,
and tertiary chemical products. Distillationresidues and filter
materials are common components. These waste streams include both
halogenated and non-halogenatedchemicals,and are generated by a broad
range of industries,including petroleum refiningand the manufacture of
chemicals, dye stuffs, pharmaceuticals,plastics, rubbers, and resins.
(D) PutrescibleOrganic Wastes
Putrescible organic wastes includewastes from the production of edible

oils, as well as leftovers from slaughterhouses, tannaries,and other
animal-basedproducts. The proper handling of putresciblewastes is of
particular importance in developingcountrieswhere extreme climatic
conditionscan exacerbate the possible health hazard associatedwith these
organic wastes.
(E) High Volume/LowHazard Wastes
High volume/low hazard wastes include those wastes which, based on their
intrinsic properties,present relativelylow hazards, but may pose
problems because of their high volumes. Examples include: drillingsmuds
from petroleum and gas extraction,and fly ash from fossil fuel-fired
power plants, mine tailings, or metaliferousslags.
(F) MiscellaneousWastes
In addition to the waste classes described above, there are a number of

other miscellaneouswaste types which have not been addressed. These
include: infectiouswastes associatedwith diseased human or animal
tissues; redundant chemicals,which may have deterioratedor exceeded
their shelf-life,and come from retail shops, commercialwarehouses, and
governmentaland industrialstores; laboratorywastes from manufacturing
and research facilities;and explosivewastes from manufacturing
operations or surplus munitions. Although these wastes typically do not
_ 24 -
represent a large proportionof total hazardous waste generation, special
provision should be made to ensure their safe and proper disposal.
2.5 Potential Pathways of Release to the Environment
The potential pathways by which ha.zardouswastes can enter the human

environment are summarizedin Figure 2-1. Some pathways correspond to a
direct input to an environmentalcompartment,such as the evaporationof a
chemical to the atmosphere. Other pathways represent indirect inputs,
such as the atmospheric deposition.of wind-borne particulatematter to
surface waters. The relative impcrtanceof each pathway is not only
dependent on the physical, chemical, and biologicalproperties described
earlier but also on the characteristicsof both the disposal site and the
underlying geology.
2.5.1 GroundwaterMovement and Contamination
The characteristicsof the subsurfaceenvironmenthave a major influence

on the aqueous transport of chemical contaminantsand micro-organismsfrom
disposal sites. Of particular importanceis the presence of an
unsaturated zone beneath the land disposal site. This is the zone, above
the water table, where water generallymoves verticallyuntil it
encounters the groundwaterflow (when the movement becomes horizontal).
It is an advantage to have arnunsaturatedzone beneath the landfill
because this severely restricts leachatemovement from the site and
therefore increases the opportunityfor attenuationby chemical and
biochemicalprocesses.
In recent years much attentionhas been paid to the transport of

contaminants,particularlyorganic compounds,in the saturated zone. It
is important to note that some chemicalswill dissolve/dilutein water,
while others--withlow chemical soLubility--willlead to compounds that
are called "floaters.' It has been found that some organic solventscan
migrate through the sub-surfaceenvironment,particularlythose with a
lower density than water. Appropriately,the "floaters"spread across the
top of the water table. By contrast, dense organic liquids, called
"sinkers," migrate vertically down the aquifer. Contaminant flow rates in
the saturated zone are highly variable and depend to a large extent on the
characteristicsof the aquifer. Transport times are generally shorter in
a sand aquifer than a clay one, but:transport can be more rapid in the
latter if the clay is fractured. The actual time scales regarding the
movement of contaminantsout of a waste site are generally very long. It
can take decades for a contaminant to migrate from a disposal site to
nearby drinkingwells. Once the chemical appears in the well water,
however, it may remain there, in elevated amounts, for many years, even if
remedial action is taken at the disposal site. Furthermore,the arrival
of one pollutant in well water may signal the arrival of dozens more
contaminants,entering the water over the course of many years.
2.5.2 Surface Water Contamination
Open water bodies near to disposal sites can receive hazardous wastes
directly from surface runoff. In addition, the groundwater flow of
- 25 -
FIGURE 2-1
Physical and BiologicalRoutes of Transport of Hazardous Substances,

their Release from Disposal Sites, and Potential for Human Exposure
Evaporation
a | AtmoDsphere Ihlto
/ / \ \ ~~~~~~~~~~~Expiration
/ z \\t~~~~~~~~~~~~Eimincffion)
Wnd Borne Disoiin \

Particles
Chemnical
Disposal
Sorption
Oh
__
Soil
DlrectContact Autc and
Terrestral
Ingestion
op |
r Man
Slte _Biota ~ orRunoff Sedime lsin \ (ofFood)
Tco oe i \0 Ing(siy/
&
f Parftiulate Sdre-% /
0 or
Ruycnof rrtin -/
| ~~~~Leoching or-_/ xrtion
DirectSurfaceRundff ON wt r Ingestlon(ofWater)
- 26 -
chemicalsmay also lead to inputs of contaminantsto surface waters.

Aerobic conditions,which generally prevail, can facilitate the chemical
and biological degradationof organic compounds,while volatilizationwill
also be more pronounced in surface waters than in groundwater. One must
be concerned about bioaccumulaticonand the toxicity of some wastes--at low
concentrations--tofish and other aquatic biota.
2.5.3 Other Pathways of Release
Those organic compoundswith a high vapor pressurewill show a tendency to

be released to the atmosphere from disposal sites. The vaporization rates
of chemicals from buried wastes in landfill sites are much smaller than
when wastes are spread over the land, or placed in surface impoundments.
Nevertheless,the quantitiesof volatile wastes lost to the atmosphereat
landfill sites can be very Large on an annual basis. Fires at disposal
sites will lead to an increase in the vaporizationof volatile compounds.
Wind-blown dispersal is another potential pathway of release to the

environment (affectingpeopLe through inhalation). Certain solid wastes,
asbestos for example, are particularlysusceptibleto wind-blown
dispersal. The mobilization of contaminatedsoil or the contaminants
themselvesmay be a particularproblem at poorly managed sites, or where
remedial activities require the use of many large vehicles.
It is conceivablethat vegetationgrowing on land near waste sites, or on

rehabilitated(former)landfill sites, will take up hazardous chemicals
via root absorptioneither from contaminatedsoil or from the waste
itself. Some chemicalsmay be translocatedfrom the roots to the upper
parts of the plant. The depositionof wind-blown contaminatedsoil
particles onto the surface of the plant is another potential exposure
pathway (particularlyfor vegetation growing in the vicinity of poorly
managed landfills.
2.6 Factors Affecting the EnvironmentalBehavior of Chemicals
This section describes the major physical, chemical, and biological

processeswhich can affect the environmentalbehavior of hazardous
chemicals at waste disposal sites. Referencewill be made to a variety of
chemicals.
Most attention is paid in this section to the behavior of chemicals at

land disposal sites as these are the predominantmethods of hazardous
waste disposal. The wastes encounteredat these sites can be complex
mixtures of organic and inorganichazardous chemicals in combinationwith
other non-hazardouswastes. Such wastes can be in the form of solids,
sludges or liquids or mixtures of all three. Major environmentalrisks
include the leaching of chemicals and subsequentcontaminationof water
sources as well as release to the air. In this respect, the geology and
hydrogeology of the site, as well as local climatic conditions, are all
important factorswhich influence the behavior of hazardous waste.
- 27 -
2.6.1 Physical and Chemical Factors
A number of physical and chemical factors are important in determining the

behavior of chemicals in the environment. They are:
o Leaching;
o Adsorption/Desorption;
o Volatilization;and
o Bioaccumulation,etc.
These factors can act in a complex and interrelatedseries of reactions

which may themselvesbe dependent on the geochemicalcharacteristicsof
the disposal area.
Generally,the higher the water solubilityof a compound, the greater the

potential for leaching from the landfill site. Many hazardous organic
compounds display low water solubilities. However, the presence of
p.rtiallywater miscible solvents, such as chloroform,can enhance the
leaching of organic compounds from landfill sites, as can the formation of
emulsions. Many inorganic chemicals ionize on contact with water to
produce dissolved ions. In the case of trace metals, solubilityis
controlledmainly by speciation,but it can be further reduced by
adsorptionand ion exchange. In some cases, the metal can form complexes
which enhance solubility. Cyanide may also enhance the solubilityof
trace metals. The fatty acids producedby bacterial degradation of
domesticwastes can also form soluble complexeswith metals.
The adsorption of compounds onto soil particles or waste material is an

important phenomenonwhich tends to restrictthe movement of both organic
and inorganic chemicals from the landfill site. In addition, the process
of adsorptionmaybe an importantfactor in retarding the migration of oil
wastes. The soil adsorptioncoefficientof a chemical describes its
potential for binding to soil particles. For organic compounds it appears
that the partitioningbetween water and organic carbon is the most
important factor. A compoundwith a low soil adsorption coefficientwill
generally tend to migrate from the landfill site. For example,phenol is
not only highly water soluble but also has a low soil adsorption
coefficient;these characteristicsare reflectedby rapid leaching of
phenol in many landfill sites.
Volatilization,as noted previously, is a potential route by which

hazardous wastes migrate out of landfills. This phenomenonmay be
particularly important for certain organic compounds and can occur at a
significant rate for chemicals such as chloroform,which have a high vapor
pressure. Conversely, leaching can be expected to be more important for
those chemicalswith a low vapor pressure, particularlyif the compound
also has a low soil adsorptioncoefficient. It should be stressedthat
factors other than the vapor pressure, such as the diffusion coefficient,
can also have an important influence on the transport of compounds in a
landfill. For example, disposal site characteristicssuch as temperature,
soil moisture, and soil pH, as well as the water solubilityof the
compound, all influence the extent of volatilization. Thus, the elevated
temperaturesencounteredat many disposal sites--theproduct of microbial
- 28 -
activity--willenhance the upward movement and evaporation of many

volatile organic compounds. Nevertheless,the downwardmigration of these
compounds has still been found to be important,particularlywhen large
quantities are disposed of, as occurs for waste solvents.
Some chemicals, like methylene chloride and ethylene dichloride,have high

vapor pressures and high solubil:ities
and thus can be lost by leachingand
volatilization.
For organic compounds, the octanol/waterpartition coefficient 'P' is

often used as an index of the bioaccumulationpotential for a chemical in
the aquatic environment. This coefficientis somewhat correlatedwith a
compound'smolecular weight. Thus, a chemical such as DDT, which has a
high P value, displays a marked potential for bioaccumulationin aquatic
organisms. This coefficient is also proportionalto the soil adsorption
coefficient,although not linearly, reflectingthe importanceof the soil
organic matter in the adsorptionof organic compounds. Therefore,this
coefficientalso provides an insight into the importanceof a compound's
ability to bind with soil particles. This is of particular relevance for
particle transport from the landfill site, either by wind-blown dispersal,
or by runoff during heavy rainfall.
2.6.2 Degradation of Chemicals
The persistence of hazardous organic chemicals is an important determinant

of their environmentalfate. Certain compounds can undergo either
chemical or biological degradationat land disposal sites, while others
are resistant to any transformationand may even be toxic to soil micro-
organisms. The pattern of degradationis not only influencedby the
conditions in the landfill. Degradationmay also be initiated during the
transport of chemicals in the leachate, surface water, or groundwater.
The major chemical processes associatedwith the degradation of organic
contaminantsat disposal sites have been identifiedas hydrolysis,
biodegradation,photolysis, and oxidation;the latter is thought to be of
particular importancein the degradationof phenols and aromatic amines.
Nevertheless,the overall significanceof chemical reactions in degrading
toxic substancesat disposal sites is largely unknown. For this reason,
simply because a contaminantundergoes efficient chemical degradation in
the Laboratory,it should not be assumed that degradationwill occur to
the same extent--ifat all--in disposal areas.
In certain instances, reactivechemicals can come into contact at the same

disposal site, resulting in fires or explosions. Figure 2-2 summarizes
the undesirable reactionswhich can occur when incompatiblewastes
containinghazardous compounds are mixed together. These reactions
include:
o Exothermic reactionswhich may result in fires or explosions;these may
be caused by alkali metals anc.strong oxidizing agents.
o Production of toxic gases such as arsine, hydrogen sulphide,hydrogen
cyanide, and chlorine.
o Production of flammable gases such as hydrogen and acetylene.
- 29 -
FIGURE 2-2
Compatibilityof SelectedHazardousWastes
Oxidising E Explosive
1Mineral Acids1
F Rre
2 Caustics H 2] GF FlammableGas
3 Aromatic H 3 GT Toxdc
Gas
Hydrocarbons F
4_ Halogenated H - - H HeatGenercion
Halogencrted H H ________
4Organics GF GF S of Toxins
Solubilisation
GF H
5 Metals HF F 5
6 ToxicMetals S S 6
Sat Aliphatic H
Hydrocarbons F
Ph)enols H
8 and Cresols F 8
9 StrongOxidising H H H H
Agents F F
10 StrongReducing HF H GF HF
__Agents GT GT H F 170
Waterand Mixtures H GF
containingWater H E GT 11
12 WaterReactive Exremnelyreactive,do nf mixD _ 12

Substances with any chemical orwaste material
I~~ I ~ 1 I 1 1 _
*-30 -
Hazards are also associatedwith certain types of wastes which are

unstable under ambient conditionsor with motion (e.g. silane metal
hydrides, alkalis metals/alloys,and organic peroxides).
Photodegradationis commonly identifiedas an importantmechanism for the

breakdown of organic compounds in the environment. However, this process
will only be of any significancein the top few centimeters of the
disposal site surface which is exposed to UV light. Photodegredationmay
be of greater importancefor those compoundswhich have vaporized from the
site, or entered surface waters.
It is currently consideredthat biologicaltransformationis a significant

degradationpathway for many contaminantsin disposal sites. These
microbial transformationsmay take place either at the land disposal site
or in groundwater. Microbial activitymay lead to the degradation of a
contaminant to harmless, or less hazardous products, but may also result
in the biosynthesisof persistent and toxic compounds. For example,
microbial transformationof three solvents--trichloroethylene,
perchloroethylene,and 1,1,1-trichloroethane--can lead to the formation of
vinyl chloride, a compound resistant to further breakdown and a proven
carcinogen. The degradationof many contaminantsis most efficient under
aerobic conditions,but these conditions only arise at the surface of the
disposal site. The environmentalconditions required for biodegradation
are well known for some chemicals. In the case of cyanide these are:
temperaturesin excess of 10 degrees C, a pH of 6-7.5, and a maximum
cyanide concentrationof 100 mg/l.
The anaerobic conditionswhich predominate in landfill sites favor the

bacterial reduction of sulphates,nitrates, and carbohydrates. Sulphate
is reduced to sulphide and nitrate is reduced to nitrite or ammonia. The
microbial production of sulphide under anaerobic conditions can cause a
marked reduction in the concentrationof dissolvedmetals in leachateby
the precipitationof insoluble sulphiles. This attentionmechanism is
particularlyimportant for some metals, notably inorganicmercury.
In anaerobic conditions,bacterial activity is also responsible for the

production of "landfillgas." Although landfill gas is generally
associatedwith the disposal of domesticwastes, it may still occur at
sites receiving hazardous wastes in combinationwith domestic refuse.
Generally, the major components of landfill gas are carbon dioxide and
methane, but hydrogen sulphidecan also be a minor constituent. Several
factors influence the rate of landfill gas production and its composition;
the main parametersbeing temperature,moisture content,waste density,
and pH value of the waste material. The optimum pH range for methane
production is 6.4-7.4 and the optimum temperaturerange for anaerobic
decompositionis 29-37 degrees C. The decompositionof some organic
components in waste is so slow that significantconcentrationsof methane
may be produced for many years after the waste has been deposited. The
major problem associatedwith landfillgas is the serious risk of fire and
explosion which occurs when the concentrationof methane falls within the
range of 5-15Z. Proper precautionsmust be taken. In addition, landfill
gas can also be a factor in flushing volatile organics from the fill.
- 31 -
2.7 Effects of Hazardous Wastes on Health and the Environment
Mixing chemicalwastes containingincompatiblechemicals may cause

explosionsand fires (see Figure 2-2). Contact with strong acids or
alkali may cause corrosion and etching of the skin as well as severe
corneal damage. Skin absorptionof certain pesticidesmay cause acute
poisoning. Most empty containers or jars for hazardous chemicals can--if
not properly disposed of--resultin incidents of severe poisoning if left
unguarded at waste storage or dumping sites. Children are especially
vulnerable. In the developed world, one of the main causes of child
mortality--betweenthe ages of 1 and 10--are accidentswhich involve
accidentalpoisoning. If chemicals are introducedon the consumermarket
and no provisionsmade to collect the empty containers,bottles, or jars,
they are likely to be stored in households or disposed of in an
uncontrolledway. This has resulted in a substantialnumber of poisoning
cases involving small children.
As previouslynoted, the release of chemicalwaste into the environment

may result in long-term exposure of the population,causing adverse health
effects due to poisoning. The following example is illustrative. Water
containing a large amount of cadmium was discharged from the Kamioka zinc
mine in Japan into a river that was used for drinkingwater downstream
from the mine. The river water was also used for irrigatingpaddy rice.
Because of the large amounts of cadmium in the water used for both
drinking and irrigationpurposes, the long-termexposure of the local
population to this chemical resulted in serious kidney malfunctionsin a
large percentageof the population. The effects,which were most severe
in pregnantwomen with low calcium intakes, as well as those women
suffering from close-spacedbirths, includedde-calcificationof the
skeleton,multiple bone fractures,invalidity,and death (Itai-itai
disease).
The cadmium intake interferedwith normal calcium metabolism, resulting in

the de-calificaitonof bone tissue (osteomalacia). In many industrial
countries both the body burden and the kidney content of cadmium have been
considerablyraised due to environmentalexposure from chemicalwaste or
cadmium impuritiesin fertilizers. However, so far no adverse health
effects have been reported. These increased levels have, nontheless,
caused a great deal of concern and measures have been taken to limit
population exposure until a satisfactorysafety margin has been identified
between cadmium levels present in the kidneys and levels at which impaired
function is likely to occur.
In other areas of Japan, industrialuse of mercury catalysts resulted in

the presence of mercury in the effluents from wastewater treatmentplants
entering coastal waters. The mercury was then converted,by micro-
organisms present in seawater, into methylmercury,a highly toxic form of
mercury. At Minamata Bay and the Agano River at Niigata, methylmercury
accumulated in fish and shellfish. As seafood is an importantpart of the
Japanese diet, many local inhabitantswere poisoned and developed severe
neurological symptons, such as impairedvision and hearing loss and
difficulties in walking or standing. Children exposed in utero exhibited
cerebral palsy syndrome or retardedpsycomotor development. These
- 32 -
Japanese outbreaks of methylmercurypoisoning are still the best

documented cases on record. Neverthelesssimilar outbreaks have occured
in other countries.
In some regions, the body burden of methylmercuryhas increased due to the

regular consumption of contaminatedfish and shellfish. Measures have
therefore been taken to regulate both the intake and the mercury content
of fish, as well as limiting the amount of mercury discharged into the
environment. Chemical elements, like mercury, are indestructableand
hence can only be redistributedinto the environment. By contrast,
organic chemicals are often degraded in the environmentto elemental
components or simple organic compounds such as carbon dioxide and water.
However, some chlorinatedor haLogenated organic compounds are extremely
persistent in the environmentand tend to accumulatein the food chain or
in the biosphere in general. Examples of such compounds include: PCBs,
dioxins, and chlorinatedhydrocarbons;the latter being used extensively
in the past as pesticides (e.g. DDT, dieldrin, and aldrin). PCBs and
dioxins may be formed by incinerationof waste containinghydrocarbonsand
chlorides. They are spread with atmosphericemissions and precipitate in
the environment. Once released, they often end up in human food chains,
lodging in fatty tissues in the bodies of humans and animals. It is known
that in some industrializedcountries,notably Sweden and Japan, levels of
PCBs and dioxins in breast milk and human fat are on the increase. The
health significanceof this increase is still uncertain, as the body
burden at which adverse health effects might occur is still unknown.
However, experiencefrom accidentalhigh level exposures has shown that
these compoundsmay cause serious effects on human health.
Leakages from landfills and dumping sites often contain large amounts of
nitrates. This has often resull:edin high levels of nitrates in adjacent
drinking water wells. Levels oilnitrates in drinkingwater exceeding 45
mg/l run a risk of methemoglobinemiain infants. This condition,which
interfereswith the oxygen transportationin the bloodstream,can be
fatal. There are several reporl:sin the literature about severe
methemoglobinemiain infants caused by contaminateddrinking water.
Another important consequenceof finding nitrate in leachate from

landfills,is the simple fact that the site is leachingcontaminantsinto
the environment. If industrial residualsare being placed in the site as
well, then the possibilityexists for a whole host of contaminantsto find
their way into drinkingwater (i:ncludingsome which are considerablymore
deadly than nitrate).
Other land disposal catastrophescan be noted. For instance, at Love

Canal in New York State, chemicals and vapors began to leak into homes and
schools causing adverse health effects and eventuallyresulting in the
complete evacuationof the town. In the United Kingdom, drums containing
heat treatment cyanide salts were discoveredon waste land used by
children as a playground.
2.7.1 Hazard Identificationand Risk;Assessment
To prevent and/or control adverse effects on health and the environment,

- 33 -
it is necessary to control all chemical and infectiousmaterials

introducedinto the human environment. The chemicalnature of each
product should be determined,togetherwith impurities,by-productsand
degradationproducts. The potential effects of these substanceson health
and the environment should then be assessed togetherwith a quantitative
estimation of levels occuring in the environment. Exposure commitments
for human populations,as well as other organisms,should be undertaken in
the final risk evaluation. From such an evaluation,measures should then
be taken to ensure that unacceptableadverse effects are avoided. The
effectivenessof these control measures should then be monitored on a
continuousbasis.
Hazard Identification
Each waste material should be assessed for organisms that are pathogenic
to man and animals. Such an assessmentcan usually be made and verified
from informationregarding the source of the waste. The chemical
composition of each waste material must also be determined in order to
evaluate potential systemic toxicity togetherwith other effects, such as
mutagenic, cytogenetic,and carcinogeniceffects, as well as effects on
reproductionand foetal/neonatalgrowth and development. In most cases,
such informationcan be found in the literature, such as the World Health
Organization'shealth criteria documents,national safety data sheets
available from ILO or other sources of toxicologicalliterature. When the
required information is lacking it may then be necessary to perform
laboratorytests.
As can be seen from Table 2-2, all the contaminantsstudied in the TCLP
test are of concern in drinkingwater because of their adverse health
effects. The MCLs set are approximately100 times the drinkingwater
guidelines for those contaminants. Arsenic, cadmium, chromium, and lead,
for example, are of concern because of their possible carcinogenicity,
while barium effects the muscles and can cause gastroenteritisor muscle
paralysis. Endrin is a potent teratogen and reproductivetoxin. Chronic
exposure to it can effect the nervous system, heart, lungs, liver and
kidneys.
Once a substance is identifiedin waste, a good place to look for

informationfirst is the Guidelinesfor Drinking-WaterQuality (World
Health Organization1984). They will tell you the health effects and
provide a recommended safe concentrationin water.
Table 2-4 lists the 25 most frequentlyidentifiedsubstancesthat were

found at a large number of hazardouswaste sites. Table 2-5 lists some
health effects informationthat may prove useful when working with wastes.
Again, the recommended levels are for drinkingwater. Designationsare as
follows: Cancer Group A = human carcinogens;B = probable human
carcinogens;Bl = at least limited evidence of carcinogenicityin humans;
B2 = usually a combinationof sufficientevidence in animals and
inadequatedata for humans; C = possible human carcinogen (limited
evidence of carcinogenicityin animals in the absence of data on humans);
D = not classified (inadequatedata); and E = no evidence of
carcinogenicityfor humans.
- 34 -
TABLE 2-4
25 Most Frequently IdentifiedSubstancesat 546 Superfund Sites
Rank Substance Percent of Sites
1 Trichloroethylene 33
2 Lead and compounds 30
3 Toluene 28
4 Benzene 26
5 Polychlorinatedbipheny]Ls(PCBs) 22
6 Chloroform 20
7 Tetrachloroethylene 16
8 Phenol 15
9 Arsenic and compounds 15
10 Cadmium and compounds 15
11 Chromium and compounds 15
12 1,1,
1-Trichloroethane 14
13 Zinc and compounds 14
14 Ethylbenzene 13
15 Xylene 13
16 Methylene chloride 12
17 trans-1,2-Dichloroethylene 11
18 Mercury 10
19 Copper and compounds 9
20 Cyanides (solublesalts) 8
21 Vinyl chloride 8
22 1,2-Dichloroethane 8
23 Chlorobenzene 8
24 1,1-Dichloroethane 8
25 Carbon tetrachloride 8
Source: Adapted from McCoy and Associates. 1985.

Hazardous Waste Consultants 3(2):2-20.Lakewood, Colorado.
TABLE 2-S
HA Summry Table
10-kg Child 70-kg Adult

One-day Ten-day Longer-term Longer-term RMD DWEL Lifetime ug/L at 10-
Canter
Chemical HA(ug/L) HA(un/L) HA(ug/L) HNAun/L) (ug/kg/day) (ug/L) HA (un/L) Cancer Risk Group
Acrylamido 1,600 300 20 70 0.2 7 -- 1 B2
Alachlor 100 100 100 100 10 360 -- 1S B2
AIdicarb 10 10 10 40 1.26 40 10 NA E
Barium 1,500 1,500 1,600 1,500 61 1,800 1,600 NA D
B-nz-n- 236 236 -- -- -- -- -- 70 A
Cadmium 43 43 6 20 0.5 18 5 NA D
Carbofuran 50 50 50 180 S 180 36 NA E
Carbon
Tetrachloride 4,000 160 71 2S0 0.7 26 -- 27 B2
Chlordano 63 83 0.5 0.6 0.046 2 -- 2.7 82
Clorob.nzeno 4,300 4,300 4,300 16,000 43 1,500 300 NA D
Chromium 1,400 1,400 240 840 4.8 170 120 NA D
Cyanide 200 200 200 800 22 770 154 NA D
2,4-D 1,100 300 100 350 10 3S0 70 NA D
DBCP 200 SO -- -- -- -- -- 2.5 B2
Dichlor-o-,m- 9,000 9,000 8,900 31,250 89.3 3,125 820 NA D

Benzenes p- 10,700 10,700 10,700 37,500 107 3,750 75 175 C
HA SummaryTable

One-day Ten-day Longer-term Longer-term RfD DWEL Lifeti; ug/L at 104
Cancer
Chemical HA(ug/L) HA(ug/L)HA(ugLL) HACug/L) (ug/kg/day) (ug/L) HA (ug/L) Cancer Risk Group
1,2-Dichloro-
ethane 740 740 740 2,e00 -- -- -- 38 B2
1,1-Dichloro-
ethylene 2,000 1,000 1,000 3,S00 10 360 7 NA C
cis-1,2-DCE 4,000 1,000 1,000 3,600 10 360 70 NA D
trans-1,2-DCE 20,000 1,430 1,430 1,430 10 350 70 NA D
Dichloro-
methane 13,300 1,500 -- -- 5O 1,750 -- 480 B2
1,2-Dichloro-
propane -- 90 -- -- -- -- -- 111 B2
p-Dioxane 4,120 412 -- -- -- -- -- 700 B2
2,3,7,8-TCDD
Dioxin) 0.001 0.0001 0.00001 3.x10-6 1x10-6 3.6x10- __ 2.2x10- B2
Endrin 20 5 4.6 18 0.045 1.6 0.32 NA E
Epichloro-
hydrin 140 140 70 70 2 70 -- 364 B2
Ethylbenzon- 32,000 3,200 971 3,400 97 3,400 eso NA D
Ethylens
dibromide 8 8 -- -- -- -- -- 0.05 82
HA Sumary Table

One-day Ten-day Longer-term Longer-term RfD DEL Lifetime ug/L at 1O-
Cancer
Chemical HA(ug/L) HA(ug/L) HA(ug/L) HA(ug/L) (ug/kg/day) (ug/L) HA (ug/L) Cancer Risk Group
Ethylene
Glycol 19,100 5,500 5,500 19,250 1,000 35,000 7,000 NA D
Heptachlor/ 10 10 S 5 0.5 17.5 -- 7.6 B2

Heptachlor-
epoxide 10 -- 0.13 0.13 0.013 0.4 -- 3.8 82
Hexachloro-
benzene SO SO SO 175 0.8 28 -- 2 B2
Hexane 13,000 4,000 4,000 14,000 -- -- -- NA D
Legionelia -- -- -- -- -- -- -- NA --
Lindane 1,200 1,200 33 120 0.3 10 0.2 2.6B(CAG) B2/C

S.5(NAS)
Mercury 1.58 1.58 1.58 5.5 0.1S8 6.5 1.1 NA D
Methoxychlor 8,400 2,000 500 1,700 SO 1,700 340 NA D
Methyl ethyl
ketone 75,000 7,500 2,500 8,600 24.7 880 170 NA D
Nickel 1,000 1,000 150 1SO 10 360 150 NA D
Nitrate/ 10 , 00 0 a 1,0008 10,000 10,000 __ 10,000 10,000 NA D

Nitrite 1 ,0 0 0 b l,ooob 1,000 1,000
o- 1,000 1,000 NA D
Oxamyl 176 175 175 175 25 875 175 NA E
a= Value given is for 4-kg infant; One-day and Ten-day HAs for all other populations is 111,000 ug/L.
b= Value given is for 4-kg infant; One-day and Ten-day HAs for all other populations is 11,000 ug/L.
TABLE 2-S (continued)
HA SummaryTable

One-day Ten-day Longer-term Longer-term RfD DWEL Lifetime ug/L at 10-4
Cancer
Chemical HA(ug/L) HAtug/L) HA(ug/L) HA(ug/L) (ug/kg/day) (up/L) HA (ug/L) Cancer Risk croup
Pontach I oro-
phenol 1,000 300 300 1,050 30 1,060 220 NA D
Styr-n- 22,500 2,000 2,000 7,000 200 7,000 140 3 C
TetrachIoro-
*thylene 2,000 2,000 1,400 5,000 14.3 500 10 66 B2
Toluene 21,500 3,460 3,460 12,100 346 12,100 2,420 -- D
Toxaphene 500 40 -- -- -- -- -- 3.1 B2 co
1,1,1-Tri-
chloroethane 140,000 36,000 35,000 125,000 35 1,000 200 NA D
Trich loro-
*thylene -- -- -- -- 7.35 260 -- 280 B2
2,4,5-TP 200 200 70 260 7.5 280 52 NA D
Vinyl chloride 2,600 2,600 13 46 -- -- -- 1.5 A
Xylenes 12,000 7,800 7,800 27,300 82 2,200 400 NA D

- 39 -
On the other hand, some dangerous compoundsare not included in health

advisories. PCBs, chloroform,tetrachloroethylene, phenol and methylene
chloride are all carcinogensand recommendedsafe levels for these
compounds in drinkingwater are as follows: 12.6 ng/l; 0.10 mg/l (total
trihalomethanes);0.88 ugll; 3.5 mg/l and 0.15 mg/l (long-termHealth
Advisory), respectively(USEPA 1986).
An analytical investigationmay be structuredaccording to known

information regarding sources of the waste. Hazard identificationshould
be followedby quantificationand an exposure commitment calculation. If
these procedures indicatea possiblehuman health risk, then it becomes
necessary to measure exposure levels. Biologicalmonitoring of the
exposed population is the preferredmethod as this quantifiesthe actual
intake of the toxic agent. If this is not feasible, intake can be
estimated from measured exposure levels in drinkingwater, food, or air.
Exposure to Man and Animals
Hazardous waste can affect human and animal health through different
mechanisms and routes of exposure. The most obvious route is direct
contact with the hazardous agent during handling of the waste, or waste
adsorbed to oil matter or via empty containers,jars or bags left at
disposal sites, dropped during transportationor reused without proper
cleaning. This could also be a source of disease as well as chemical
contamination. Children are an especiallyvulnerable group as they are
likely to play around waste bins etc., and may put fingers or contaminated
articles in their mouths. Inhalationof dust from waste storage and
dumping sites may also constitutea hazard. This is, for example, the
case for asbestos-containing material. Inhalationof vaporized chemical
waste is also a potential exposure pathway,but is only likely to be of
significanceto the on-site workforce.
Groundwater can be contaminatedfrom dumping sites and landfills.

Hazardous agents, such as bacteria,viruses, and chemicals can be
transferred to drinkingwater wells in this way. Certain viruses and
bacteria may survive for weeks to months in soil and/or inadequately
treated sewage sludge, thus increasingthe risk of such agents being
transferredto drinkingwater supplies.
The transport of contaminantsin surfacewaters results in a rapid and

extensive dispersionwhich can greatly increase the size of the exposed
population. Drinkingwater can also be contaminatedby direct transfers
from disposal sites or by animals (e.g., birds) to surface reservoirs.
Seabirds can also transfer bacteria from coastal sewage outlets and
treatment plants to drinkingwater reservoirs. Other animals (e.g., rates
and insects)may also transfer contagiousdiseases or dangerous chemicals
from dumping sites to households in the community.
Chemicals from hazardouswaste may be taken up by crops from soil-bound

particles or contaminatedsurface-or groundwaters,or if contaminated
water is used for irrigationpurposes. The spreadingof wastes on
agriculturalland and deposition of air emissions from smoke stacks and a
variety of industrialpoint sources constituteother pathways for chemical
40 -
contaminationof vegetation and crops. Consumptionof contaminated

vegetationby animals can result in the tropic transfer of hazardous
chemicals. Livestockmay ingest large quantitiesof soil when feeding on
pasture and this is often a significantsource of exposure in areas with
contaminatedsoils.
Finally, release of waste materials into the sea and via freshwater
sources leaching from disposal sites and treatment plants as well as
atmospheric deposition,may lead to the uptake of chemicals by aquatic
organisms. Those compoundswith high partition coefficientstend to
bioaccumulatein aquatic food chains. This is of particular significance
for compounds which are persistentin the environmentas these show marked
accumulationin fish. Consumptionof contaminatedseafood can be a
significantsource of human exposure,particularlyfor fishing
communities. Figure 2-2 summarizesthe different exposure pathways of
hazardous wastes back to human populations.
Assessment of Health Risks
With identificationof a hazard, accessinghealth effects data-including

dose-responseinformationon the particular contaminant(s)--and
determinationof public exposure to the hazard, a risk assessmentcan then
be made. The risk of adverse effects on human health and the environment
from the presence of hazardous chemicals or pathogenic organisms present
in waste is fully assessedby quantifyingtarget organism exposure. This
will determinewhether there is a potential adverse health risk and
whether there is a sufficientsafety margin between exposure levels and
levels known to cause adverse health effects. The safety margin required
varies between a factor of 2 to an order of magnitude greater, depending
on factors such as the type of effect induced, the number of people at
risk, or the extent of environmentaldamage. A substance causing
irreversibleinjury and/or death will require a larger safety margin than
a substancewhich may induce mild skin irritation,for example.
Similarly,if thousands of people are at risk, the safety margin has to be
larger than if just a few individualsare at risk. If the risk assessment
reveals that the hazardous waste will impose an unacceptablerisk to human
health or the environment,then measures must be taken to limit the risk
to an acceptable level.
During the period 1964-1972 an estimated 300,000 barrels of liquid and

solid wastes were buried in shallow trenches at a 200 acre dump site in
Hardeman County, Tennessee (U.S.A.). In 1972, a nearby test well was
found to be contaminatedwith hazardous chemicals,and the site was
closed. An analysis of water from private wells close to the dump showed
no contamination. However, five years later, in 1977, the situation
changed dramatically. Residents in the area of the dump became alarmed by
the unusual and unpleasant odor and taste of their well water. Some
people experienced skin and eye irritation,weakness in the upper and
lower extremities,severe gastrointestinalsymptoms including nausea,
diarrhea, and abdominal cramps. The local authoritieslaunched an
investigation. Analysis of the well water revealedhigh concentrationsof
carbon tetrachlorideand small amounts of other organic compounds known to
have been dumped at the site by a pesticide manufacturer. The highest
- 41 -
concentrationof carbon tetrachloridefound in one well was 18.7 mg/I. As

no method for biologicalmonitoringof carbon tetrachloridewas available,
it was decided to look for effects on liver function, as this is the main
target organ in carbon tetrachloridetoxicity. Liver function tests were
performed on 36 exposed individualsand compared to a reference population
of 56 people. A higher prevalenceof enlarged liver and impaired function
tests was observed in the exposed group. All signs returned to normal
after cessation of exposurewhen examined a year later in a follow-up
study.
It is important that in any case where potential exposure is discovered

from hazardous wastes, the public is informed immediatelyabout the source
of exposure and the potential health risks involved. Such risks should
then be comparedwith other risks, such as those associatedwith smoking,
traffic accidents, alcohol consumption,and other estimable risk factors.
An information system should be set up to ensure that the progress of
ongoing investigationsis being reported adequately. Such informationis
necessary in order to prevent the public from over-reactingand falling
victim to political exploitation.
2.8 Degree of Hazard Concept
In identifyingand classifyinghazardous wastes, it is important to

recognize that there are varying degrees of hazard associatedwith
different waste streams. To reflect these differences,regulations in a
number of countrieshave examinedmethods of ranking wastes according to
how great a hazard they present.
There are strong economic arguments for doing this: It enables resources
to be allocated so that the most dangerouswastes can be tightly
controlled. In a number of European countries,this type of approachhas
been adopted in national regulationsusing concentrationsof constituents
to indicatewhether or not a waste should be subjected to a high degree of
monitoring and control. Other "degreesof hazard' schemes have considered
the mobility of wastes as a criterion for establishingthe degree of
hazard.
There are, however, a number of difficultiesin implementingthis type of

quantitativeapproach to degree of hazard assessments. In the first
place, the amount of informationneeded is daunting. For this reason (and
others) an alternativeapproach is recommendedhere. Under this system,
three main categoriesof waste are defined.
o The first category includesthose wastes of priority concern (Category

1) known to contain significantconcentrationsof constituentsthat are
highly toxic, mobile, persistent,or bioaccumulative. Examples of
Category I wastes would include the following:
* chlorinated solventwastes from metal degreasing. These are

included because of their toxicity, mobility, and--to some extent
--persistence in the environment;
* cyanide wastes are includedbecause of their acute toxicity;
* PCB wastes are on the list because of their persistenceand
bioaccumulativeproperties.
- 42 -
o Most wastes not singled out for special attentionwould be designated

as Category 2 wastes. These would include metal hydroxide sludges
(excludinghexavalentchromium) for which the toxic metals are in a
relatively insolublephysical form with low mobility.
o Category 3 includes primary large volume, low hazard wastes and some
putresciblewastes, for which the cut-off between a 'hazardous'and
'non-hazardous'waste is least clear-cut.
It is emphasized,however, that this scheme is not intended to diminish

the concern for the proper handling of Category 2, or even Category 3
wastes. Rather, it is an attempt to identify those waste streams for
which a consensus has been reached that a particularlyhigh degree of
hazard is present, and accordinglyfor which a high degree of attention is
warranted. It also allows certain related low hazard (Category3) wastes
to be brought under scrutiny, since in some local circumstancestheir
control may assume high priority.
In Annex 2, an attempt has been made to categorizevarious types of waste.

However, in some cases more specific informationon concentrationsand on
properties--suchas flashpoint--isrequired. These factors should be
taken into account in assigning a waste to a particular category of
hazard.
As new substancesof concern surface and the need for additional

health/environmentaleffects informationdevelops, please consult your
local/nationalhealth depart:ment.If necessary, they will in turn contact
their local UNEP/WHO representativefor assistance.
2.9 EnvirormentalEffects of HazardousWaste Disposal
Adverse effects on biota can arise at disposal sites as a result of

constructionactivitiesand the subsequentrelease of toxic chemicals to
the environment. In addition, the plants and animals living in the
vicinity of such sites can be used to evaluate the geographicalextent and
intensity of contaminationresulting from hazardous waste release. This
activity, termed biologicalmonitoring,generally relies on measurement of
the concentrationof the contaminant(s)in the species selected for
examination. The presence of sub-lethaleffects may also be investigated,
but these are often difficu:Ltto relate in a causal manner to a specific
chemical. Biologicalmonitoring offers the advantage that containment
levels in biota are often muichhigher than in the physical environment.
This is of particular importancein the aquatic environment,where
pronounced bioaccumulationresults in markedly elevated levels of certain
organics in fish, even in waters which contain low levels of these
compounds. In the case of food crops or livestock,measurement of the
pollutant concentrationwilL not only provide an insight into the extent
of environmentalcontamination,but will also allow an estimationof the
potential exposure resulting from the consumptionof such food items.
Increased mortality of biota, particularlylarge animals, can provide an

early warning of contaminant release from a disposal site. An example is
the numerous cases of fish deaths resulting from episodic inputs of
- 43 -
chemicals to surfacewaters. Such events can be caused by surface run-off

from disposal sites--landfillsand impoundments--during periods of heavy
rainfall or due to dike failure. Adverse effects can also extend from the
individualor populationlevel to effects on the functioningof the
ecosystem itself. This may result in changes in nutrient cycling or
reduced primary production in the impactedarea.
2.9.1 Effects on the TerrestialEnvironment
Effects on the terrestialenvironmentat disposal sites tend to be of a

localized nature. One effect of importance,however, is that the
production of landfill gas depletes the oxygen supply in the upper layer
of the landfill, causing vegetationto die off. This effect can produce
problemswhen re-vegetationof the site is being carried out. Metal-rich
wastes can also inhibit the re-vegetationof disposal sites. Those areas
of the site lacking vegetationwill be susceptibleto erosion; wind-blown
dispersal, and episodic flooding can result in the environmentalrelease
of contaminants. Land spreadingof certain industrialwastes can result
in significantinputs of metals and organic chemicals to agricultural
land. Certain metals are phytotoxicand if soil levels are sufficiently
high these can reduce crop productivity. Other metals can accumulatein
the edible portions of crops, which may lead to problems of exposure for
human consumers.
2.9.2 Effects on the Aquatic Environment
The efficient dispersalwhich occurs when pollutants enter surface waters

is an important feature of this environmentalcompartment. Thus,
widespread contaminationmay arise from a single source of discharge,
particularly in rivers, drainage canals, and coastal waters. As mentioned
earlier, fish deaths resulting from contaminant inputs are often the most
visible sign of an environmentalimpact. In addition, attentionhas
recently focused on sub-lethaleffects observed in button-dwelling
commercial fish species caught near waste dump sites in coastal waters.
The effects observed include epidermal lesions and liver neoplasms; in
some coastal waters these effects have been related to elevated levels of
aromatic hydrocarbonsin the sediments.
2.10 Summary
A working definitionfor hazardous waste(s) is developed in this chapter

and examples of such wastes are given. The range of possible industries
for a country to have are listed togetherwith the wastes they typically
produce; and a classificationis made. Movement of waste components in
the environment is discussed togetherwith their varied effects on human
health and the environment. A scheme for classifyinghazardous wastes by
the degree of hazard they pose is proposed.
- 44 -
2.11 References 2.1 - 2.10
Federal Register. 1986. 51 (114) (Friday, June 13): 21685. Washington,

D.C.: U.S. Government Printing Office.
Federal Register. 1986. 51 (216) (Friday, November 7): 40643, Washington,

D.C.: U.S. Government Printing Office.
USEPA. 1986. Superfund Public Health Evaluation Manual, EPA/540/1-86/060

(October). Washington, D.C.: Office of Emergency and Remedial
Response.
World Health Organization. 1984. Guidelines for Drinking-Water Quality,

3 Vols. Geneva.
- 45 -
ANNEX 2 - Waste Types for Proposed Classification Scheme
I INORGANIC WASTES
ACIDS AND ALKALIS
Industrial
Waste Streams Industry/Process Groups
Acid
Spent sulphuric acid Galvanizing D
Spent ferrous pickle liquor Steel pickling D
Acid strip solution Metal finishing D
Spent nitrating acid Organic synthesis F
Spent chromic acid Anodising D
Spent brightener for stainless steel Metal finishing D
Acid tars Coking C
Spent reagents Pesticide manufacture F
Alkalis
Alkaline cleaning agents Metal degreasing D
Spent ammoniacal etchants Electronics G
Spent caustic baths Metal finishing D
Waste ammonia Photocopying shops, F/L
chemical synthesis
Caustic sludge Oil re-refining F
Spent caustic Oil refining C
Ammonia still lime sludge Coking operations/gas C
works
CYANIDE WASTES
Untreated rinse water Electroplating D

Spent electro-plating process solutions D
Heat treatment wastes Steel production D
Spent concentrates and semi-concentrates Hydrometallurgy D
Chemical synthesis F
Fumigation L
HEAVY METAL SLUDGES AND SOLUTIONS
Lead sludges from diaphragm cell process Chlorine production F

Wastewater treatment sludge from the
mercury cell process
Brine purification muds from the
mercury cell process
Wastewater treatment sludges Chrome pigments F
Wood preserving (1) H
Surface impoundment dredged solids Lead smelting (2) D
Emission control sludge Lead smelting (3) D
Treatment process wastewater sludges Zinc production D
Acid plant blowdown
- 46 -
Industrial
Electrolic anode sleeves and sludges

Cadmium plant leachate residue
Lead sludges Battery production G
Sludge Tin plating mill D
operations
Galvanizing mill
operations
Acid plant blowdown slurry sludges Copper production (2) D
Wastewater treatment sludges Copper rolling and D
drawing
Spent pickle liquor and sludge Copper production D
Zinc and other heavy metal sludges Textiles industry H
Emission control sludge Production of steel in
electric furnace (2) D
Spent pickle liquor Steel finishing D
operations
Untreated wastewater Manufacture of explosives F
Wastewater treatment sludges Manufacture/processing of F
explosives
Mixed metal sludges Paint production F
Ink formulation F
Waste sludges Photographic processing F
Spent reagents Electronics industry G
Etching solutions/rinse waters Plastic plating G
Grinding and polishing residues Metal finishing D
Lead sludge Glassmaking E
ASBESTOS WASTES
Asbestos powder Preparation and processing E

of asbestos
Lagging materials Power stations, industrial Various
manufacturing, gasworks
dockyards, hospitals and
educational
establishments
Asbestos diaphragms Chlorine production F
SOLID RESIDUES N.O.S.
Emission control dust Production of steel in D

electric furnaces (2)
Dust and sludge Ferromanganese furnaces D
Silicomanganese electric D
furnaces
Ferrochrome electric D
furnaces
Iron and steel foundries D
Waste sand Iron and steel foundries D
-47 -
Industry/
Waste Streams Industry/Process Group
Emission control dust Lead smelting (3) D

Blast furnace slag Copper smelting (3) D
Spent catalysts Chemical synthesis F
Solid residues Rubber production F
Spent activated carbon wastes Manufacture of sulphuric F
acid, chemical synthesis
Scrap batteries Miscellaneoussources Various
Spent iron oxide Gas purification/coking C
Notes: (1) using chromated copper arsenate

(2) Primary
(3) Secondary
- 48 -
II OILY WASTES
OILY WASTES
Industry/
Waste Streams Industry/Process GrouP
Used oil wastes Vehicle repair shops, G/L

petrol stations
Acid waste oils Textiles H
Contaminated fuel oils Oil tanks and reservoirs Various
Compressor condensates Compressors Various
Sand trap and interceptor wastes Manufacture of building materials E
Chemical synthesis F
Sand traps, storage tanks Various
Oily sludges containing cyanide Surface treatment of metals G
Oily sludges Oil recovery/cleansing F
Oil prospecting and mining C
Petroleum refining C
Bottom sludges from tanks
API separator sludge
Heat exchanger sludge
Dissolved air floatation float
Silt/storm water runoff
Oily sludges Coking plants and gasworks C
Caustic sludge Oil re-refining F
Drilling and cutting emulsions Metal working G
Waste vegetable oils Production of vegetable oils A
- 49 -
III ORGANIC WASTES
ORGANIC CHEMICAL RESIDUES N.O.S.
Industrial
Halogenated
Propylene dichloride in admixture Propylene Oxide/ F

with lime slurry Propylene Glycol
Distillation residues containing Ethers and Aldehydes F
1-10Z chlorinatedhydrocarbons
(e.g., chlorinated toluenes from
manufacture of benzaldehyde)
Residue with low concentrationof Isocyanates F
o-dichlorobenzene
Phosphoricacid contaminatedwith Alkylated Bromides F
brominatedhydrocarbons
Tarry residue (m.p. 600C) containing Dyestuff intermidieates F
chlorinated aromatic compounds and Dyestuffs
Aqueous waste containinglow
concentrationsof mono-and
tri-chlorobenzene
Tarry residues of 1-2Z halogen Pharmaceuticalsand F
(chlorine,fluorine, bromine) content Fine Chemicals
Spent filter cake of approximately
0.1X chlorine content
Chlorinatedhydrocarbon in admixturewith
toluene and dissolved solids (chlorine
content 1Z)
Contaminatedmixtures of chlorinated
solvents (e.g., methylene chloride,
chloroform,ethylene dichloride,
chlorobenzene,with non-halogenated
hydrocarbon solvents)
Solvent waste containingsmall amounts of
methylene chloride and and alkyl chloride
Aqueous streams of about 0.1% chlorinated
xylenes and terpene alcohols
Still residues containingup to 2Z films and
disposables
Aqueous stream containingabout 40 ppm
chlorinatedhydrocarbonswith traces of
brominated and iodated compounds
PVC (with or without additives)off-cuts, Plastics and Rubbers F
films and disposables:waste from
machining of PTFE/Graphiteproducts
PVC granules from processingoperations
Slurry of chlorinatedrubber and rubber
in carbon tetrachloride
Waste stream containingchlorinated Dyeline intermediate F
hydrocarbons (10X chlorine content) products
- 50 -
Industrial
Epichlorohydrinwastes Epoxy and phenolic F

resin
Contaminatedchlorinatedhydrocarbon Products (research) F
solvents (e.g., methylene chloride,
chloroform)
Ethylene dichloride tars Chlorocarbonproduction F
Source: Her Majesty's StationaryOffice. 1979. HalogenatedOrganic Wastes,

Waste Management Paper No. 15, Annex 2. London.
- 51 -
III ORGANIC WASTES
ORGANIC CHEMICAL RESIDUES N.O.S.
Industrial
Non-halogenated
Spent aqueous caustic soda solution Oil refining operations C

Distillationresidues containing45 per
cent aromatic hydrocarbons (xyleneto Petroleum refining C
methyl naphthalene)
Still bottoms containingoctyl phenyl
naphthylamineand polyisobutylene
Tars containingpolymerizedmethyl- Heavy organic chemicals F
methacrylate,alkylated phenols, manufacture
cyanovaleramideand condensation
products, hexamethylenetriamine
Filter press cake containing 8 per cent Chemical manufacture F
naphthenates,4 per cent naphthenic
acid and metallic oxides
Still residues containing: Dyestuffs and inter- F
diphenylamine,aromatic amines, mediates manufacture
inorganic compounds, 2-naphtholand
oxidation products, phenol
decompositionproducts and amine
decompositionproducts
Distillation residues containing Productionof chemical F
phenylamines,nitrated phenylamines intermediates
and phenyl ethers
Glycol and glycol ether residues in Petrochemicals F
admixture with hydrocarbon sludge, manufacture
plastic powder and water
Liquid cyclopentadieneresidue Petrochemicals F
manufacture
Dimethylformamideresidues Pharmaceuticals F
manufacture
Residue containingup to 20 per cent
organic amines
Liquid comprising 70 per cent toluene,
6 per cent chlorphenol+ 20 per cent
by-products
Distillationresidues - terpene Fine chemicals F
hydrocarbons and weak acid stabilizers manufacture
Waste from hydroquinoneprocessing,
containing 0.2 per cent insoluble tars
and 35 per cent soluble tars
Caprolactam residues Fibers manufacturing F
Still bottoms containing spent caustic, Lube oil additive F
alcohols manufacture
Tar slurry (1 per cent coal tar + water) Aluminum smelting D
- 52 -
Industrial
Phenol-formaldehydeand epoxy resins, Plastics fabrication F

varnish blends and solvent
Propylene polymerizationresidues; Plastics manufacture F
polymerized ethylene granules
Tar emulsions Town gas manufacture C
(coal carbonization)
Acid tar washing of BTX fraction C
(coal carbonization)
Distillationbottom tars Phenol production F
Centrifuge and distillationresidues Toluene diisocyanate F
production
Source: Her Majesty's StationaryOffice. 1977. Tarry and DistillationWastes

and Other Chemical-BasedResidues,Waste Management Paper No. 13, Annex 3.
London.
553-
III ORGANIC WASTES
HALOGENATED SOLVENTS
Industryl
1,1,2 - trichloro - 1,2,2, -trifluoroethane Dry cleaning L

Perchlorethylene,
Perchloroethylene,trichloroethylene Textiles and leather H
Trichloroethylene,1,1,1, - trichloroethane Metal cleaning G
1,1,2 - trichloro -, 1,2,2, - trifluoroethane
Dichloromethane Paint stripping L
Chloroform, carbon tetrachloride Industrialand L
domestic cleaning
Chlrobenzene;1,2 - dichlorobenzene Chemical synthesis F
NON-HALOGENATED
SOLVENTS
Methyl ethyl ketone, "SpecialBoiling Point" Adhesive manufacture F

aliphatic hydrocarbonstoluene
"SpecialBoiling Point" aliphatic Motor vehicle G
hydrocarbons,xylene, toluene, manufacture
white spirit, kerosene, esters
White spirit, kerosene, refined paraffin, Cleaningmaterials and F
"SpecialDistillates" polishes
Kerosene and white spirit (with Engineering industries G
significantlygreater quantitiesof
chlorinatedhydrocarbon solvents).
n-Hexane, ethanol,methanol, isopropanol Extractive industries F
(essentialoils, etc.)
Propylene glycol, isopropanol,diacetin, Food flavorings,
glycerol triacetate essences, perfumes
cosmetics and
toiletriesmanufacture
"SpecialBoiling Point" solvents,paraffin, Industrieswhere large G
glycerol triacetate fleets of vehicles
require maintenance
- including road,
rail and air transport
White spirit, kerosene Leather industry H
Petroleum fractions of the white spirit type Organic wood H
preservatives
Methanol, IndustrialMethylated Spirit, Photographicindustry J
acetone, various glycols, ethanol, ethyl
acetate, cyclohexane
White spirit, 'SpecialBoiling Point" Printing industry J
solvents, kerosene, ethanol, isopropanol,
ethyl acetate, butyl acetates, acetone,
methyl ethyl ketone, toleuene, xylene,
methyl isobutylketone
- 54 -
Industry
Toluene, xylene, white spirit, cellosolves, Shipbuildingand G

isobutanol,methyl ethyl ketone, refitting
methyl isobutyl ketone
Petroleum hydrocarbons Tyre manufacture F
Source: Adapted from Department of the Environment.1977. Waste Management

Paper No. 14, Annex 1. London: Her Majesty's StationaryOffice.
POLYCHLORINATEDBIPHENYLWASTES
Solid and liquid wastes Manufacture of PCBs F

Dielectric fluid/solidwastes Scrap transformers G
Dielectric fluid/solidwastes Scrap capacitors G
Hydraulic fluids Mining equipment, G
aircraft
Heat transfer fluids Chemical industry F
Plasticiser residues Chemical processing F
Plastics processing F
- 55 -
III ORGANIC WASTES
BIOCIDE WASTES
Industrial
Chemical Classes Waste Types Industry/Process Groups
Insecticides Still bottoms Manufacture of biocides F

o Organophosphorus Filter media Biodice formulaltors F
compounds Extractionunits packers F
o Organochloride Packaging importers F
compounds Clothing wholesalers F
o Carbamates - Effluent treatment distributor F
Herbicides sludge
o Phenolics Sweepings
o Phenoxyacids Spill clean ups
o Substitutedureas Washings
o Triazines
o Benzoic acids
o Dinitroanilines Empty containers Agriculture users A
o Anilides Unused products Animal husbandry users A
(dips)
o Others Spills Horticultureusers A
Fungicides Industrialusers
o wood preservation H
o Dithiocarbamates o paint industry F
o Phthalimides o paper and board J
o textiles (not wool) H
o electric cable G
o tobacco A
o adhesives F
o building industry E
Public sector users L
Home and garden users L
Drum reconditions G
Service companies L
(rodent/birdcontrol)
- 56 -
BIOCIDE WASTES
Industrial
Waste Streams (1) Industry/Process Groups
Lacquering residues Lacquering shops G/H

Old lacquers Paint/lacquer shops (trade) G/H
Old paints Paint/lacquer shops G/H
Lacquer sludge
Paint sludge
Coating material residues Manufacturing of coating mats F
Printing ink residues Manufacturing of printing inks F
Printing works J
Resin residues Plastics processing F

Manufacturing of coating mats F
Manufacturing of synthetic resin F
Resin oil residues F
Manufacture of resin H
Paint residues Paint production F
(1) Wastes typically contain mixtures of aliphatic solvents, resins and may
also include heavy metals.
- 57 -
IV PUTRESCIBLEORGANIC WASTES
Industrial
Waste Streams Industry/Process GrouDs
Spoiled vegetable oils Productionof edible oils A

Production of edible fats A
Esterified oil residues Production of pharmaceuticals F
Productionof articles of F
personal hygiene
Butcheringwastes; including Slaughterhouses, A
blood, offal and intestines meat processing A
meat packing A
fish processing A
Poultry Poultry and feather processing A
Fish wastes Fish processing A
Animal carcasses Livestock raising A
Pharmaceuticalindustry F
Hideglue Tanyards and fur industry H
Fleshings
Residues
Hide liming sludge
Tanyard sludge
Sludge and residues Processingof natural gut A
Boiling out residues Processingof animal products A
- 58 -
V HIGH VOLUMEILOW HAZARD WASTES
Industrial
Drilling muds Petroleum/gas extraction C

Fly ash Power generation C
Mine tailings Mineral extraction B
Contaminated soil Miscellaneous Various
Flue gas desulphurization sludges Power generation C
Phosphogypksum sludges Fertilizer production F
Titanium dioxide wastes Pigment production F
- 59 -
VI MISCELLANEOUS WASTES
INFECTIOUS WASTES
Industrial
Waste Streams IndustrylProcess Groups
Special faeces Livestock raising A

Veterinary quarantine K
Contagious wastes ]_-Human and animal health institutes K

Animal and human tissue Microbiological laboratories K
Contagious hospitals K
Microbiological industries K
Microbiological institutions K
Dressing wastes Hospitals K

Disposable linen Therapeutic institutions K
Disposable hospital wastes
LABORATORY WASTES
Waste pharmaceuticals Pharmacies L

Laboratory chemical residues Manufacture of pharmaceuticals/ F
fine chemicals
Research institutes Various
Factory laboratories Various
EXPLOSIVE WASTES
Waste munitions Armaments F/G

TNT, azides Manufacture of explosives F
Nitrated organic chemical Chemical synthesis F
wastes
- 60 -
CHAPTER 3 - Planning for HazardousWaste Management
3.1 Introduction
Once the problems of hazardous waste within a particularcountry have been

recognized,it will be necessary to formulate policies and strategiesto
tackle them. Legislation and regulationsmust be developed and plans for
facilitiesto recycle, treat and dispose of the waste need to be drawn up.
A coherent and well thought out plan is essential before one begins to
construct facilitiesfor hazardous waste management. A hurried decision
can result in an inappropriateor overly expensive facility or in serious
environmentalpollution.
3.2 A Framework for Planning
Preparation of a plan for hazardous waste management is made easier if

undertakenwithin a systematicframework. The processes involved in
deriving a plan have been discussed in depth by Wilson (1981 and 1985),
and this general approach to planning for waste management can be easily
adapted for hazardous waste.
The systematicframework is perhaps most appropriate to planning at a

regional or national level, but it can also be applied at a local level to
a group of industrialplants or even to a single plant. However,
effective planningmust be based on a good inventory of the types and
volumes of hazardouswastes presently being generated as well as good
projections of future waste production.
At its simplest,a long=termplan for hazardouswaste management should

specify:
o what facilitiesare to be provided for the recycling,treatment or

disposal of wastes;
o where and when those facilitiesare to be built,
o and the capacity of the planned facilities.
It will always be possible to think of a number of alternativeplans, and

these require technical evaluationbased on a number of often conflicting
criteria. Political considerations,cost, environmentalimpact, technical
reliability and flexibilityto deal with an uncertain future must be taken
into account. Once all the options have been evaluated, the final choice
is often a political decision.
The steps involved in deriving a plan for hazardous waste management are
shown schematicallyin Figure 3-1. This step-by-stepapproach includes
both strictlypolitical decisions based on good technical analysis as well
as steps involvingboth political and technical aspects. (See Figure 3-1.)
- 61 -
FIGURE 3-1
Steps in the Development of a Plan for Hazardous Waste Management
| Definethescope
of the plan
r2
I
Definethe objectlvs
andconstralnts 1|
_1 3 Forrnultekey
_
I questions
___ _____ ___ ___ __

- __ _
4400 _
4Collect _ _
r Reviewexisting
situatlon I
j Lr i r-------_L________2r_____
L-- A
I 6AIdentify 6BIdentityand I
.L and analyse I assesspotential
options I I sites_I
'-------- , -
8 AnalyseIntegrated pians
9 Decislons | Political
F 11reogula-r I
r ~~~~~~-~~~~ ~~~- ' ' r n ~~~~~~~~Technical
L-J
revlew, .Ir - ------- _
updating I 10implemeritatlon I|
- 62 -
Steps in Development of a Plan for HazardousWaste Management
o Step 1. At the outset it is necessary to define the scope of the plan.

This is perhaps the most important step in the whole planning process.
The plan must focus on the essentialsof the problem, but must not be
so narrowly focused that it only solves a part of the overall problem.
o Step 2. The next important preliminarystep is to determine both the

objectives to be achieved by the plan and the constraintswithin which
it must operate.
o Step 3. At this point it is possible to formulate the key questions

which need to be answered. These will initiallybe posed in fairly
general terms, but will graduallybecome more specific as the planning
process develops.
o Step 4. Having formulatedthe key questions, it is necessary to

collect the informationrequiredto answer them, for example on the
types and quantitiesof waste and on the options for waste treatment
and disposal.
o Step 5. The next step is the preliminaryevaluationand assessmentof

available technologies. Each option must be assessed as to how well it
meets the specifiedobjectives. Some, such as cost, can be measured in
quantitativeterms, while other considerationslike technical
reliabilitymust be evaluated in more qualitativeterms.
o Step 6. At this point, it will be possible to draw up a preliminary

appraisal of the criticalproblems facing the area, region or country,
and a short-listof technical options for solving them. It will be
necessary to repeat some of the previous steps in the planning process,
such as reviewing the scope of the plan and re-examiningthe
objectives. When the most criticalproblems have been identified,
effort can be devoted to refining the estimates of the quantity of
particularwastes or reconsideringthe basis of initial assumptions.
o Step 7. Once a short list of options has been drawn up, various
combinationsof those options should be looked at in order to generate
a number of alternative integratedwaste managementplans. These plans
are then evaluated in light of the specified objectivesand
constraints.
o Step 8. This short list of alternativeplans is then subjected to

another round of review and feedback. The final selection of a
preferred plan will generally be a political decision.
o Steps 9 and 10. The selectionof a plan is not the end of the process
but rather the beginning. The plan must be implementedand it will
require regular review and updating.
This representsa simplificationof the total planning process.

However, the main purposes of presenting such a framework are to
demonstrate the advantagesof a systematicapproach, and to emphasize
- 63 -
that planning is not a simple, once-throughexercise,but rather an

interactiveprocess involving both political decisionmakers and
technical specialists.
The remainder of this chapter expands on importantaspects of each of the

above steps.
3.3 Scope of the Plan (Step 1)
3.3.1 Basic Elements to be Considered
There are a number of basic elementswhich need to be consideredat the

outset in order to fully define the scope of the plan. These include:
o the quantitiesand types of wastes to be covered;
o the componentsof the waste management system (e.g. storage,

collection,transport, treatment,and disposal) to be includedwithin
the plan;
o the geographicalarea for which the plan should be prepared;
o the time horizon;
o the responsibilitiesof governmentversus those of industry.
3.3.2 Types of Waste
It is difficult and inappropriateto plan for the management of hazardous

wastes in isolation from other wastes. A proper system for hazardous
waste managementmust exist alongside that for non-hazardousmunicipal,
commercial and industrialwastes. If such wastes are not properly
managed, for example by tipping at a municipal work dump, then it will be
rather more difficult to enforce the use of proper facilitiesfor
hazardous wastes.
If a proper system and plan already exist for dealing with ordinary
wastes, then it makes sense to develop a complementaryplan for hazardous
wastes. If, however, such a system does not exist, then it is necessary
to develop plans for both non-hazardousand hazardous wastes in parallel.
This will include systems for determiningsources, quantitiesand
classificationsof hazardous wastes, and means for trackingwastes during
transportation,treatment and disposal etc. as well as an assessmentof
current practices.
3.3.3 Components of the System to be IncludedWithin the Plan
A simplifiedoverview of the stages which may be involved in hazardous

waste management is shown in Figure 3-2. These stages include:
o waste avoidance,reuse or recycling;
o in-house storage of waste on the producer'spremises;

- 64 -
FIGURE 3-2
Componentsof the Hazardous Waste System
Wasteavoidance
direct recycling Waste Recovery,
generator Re-use
U .
In-house
storage
u z ~~~~~storage
| Collectiorn/| m M |Transpadsps
0 0 o
~~~~~~~~~~~~......
... . ... ... ........... . ..
- 65 -
o collection of the waste from those premises and its subsequent

transport;
o interim storage,which may include a collectionor transfer station

which accumulateswastes until sufficientquantity is available for
economic transport;
o secondary transport;
o treatment or recycling;and
o final disposal.
A comprehensiveplan for hazardous waste management in a region or country

must encompass all of these stages. The plan must not be restrictedto
what happens to waste once it leaves the producers'premises. Facilities
for on-site storagewithin the factory grounds and treatment and disposal
by the producer himself must also be considered. See Figure 3-2.
3.3.4 GeographicalLimits
The choice of the geographicalarea for which a waste management plan is

to be produced is important and often requires cooperationbetween several
regional or local governmentbodies and industry. For example, in the
case of municipal waste, each autonomousmunicipalitymay wish or be
required to take responsibilityfor its own waste. The question of
regional cooperationbecomes important for large metropolitanareas with a
rural hinterland.
For hazardous waste, the waste quantitiestend to be relativelysmall and

the level of expertise required to deal with the wastes is relatively
high. Thus, in the majority of developingcountries planning at either a
regional or a national level makes the most sense. Individual industries
or local groups of industriesalso need to make their own plans, perhaps
in cooperationwith the authorities.
If local or regional planning is to be adopted, then coordinationof those

plans at a regional and national level is essential. International
cooperationin the provision and use of specializedfacilitiesmay also be
necessary. For example, there is insufficienthazardous waste to justify
the provision of a high temperatureincineratorin each of the States on
the Arabian Gulf, but a regional facility serving some or all of the
States could prove viable. In Europe, internationalcooperationmay
continue to be necessary to support specializedfacilitiessuch as those
for PCB incineration,mercury recycling or secure, long-term storage in a
salt mine.
3.3.5 Choice of Timescale for Planning
One cannot be dogmatic about the time horizon for waste management
planning. It will depend very much on local circumstancesand needs.
There may be an immediateneed to separate a short-termaction program,
- 66 -
intended to provide substantialimprovementsin the standard of operations

over one, two or three years, from a long-term plan.
In longer term planning for new treatment and disposal facilities the
appropriate timescale is determinedby the anticipatedlifetime of those
facilities.
The time scale is also related to the types and quantitiesof waste being
generated, and to the planner's ability to forecast the future. If it is
difficult to see further than one or two years ahead, then a key factor in
developing and assessing a plan must be its flexibilityto handle future
changes as they occur. In that case, when the quantity of hazardous
waste that will need to be in handled in the future is uncertain, it may
be appropriate to consider a phased implementationplan.
In general, a reasonabletimeframe for which a hazardouswaste management

plan should be developed is between 5-20 years, perhaps most commonly
between 10-15 years.
3.3.6 Government and IndustryResponsibilities
Hazardouswastes are produced mainly by the manufacturingindustry, and in

many countries industriesthemselvesare responsiblefor arranging the
disposal of their wastes. Where it is possible and reasonablyeconomic
for a company to treat or dispose of its waste on its own property,
government involvementis limited to monitoring the situationand ensuring
that the facilitiesmeet standards.
Where an industry does not generate a sufficientquantity of waste to

justify its own treatment or disposal facility, then facilitiesto treat
or dispose of the waste from a number of industriesare required. Such
facilitiescan be provided:
o by an independentcompany;
o by producer companies acting in cooperation;
o directly by Government;or
o by a combinationof the above, perhaps with the participationof an

internationalor foreign agency to provide technology, training or
financing.
In countries with existinghazardous waste management systems all of the

first three alternativesor combinationsof them exist. Public
authoritiesmay be involved either directly, for example as partners in a
joint venture with producing industries,or indirectly,for example
providing low-cost finance for capital investment.
In addition the Governmenthas responsibilityfor:
o setting environmentalstandards,regulations,or objectives;

- 67 -
o ensuring that waste treatment and disposal facilitiesmeet those

requirements;
o monitoring environmentalquality;
o maintaining inventoriesof waste generation;and
o enforcing compliancewith laws, regulations,etc. governing the

building and operating of treatment and disposal facilities.
3.4 Objectivesand Constraints (Step 2)
3.4.1 Objectives and TechnicalAssessment Criteria
It is important at the beginning of the planning process to have a clear

idea of the objectivesto be achievedby a plan for hazardous waste
management. These objectivesthen need to be translated into clear and
simple criteria which can be used for the assessmentof alternative
options and plans.
The principal objective of any plan for hazardous waste management is to

ensure safe, efficient and economicalcollection,treatment and disposal
of wastes; and to ensure that the system is reliable now and for the
foreseeable future.
This broad statement encompassesa number of objectives,which need to be

expanded to reflect particular local conditions. For each objective a
number of assessmentcriteria can be specified. Some of these objectives
are elaboratedbelow.
o Health Effects
To reduce health risks and nuisance associatedwith the storage,

collection,treatment and disposal of hazardous wastes.
O EnvironmentalImpact
To reduce environmentalpollution risks associatedwith hazardous waste

treatment and disposal.
o Technical Reliability
To ensure that any hazardous waste technologiesused are proven, safe,

flexible, and maintainableunder local conditions.
o Political Acceptability
Depending on local conditions,important objectivesmay include:
* maximizing the number of jobs created

* public acceptabilityof the facilities.
- 68 -
o Resource Recovery
To maximize the utilization of both the material and fuel value of

wastes. There may also be a requirementto minimize land usage, or to
restore poor quality land.
o Economic Viability
To minimize costs, subject to other (often conflicting)objectivesand

constraints.
o Resource Conservation
To minimize the amount of hazardouswastes generated and ensure that

all such wastes are collected, treated and disposed of properly.
With so many possible objectives to be achievedby a plan, it is clear

that no single plan will be best measured against all of the criteria.
However, by explicitly setting out the criteriaby which each of the
options and plans are to be assessed, it is possible to achieve a much
more systematicapproach to the process of comparison.
3.4.2 Constraints
one way to simplify the evaluationprocess is to prioritize the

objectives, perhaps reducing the number of objectives to be met by
substitutinginstead a number of constraints. For example, instead of
stating that environmentalimpact must be reduced to a minimum, one could
define instead environmentalstandardswhich must be met. These standards
are then used to 'screen'out some alternatives,and the remaining
alternativesare then measured against the other criteria. 1
A variety of constraintsare likely to require particular considerationin
developing countries.
o Financial Constraints
There may be limits imposed by the national governmenton total

expenditure,or specific limits on capital expenditure,phasing of
expenditures,cost recovery, or the imports required to implement a
plant. The governmentmay wish to avoid a negative impact on the
balance of payments. The extent and rigidity of these constraintswill
depend on the financing arrangementsfor any facilities. If the
financing is to be provided largely by internationalcompanies, then a
different view may be taken than if the source is either the national
government or local companies.
O Manpower Constraints
Any local shortage of skilled manpower for management, supervision,
l'screen' a process of selection or 'filtering'which may be likened to sorting

physical material by passing through a mesh screen to separate large and small
particles.
- 69 -
operation or maintenance of facilitiesmust be taken into account.

This constraintrelates directly to the objective that facilities
should be reliableunder local operating conditions. It also
identifiesthe need for training to enhance locally available skills.
o Land Use Constraints
Most hazardous wastes are generated near urban areas, where there is
often a shortageof land. Shanty towns and other unofficialhousing
developmentsoften grow up in close proximity to industrialplants, on
land which could otherwise be available for on-site treatment and
disposal facilities. In preparing a plan for hazardous waste
management, liaison with other plannerswho are providing facilities
for housing, industryand services, is essential. Parks, wildlife
areas, and public water supplies,etc. should be identifiedas
constraints in identifyingsuitable land for all facilities.
o Local EnvironmentalConstraints
In many urban areas in developingcountries there is a high groundwater

table, and often groundwateris the main source for domestic and even
industrialpurposes. This is an example of a physical environmental
constraint, in this case on land disposal options. Climate may also
restrict the applicabilityof certain options, such as solar
evaporationponds.
o Time Constraints
Long and complicatedland purchase procedures or intense local

oppositionmay lead to long delays and prove to be a time constraint at
certain sites. In fact, this factor may be critical in deciding on a
site.
3.5 The Key Questions (Step 3)
Having defined the scope of the plan, the objectivesto be met and the
principal constraints,it is possible to formulate a series of key
questions that need to be addressed by the plan.
Some of these questionsmay be rather general in nature, as illustratedby

the following examples.
o What are the existing quantities,compositionand location of hazardous

wastes requiring treatment and disposal? How are these likely to
change?
o To what extent are differentwaste streams kept segregated?
o How are the wastes stored, collected and transportedat present? What
are the principal problems and difficulties?
o How are the wastes recycled, treated or disposed of? What are the
principal problems and difficulties?
- 70 -
o What options for recycling,transfer, treatment or disposal are

available for overcoming these problems? How do these options rate
against the various objectivesand constraintsof the plan? Which of
the available options would prove most appropriateto the local
circumstances?
o How many facilitiesshould be provided? Should these be within

individual factories,serving a group of industries,or serving the
whole country? Where should such facilitiesbe located? Are there
clear priorities as to which facilitiesshould be developed first?
o Are the existing organizationaland management arrangementsadequate

for implementingthe selectedplan? Is the existing legislation
adequate? Are sufficientresources available for enforcement? How is
the overall plan to be financed?
These general questions encompass most of the subsequentsteps set out in

Figure 3-1. Each individualplanning study will require the formulation
of a set of key questions.
Initially, this list of questionsmay be posed in fairly general terms.

As the scope of the plan and the objectivesand constraints are defined,
some more specific questionswill be apparent. As one proceeds through
the subsequentsteps in the planning process, particularlythe review of
the existing situation and the initial identificationand analysis of
available options, it will be possible to focus the study more precisely
by redefiningthe key questions in more specificterms.
3.6 InformationRequirements (Step 4)
3.6.1 Introduction
Information is required at all stages in the preparationof a waste

management plan. Informationgathering should not be seen as a once-and-
for-all exercise, but rather as a step-by-stepprocess, beginningwith
preliminary informationwhich is used for the initial screening of
options. The results are then used to identify those key items of data to
which the evaluation is most sensitive,and additional resources are put
into obtaining better data on those particular aspects.
Five particular areas may be identifiedwhere informationwill be

required:
o current sources,quantitiesand compositionsof hazardous wastes;
o forecasts of future waste production;

o existing facilitiesand practices for hazardouswaste management;
o informationon the performanceof alternativetreatment and disposal

management options measured against the various assessmentcriteria.
An important element here will be informationon existing industrial
facilities (such as cement or lime kilns) which could be adapted for
_ 71 -
hazardous waste treatment;and
o current and potential markets for materials or energy recovered from

hazardous wastes.
In the short term, considerableingenuity is often required to collect the

data necessary to review the existing situation and determine the need for
immediate action; in the longer term, systems can be establishedthrough
enactment of legislationand regulationsthat provide essential
informationon a regular basis.
3.6.2 Information on Waste Generators
There is often a shortage of informationon the sources, quantitiesand

types of hazardous wastes produced in an area. Here are four different
approaches to data collection:
o a desk study may produce order of magnitude estimates based on

internationalexperience:
o wastes may be monitored at treatment and disposal facilities;
o a sample survey of waste generatorsmay be conducted,using either a

postal questionnaire,interviewsor a combinationof both; and
o a comprehensivesurvey of waste generatorsmay be attempted. This is

generally only possible in the long term, when comprehensive
regulationsto control hazardouswaste have been implemented.
(i) Desk Study
In a desk study all existing informationon potential waste generators,

the type of industry, its size and location should be completed from
existing governmentrecords.
The World Health Organization(1982) has published guidelines for the

rapid assessmentof quantitiesand types of pollution and waste sources,
including dischargesto air, water and land. The rapid assessment
procedure is designed to utilize wherever possible data readily available
in most countries,generally avoiding the need for extensive factory or
source sampling surveys.
Here are some examples of the rapid assessmentmethod:
o estimationof hazardouswaste generationby multiplying the employment

in a particular industrialsector by standard load factors.
o estimation of pollutant loads in effluentsby multiplying a population

figure, the production capacity of a particular type of industrial
plant or the number of employees in a particular industrialsector by
an appropriate load factor; and
- 72 -
o estimationof organic pollution load due to animal manure by

multiplying the number of animals of a particular type by a standard
load factor per animal.
The WHO report contains extensive tables of the necessary load factors for
these calculations. Unfortunately,the extent of informationavailable
for hazardous wastes is comparativelylimited.
Experiencewith carrying out detailedwaste surveys in the UK and

elsewhere has shown wide variations in waste-per-employeefigures even
within narrowly defined industry sectors. The use of locally derived
factors (see iii below) is strongly recommended,because standard factors
meant to be applicable in all countriesare questionable. An example of
this approach is given in Annex 3C.
At the present time, the extent of informationwhich may be obtained from

a preliminarydesk study is limited. Internationalexperience is useful
in identifyingthose types of industrywhich may be expected to produce
hazardous waste (see Chapter 2). However, for quantificationof the types
and quantitiesof waste, there is no real substitutefor specific local
surveys.
(ii) Monitoring of Wastes Delivered for Treatment/Disposal
This approach attempts to measure the quantitiesof different types of

waste currently being treated or disposed of, rather than measuring
generationat source. The method can be applied either to all types of
waste entering a site, or attentionmay be focused on specifically
hazardous wastes. Quantitiesentering recognizeddisposal sites are
likely to underestimatethe total, because of losses at various stages en
route to the disposal site (for example on-site disposal or temporary
storage by the waste generator,intermediatesalvagingof waste,
unauthorizeddumping, etc.).
Despite these limitation,this approach can give a reasonablyreliable

indication of the amounts and types of waste generated. The extent to
which the results are affected by losses en route to the treatment or
disposal site can usually be judged by observation,for example by looking
for evidence of dumping elsewhere.
Information should be recorded on printed record sheets, including:
o date;
o time of arrival of deliveries;
o source of waste (e.g., local authority,hospital, name of firm, etc.);

and
o the weight of each load, if a weighbridge is available.
If a weighbridge is not available,the type and approximate size

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(capacity)of vehicle (e.g., compressionor non-compression,the

approximatevolume or qualified statementon vehicle size - "large four-
axle tipper", 'small two axle tipper," etc.) should be recorded. Where
loads delivered are (e.g., quarter,half, three quarters, or completely
full) should be recorded along with the appearanceof the waste (e.g.,
mixed paper, metal slags and sludges,etc).
Ideally recording should take place continuously,but if continuous

monitoring is not possible, entering loads should be recorded for at least
two weeks (includingweekends). Recording of loads entering a disposal
site is likely to require additionalmanpower at the site to minimize
delays for arriving vehicles.
(iii) Sample Survey of Waste Producers
Theoretically,a survey of waste generationat the sources should

represent a more accurateway of estimatingquantitiesof hazardous and
other industrialwastes. Ideally, an initial survey should be carried out
by contactingall firms in the area under consideration, but if the
number of firms is too large, a representativesample should be chosen. A
statisticalanalysis of the results will show how different factors (e.g.,
type of industry,number of employees,locality) effect the waste
production of a firm. Subsequentsurveys to update the informationcan
then be carried out by sampling firms to see how the effect of these
factors has changed.
In most areas, the cost and timescale of a complete survey is likely to be

prohibitive,so a compromisemust be reached between cost and accuracy.
In a sample survey, a statisticallyselected sample of waste producers are
approached for information. A number of comments can be made concerning
the selection of a suitable sample.
o Information is requiredon the number of premises within each

industrial classification. Extrapolationfrom the sample to estimate
the total waste production is generally on the basis of an assumed
constantwaste generationper employeewithin each industrialgroup.
The industrialclassificationsused should thus be:
* standard categoriesfor which statisticalinformationon the number

of premises and number of employees is available;and
* sufficientlynarrow in scope so that it is reasonableto assume a

constant waste generationper employee.
o The sample should be stratified,for example identifyingthree groups

which are expected to generate:
* large quantities;
* medium quantities;or
* small quantities of industrialwastes.

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This stratificationcould be based either on known waste production, or,

more likely, on numbers of employees.
o The sample to be surveyed should be selected to include lOOZ of the

first group, a large percentage of the second group and a smaller
sample of the third group. Within each group, firms should be selected
at random and care should be taken to ensure that prior knowledge or
ease of access, etc. does not influence the selection.
o Statistical testing will be necessary to identify those cases where the

assumption of a constantwaste productionper employee is not
appropriate.
The survey may be carried out either by sending a questionnaireto waste

producers for them to fill in and return or by conductingpersonal
interviewsor by some combinationof the two. However, it is advisable
that the person carrying out the survey goes around the sites with the
factory employees responsiblefor process operation and waste disposal.
Invariably,answers provided by companies to waste survey questionnaires
are quite inaccurateand must be verified by a qualified hazardouswaste
specialist.
Experience from many parts of the world suggests that personal interviews
are much more reliablethan postal questionnaires,although the latter may
be useful as a supplementarysource of information. The use of well
trained personnel is essential for interviews,so that the interviewerhas
a good idea of what types of waste to expect and is able to ask the right
questions.
A particular advantage of carrying out a survey by personal interview is

that it promotes informationexchange, informing industry of the concerns
and intentionsof governmentand enabling the authorities to form a
picture of the technical competenceand expertise of the industries. The
informationgained through this exchangewill assist in decidingwhether
treatment and disposal should be under the control of industry or under
the control of government,or a combinationof both.
In Annex 3A, an example is given of a typical waste generation

questionnaire. This particularone was used as a basis for both
interviews and a postal questionnairein a recent waste production survey
in England. The advantage of using a standard form to record the
information is that it allows easy analysis, ideally by direct entry into
a micro-computer. The UNDP/World Bank are developinga P.C. computer-
based system for carrying out hazardous waste surveys in developing
countries using the techniquesdiscussed above. An example of the
methodology is given in Annex 3C.
(iv) ComprehensiveSurvey
As discussed above, a comprehensivesurvey of waste producers is generally

not feasible. However, the desirabilityof producing comprehensive
information should be kept in mind when drafting national regulations for
hazardous waste management.
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There are at least three ways in which comprehensivedata can be produced

as a by-product of regulationsto control hazardous wastes.
o Perhaps the most comprehensiveis the (annual)report by waste

producers,which forms part of a registrationscheme in a number of
countries. The producer is required to make a regular report to the
authorities on quantities,composition,and treatment and disposal
methods. A number of countries view this as a vital part of the waste
management system, providing good informationand allowing government
to learn more about waste productionand so to check the data.
o As discussed in Chapter 6, the manifest or trip-ticket system is used

in many countries to ensure that waste arrives at its designated
destination. If a central authority receives a copy of each manifest,
this informationcan be used as a basis for compiling data on those
wastes which are treated or disposed of outside the producing factory.
However, such a system does not record informationon wastes which are
treated or disposed of on-site.
o An (annual)report by treatment and disposal facility operatorsmay

also be required as part of a registrationor licensing scheme.
Compared to similar informationreportedby waste producers,data from
treatment and disposal facilitiesgive less insight into the origin of
the waste and thus into the possibilitiesof alternative recycling,
treatment or disposal methods.
3.6.3 Forecasts of Future Waste Generation
No matter how detailed the survey method, the results are only valid under
the socio-politicaland economic conditionsprevailingat the time of the
survey. Any changes in governmentregulations,or in the political or
economic conditionswhich directly or indirectlyaffect the cost or
acceptabilityof current waste disposal practiceswill affect the
hazardous waste inventory.
Forecasting future generationof industrialwastes is therefore

notoriously difficult. In addition,many industriesdo not plan for more
than two or three years ahead, and those plans tend to be confidential.
The typical waste survey questionnaireshown in Annex 3A includes a
question asking for informationon changes in waste quantitiesor types.
In many developingcountries, the best source of informationon which to
base forecasts is likely to be the Ministry of Industry or the equivalent.
3.6.4 Informationon Existing Treatment and Disposal Methods
The identificationof existing treatment and disposalmethods will be an

important by-product of the surveys as described in Section 3.6.2 (ii) and
(iii) above. For each method in use, the detailed informationdescribed
in this section is required.
For any existing treatmentplants, informationshould be readily

available. For each plant it is necessary to know:
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o its location;
o age;
o type (incinerator,chemical treatment,etc.);
o operating capacity;
o current throughout;
o remaining useful life;
o manpower requirements;
o percentages of recoveredproducts, if any, and revenue received;
o operating cost; and
o ownership.
Figures for current throughoutshould be checkedwith those from

elsewhere,weighbridge records,numbers of vehicles dispatchedto the
plant, etc. -- in order to obtain the most reliable figure. The
experiencehas shown that waste transportersand handlers record waste by
the size of the tanker vehicle or truck used and not based on the actual
quantity of waste removed or disposedof. Data must be corrected by close
examinationof the figures and by multiplying by a correctionfactor for
the type of waste.
It may be necessary to contact the manufacturer/plantsupplier to advise

on the scope for increasingplant throughout,future availabilityof spare
parts, etc. If available, existing records may indicate the periods of
breakdown and downtime and enable a measure of reliabilityto be
determined. It may be necessary to obtain an expert engineeringopinion
on the remaining useful life of the plant and any modificationsrequired.
For each existing disposal site, including on site storage and disposal at
industrial sites and those receiving industrialor hazardous wastes along
with other wastes, informationis requiredon:
o its location;
o the daily/weeklyamount and types of waste deposited there;
o the remaining capacity;
o facilitiesavailable on site (water, electricity,laboratory, sewer,

telephone);
o its suitability (hydrogeologically,

on amenity grounds, etc.);
o ownership;
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o planned future use, if any; and
o methods of extending the life of the facility (e.g., by creating a new

land form).
Determining the location of sites should generally present no problems,

although unofficial sites may need to be sought out. The quantitiesof
waste, if no weighbridge is on site, will require monitoring. The
remaining capacity will require a detailed survey unless a visual
inspection indicates that the amount is not of a sufficientorder of
magnitude to make a future contributionto waste disposal in the area. An
assessment of the suitabilityof each site may require the use of
specialist advisors, the drilling of boreholes and the testing of nearby
streams and water sources.
3.6.5 Information on Potential Options for Recycling,Treatment and Disposal
In formulatinga plan for hazardous waste management it will be necessary

to consider many alternativesfor recycling,treatment or disposal,
including some not currently used in the area under study. One of the
main purposes of this technical manual is to make availablebasic
informationon the various options, their technical and economic
characteristicsand their suitabilityfor particular types of waste.
Some informationon potential options can only be obtained locally.
o Information is required on existing industrialfacilitieswhich could

be adapted for hazardous waste treatment. For example, cement or lime
kilns or industrialboilers could be adapted for the incinerationof
hazardous wastes.
o Information on suitable sites for future waste treatment or disposal

facilitiesmust also be collected. This is a vital input to the
process of site-selection,which is discussed in Section 3.9 below.
3.6.6 Market Survey
The viability of waste recycling resource recovery or energy recovery from

wastes depends on the present or potentialmarket for the recovered
materials or energy. The economic incentive for waste recycling or
recovery depends very much on governmentpolicies and regulationswhich
affect the cost of disposal. A market survey is thus essential to assess
the local situation.
The first step is to establish the base-line position, current market

prices for the various materials, the specificationof quality required
and the pattern of demand for energy. Ideally,historical information
should be sought in addition to current prices, since the markets for many
recycledproducts can be rather unstable.
Some products recycled from hazardous wastes may not be direct substitutes
for existing products. In such cases, establishingthe acceptabilityof
- 78 -
the product, the size of the market and the possible sale price may prove
to be more problematical.
Often specific researchwill be requiredon a case-by-casebasis in order

to locate a market for a particularwaste stream (see Section 6.4.3 on
waste exchanges).
Recovered products from hazardouswastes will often take the form of

energy, such as electricityor steam from incineration,or of fuel
products, such as waste oil or contaminatedsolvents. A detailed study of
the pattern of energy usage will be necessary, including the ability, both
technical and financial,of medium-sized industrialusers to switch to a
novel energy source.
3.7 Review of the Existing Situation (Step 5)
After the preliminary collectionof information,an objective review of

the existing situation is required. One purpose of the review is to focus
the planning on significantproblems and inadequaciesin the existing
system. This review involves a repetitionof proceeding steps, with the
key questions being reformulatedin more specificterms and additional
informationbeing collectedwhere required.
The cyclical nature of the planning process is important. Collecting

informationis often very time-consumingand expensive. By examining
initial informationin order to identify specificproblem areas, and then
going back to collect more detailed informationwhere it is required, one
can be sure that the informationbeing collected is going to be used.
Data should never be collectedwithout a clear purpose in mind. Improving
hazardouswaste managementwill usually require some increased costs.
These include:
o capital costs for procurement of land, facilitiesand equipment;
o operating and maintenance costs associatedwith hazardous waste

management systems -- including adequatemanpower and training
programs; and
o administrativeand enforcementcosts associatedwith the management

system selected.
3.7.1 Economic Considerations
(A) Costs and Benefits
In theory, the total benefits in terms of improved public health,

protection and conservationof land and other natural resources,and
reduction of risk to future generations should always exceed the total
costs of the hazardouswaste management system. In practice it is very
difficult to measure accurately the benefits and the costs because the
necessary information is either not available or very difficult to
develop.
- 79 -
In the absence of precise informationgovernmentauthoritiesmust utilize

more pragmatic decision-makingtechniques. In cases where careless
handling and disposal of hazardous wastes pose imminent danger to public
health, the governmentmust move quickly to correct the problem. When the
projected impacts are less severe, governmentscan be more cautious in
trying to evaluate the costs of the proposed program in terms of its
relative effectiveness. There is extensive literatureon the use of
environmentalcost-benefitand cost-effectivenessanalysis; references
specificallyrelated to hazardous wastes are included in the bibliography
of this chapter.
(B) Who Pays?
There is no single answer for the question of who pays for the design and
financing of a national hazardous waste management system. Usually either
the polluter pays or society pays.
o Under the polluter-paysconcept, governmentimposes direct regulations

on generatorsand disposers of hazardouswaste material. These
regulationsmay restrictcertain disposal options or specify the
required treatment technology. This approach requires a well trained
staff of technical experts and an effective enforcementprogram.
Direct regulation is economicallycomplex because the cost of complying
with treatment facility standardsvaries greatly for different sources
of hazardous waste. The possibility of having undesirable side-effects
(e.g., plant closures and loss of employment)increaseswith the
strictnessand extent of the standardsprescribed, although experience
shows that in well run companies efficiencyis enhanced through waste
reduction. Alternativelygovernmentmay impose a tax or charge system
on the generationand disposal of hazardouswastes. This tax (or
charge) could be designed to encourage less generationof hazardous
materials and/or to produce the revenuesneeded to pay the costs of the
hazardous waste management system.
o Under the society-paysconcept, governmentmay use general revenues to

pay the costs of the hazardouswaste management system or to provide
subsidies,low interest loans or tax credits to generatorsand
disposers of hazardouswaste as incentivesto improve their operations.
Table 3-1 and 3-2 illustratesome of the pros and cons of taxes and
subsidies. For uncontrolleddumping of hazardouswaste society pays in
the long term if not in the short term.
o More often than not a combinationof "polluter-pays"and "society-pays'

is adopted in practice, particularlyin the early stages of developing
a national hazardous waste management program.
The following section on financialconsiderations,provides more detailed

guidance related to hazardous waste management systems and large projects
which are key componentsof the system.
3.7.2 Financial Considerations
The construction,operation and maintenance of hazardous waste management

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TABLE 3-1
Advantages and Disadvantages of Taxes
Advantage Disadvantage
Minimizes control costs Decreases corporate funds for R&D
Minimizes need for enforcement Major administrative problem
Encourages cost-effectiveness No precedents
Cost-benefit analyses performed Unforseen economic dislocation

by each polluter possible
Capable of rapid implementation Encourages governmental control
Revenue raiser for social costs If tax is too low, it could be

construed as "license to pollute"
Tax continues during litigation If tax is too high, is tantamount

to fine
Creates incentive for process Quality standards absent, health

modifications protection not assured
Precludes use of incentives
Can be distorted into revenue

collecting mechanism
Inflation may reduce impact, as may

economic growth
No set goals
Source: Haas, Charles N. 1985. Incentive options for hazardous waste

management. Journal of Environmental Systems 14(4).
- 81 -
TABLE 3-2
Advantages and Disadvantagesof Subsidies
Factor Advantage Disadvantage
Establishment Likely to be only Rewards those who have yet to comply

weakly opposed Encourages increase in discharges
initially
Subject to pork barrel treatment,on
budget item
Obtaining initial level of pollution is
costly
Change Can provide incen- Not effective in crises

tive for continued May be difficult to reduce
abatement.
EncouragesR&D
Not biased to single
technology
Like to be more
stable
Administration Spreads costs more Can encourage entry of marginal firms

diffusely than May be construed as blackmail
taxes Does not discourageconsumption of goods
leading to pollution
May need complex bureaucracy to
administer
Enforcement Likely to be lower Will usually not be high enough to cover

full cost, hence some standardsmay
still be necessary
Source; Haas, Charles N. 1985. Incentive options for hazardous waste

management. Journal of EnvironmentalSystems 14(4).
- 82 -
systems represent a major financialundertakingand such considerations

are an essential element of the planning process. The financial resources
available from the public or private sector will necessarily influence the
choice among proposed alternatives. Close attentionmust be paid to the
cost of amortized capital, operation,and maintenance and to industry's
willingness and ability to pay. It is also essential to identify and
resolve the problems involved in raising the initial capital required for
implementingplanning decisions.
A thorough financial analysis of all the alternativetechnical solutions

must be made. Among the issues to be addressed are the costs and benefits
of each alternative,the methods and sources of funding, the allocationof
costs on an equitable basis among the polluters and the beneficiariesof a
project, and the willingness of governmentto contribute. Often
governmentsare willing to contributebecause of real concerns about
public health.
This section presents (1) the frameworkwithin which financial issues are
identifiedand analyzed; and (2) the essential elementswhich should be
considered in allocatingcosts.
(A) The Financial Analysis
The financial analysis should include the followingmajor elements:
o Preparation of cost data to compare costs of the available technical

alternativesand select the most appropriatealternative.
o Identificationof the responsibilitiesof the principal agency and the

institutionalarrangementsthat will influence financing of the
collection and treatment system.
O A financing plan which identifiesthe various participating

organizations,establishesthe responsibilitiesof each, estimates the
contributionof each organizationto the annual capital and operating
costs, and identifiespotential sources of financing.
Identificationand evaluationof the secondaryimpacts which could result

from the proposed program, such as new employmentor industrial
development,etc.
(B) Developing Cost Data
Cost data are required for determiningthe share of costs to be assigned

to each institutionor agency involved in the proposed project. Estimates
should be prepared jointly by the planning agency, prospective owner (if
private sector) and the consultingengineer or firm. If most of the
estimates are prepared by a consultant,then the other parties should be
certain that all major cost categorieshave been identifiedand all
assumptionsare reasonable. Costs should be projected at least five years
into the future, and preferablyover the life of the facility,
particularlyif certain costs can be predicted to occur in later years.
Costs which will be affected by inflation should be identifiedand
- 83 -
properly adjusted as part of the projectionprocess.
The basic costs associatedwith constructionwill include:
o land, rights-of-way,and easements;
o engineering,architectural,consultant,and legal fees;
o actual constructioncosts, including the local agency's labor, freight,

and storage charges; these should also include cost increases that
could result from project delays;
o equipment costs, including freight and storage charges;
o financing charges (based on the financingmethod used), interest during

construction,accountingand audit fees, taxes, and other related
costs;
o annual operation,maintenance,and replacementcosts; and working

capital and spare parts allowances should be made for the effects of
inflation on these costs over the projected life of the project; and
o administrativecosts for the organizationresponsiblefor execution and

long-term operation of the project.
o identificationof lease and foreign exchange cost component.
In many instances, data for estimatingthe costs for constructionand

operationmay originate from a variety of reference sources and be based
on different time periods. In order for the informationto be useful it
must be adjusted to a common base -- the prices that would prevail for the
year in which the estimates are being prepared.
Data on costs can be adjusted to a common base by the use of annual costs
indices. These indices represent the changes in price levels from year to
year, based on the levels establishedfor a specific year which is used as
a referencepoint. The annual index reflects the changes due to inflation
and other factors which influenceprice levels.
(C) Sources and Methods of Financing
In implementingpollution control plans provisionsmust be made to finance

the capital costs of constructionas well as long-termoperation and
maintenance,and future capital costs. Provisions should cover the
complete system, including all its segmentsand phases. Funds may come
from the private sector or one or more governmentallevels (national,
state and provincial, regionaland municipal), and from industrial
participantsand traditionalsources for financing (e.g., banks).
Internationallending institutionsmay also provide financial assistance
in the form of both grants, loans and equity. All these sources should be
investigatedduring the planning process.
- 84 -
In some countries national and state governmentsmay provide subsidies or

loans or tax breaks for capital (includingconstruction)costs. Within a
country or state such funds may be available through several agencies,
depending on such local factors as location, economic conditions,
developmentneeds, etc.
Local sources of capital funds include tax revenues loans, and bond issues
of various types. Municipal governmentsgenerally have little or no
surplus tax revenues, and hence are considereda poor source of funding.
Usually the local governmentmust resort to borrowing in order to furnish
its share of the cost. However, in developingcountries, loan funding,
independentof government sources,may often be unavailable. The project
must then be cut back in scope or else extended over time to facilitate
financing from such annually allotted budget sources as are available.
Sources of capital at the local level include the following.
o Bonds - Although not frequentlyused in developingcountries,theymay

take the form of:
* special assessmentbonds - issued to cover costs where specific

private beneficiariesexist, and retrieved through payments from
these private sources as opposed to general taxpayers;
* general obligationbonds - backed by the credit of the issuing

agency in contrastwith revenue bonds which may not have the full
faith and credit of the issuing agency but depend on revenues
generated by project-financedincome or from specified sources;and
- industrial developmentbonds - issued by industry to finance capital

costs for a variety of purposes, including pollution control.
Government incurs no obligationsince bonds are retrieved by
payments received from industry.
O Leasing/InstallmentPurchase - local governmentacquires public

facilitieswithout initial capital expendituresfor outright purchase.
The lessor can be a private firm or a non-profit corporation.
o Taxes - this is a broad category in which part or all of the revenues

generated are designated for a specificuse. Types of taxes used
include general sales, selective sales, use, ad valorem, property, and
others.
o Charges, Fees, and Permits - refers to the form of assessmentlevied

upon the beneficiariesof the public service. These may cover the
capital costs, operating costs or both. For a self-supportingprogram
the system should reflect the full cost of operation,maintenance,
depreciation,and interest on debt. It should also cover a return on
that portion of capital costs not financedby debt (e.g., government
capital grants). In addition, funds generated from operationsshould
be adequate to cover at least all operating costs and, if possible, all
necessary requirementsfor debt service including sinking fund
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contributionsfor debt not redeemedby installments.
(D) IdentifyingAgency Responsibility
Institutionalcapabilityfor assuring cost-effectivemanagement is

critical. Proper management requiresthe execution of certain basic
administrativefunctions,such as continuousplanning and monitoring,
operationsand maintenance, regulation,and financial administration.
These activities can be adversarial (such as operation and regulation),
and when that is the case they should not be carried out by a single
agency; however, responsibilityfor each function should be assigned so
that inter-agencycoordinationis achieved. For example, a special
district that owns and operates a hazardous waste management facility
should work closely with the economic developmentagency in identifying
future capacity needs.
(E) Preparing the Financial Plan
The purpose of the financial plan is to show in detail how the project is
to be financed. It will determinewhether or not the project is
affordablewith available resources. Who will pay? How much will each
participant or beneficiary pay? When are payments to be made? These and
related questions are not easily answered.
As a start, implementorsand policy-makersinvolved should make a

preliminary financial analysis, organizingand evaluating the information
already assembled. The analysis should show the participating
organizations,the responsibilitiesof each agency, and funding sources
for each of the costs shown. Assumptions bearing on costs and funding
should be clearly detailed.
The financial plan should include both a burden and risk analysis. The
former identifiesand attempts to predict the future financialburden on
each of the affected institutionsand on the host locales. The risk
analysis shows the extent to which projected costs could vary in the event
of unanticipatedfuture changes in the proportion of external to local
capital funding, and to changes in the costs for services, etc. As a
planning tool, it is essential to have a fall-backposition for financing
if earlier assumptionsdo not materialize.
(F) Privatization
Privatizationas an alternativemethod of financingvarious types of

public works has been used frequentlyin some countries during the past
ten years. Under privatizationarrangementsa private entity finances,
designs, builds, owns, and operates the treatment facilities,and sells
the services to industrialcustomers for disposal fees. Either the
private entity or the communitymay assume responsibilityfor setting and
collecting service charges, and for all other dealingswith the customers
served. Partial privatizationhas also been used successfullyin some
cases where a private contractoroperates and maintains the system and
provides services to customers for a fee.
- 86 -
Success of the privatizationapproach depends to a large degree on the

effectivenessof enforcementof governmentpollution control regulations,
the tax structure,tax treatment of private investments in these
facilities,depreciationbenefits and other tax benefits. In many
instances,special legislationhas been necessary to make the method a
viable alternative,since the method may result in a transfer of national
public revenues (i.e., governmentgrants) to the local level via a private
entity. Principal incentivesfor consideringprivatizationmay include:
o inability of the community to raise needed capital;
o tax advantages to the private operator;
o expected greater efficiencyin the private sector due to fewer

constraints than in the public sector, and
o transfer of risk for proper operation and maintenance.
A possible disadvantageof privatizationis potential loss of control on

the part of the public agency. Loss of control can be minimized by
addressingthe following issues in the agreement between private operator
and public agency:
o level of service, especiallywith regard to reliability,safety, public

health risks, and future expansions;
o future increases in costs resulting from factors which cannot initially

be fully determined (change in hazardouswaste characteristics,new
treatment requirementsdue to new laws and regulations,etc);
o environmentalconcerns (pollution,aesthetics,noise, odors);
o future transfer of ownership of the facilities;
o resolutionof disagreementsbetween the parties;
o utilization of future financial assistancewhich might become available

from outside sources; and
o regular inspectionsand regulatorycontrol.
(G) Revenue Systems
A purpose of all charge systems - regardlessof whether the charge is

levied on the user or on the waste, - is to raise the revenuesnecessary
to finance the facilitiesrequired to improve and protect the environment.
Some type of pollution charge is currently imposed in many countries. All
too frequently,public agencies make satisfactoryfinancial arrangements
for capital constructioncosts, but fail to plan for the funds needed for
long-term operation and maintenance and debt servicing.
Local sources of operating income may take the form of either user charges
or taxation, but user charges are the predominantmethod utilized. User
- 87 -
charges can be designed to correspondto the amount of usage, or the

extent of the pollution load, and are therefore consideredto be more
equitable than taxes.
To make the pollution control program self-supporting,charges should

reflect the full cost of operations,maintenance,depreciation,debt
amortizationand interest. The inclusion of a depreciationfactor assures
the availabilityof funds for future plant and equipment replacements. If
charges are not designed to recover all costs from those receiving the
services, then the system will need to be subsidizedand the financing
plan prepared accordingly. All financing sources should be clearly
identified.
Due to the chronic shortagesof government funds in most developing

countries, it is vital to find a way to retain the revenue generated by
the hazardous waste management program for running and maintaining the
program and not to let that revenue be put into a general fund.
(H) Revenue Requirements
The approach to determiningannual revenue will vary according to

ownership and regulatoryrequirements,as well as local policies and
circumstances. For most facilities,rates are set so as to provide the
annual income necessary to meet those operating and capital expenses
(includingdebt service)not otherwiseprovided through subsidies,grants,
or other sources. This is generally referred to as the cash basis. The
following elementsmust be covered when determiningincome requirements,
others may be includedwhere necessary.
o Operation and maintenance,to cover:
* collection system;
* treatment facilities;
* accountingand collection;
* customer services;
* administrativeand general expenses; and
* depreciation.
o Management and administrationfor capital projects.
O Materials and supplies for capital improvementand other projects.
O Routine capital purchases (e.g., office machines, computers, laboratory

equipment,major machinery, spare parts, etc.).
O Payments for hazardous waste treatment obligations, (e.g., when part of

a service area may be served by another facilityor certain services
are performed under contract).
- 88 -
o Bond coverage requirements.
o Debt service requirements.
O Plant replacements.
Annual revenue requirementsmay also be establishedon a utility basis

which means that a publicly owned entity is required or permitted by
statute to follow rate-makingpractices employedby investor-owned
utilities. The utility basis may be preferable for establishingthe costs
of serving customers outside service area boundaries. The method also has
other benefits, such as recovery of cost over the life of the facility.
The four major components of the utility method are:
o operation and maintenance expenses;
o taxes and payments in lieu of taxes;
o depreciationexpenses; and
o the rate base (often based on the total original cost value of
facilitiesused or under construction)for providing services, and on
which the financial rate of return is calculated.
The revenue structure should be subjected to a trial or test period of at

least 12 months. The test period should be sufficientlylong to be
representativeof the time during which the rates are expected to be in
effect.
(I) Allocating Costs
As stated previously, the revenue structureshould cover all of the

expenses needed for capital costs and operations. Various approacheshave
been used. A common method is to base costs on the "cost-causative"
operationsperformed by the hazardous waste treatment facility.
Under this method, costs are assigned according to the cost-causative

agent or factor, which is defined as that characteristicor property of
the hazardous waste or of the customers'requirementswhich predominantly
influences the size and cost of the plant's components. Examples of cost-
causative agents are average and peak waste generation, flammable agents,
reactive agents, corrosive agents, and toxic agents. Certain basic data
are required for determiningthe design and cost of needed facilitiesand
the assignmentof costs. As a minimum, the following factors, or cost-
causative agents should be established:
o number and type of customers;
o average and peak hazardous generation rates;
o waste characteristics;
_ 89 -
o area and density of the collection system;
o contributionfrom other environmentalprotectionactivities (e.g.,

abandoned site cleanups, sludges from wastewater treatment);
o siting incentives to mitigate impact on the host community; and
o projected future potential customers and service needs.
Identifiablecosts are assigned to each of these componentsfor

establishingcharge rates. It is necessary to recognize seasonal or other
use variations. For example, a refinerycould generate large amounts of
hazardous waste meeting demands for gasoline during the tourist season in
the U.S. or Europe.
Once costs have been assigned to the cost-causativefactors then the total
service costs must be distributed according to the customers'classes.
This can usually be done in three steps.
o The first step is to identifythe types of services to be provided,

classify the customers to be served, and assign services to each
customer class. Classificationshould reflect groups of customerswith
similar service needs which can be satisfied at similar costs to the
utility. Customer classificationis based principally on waste
generationrates and characteristics,type of service provided,whether
the wastes accepted for final disposal are pre-treated or raw, and
other similar considerations.
o The second step is to establish common bases for assigning cost

responsibility. Each class of users is responsiblefor a specific
number of service units which represent its share of the overall waste
stream, capacity and customer costs. A service unit refers to the
resources required to handle one unit, such as a cubic meter of waste,
a kilogram of incinerationcapacity, etc.
Considerationshould also be given to allocatingthe costs of sampling

industrialwaste and monitoring any required industrialpre-treatment
measures. Each customer class might also be required to share in the cost
of remedial handling of wastes from abandoned site cleanups.
o The final step is the establishmentof costs per unit of service for
each component, and the distributionof total costs per unit of service
for customer classes. Responsibilityfor cost of service is assigned
on the basis of projectedwaste quantity and quality, system capacity,
and units of service assigned to each class.
(J) Alternative Cost Allocation Procedures
While the cost-causativeprocedure is most widely used, other approaches

have also been successful. No one method can be considereduniversally
applicable, since local circumstanceswill dictate the approach to be
used. The underlyingprinciples for all the methods are that ideally the
- 90 -
total revenue collected should cover the total cost of the services
provided, and that the distributionshould be equitable and enable the
utility to operate on a self-supportingbasis.
3.7.3 InstitutionalConsiderations
Hazardous waste management is a key element in preservingenvironmental

quality. How effectivelyenvironmentalgoals are achievedwill depend
upon the degree to which a country's laws and policies are enforced.
As used in this section the term "institution"denotes the organizational

forms responsiblefor management of various functions and programs. An
"institution"could include the following:
o a national government agency or department;
o a state or provincial agency;
o a regional or river basin organization;
o a special district or authority;
o a county or municipal government;and
o a private entity, such as a public utility or an organizationoperating

under a governmentalcontract.
Regardless of the levels to which individualfunctions are assigned the

organizationalstructuremust clearly delineate authority and
responsibilityfor each of the political levels involved in order to
assure successfuldevelopmentand implementationof control programs and
projects.
(A) The National Organization
Responsibilityfor hazardous waste management in the smaller and less

developed countries usually rests with the Ministry of Health, since
pollution is thought of in terms of excreta disposal,which can have
serious health consequences. The developed countries, on the other hand,
have in most cases committed themselvespoliticallyto effective hazardous
waste management through the establishmentof an environmentalagency
under an administratorreporting directly to the head of governmentor to
a cabinet minister. This agency is responsiblefor protection of all
facets of the environment. Whatever the situation,it is extremely
important that such an agency have a high enough governmentalposition to
have access to the decision-makinglevel of authority and to be readily
responsiveto presidential,executive,legislative,and public needs. The
agency must also be provided with sufficientresources to accomplish its
missions.
The national agency should concern itself with major policy and planning
issues and with establishingthe criteria to be applied by lower
- 91 -
governmentallevels in resolvingmajor issues. Hazardous waste

management involvesmany disciplines and interests. Other national
agencies are also frequentlyinvolved, in particular the Ministries of
Finance, Planning, and Industry. The Ministry of Education, for example,
can play a role in establishingand implementingtraining programs. The
interests and areas of responsibilityof other agencies should be taken
into considerationduring the planning of a national hazardous waste
management program.
Whatever the organizationalstructure,the responsibleagency must be

provided with sufficientstaff, funds and other resources to enable it to
carry out its assignedmissions. It is essential that the agency is given
full political and other governmentsupport on a continuingand long-term
basis.
Although institutionaland administrativearrangementsfor hazardouswaste

management can and do vary from country to country, there are a number of
basic functionswhich are common to most situations. These are listed
below and should be used for reference in establishingor modifying
programs. Whatever the final organization,provision should be made for
periodic assessmentand for mechanisms to make any changes indicated as
time passes.
The functions consideredto be of major importanceat the national level

include the following:
o Development and evaluationof national program policies, as well as

appropriaterecycling,treatment and disposal strategies.
Establishmentof proceduresfor updating and disseminatinginformation
about national programs and policies on a current basis.
o Establishmentof program planning criteria for application at the

national, state, provincialand local levels.
o Development of general criteria for siting hazardous waste facilities.
O Identificationof significanthazardouswaste problems and organization

of research on effects on human health and the environment.
o Establishmentand maintenance of demonstrationprograms for new

technologiesand applied research, emphasizingthe use of low-costand
most appropriate technologies.
o Establishmentof criteria and guidelinesfor the use and disposal of

known hazardous substances.
o Establishmentand maintenance of a nation-widehazardous waste

monitoring program with adequate laboratory,equipment and manpower
resources. Promotion of complementaryprograms at state and local
levels.
o Establishment,maintenance,and enforcementof a manifest system

- 92 -
for generation, transportationand disposal of hazardous wastes.
o Establishmentof criteria for resource allocationand cost recovery, as

well as project selection criteria to be applied in deciding on
investmentalternatives.
o Provision of technical and financial assistanceto states, provinces,

municipalitiesand other pollution control agencies on planning,
management, research and training, and on solving difficult or new
types of problems.
o Establishmentof criteria and programs for training hazardous waste

control personnel.
o Compilation of scientificand technical informationon hazardous waste,

disseminationof this informationto agencies, institutions,the
general public and other segmentsof society.
o Coordinationwith other governmentagencies having an interest in or

involvementwith hazardous waste management efforts.
o Establishmentand maintenance of a mechanism for citizen participation

in resolvingmajor issues and for public appeal of agency decisions.
O Establishingcriteria possibly based on internationalagreements for

transportationand movement of hazardouswastes.
(B) The State or ProvincialOrganization
An active interest in hazardouswaste control on the part of state or

provincial governments is often a key factor in effectivemanagement. The
state government'sresponsibilityis central, and progress toward solving
problems and settling issues may be influencedto a high degree by the
effectivenessof state action.
In larger countries,both developed and undeveloped,state or provincial

governmentshave varying degrees of authority delegatedby the national
government. In smaller countries,however, all authority generally
reposes in the national government. Where the latter is the case the
functions as given below should be carefully examined and those which are
applicable should be assumed by the national authority.
A number of conditionswill affect productiveuse of economic and human

resources -- the two vital ingredientsof a successfulprogram. These
conditions include the legal basis for the program, the available
resources, the administrativeorganization,the availabilityof reliable
information for adequateplanning, and a proper balance of program
operations.
Organizationfor hazardous waste managementmust take into consideration

the number and types of municipalitiesand other local units and the
state's relationshipto them, and the distributionof responsibilities
within the state governmentstructure itself.
- 93 -
The number of lower civil subdivisionshaving authority over hazardous

wastes and autonomy in exercisingsuch authority directly affects the
demands on the responsiblestate agency and its program effectiveness.
There is no single best organizationalarrangement for hazardous wastes
management. Whatever structure is adopted, it must ensure (as has already
been stated) effectiveuse of personnel and resourcesby all of the
agencies involved - national, state, and local. An integratedapproach by
all agencies is essential.
A balance of activitiesis necessary for ensuring a successfulprogram.

Such activities should include provisions for:
o Securing adequate funding
o Updating the informationon the nature and characteristicsof the

problem for program planning purposes
o Establishingthe full scope of measures for securing compliance, such

as informationand educationprograms, administrativereadiness,and
the legal capability for positive enforcementaction
o Continuing surveillanceand technical study of hazardous wastes
o Technical review and assistanceto municipalities,special districts,

and industry. Along with personnel resources,the organizationwill
also have other needs, such as well equipped laboratoriesand field
facilities.
The following functions of the state, regional, or provincial government

are vitally important.
o To establish and maintain on a current basis a clear definition of

hazardous wastes and an inventory of hazardous waste production.
o To establish and maintain technical design standards for hazardous

waste management systems.
o To establish and maintain a manifest system to cover the transportation

of hazardous wastes.
o To conduct investigationsand inspectionsto ensure compliancewith

standards,policies, regulations,permits, licenses, and other state
statutory provisions. To carry out enforcementactions when violations
occur.
o To provide technical assistanceto other state agencies, local

jurisdictions,industries,and the public in general covering:
* laboratoryservices, through central or regional laboratories;
* management information services;

- 94 -
* data collection,processing and evaluationaid; and
* environmentalinvestigationson special problems.
o In cooperationwith national agencies, to coordinatethe financialand

cost recovery policies in line with criteria established for resource
allocation, sub-projectselection,operation and enforcement.
o To disseminate technical advice and informationon hazardous waste

management to state and local agencies, committees,associations,and
other segments of the general public.
o To coordinateemergency response capabilityat local levels.
O To devise a registrationsystem for recording the location and relevant

details of hazardous waste disposal sites on private property as well
as for publicly operated facilities.
(C) The Local Organization
The local organizationis usually a political and corporate entity

establishedby law for the purpose of acquiring,constructing,improving,
maintaining, and operatingprojects for the public's use, including
hazardous waste collectionand treatment facilities.
Many hazardous waste disposal problems can be reduced by proper regulation
of collection system usage. Ineffectivecontrol of municipal waste use
can result in uncontrolledindustrialhazardous waste discharges.
In the urban areas the control functionsmay be vested in an independent

municipal agency or assigned to another department (such as public health,
public works, etc.) in the municipal government. The organizationfor
managing the hazardous waste collectionand disposal systems can take many
forms and will depend upon local circumstances.
Major considerationsfor an effective state, regional, or local program

include the size of the staff, occupationalskills required, and the
quality of administrativeleadershipand skills. The agency should also
be provided with adequate legal services,either as part of its own staff
or through state legal agencies.
Factors to be considered in organizingthe staff include the total

population, the populationdensity and distribution,extent of
urbanization,degree of industrialization, types of industries,and types
and sizes of hazardous waste collectionand disposal facilities.
At the local level, the staffs are the direct providers of many services
to the public. Hence, local personnelmust have the skills to establish
and maintain the level of service desired by the national and state
governments.
Responsibilities,authorities,levels of activities, and relationships

among the agencies charged with managementof hazardous wastes will change
- 95 -
over time. The organizationalstructuresneed to be sensitive to major

and significantchanges, and be flexible enough to make adjustmentswhen
the need arises. At all levels, frequent retrainingand upgrading of
skills are essential to maintaining an efficientwork force.
An effective hazardous waste management program will only be possible if

air and water pollution control regulationsare also effectively enforced
and integratedinto a fully coordinatedenvironmentalcontrol program. If
water pollution control is lax, hazardous materials will not be separated
from polluted industrialeffluents prior to discharge into the environment
and quantities of hazardous wastes properly disposed of will be
correspondinglyless than under a strict enforcement regime.
Where a small community is adjacent or close to a larger one the smaller

city may wish to utilize the facilitiesof the larger one through contract
arrangements.
The use of a joint plant by several small communities in a region has

proved effective in many cases. Because of economies of scale, one plant
can be constructedand operatedmore economicallythan two or more smaller
plants. The cost of transportingthe hazardouswastes to a central
treatment facility, however,will have a bearing on the economics of such
arrangements. In addition, the risk of transportationaccidentsmust be
taken into account.
Whatever the organizationalstructuremay be, the most important functions

to be performed at the local level include the following:
o To operate continouslyand maintain the hazardous collectionand

disposal systems in such a manner as to protect the interests and
promote the well-being of the area served and its people. To initiate
repair, replacement,expansion,and improvementprojects as necessary.
To review and approve designs and constructionfor all projects.
o To establish and enforce standards for the control of industrial

hazardous wastes.
o To monitor, inspect and conduct laboratorytesting to assure compliance

with all applicablerules and regulations.
o To coordinatehazardous waste collectionand treatment activitieswith

those of other agencieswhich may be involved at the national, state
and regional level.
o To coordinatethe applicationof financial policies, project selection

and resource allocationcriteriawith national, state and provincial
levels.
o To establish an emergency response capabilityto handle accidental

spills of hazardous wastes through coordinationof all public and
medical services, etc.
- 96 -
o To establish community liaison and informationprograms to keep

citizens informed on all aspects of the hazardous waste management
program.
o Even if the disposal of hazardouswaste is well planned and all

necessary precautions are taken, continuousmonitoring is required to
check the adequacy of safety measures. Hazardous wastes tend to vary
in composition and quantity to an extent which cannot always be
anticipated. Environmentalconditionsmay also be subject to changes
which influencethe effectivenessof safety measures. The monitoring
strategy should therefore include regular analysis of the content of
hazardous agents not only in waste but also in drainagewater and
ground water adjacent to landfills or dumps, as well as the content at
the site of deposition. Similarly,levels of hazardous substances
emitted from the stacks of incinerationplants and in the surroundings
of such plants should also be monitored.
3.7.4 Staffing and Training
The staffing structuremust be based on the specific functions assigned to

an agency, and will need to be establishedon an individualcase-by-case
basis. This section,therefore,will be limited to discussinga number of
factors which should be considered in assemblinga staff.
The shortage of adequatelytrained personnel at all levels of government

has been a major obstacle to developingand implementingprograms in both
industrializedand developingcountries. No one profession is dominant in
control efforts. As problems become more complex multi-disciplinaryteams
with expertise in the following fields are required: civil, chemical,
mechanical, and electricalengineering,the biological sciences, chemistry
and the physical sciences,mathematics,operational research and systems
analysis, financialanalysis, economics,computer technology and
applications,and others.
At all levels, but particularlyat the national level, it is essential to

have highly skilled professionalcapability,plus a comprehensivegrasp of
the hazardous waste management field. An adequate supportingtechnical
and administrativestaff is also essential.
3.8 Evaluation of Options (Step 6)
3.8.1 Introduction
Having identifiedand quantifiedthe major types of hazardous wastes and

the deficienciesin the available facilities,particularlyfor treatment
and disposal, the next step is to identify and screen the available
options for hazardous waste management.
Much of the detailed informationin this manual is aimed at enabling the

planner to identify a number of potential technologiesfor consideration
in his country and to evaluate those options against his own particular
objectives and constraints. It has been the sponsors' intention to
- 97 -
provide sufficientinformationto allow a shortlist of appropriate

solutions to be drawn up at a "pre-feasibility'level of detail. To go
beyond that point more specific informationrelevant to the local
circumstanceswill be required in order to determine the most appropriate
and cost-effectivesolution.
3.8.2 The Hierarchy of Options
For any particularhazardous waste stream (i.e., type and quantity), it is

possible to define a 'hierarchy"of preferredmanagement options, which
should be considered in turn, the objective being to limit as far as
possible the quantity of hazardous wastes requiring final disposal. In
general, the sequencewill be:
o waste avoidance or reductionat source;
o recycling or resource recovery;
o treatmentby physical, chemical or biologicalmeans to destroy, convert

or immobilizehazardous constituents;
o incinerationto destroy organic wastes;
o disposal on land; and
o disposal at sea.
3.8.3 PracticableOptions
Throughout this technicalmanual, efforts have been made to identifyand

discuss a number of relativelysimple options which may be practicable
where quantitiesof waste or financial resources are too small to justify
conventionalfacilities.
Examples of such practicableoptions include the following:
o solar evaporationponds as a means of sludge dewatering or drying;
o use of evaporationpits for very small quantities of solvents,where

recovery or incinerationis not practicable;
o encapsulationof very small quantitiesof difficultwastes in cement,

prior to their burial in a landfill;
o adaptation of existing lime or cement kilns, or industrialboilers, to

burn hazardous wastes;
o the use of engineeredopen-pit incineratorsto burn small quantities of

hazardous wastes in isolated areas; and
o "stabilization"of oily sludges by mixing with sand, or similar

material, and weathering. The product may be used as a low-grow
- 98 -
asphalt substitute, for example to encourage rainfall run-off from the

surface of a landfill site.
There is little informationavailable on these and other options which may

be of particular interest to some of the less developed countries where
both financial resources and the quantitiesof hazardous wastes are
limited.
3.8.4 IdentifyingSuitable Options for Particular Types of Waste
The first objective of any waste managementprogram should be to minimize

the amount of hazardouswaste being generated and the amount requiring
disposal. This objective can best be achieved through waste recovery and
recycling.
The selection of appropriatetreatment and disposal facilitieswill depend

largely on the types and quantitiesof hazardous waste which are generated
and on specific local factors. Not all options are suitable for all types
of waste. Detailed considerationmust always be given to the composition
of the waste and other local factors.
As a general guide, Table 3-3 indicatestreatment and disposalmethods for

12 generic types of industrialwaste, as recommendedby the Environmental
ProtectionAuthority of Victoria in Australia (1985). Table 3-4 indicates
both the hazardous propertiesand the recommendedtreatment or disposal
methods for a large number of common industrialwastes. It should be
emphasized that these recommendationsare for the general situation as
pertaining in the State of Victoria. In practice, choices will be
influencedby the degree of pre-treatmentcarried out by the waste
generator and/or by the availabilityof suitable facilitiesfor treatment
or disposal.
In a country with an establishedwaste management system, it is possible

to draw up a "decisiontree" to provide guidance to generatorson the
appropriate treatment or disposalmethod for particular groups of wastes.
Figures 3-3 and 3-4 provide examples of such decision diagrams as prepared
in the United Kingdom for tarry wastes and pesticide wastes. Although
some of the terminology in these diagrams is specific to the United
Kingdom, they do provide useful examples of the sequence of questions
which need to be asked in order to decide on the suitabilityof a
particular option for a specific type of waste.
3.8.5 Evaluation of Options
The various options for providingwaste treatment and disposal facilities

must be compared and evaluated in terms of their performance as measured
by the various objectives and constraintsestablished at Step 2.
Many evaluationtools have been developed to assist the decision-makerin

comparing alternatives. The most helpful is probably the use of a simple
tabular or matrix presentationin which each option is compared directly
against each evaluationcriterion,with entries in the table being made in
TABLE 3-3
Recommended Disposal Methods in the State of Victoria, Australia
Treatment Immobilization
Physical Chemical
Chemical fixation
Recovery Incineration Bilogical Encapsulation Landfill
Effluents, Washwaters xxx
Acids, Alkalis xxx
Heavy Metals xxx xxx residues
Toxic Inorganics xxx xxx residues
Reactive Wastes xxx
Non-toxic Inorganics xxx xxx
Solvents, Oils xxx xxx
Resins, Paints, Organic Sludge xxx xxx
Organic Chemicals xxx xxx xxx
Pesticides xxx xxx
PCBs, Chlorinated hydrocarbons xxx
Putrescible, Biodegradable Wastes xxx xxx
Source: Environmental Protection Authority of Victoria. 1985.

Draft Industrial Waste Strategy for Victoria. Melbourne.
TABLE 3-4
Properties and Disposal of CommonIndustrial Wastes
RecommendedDisposal
Waste Type Code Property (items in C ) refer to treatment residues)
S F R P Od r pc s I I b i d
Abattoirs residues 081 x x x x x (x)

Acids and solutions
(inorganic)
Alkylationacid 029 x x x x (x) (x)
Boric 029 x x x (x) (x)
Chromic 023 x x x x (x) (x)
Fluosilic 029 x x x x (x) (x)
Fluoboric 029 x x x x (x)
Hydrochloric 021 x x x x (x)x
Hydrofluoric 023 x x x x (x) 0
Nitric 022 x x x x (x)
Perchloric 029 x x x x (x)
Phosphoric 022 x x x x (x)
Picklingacids 029 x x x x (x)
Sulphurous 029 x x x x (x)
Sulphuric 021 x x x x (x)
Acids, organic
Acetic 029 x x x x x x (x) (x)
Benzoic 029 x x x x x
Butyric 029 x x x x (x) x x (x)
Formic 029 x x x x x x (x) x (x)
Lactic 029 x x x (x) x (x)
Oxalic 029 x x x x (x) (x)
Sulphonicacids 029 x x x x (x) (x)
Trichloac-tic 029 x x x x (x) (x)
Alkaline materials
Ammoniacalsolutions 031 x x x x x (x) (x)
Caustic soda or
sodium hydroxide 031 x x x x (x) (x)
TABL 3-4 (continued)
RecommendedDisposal
Waste Type Code Property (items in ( ) refer to treatment residues)
S F R P Od r pc a I I b i d
Lime Slurries 032 x x x x

Lime neutralized
metal sludge 033 x x x
Sods ash or sodium
carbonate 031 x x x (x) (x)
Sodium phosphateor
polyphosphates 031 x x x x (x) (x)
Sodium silicate 031 x x x x (x) (x)
Sodium sulphide 045 x x x x (x) (x)
Sodium peroxide 051 x x x x (x) (x)
Alkaline cleanors 031 x x x x (x) (x) I
Alkali metals OSS x x x x x (x) (x)
Animal residues 081 x x x x x x
Antimony compounds 045 x x x (x) (x)
Arsenic compounds 045 x x x (x) (x)
Asbestos wastes 181 x x x
Bags-previously
containedhazardous
materials 121 x x x x
Barium salts 046 x x x x (x)
Bleaching powdersand
solutions 051 x x x x x x
Boron (compounds of) 045 x x x x
Cadmium (compounds of) 045 x x x (x) (x)
Cannery wastes 082 x x x x
Cattle dips and
residues 049 x x x x x (x) (x)
Carbonization liquors
(wood or coal) 169 x x x
Chlorinatedhydrocarbons
Chloroform 074 x x x x
Carbon tetrachloride 074 x x x x
R-commendedDisposal
S F R P Od r C s I I b i d
Ethylenedichloride 074 x x x x
Perchlorethylene 074 x x x x
Trichloroethane 074 x x x x
Trichloroethylene 074 x x x x
Chromium compounds 046 x x x x (x)
Copper compounds 046 x x x x (x)
Cyanides
Plating residues 013 x x x (x) (x)
Heat treatment
residues 014 x x x (x) (x)
Metal complexes 01S x x x (x) (x)
Organo-cyanides 159 x x x x x (x)
Detergents 156 x x x x (x) °
Disinfectants 169 x x (x) (x)
Drugs (see
Pharmaceuticalsand
residues
Dyestuffs 061/9 x x x
Explosives 063 x x x x
Fats, grease 104 x x x x x x
Fish residues 081 x x x x x
Fluoridesand compounds
containingfluorine 042 x x x x x
Fruit residues 082 x x x x (x)
Fungicides(see
Pesticides)
Grease trap residues
domestic 083 x x x x
commercial 084 x x x x
Hydrocarbons
Lubricatingoil 101 x x x
Light oils 101 x x x
RecommendedDisposal
S F R P Od r pc s I I b 1 d
Solvents (low flash-

point) 072 x x x
Ins-cticidesand con-
taminatod containers
(see Pesticides)
Isocyanatos 159 x x x x x (x) (x)
Lead compounds 046 x x x (x) (x)
Lime slurries 032 x x x x
Lime neutralized metal
sludges 033 x x x
Manganese compounds 047 x x x (x) (x)
Mercaptans 153 x x x x x
Mercury and compounds 046 x x x (x) (x) O
Methacrylates 153 x x x x x x
Motor fuel additives
and residues 071 x x x x
Nickel compounds 045 x x x x (x)
Nitrates 061 x x x x (x) (x)
Oils
Cutting oils 101 x x x x
Cutting mulsions 103 x x x (x) (x)
Hydrocarbon 101 x x x x
Lubricating 101 x x x x
Organo-Nitrates 159 x x x x x
Oxidizing agents
Chlorates 061 x x x x (x) (x)
Chromates 051 x x x (x) (x)
Nitrates 061 x x x x (x) (x)
Permanganates 061 x x x x (x) (x)
Peroxides 051 x x x x (x) (x)
Paint thinners (low
flashpoint) 072 x x x
Pesticides 161/9 x x (x) (x) x
TABLE8-4 (continued)
RecommendedDisposal
WasteTy" Code Proporty (items in ( ) refer to treatment residues)
S F R P Od r pc I I b 7 d
Peroxides 061 x x x x (x) (x)

Pharmaceuticals
and
residues 164 x x x (x) x x
Phenoland phenolic
compounds 152 x x x
Phosphorus residues 064 x x x x x x (x) x
Picklingacids/
solutions 029 x x x x (x) (x)
Poisons(anymaterial
whichwouldbe
labelledunder
Schedules1-7 of the
Poison*Act) 046 x x x x
K
Polychlorinated
Biph-nyls (PCBx) 156 x x x
Rndioactivmaterials
(controlled under
other Acts) 171/2 x x (x) (x)
Scallopshells 081 x x x
Seleniumcompounds 046 x x x x (x)
Sheep dips and residues 049 x x x (x) (x)
Solvents, low flash-
point 072 x x x
Sulphides 046 x x x x (x) (x)
Sulphites 045 x x x x (x) (x)
Surfactants 155 x x x x
Tetrasthyllead
residues 161 x x x (x) x
Timber preservatives 049 x x (x) (x)
Thallium compounds 046 x x x (x) (x)
Triple InterceptorTrap
residues (T.I.T.) 103 x x x x
Turpentine residues 071 x x x x
RecommendedDisposal
S F R P Od r pc a I I b i d
Vanadium compounds 045 x x x (x)

Vegetablewastes 082 x x x x x
Waxes-animalA plant 182 x x x x x
Weedicides (s-e
Pesticides)
Whit, spirits 072 x x x
Zinc compounds 046 x x x x
C
Recommendationsare those for general situations. Practicalchoiceswill be influencedby appropriatepro-treatmentand/or
n
availabilityof suitablefacilities. Disposalto sewers watercoursesand landfillis subject to acceptancecriteria of
relevantauthorities.
S - toxic, carcenogenic r - recovery, recycle

F - flammable pc - physical/chemical treatment
R - corrosive,highly s - solidification
reactive
P - putrescible I - landfill (normal) (licensed)
Od - odorous l* - landfill (impervious) (licensed)
b - bilogicaltreatment
i - incineration
d - water/sewerdischargesubject to agreement or license
Source: EnvironmentalProtectionAuthority for Victoria.1986.

Draft IndustrialWaste Strategyfor Victoria.
FIGURE 3-3 Tarry Wastes, etc. Technical Memorandum: Liquid and Solid Waste
syes
Isa suItoble Na SPECiAL
Incinerator _ TREATMENT
iSLIQDAND availablea (6) (4)
SOL WASTEStye
Iswaste No
combustible?
iRODiJCERES
could
siecitt
landfill pro-
h
yes
over- cedures
cobustIle pract ? come this?
_quantityod eg: Immedlate
the waste burlcjl? the waste
\wAll
giverCseto a
dnifcnt No yes slgntflcant
E
Source:theUnted en 197 Waste Maxnageent
oKiNgddomeso Par
t o.s
a1 l O No-q
yoessthewaste
hadti or It libes to ttantloy nuolbeipelssaoxcnce?ho | noficeR |I

London Herf Maestys
h at 2 N i ge Is rtons
tro ts icro s c to seh aleaityre o
Notes I.Rcovey isaokeneoinltei
|RECOvR (1) | swse

W| ° 1sneta o 2°No t or| polt e°
and tom.nmze
landfill sitehydraulicloadntecasel,
capacity, combustible? nmpach a t m i pollutina so Ing s
Yes | sa sulai | |boeradbe| | EFUN |

, nctnramtorII I I I-
|avalalobe? (6) || l l |N e
Note:The
bovelandill ispo alrue rpresenta l idalie sigtuain.I i eogxedtidate
I utabiitcano
Ino
o l bedeemie
l l
remoel,sincesct l~~~~~~~n
osdrona oa conditions, tegreolodn, eAteoSSc
Lh ITiEsadrtsbegdtont
t ,e + t + |~~~~~~~~~~~~r
t | dependenton loodlng
{E1 3~~~~~~~~~~~~NI SPECA L|| TSPECALET and rature of woste
t (2) (3) i | ~~~~~~~~~~~~~~~consult

RWAi |
| neu { | ~discharge
I or,rEctL9) | CAS2 | | LS3 |
Kingdom of
theoEnvironment. 1977. Waste ManagementPaperNo. .lquor
13. sp yes i TRhistshoul i inErto 6 T isEs
Source: United
London: Her Majesiys stationaryoffice. |mD
toxlcitlescondratesof blodegradatlon of
'Note:Theaobove landill dlspoal routesrepresentanideallzed sltuatlon. ItIsrecognlzed that sltesuitabllity cannot be determlned remotely, slncesuch conslderatlons as local condltlons, degree oflocading,the relative
Scotland)and other relevantbodles.
wasteswill Influence siteselectlon. Inproctice, the mutual sultablllt ot sitesand wastes mustbeassess d by local consultatlonbetween theWaste DlsposalAuthoritles,the Regional Authorlites(RlverPurlflccatlonBEoardIn
options.to prolong the life of limiteIcd ladill
Notes:1 , Pecyery Istaken to Include the recoveryof potential heat values. 2. No optlon Is given for thls Incinerationstep,subJectto itstechnlcal feasibillty. A l other inclneratlon recommendatIons are preferred
t dISPOa. 4.InaddIfon to (3) aboveth1s
capacity, and to mlnlmize landtilllslte hydroullc loodIn thecoaseof llqulds. 3.In thiscontext, specilultreatmentwilllencormpasschemical trectrnent (which mav Include neutralizatlon), chemlcal solldlfcatlon ormineshCa for solidwastes than for liquld wastes,
could Include submissionto Mlnlstryof Agriculture, Flsheries and Food forconsideratlon or sea41sposal. 5. Inaddliton to (3) and (4) ab yve,special treatment Inthis context should Inclucle Inciner tlon. 6.ThlsIs lesslikely
my be suitable for some solid materialssubject to the constraintsimposed by design consideratlons. except where a wastes aggessiveor
although suitable tacilitles do existwtthin the private waste disposalsector. In addition, municipal refuseincinerators 0
at4O C are subjected toa naked flame(applied remotely- i.e.,a
othervise hazardouspropertlesexcludethlsfromaspectsotfsafety. 7.Asimplevwdelyappilcabletest procedure Isrecommendedwhereby 5 ml of o liquid woste in a shallowdish maintained
may produce residueswhichshould beconsidered
toperis preferabletoa match orcigarette lighter). Al iliquldswhich ignite and sustaincombustlon aredeemedtobecapableof buming unsupported. 8.Neutralizatlon,recoveryand incinerationoperations
(III).
aswastesfordisposal. 9. Class1,11and ill sitesreferto stes providingaslgnficant element of contalnment (I), sitesallowng slowleachate migration (II)) and sitesollowing rapid leachate migratlon
- 107 -
FIGURE 3-4
Decision Diagram of Disposal Guidelines for Pestice Wastes
Considertype, concentrationof active L _- Residue

Any suitableand safe rInsignificant Ingredient(a.I.)and quantity of waste
disposalprocedure ,Sgnificant
Doeswastehave any recoveryor Yes RECOVER Or
recycling potential? RECYCiEE o
or SUPPL_ER
no
^ | ~~~~~~~~~~~~~~~~~~~~~(3)
Productionwastes-solids,
semi-solids Diluteaqueoussolutionsand
and sludges.non-aqueousliquidsand slurries
Packaging Redundantor somerelativetyconcentrated slurries
waste damaged stock,and and aqueousliquids
unwantedproducts I 1 (4)
1
(4.5) Doeswastepresenta significanthealth, Doeswaste presenta significant
iswastecontaminated yes Doeswastepresenta handlingor environmentalhazard? health,handling or environmental
withraw materials significanthealth, (9) j yes (7) hazardor seriousamenity
orproducts? handlingare"'viron - Does waste bum nuisance?
mental hazard,any Iyes unsupported? (6)
4m serious arnenity (10) rno I
| LANDFILL
nuisance
6skg
j or sesunty ~~~~yes iscemical or biological Could
virtueotthis be ve)come
ready (e g b
biodegrodabilit)?fIR~M~
yeG | isa suit |n, able no (4) I
no (4 yes
no is waste no ~Could
special incinerator
combusibe? r tlandfillpro- available? Doeswastegiveriseto Consultwateror sewerage Consult
yes lR thicedures
overcome no any eriusamenity authoity redischarge or WDAfor
(8)(e.g., this ~~~~~nuisance
no issuitableo Immediateburial Could spec TRADE
EFFLUENT LANDFILL
incinerator and cover)? landfillpro- no
| | available?
| B | |~~cedures ye t
I | | yes ovIrsrercome
thtsl |WilMwasteproducea no
(eg., Imine- signgifiantquantityat
r----, ~~~~~diate
burlai leachate?
INC INERATE SUPERViSED
BURiAL| and cover)? ye
Identify hazards
from solublespecies
| SPECIALTREATMENT AND LANDFILL

according to concentrationof a.i,toxicity,persistence.
etc. of hazardous
componentsin waste,the hydrogeologicalstatusofthe site,etc.
The waste producer (if necessarybyfinding outfrom the supplier) should be the primary sourceof information on the propertiesof a porticularwaste. I .Thequantities ofboth current and
future arsings of specific wastes and the handling capacity and looding of potentia. disposalsites are factorsto be considered when deciding on a disposalroute. Thedisposalof a
particularwasteasa one-offarising may requirea totally different solutionasopposed too similarmrterial arisingon a regularbasisin quantitieswhich may be ordersofmagnituoe greater
orsmaller. Theoverall propertiesofowaste should betoken intoaccount, aswell asthe propertiesofthe active ingredient(s). 2 Recoveryincludesreuseasa fuel,and sellingclean empty
containersas scrap. 3.Someaqueouswastes containing relativelyhigh concentrations oforganicand/or inorganic chemicals maynotbe reodilyamenable totreatmentordischorge as
liquid effluent. 4 Thegeneration o otffensiveodoursis likelyto be the main amenity nuisonce. 5.Securedisposalisof importonce fotarl bronoed products and forol materials attractive to
childrenorwhich could be subjectto misuse.6. Inthis context special treatment could includechemical ond/orbiological treatment. Ortheuseofphysical methodssuch assettlementof
aqueous suspensions.sometimesby lagooning withinthe factorycurtilage. 7.A simple widely-applicabletest proceoure isrecommended whereby5 ml of aliquid waste in ashallowdish
are sublect to a naked flame (apptied remotely;-iea taper ispreferabletoa match orcigarette lighter) and the temperatureslowly raisedto4O C. with frequent application ofthe naked
flame. All liquidswhich ignite and sustaincombustion are deemedto be capoble of burning unsupported. 8. ncinerationftcilities existwdhin theprivatewastedisposal sector. Municipal
incinerators may be suitablefor smallarisingsofsome solicmateials (particularly pockaging wastes,rejectproductsand returned goods) attertaking into account handling, satetyano
plant design considerations. 9. Liquids that burn unsupported should be incinerated where technically feasible 10. Chemical properties of consequence might include pH value,
reactivity ofwasteswith acidstop roducetoxicgases, liabilityto spontaneouscombustion,or oxidizing potential towardsorganic moterials.Undesirablebiological acJivitymight resulttrom
the presenceofcertain microbiological pesticideactive ingredientsin significantquantity. 11 Special treatment inthis oontext could includechemical treatment,fixation forinorganic (or
mainly inorganic) wastes, or physical methods such as puncturing or crushing of empty containers. The hydrogeological statusof a landfill sitewill take account of itsability to contain
leachate or otherwiseallow of dilution and attenuation by natural processesin the underlying strata.
Source: United Kingdom Department of the Environment. 1980.Pesticide Waste Management Paper No 21. London: Her Majesty's Stationary Office.
- 108 -
a mixture of quantitativeand qualitativeterms. This ensures that all of

the relevant informationis available to the decision-makerin a
systematic framework. A multi-criteriacomparisonof this kind requires
careful judgement, and will generally result in the selectionof a short-
list of options for further consideration. The use of a more mechanistic
approach, for example ranking and weighting, tends to miss the multi-
dimensionalnature of the decision and is not, in general, to be
recommended (Wilson 1981).
3.9 Site Selection (Step 7)
3.9.1 General Principles
In parallel to the analysis of treatment and disposal options, it is

necessary to identify and assess potential sites for new facilities.
Major waste handling facilitiesshould be sited in accordancewith
planning criteriawhich incorporatesafety, environmental,social,
political and technical constraints. Consistentwith the overall planning
process, the goals of site selection should be:
o to minimize health risks;
o to maximize public acceptability;
o to minimize environmentalimpacts;and
o to minimize costs.
Risks to human health, environmentalimpacts and public acceptabilityare

important factors to be considered in the site selectionprocess. There
may even be instanceswhere they overlap in significance. For example,
there may be situationswhere relativelyminor health risk-related
concerns are supersededby major environmentalimpacts. Similarly a major
cost considerationmight supersedea minor risk or environmentalimpact
consideration.
To meet the siting goals, two basic tasks must be undertaken:
o the definitionof factors and criteria for site selection;and
o the establishingof methods to apply the criteria in a rationalway.
3.9.2 Siting Factors
Listings of selectioncriteriahave been developed over the years in a

large number of siting studies. While there is general agreement on the
basic types of siting factors to be used for hazardous waste facilities,
the manner of their classificationand presentationvaries widely. Table
3-5 is a listing of siting factors prepared for hazardous waste facilities
in Victoria, Australia (EnvironmentProtectionAuthority of Victoria
1985).
- 109 -
TABLE 3-5
Siting Factors
Physical Constraints
o Surface soils
o Subsurfacegeology and aquifers
o Topography
o Surface water and streams, flooding
o Seismic stability
o Land stability
o Wind direction
Ecological Constraints
o Flora and fauna

o Conservationvalue
o Habitat value
Human Values
o Landscape
o Recreationvalue
o Historical/archaeological/cultural
o Population density
o Employment opportunities
Land Use
o Agriculturalvalue
o Extractive industry/mining
o Water supply (surfaceand subsurface)
o Developmentpotential
o Transportationcorridor or utility use
o Land use designation (residential/industrial,
etc.)
Waste Disposal Suitability
o Proximity to users
o Transport access
o Availability to utilities and services
o Adjacent land use; zoning
o Site modifications
Source: EnvironmentalProtectionAuthority of Victoria. 1985. Draft

IndustrialWaste Strategy for Victoria. Melbourne.
- 110 -
The factors are presented here as points for considerationrather than the
basis for absolute exclusion criteria. Not all the factors listed are
equally applicable to each type of hazardouswaste treatment and disposal
facility.
For example, for landfillsand storage or evaporationponds, the physical

characteristicsof the site should be more importantthan for other types
of facilitieswhere the wastes do not remain on the site and do not
normally come into contactwith the soil. Special attention should be
given to the hydrogeologicsuitabilityof the site (e.g., subsurface
geology and aquifers and permeabilityof soils). To some extent these
constraintscan be overcomeby site modification (e.g., by the use of
liners to provide artificialbarriers to waste migration). The strategy
recommendedhere, however, is to select,wherever possible, sites with a
high degree of natural containment. Careful attention to the
hydrogeologicconditionscan reduce the site preparation cost considerably
and can substantiallyincrease the safety of these facilities.
Special physical constraintsalso apply in the case of incineration.

Considerationshould be given to the prevailingwind direction and air
dispersioncharacteristicsof the site. Avoid areas prone to atmospheric
inversion conditionsor upwind of and in close proximity to residential
areas.
Ecologicalconstraintscannot readily be overcome by plant design changes

and in some cases may be treated as exclusion criteria in identifying
suitable sites.
The constructionand operation of all hazardous waste treatment and

disposal facilitieswill have a disruptive influenceon human values,
(e.g., landscape, recreation)as a result of traffic, noise, possible
odors, etc. To some extent, these can be mitigated by inclusion of a
buffer zone or other measures. In other cases, mitigationwill be only
partially successfulor will not be possible at all.
The importanceof existing land use is determinedto some extent by the

pattern of future development,both urban and rural. The extent to which
a waste disposal facilitywould compete with agriculturalor mining
interests for example will vary from place to place. Water supply
catchmentsand future developmentzones are best avoided to eliminate any
potential conflicts,and to give some assurance of long term environmental
security.
The suitabilityof a site for waste disposalmust also be assessed so that

the facility can effectivelyserve its intended customers and can itself
draw on utilities such as sewerage,drainage and power.
In general, the relative importanceof the various siting factors depends

very much on the local physical, social and economic conditions. Certain
critical choices, or "trade-offs",may have to be made, for example:
o the preservationof agriculturalland versus the potential for local

environmentalimpacts;
- ill -
o the minimizing of transportationdistanceversus optimizingsite

hydrogeologicsuitability;and
o the use of vacant land near existing urban developmentversus a site in

a remote rural area.
Such trade-offsrequire careful consideration,and should be made with the

participationof the communitiesand organizationspotentially effected.
Public participationis an important step in obtaining public acceptance.
The need for public input has been clearly illustratedin many siting
efforts for hazardous waste treatment and disposal facilities (Centaur
Associates Inc. 1979). The reader is referred to a handbook prepared by
the United States EnvironmentalProtectionAgency which discusses in
detail the techniquesthat can be used to address local concerns (U.S.
EnvironmentalProtectionAgency 1982).
3.9.3 A Phased Approach to Site Selection
The site selectionprocess should be a step-by-stepevolution involving

the evaluation of alternativesand the narrowing of geographic focus. A
case study is presented in Annex 3B.
During each phase of site selection,the size of the study area is reduced
by identifyingissues,-developingcriteria appropriate to the scale of
investigationand applying the criteria in a structuredformat. This
phased approach offers the advantage of reducing the total amount of data
to be handled and restrictsdetailed evaluationto relativelyfew sites.
The number of phases and their complexitycan be varied to suit the nature
of the facilities,the study area and the preferencesof the waste
controllingauthority. Typically however, a project siting exercise might
be carried out in four phases:
o Phase 1 - Definitionof study areas and site requirements,including

land area.
o Phase 2 - Identificationof areas for potential sites by applicationof

exclusion criteria to the study area.
o Phase 3 - Identificationof candidate sites by 'screening'of areas

identifiedin Phase 2.
o Phase 4 - Comparative evaluationof candidate sites using detailed site

evaluation criteria.
Providing that the criteria for each phase of the site selectionprocess
are chosen appropriately,the phased approach should result in an
environmentallyand economicallysound selection of sites.
3.10 Review and Feedback (Step 8)
It has been emphasizedthroughoutthis discussionthat the planning

process is not a linear sequence of steps, but rather a complex structure
- 112 -
where one gradually learns from experienceand uses that information to

re-evaluatepreceding steps.
At this point in the procedure, it will be possible to draw up a

preliminary appraisal of the criticalproblems facing the area, region or
country, and a short list of technical options for solving those problems.
Feedbackwill be necessary:
o to check the scope of the plan;
o to re-examinethe objectivesand constraints;and
o to obtain better information on certain key aspects.
In the initial screeningof available technologiesand options one should

consider as many alternativesas possible. The analysis should be
sufficientlydetailed to identifythe most critical assumptions or items
of input data (for example particularwaste quantities,particular items
in a cost estimate or particularenvironmentalimpacts of a facility),so
that more effort can be devoted to obtaining better informationon those
aspects.
3.11 Generating and EvaluatingAlternative Plans (Step 9)
Following any necessary review and feedback, the planner will have
produced a short-listof technologiesfor hazardous waste managementwhich
are potentially attractivein terms of local needs and circumstances. If
the quantities of waste are relativelysmall, or the waste sources are
relatively concentrated,then perhaps the planner has enough information
at this point on which to base the choice of an appropriateplan.
However, in some cases, it may be necessary to take into account the
geographicaldistributionof waste generators,and also a number of
possible locations for each of the alternativetreatment or disposal
facilities. A relativelyconcise short-listof alternativetechnologies
may thus give rise to a much longer list of feasible alternativeplans,
taking into account the various combinationsof alternativesfor
collectionand transport and for the location of facilities.
In evaluatingalternativeplans, it is important to considerhow easy it

will be to implement the different schemes. Particular questionswhich
need to be considered include:
o what regulationswill be requiredto ensure that the system is used?
o how easy will it be to enforce the use of the system?
O are there significantdifferences in the organizationalarrangements

required?
o how able is the overall system to cope with a failure in any one part?
O how is the scheme going to be financed?

- 113 -
Alternative plans require systematicevaluationand assessmentagainst the

various objectivesand constraints. For example, a careful trade-off is
required between the benefits of concentratingall the wastes at a central
facility,with increased safety and securityof the operation and
decreased treatment/disposalcost, as against two or more local
facilities,which have the counterbalancingadvantage of reducingboth the
risks and the costs associatedwith transportation.
The evaluation of alternative regionalplans for waste management

including use of collectionand transfer stationsmay be attempted using
computer models. These models generally utilize linear programming or
similar techniquesto produce an "optimal"solution for a given situation.
A number of comments should be made (Wilson 1981 and 1985):
o mathematicalmodels can, in general, focus only on one criterion,which

is usually that of least cost;
o to be useful, a model should incorporatesensitivityanalysis, to

identify both critical assumptionsand key items of uncertain data;
o the most useful type of model is not a "black box" to produce the
optimum solution,but rather an "interactive",user-friendlymodel
which can be used by the waste manager himself to construct and
evaluate alternativeplans; and
o most "black box" models, and those interactivemodels as exist, are

designed for regional planning of solid waste management, usually in
developed countries.
In the longer term, computermodels are likely to play an increasingrole

in developingcountries in planning for waste management, including
hazardous wastes, and planning authoritiesmay wish to develop their own
capability in this field.
3.12 Selecting and Implementingthe Preferred Plan (Steps 10 and 11)
In principle, once the alternativeplans have been evaluated,it is

possible for the decision-makersto assess the advantagesand
disadvantagesand to select the preferred plan. However, in practice
another review and feedback exercise similar to that described in Section
3.10 is required.
The implementationof a plan for hazardous waste management does not

simply depend upon the mandate of the authorities. It must be a
cooperativeexercise between the authorities,the waste producers and
those who operate the disposal facilities,possibly also includingthe
general public.
Coordinationand consultationwith all of these interestedparties is

essential for successful implementationof the selected scheme.
A plan for hazardous waste management is not an end in itself, it

- 114 -
representsmerely the first step. It must be implemented,its progress

monitored and it must be regularly reviewed to identify the need for
change. Among the aspects which require particularattention are the
following:
o adequate regulations;
o effective enforcement;
o coordinationwith, and cooperationfrom, waste producers;
o professionalmanagement of facilities;and
o proper training of staff.
3.13 References 3.1 - 3.12
Centaur Associates, Inc. 1979. Siting of Hazardous Waste Management

Facilities and Public Opposition. Prepared for United States
EnvironmentalProtectionAgency. Washington, D.C.
Environment ProtectionAuthority of Victoria. 1985. Draft IndustrialWaste

Strategy for Victoria. Melbourne.
United Kingdom Departmentof the Environment.1976. Waste Management

Paper No.2; 1977. Waste Management Paper No.13; and 1980. Pesticide
Waste Management Paper No.21. London: Her Majesty's StationaryOffice.
United States EnvironmentalProtectionAgency. 1982. Using Compensation

and Incentiveswhen Siting Hazardous Waste ManagementFacilities. A
Handbook. Washington,D.C.
Wilson D.C. 1981. Waste Management - Planning Evaluation, Technologies.

Oxford: Oxford UniversityPress.
Wilson D.C. 1985. Long-term planning for solid waste management. Waste
Management & Research, 3: 203-216.
World Health Organization.(WHO) 1982. Rapid Assessment of Sources of Air,

Water and Land Pollution. Offset PublicationNo. 62. Geneva: WHO.
3.14 Bibliography 3.1 - 3.12
Anderson, Fredick R., et al. 1977. EnvironmentalImprovement through

Economic Incentives.Baltimore:The Johns Hopkins UniversityPress.
Bernstein,Corrine S. 1985. Private funds, public project. Civil

Engineering 55 (9).
Haas, Charles N. 1985. Incentive options for hazardous waste management.

Journal of EnvironmentalSystems 14 (4).
- 115 -
Hufschmidt,Maynard M., et al. 1983. Environment,Natural Systems, and

Development -- An Economic Valuation Guide. Baltimore:The Johns
HopkinsUniversityPress.
Jones, David C. 1984. Municipal Accounting for DevelopingCountries.

CIPFA-World Bank Publication.Washington, D.C.: The World Bank.
Kalbermatten,John M., et al. 1982. Appropriate SanitationAlternatives

- A Technical and EconomicAppraisal. World Bank Studies in Water
Supply and Sanitation1. Baltimore:The Johns Hopkins UniversityPress.
M. M. Dillon, Ltd. 1985. Site SelectionProcess, Phase 4, Selectionof a

Preferred Site. Prepared for Ontario Waste ManagementCorporation.
Toronto.
Monet, M. P. 1985. Financing resource recoveryprojects. World Wastes 28

(6).
Organizationfor Economic Cooperation and Development.1986. The Costs

and Benefits of Hazardous Waste Management. Paris.
Peskin, Henry M., and Eugene P. Seskin (eds). 1985. Cost Benefit Analysis
and Water Pollution Policy. Washington,D.C.: The Urban Institute.
UN Economic Commissionfor Europe-Committeeon Water Problems. 1984.

Principles and Methods of Economic Incentives includingthe Fixing of
Fees and Charges in Water Supply and Waste Water Disposal Systems.Vol.
1. Geneva.
U.S. EnvironmentalProtectionAgency. 1983. Benefit-CostAssessment

Handbook for Water Programs. Vol. 1. Research Triangle Park, North
Carolina: Research Triangle Institute.
U.S. EnvironmentalProtectionAgency. 1984. Financing CapabilitySummary

Foldout - A SimplifiedApproach. Washington,D.C.
Ray, Anadarup. 1975. Cost Benefit Analysis -- Issues and Methodologies.

A World Bank Publication. Baltimore:The Johns Hopkins University
Press.
Shubnell, Lawrence. 1982. Project Structure and Financial Risk Sharing:

Financing the Bresco Project. Maryland: GovernmentFinance
Association,Inc.
Watson, Douglas J., and W. Johnson Gerald. 1985. Privatizationfills the

funding gap. In Public Works. Ridgewood,New Jersey: Public Works
Journal Corporation.
- 116 -
ANNEX 3A - A Typical Wastes GenerationQuestionnairefor Use as Part of a Waste

Disposal Survey
Notes on the Waste GenerationQuestionnaire
This questionnaireis designed for use both in personal interviewsand in a

postal survey. It allows direct entry of the data into a computer for
processing.
The questionnaireis designed to obtain informationon a wide variety of waste

types, primarily those produced by industryand commerce.
The first page comprises general informationon the firm, its products or
services and the number of employees. For computerizationthe firm is given a
unique serial number and assigned to an MLH group (the minimum list heading
which is a subdivisionof the UK standard industrialclassification)and a
local authority area, which allows the informationfrom the survey to be sub-
divided on a geologicalbasis.
Question 1 contains informationon the types of waste produced. Part (A)

distinguishes10 broad waste types while Part (B) sub-dividesindustrialwastes
into some 20 types. Both of these categorizationsare based on those of the UK
Department of the Environment (1976). It will be noted that an additionalsix
waste categoriesare allowed under category (B), in order that the waste
producer can describe this waste in his own words if he is un-sure as to which
category it should come under. These wastes can then be re-classifiedby the
survey team.
Questions 2 to 8 are answered for each type of waste separately. Typically,a

firm might fill in four columns for, say, waste types I, IIIA, and VIII.
Question 2 categorizeseach waste stream by its physical form: solid, semi-

solid or liquid.
Questions 3 asks the producer to categorizehis waste according to its

hazardous properties. The quality of this informationfrom postal returns is
generally poor.
Questions 4 to 7 concern the quantity of waste. Most producers do not measure

or weigh the waste quantities, so the aim of these questions is to enable an
estimate of the volume to be derived from their size and the frequencywith
which they are emptied. In order to manipulate the informationfrom the survey
in tons, the computer program also requires the survey team to assign a typical
waste density to each type of waste.
Question 8 concerns the treatment or disposal arrangementsfor each type of

waste. In the particular area for which this questionnairewas designed, the
predominant disposalmethods are by landfill, operated either by the local
authority or by a private contractor,or by the producer himself. For general
use, other disposal options should be added to the list on the questionnaire.
- 117 -
Question 9 concerns by-productswhich are sold to other companies for recovery,

recycling or reuse. Information is requestedboth on the type of waste and on
the quantities.
Question 10 invites the respondentto provide any informationon likely changes

in the quantities or type of waste to be generated in the future.
- 118 -
WASTE DISPOSAL SURVEY

WASTE ARISING QUESTIONNAIRE
Name of firm
Products / Services
No. of employees
Address
Tel. No./Ext. No.
Name of contact Position
Date
OFFICE USE ONLY
Serial No. Code
MLH Group L.A. Area
Postal survey (Dates of despatch) 1. 2.
Interview (Personal) YIN on by whom
Interview (Telephone) YIN on by
NOTES:
- 119 _
1. Waste type (classification)

Please identify the types of waste produced by your premises by ticking one or
more of the primary categorieslisted below:
a) Category Waste Type

I Household and commercial (inc. waste . . . . . .
from offices, shops, etc.)
II Medical, surgical and veterinarywastes. . . . .. .
III Industrialwaste (see below for details) . . . . . .
IV Mine and quarry waste . . . . . . . . . . . . . . .
V Radioactivewaste ......
VI Farm waste ......
VII Constructionand demolitionwaste . . . . . . . . .
VIII Sewage sludge, gully and cesspit emptyings . . . . .
IX Old cars, vehicles, etc. . . . . . . . . . . . . . .
X Ash (from incinerators),etc... . . . . . . . . . .
If you have ticked category 'III' above, please specify the waste type produced
by ticking one or more of the categorieslisted below:
b) Category Waste Type Examples

A Inorganic acid......... (sulphuracid, etc.)......
B Organic acids c i ds.....
C Alkalis................ (Ammonia,caustic, etc.)..
D Toxic metal compounds.. (Lead, zinc compounds, etc.)
E Non-toxic metal compounds (Iron, etc.).......
F Metals (elemental)..... (Mercury,aluminium)......
G Metal oxidesxides....
H Inorganiccompounds.... (Cyanides,sulphides).....
T Other inorganics....... (Asbestos,slug, silt, etc.)
K Organic compounds...... (PCB's cleaning solvents,
etc.)
L Polymericmaterials.... (Epoxy resin, latex rubber,
etc.)
M Fuel, oil and greases.. (Fats,waxes, kerosene, etc.)
N Fine chemicals and
biocides............. (Pesticides,cosmetics,
drugs, etc.)
P Misc. chemicalswastesastes...
Q Filter materials, treatment .........
sludge and contaminatedrubbish
R Interceptorwaste, tars. (From pits and traps, etc.)
S Miscellaneouswaste..... (Soaps,paper, glass, etc.)
T Animal and food waste... (Slaughterand processing
waste, etc.)
Please describe any industrialwastes not falling within the above waste types.
U
V
w
x
y
z
- 120 -
Please respond to the following questions for each waste category (and sub-
category for industrialwaste) ticked in question one (1). Should further
space be needed, please photocopy relevantpages.
Waste category
2. (a) What is the nature of the waste?
o solid
o semilsolid
o liquid
(b) Do you have any informationon the chemical compositionof the waste
(yes/no)?
If yes, please attach details on a separate sheet.
3. In your experience, is the waste:
o flammable
o toxic
o corrosive
o odorous
o non-hazardous
4. Please state the numbers of units of each of the following types used for
temporarywaste storage:
o dustbin/sack
o bulk bin
o skip
o tank
o drum
o other (specify)
5. What is the size of each of the units described in (4) above?
o dustbin/
sack
o bulk bin
o skip
o tank
o drum
o other
(specify)
NB. Please give approx. sizes in litres or m3 (cubic metres).

For example standard dustbin = 70 litres, a standardpaladin (industrial
dustbin) = 950 litres (0.95m3)
- 121 -
6. How often are the units emptied per week?
o dustbin/
sack
o bulk bin
o skip
o tank
o drum
o other
(specify)
7. What is the weekly waste total calculated from 4-6 above (m3 )?
8. What are your current disposal arrangementsfor each waste category?
o Local
authority
o Contractor
(name)
o Self (specify:
e.g. burn, bury
or transport
else-where)
o Other (specify)
9. Does your company produce any 'waste'by-productswhich are sold to other

companies (i.e., scrap, metal, plastics, paper, oil, solvents, tires)?
If yes, please specify:
10. Are there likely to be any changes in the facilitiesoperated by your

company which are likely to increase or decrease the volumes of waste
generated (i.e., due to an expansion or retractionprogramme)or alter the
type of waste generated (due to a process change) in the foreseeable
future?
If yes, please specify:
Thank you for your cooperation.

Please return the above forms in the SAE provided at your earliest
convenience.
Please do not hesitate to telephone for additional informationor
assistanceto complete the above.
Source: EnvironmentalResources Limited (ERL). 1987.

- 122 -
ANNEX 3B - The Siting of a HazardousWaste Management Facility in the Province

of Ontario, Canada - A Case Study
Introduction
This case study describes the siting of a hazardouswaste management facility

undertakenby the Ontario Waste Management Corporation (OWMC). Ontario Waste
Management Corporation is a ProvincialCrown Corporation in Toronto which was
set up by the Ontario Government. The prime responsibilityof OWMC is to
establish and operate a hazardouswaste management system for Ontario by
properly treating and disposing of all hazardouswastes generated in Ontario
that require special treatment and disposal.
As part of this mandate OWMC has undertakena facilitiesdevelopmentprocess of

which site selection forms a major component. A preferred site was selected
after exhaustiveevaluationof possible options, and at the time of writing is
undergoingmore detailed evaluationto confirm its suitability. The summarized
description of the siting process providedhere is abstracted largely from
reports prepared by OWMC (1983 a,b; 1984; and 1985).
This case study is presented as an example of how siting a hazardous waste

management facilitywas undertaken in a particular situation. It is intended
to demonstrate the principles that should be followed in the siting process
rather than prescribe a detailed set of steps that must be taken in every case.
This case may involve a more detailed and lengthy process than is appropriate
in all situations. These considerationsshould be borne in mind when using the
case study as a model for siting of facilitiesin developingcountries.
Facilities DevelopmentProcess
To understand the selection study, it is important to know something about the

overall FacilitiesDevelopmentProcess within which site selection is
incorporated.
The FacilitiesDevelopment Process was designed to move OWMC through the

process of selecting a site hearing and approval processes required prior to
construction. The process consists of five phases as shown in Figure 3B-1.
Phase 1 was completed in September,1982. It defined the nature and size of

the industrialwaste problem in Ontario, as well as the principles, goals and
objectivesof the program. Phase I also outlined possible treatment
technologies,described the hydrogeologicconditionsthroughout Southern
Ontario (i.e., the underground rock and soil conditionsand how they affect
undergroundwater movement) and identifiedthe engineering,planning and
environmentalissues that should be consideredin later phases. Preferred
hydrogeologic conditions -- specifically, thick, uniform clay-textured soils --
were considered an important site requirementto provide natural containment
and thereby avoid total reliance on engineeredsafety features to contain
potentially toxic waste residues.
Phase 2 was completed in January, 1983. It resulted in the search for sites
being narrowed to the Golden Horseshoe region of Southern Ontario where
approximately70Z of Ontario's specialwaste is generated and where the risks
- 123 -
FIGURE 3B-1
FacilitiesDevelopment Process
JAN. SEPT. JAN. MAY MARCH SEPT.

1982 1982 1983 1983 1984 1985
PHASE: 1 2 A3 B A 4 B 5
INFORMATION CHOOSE CHOOSE CHOOSE: SITE PUBLIC
GATHERING CANDIDATE CANDIDATE . PREFERRED I SPECIFIC HEARINGS
REGION& i SITE(S) I STUDIES
& UNDER
GENERIC I .TECHNOLOGIES DESIGNS ENVIRONMENTAL
TECHNOLOGIESAREAS I STES CONCEPTUALI ASSESSMENT
i DESIGNS I ACT
Source:
OntarIoWasteManagement
Corporation.
1985.Facilities
Development
Process.
Phase
4AReport.
- 124 -
and costs associatedwith transportingthese wastes are minimized. In

addition, in Phase 2 it was determinedtreatment and disposal facilitiesshould
consist of three major components:
o high temperaturethermal destruction;
o physical/chemicaltreatmentprocesses, including solidification;and
o engineered landfill,
and that only one installationof each major component should be constructed.
In Phase 3, OWMC identified20 candidate areas within the Golden Horseshoe

which were selected on the basis of environmental,transportation,airshed, and
agriculturalland use considerations.
Within these areas, OWMC then identified152 potential sites by applying a

series of 40 factors encompassinga range of physical, social, resource,
biological, land use, transportationand agriculturalconsiderations. By
introducingmore detailed informationon these factors, these potential sites
were then reduced to eight candidate sites.
Finally in Phase 4A, a preferred site was identifiedand the conceptual design
of the facility developed. A perspective drawing of the proposed facility is
shown in Figure 3B-2.
Within this FacilitiesDevelopment Process, the site selection study was

undertaken in five steps. The steps in the site selection study and their
relationshipto the overall FacilitiesDevelopmentProcess can be summarizedas
follows:
o Step 1 (Phase 2): Narrowing the Search to a Single GeographicRegion in

Ontario.
o Step 2 (Phase 3): IdentifyingCandidateAreas within this Region.
O Step 3 (Phase 3): IdentifyingCandidate Sites within Candidate Areas
o Step 4 (Phase 4A): Comparisonof Candidate Sites and Identificationof a

Preferred Site(s).
o Step 5 (Phase 4B): Detailed Testing of Preferred Sites.
This step-by-stepapproach to site selection is illustrated schematicallyin

Figure 3B-3. The principles, goals and objectivesdeveloped for site selection
and each of the five steps themselvesare outlined in the following sections.
Principlesand Goals of Site Selection
General Principles
The following general principleswere identifiedin shaping the search process

for sites:
- 125 -
FIGURE 3B-2
Perspectiveof Proposed Facility: Two Possible ConceptualArrangements
VaughanRd.E, (Thisarrangement used for site selection purposes.)
to
North
Vaughan~ rO Rd.E 0Highway 20-

Vaughan Rd- E
r t h ~~~to
HighwA 20 ;;,7!w
LEGEND 6. Physical/Chemical Treatment, N SCHRAM

1.Gate Houseand WeighScales Solidificationand TankStorage FACILTY RD
2.AdministrationOfficesand 7.IncineratorTankFarm \ _
Laboratory 8.Waterand EffluentPonds
3.UnloadingBays 9.SubStation/EmergencyPower IAUGHAN
4.DrumStorageand Handling 10.Maintenanceand Workshops RD.E.
5.Incinerator 11.TruckWash IP G
HEASLP GEE
RD. RD.
Source:OntarioWasteManagement Corporation.1985. FacilitiesDevelopmentProcessPhase4A Report,

- 126 -
FIGURE 3B-3
A Step-by-StepApproach to Site Selection
Candidate
Sites Preferred
Candidate Sites
Geographic Areas
Region L
(GoldenHorseshoe)
Southern
iOn-the-Land Pb
Stepnvestigation HeaL S
StepI Step2 Step3 Step4 Step5

- 127 -
o Progressive refinementof the search process: The process must move

through a series of steps, which involve the evaluationof alternatives
and the narrowing of geographicfocus.
o Definition of the environment: The very broad and inclusive definition of

the environmentused in the Ontario EnvironmentalAssessmentAct (1975)
was adopted by OWMC. The environmentalimpact assessmentprocess embodied
in this Act also was adopted by OWMC.
o Protection of human health and the environment: The primary consideration

must be protectinghuman health and the environment.
o The involvementof those who might be affected: Agencies, organizations

and people who might be affectedmust be consulted at key decisionpoints
in the process (i.e., site selectionmust include a thorough consultation
process).
o Efficiency and effectivenessof the process: The costs and time involved
in conductinga detailed analysis and evaluationof every conceivablesite
across the entire province were consideredprohibitive. The search and
selection process must focus available resources systematicallyon
critical concerns and reach definite conclusionsas quickly as possible.
Goals and Objectives
Based on these principles, three site selection goals were adopted by OWMC, in
the following order of importance.
o Minimize risk to human health.
o Minimize environmentalimpacts.
o Minimize financial costs to OWMC.
Although this ranking was assigned to reflect the general prioritiesof OWMC
and the public, it was also recognizedthat there would be instanceswhere
these goals overlap in significance. For example, there may be instanceswhere
relativelyminor risk-relatedconcerns are overriddenby major environmental
impacts. Similarly,a major cost considerationmight override a minor health
risk or environmentalimpact consideration.
In addition to these three goals, specificobjectiveswere also formulated.

The objectives represent a refinementand elaborationof the goals. In the
case of the goal of minimizing environmentalimpacts, for example, the
objectives specify different elements of the environmentto be protected.
The goals and objectiveswere applied to the entire site selectionprocess.
For each step in the process specificfactors were identifiedpertainingto the
areas of concern being addressed in that step. A large number of objectives
were developed to assist in shaping and directing the site selectionprocess.
These objectives are listed in Table 3B-1.
- 128 -
TABLE 3B-1
Site Selection Objectives
I. Goal
o To minimize risk to human health.
Obiectives
(A) Site - 'Pathways'into the Environment
(1) To site facility componentsin hydrogeologicsettings that will restrict

naturally the movement of contaminantsand protect ground water resources,
and to utilize engineeringmeasures where required to ensure maximum
environmentalsafety.
(2) To site facility componentsin hydrogeologicsettings that will restrict

naturally the movement of contaminantsand protect human health, surface
water resources and aquatic ecosystems.
(3) To site facility componentsin airsheds that have atmosphericdispersion

characteristicswhich will protect air quality and aquatic and terrestrial
ecosystems.
(4) To site facility componentsin settings that minimize the hazards to the
site as a result of such conditionsas flooding, potential susceptibility
to seismic disturbance,and slope failures, and to utilize engineering
measures where required to ensure maximum environmentalsafety.
(5) To site facility componentsin settings that facilitateenvironmental

monitoring as well as the applicationof countermeasures,including back
up emergency services.
(6) To site facility componentsto minimize potential contaminationof food

chains in the environment.
(7) To site facility componentsto minimize hazards to the site from other
uses which might contributeto the likelihoodor severity of a release of
contaminants.
(8) To locate effluent discharge locations (if required)with dispersion

characteristicsthat will protect human health, surface water resources
and aquatic ecosystems.
(B) Site - Human Exposure
(1) To site facility componentsto minimize the number of people who might be
exposed, as well as the durationof their exposure, to contaminantsin the
event of a release.
- 129 -
TABLE 3B-1 (continued)
(2) To site facility componentsto minimize the potential for the

contaminationof existing wells and other sources of water for human or
animal consumption.
(3) To site facilitycomponents to minimize the potential for exposure of

populationswhich are sensitive to exposure and/or are difficult to
evacuate.
(C) Transportationand Discharge - 'Pathways,into the Environment
(1) To select transportationroutes and modes which minimize the likelihoodof

a release of contaminantsduring transit.
(2) To site facility componentsto that the physical settings along the access
routes to the site(s) naturally restrict the movement of contaminantsand
protect human health, terrestrialand aquatic ecosystems.
(D) Transportationand Discharge - Human Exposure
(1) To site facility componentsto minimize the number of people who might be
exposed and the duration of that exposure to contaminantsalong access
routes to the site(s) -inthe event of a release.
(2) To site facility componentsto minimize the potential for exposure of

populationswho are sensitiveto exposure and/or difficult to evacuate
along access routes to the site(s).
II. Goals
o To minimize environmentalimpacts.
Obiectives
(A) Physical and Biological
(1) To avoid destructionand minimize disruptionof significantnatural

ecosystems.
(2) To avoid destruction and minimize disruption of significantvegetation or

wildlife populations.
(3) To avoid destructionand minimize disruptionof rare or uncommon species

of plant and animal life.
(4) To avoid destructionand minimize disruptionto significantlandforms and

other physical features.
(5) To minimize physical impacts on surface water such as sedimentationand

changes in base flow.
- 130 -
(6) To minimize impacts on surface water quality from emissions.
(B) Resources
(1) To minimize the amount of land required to safely construct and operate
the facility component(s).
(2) To minimize displacementof prime agriculturalsoils.
(3) To minimize displacementand disruptionof existing farm enteprises.
(4) To minimize disruption to productive agriculturalareas and to stable

agriculturalcommunities.
(5) To minimize displacementand disruptionto other natural resources uses

such as mineral aggregates.
(6) To minimize disruption of economicallyand/or recreationallyimportant

biological resources.
(7) To minimize displacementof and disruptionto heritage and archaelogical

resources.
(8) To minimize displacementof areas with a potential for resource

development.
(C) Land Uses and Land Ownership
(1) To minimize conflictwith existing,committed,proposed and planned land

uses.
(2) To minimize the potential for the establishmentof the facility components
in locations characterizedby similar industrialuses.
(3) To minimize the amount of private property required and the disruptionto
land ownership patterns.
(4) To minimize conflictwith Federal, Provincial,municipal and native

communities,policies, programmesand plans.
(D) Social
(1) To minimize the displacementof people, particularlythose groups and

individualsvulnerable to change.
(2) To minimize conflict between the facilitycomponents, operationsand the

use and enjoyment of properties in the vicinity of the site(s), as a
result of visual intrusion,noise, etc.
- 131 -
(3) To minimize losses or impacts on buildings and features of archaeological,

historical, symbolic, cultural or social significance.
(4) To maximize compatibilitybetween the facilitycomponents and the

character, image, traditionsand lifestyleof the affected area.
(5) To establish the facility components,to the extent possible, in areas in

which the local communities can adapt to the type of changes which might
result from the project.
(6) To maximize community acceptanceof the facility components.
(7) To maximize compatibilitywith the visual character and appearanceof the

landscape in the vicinity of the facility components.
(8) To minimize conflict between the transportationof hazardouswastes to the

facility components and the use and enjoyment of propertiesalong access
routes to the site(s).
(9) To minimize conflictbetween facility-relatedtraffic and local traffic by

ensuring that access routes provide an acceptable level of service.
(E) Economics
(1) To maximize local employmentopportunities.
(2) To minimize the displacementof businesses.
(3) To minimize property value depreciation.
(4) To minimize disruption to the operationsof local businesses.
(5) To maximize compatibilitywith the local and regional economic character

of the affected area.
(6) To minimize adverse effects upon the provision and use of public and
private community services and facilities.
(7) To minimize the burden on municipal services and finance.
III. Goal
To minimize financial costs to OWMC.
Objectives
(A) To minimize capital and operating costs to the greatest extent possible
without sacrificingenvironmentalquality.
(1) To minimize approvals costs.

- 132 -
(2) To minimize site acquisitioncosts.
(3) To minimize on-site developmentcosts (e.g., clearing, drainage, grading,

screening and other engineeringmodifications).
(4) To minimize off-site development (e.g., service extensions,road

improvements).
(5) To minimize development and/or operationscosts associatedwith the

constructionand operations of the facility component(s),e.g. (duplicate
facility).
(6) To minimize developmentand/or operationscosts necessitatedby site or

area characteristics(e.g., special remedial or monitoringmeasures to
protect human health and the environment).
(7) To minimize on and off-site development and/or operationscosts associated

with effluent dispersion (e.g., pipelines).
(8) To minimize transportationoperationscosts associatedwith hauling

hazardous wastes to and among facilitycomponents.
- 133 -
No one site can satisfy all the site selectionobjectives. With any given site
or area under consideration,some objectiveswill be largely satisfied. Other
objectiveswill not be satisfiedor will only be partially satisfied. Thus, in
the process of identifyingand comparing potential sites, considerationwas
given to differences in the levels of satisfactionof various objectives. For
example, trade-offsmay have to be made between a facility location in an area
of potential environmentalsignificanceversus a locationon good agricultural
land. The considerationof such "trade-offs"was crucial to decisions
concerning the acceptabilityof the risks, impacts and costs associatedwith
the preferred site(s).
Establishingthe inventory of hazardouswastes was another important element of

the informationgathering exercise in Phase 1, but this is not describedhere.
However, it was established that 30,000 tons per year of organic waste and
120,000 tons per year of inorganicwaste were being generated in the region.
Step 1 - Narrowing the Search to a Single Geographic Region in Ontario
In selecting a single geographicregion in Ontario as the area for further

study, considerationwas given principally to two factors:
o geological and hydrogeologicalconditionslikely to offer higher

probability of locating suitable sites, particularlywith regard to
landfilling;and
o proximity to the principal areas of hazardouswaste generationin the

Province.
Based on these considerationsa number of zones of land within the geographic

region of the Golden Horseshoe,an area at the west end of Lake Ontario where
approximately70Z of Ontario's specialwaste is generated,were selected for
further consideration. These zones were consideredgenerally to have more
suitable geological and hydrogeologicalconditionsfor the natural containment
of hazardous wastes. By focusing on these zones, a second natural level of
protection beyond that provided by the engineereddesign of the facilities
would be built into the search and selectionprocedure.
Step - 2 Identifying CandidateAreas Within this Region
Siting Factors
In Step 2 of the siting process, considerationwas given to siting factors for

the individualcomponentsof the facilitiesas well as for the facilitiesas a
whole (i.e., the option of having the facilitiessplit between two locations
was introduced). Siting factors were developed based on environmental,
transportationand land use considerationsand the following guiding
principles:
o Protection of the environment. A second natural level of protectionof

the environment beyond that provided for by the design and operating
procedures of the facility is essential.
- 134 -
o Likelihood of suitability. Because the factors addressed at this stage

are at a broad regional scale, the suitabilityof a selected candidate
area can be expressed at this stage only as a likelihoodor probability of
suitability,subject to later more detailed investigations.
o The maintenance of choice. As decisions on exclusion are made, there must

be the assurance at each step of the process that no significantor unique
alternativesare being discarded.
Using this approach, 19 candidate areas were identifiedwithin the Golden

Horseshoe and, following further analysis, a twentieth candidate area was
subsequentlyidentified.
Estimation of Site Size
Concurrentwith Step 2 of the siting process, a number of refinementswere made

to the facility design and operationsconcepts. Of particular relevance to
siting were the issues of buffer zones and facility arrangementoptions, and
their influence on site size.
(A) Buffer Zones
The size of any buffer zone will depend on the characteristicsof the site and
its surroundingarea. OWMC's general approachwas to consider sites that
provided adequate space beyond the operating area of the treatment facilities.
This extra space was necessary to monitor for any accidentalreleases of
contaminantsand to provide a zone where appropriatecontainmentaction would
be possible if there were an accidentalrelease. This area of space around the
operating area is called the technical buffer zone.
Preliminaryplanning estimates suggested a minimum technical buffer zone of 400

m around treatment facilities,except in heavy industrialareas where the need
might be less. This buffer zone was included in the estimated site size to
minimize impacts on sensitiveuses and features that might exist in close
proximity to the facility.
(B) FacilityArrangement Options
The second issue that affected site size was how the three major waste
treatment and disposal componentscould be grouped for siting purposes. The
three facilities can be arranged in five variations:
Dispersed
1. separate incinerator
separate physical/chemicalplant
separate landfill
Partially Integrated
2. incinerator with separate landfill

and
a physical/chemicalplant
- 135 -
3. physical/chemicalplant with separate incinerator

and landfill
4. incinerator
and with separate
landfill physical/chemicalplant
Fully Integrated
5. incineratorand
physical/chemicalplant all at one location
and landfill
Of these five major facilityarrangementoptions two were preferred by OWMC:

Option 5, the fully integratedfacility on a single site; and Option 2, the
incineratorand physical/chemicalfacilitieson one site with the landfill on a
second site. These two facility arrangementswere found to minimize both
transportationcosts, risks and environmentalimpacts as well as capital and
operationalcosts.
(C) Site Sizes
Based on an initial capacity of 150,000 tons/year of hazardous waste, waste

quantity informationindicated that about 30,000 tons would be organic waste
and 120,000 tons inorganicwaste. The physical/chemicaltreatment plant would
be sized to process 50,000 tons/year of inorganicwaste on a one-shift-per-day
basis. Additional shifts would permit the plant to treat up to 120,000
tons/year of inorganicwaste. The incinerationplant would comprise one rotary
kiln system sized to process 30,000 tons/year of organic waste on a three-
shift-per-daybasis.
Designing treatment facilitiesof this capacity, and a standardengineered

landfill capable of receiving the treated residues from the incinerationand
physical/chemicaltreatment processes for two to three decades,was estimated
to require the followingminimum site sizes includinga technical buffer zone:
o for an incineratorand a physical/chemicaltreatment plant located

together: 80 hectares (200 acres);
o for an engineered landfill located separately:110 hectares (275 acres);
o for all three components located on one site (a physical/chemical

treatment plant, an incineratorand an engineered landfill):190 hectares
(475 acres).
These estimateswere used in the next step of the site selectionprocess:

identifyingcandidate sites within candidate areas.
Step 3 - IdentifyingCandidates Sites Within Candidate Areas
Step 3 in the selectionprocess was itself subdividedinto three basic

narrowing stages, described below.
- 136 -
(A) The Identificationof Site Areas: ConstraintMapping
In the first stage, smaller areas, called site areas, were identifiedwith the
larger candidate areas. To identify these site areas, data were first
collectedwithin the candidate areas on a long list of factors. Certain
factors were then identifiedas "exclusionary"(i.e., factors which should rule
out certain areas from further considerationat this time). The exclusionary
factors are shown in Table 3B-2. These exclusionaryfactors were then mapped
and certain areas excluded, and site areas free of those factors were
identified. This technique,called constraintmapping, resulted in the
identificationof a large number of potentially suitable site areas (i.e., 152)
for examination in greater detail.
(B) The Identificationof Potential Sites: Site Screening
The second stage reduced the site areas in number and size to potential sites.
It involved the collection of detailed data on each site area and the
applicationof certain 'screening"factors.
During the screening process, site areas were either dropped from further
considerationor reduced in size. The screening factors addressed the
following questions:
(i) Are there areas which are too small or unsuitably shaped to accommodatethe
size of facility required? (Site Size and ConfigurationScreen).
(ii) Are there areas which are crossed by major services? (SuitabilityScreen
- Linear Facilities).
(iii) Are there areas which are less suitablebecause they contain a very
sensitive environmentalarea? (SignificantEnvironmentalUnits [SEUs] as
identifiedby provincial and/or municipal agencies).
(iv) Are there areas which are unsuitablebecause they would result in severe
environmentalor social impacts? (SuitabilityScreen - Severe Impacts).
(v) Are there areas which have a number of constraints and no relative
advantagesover the site areas which could be retained? (SuitabilityScreen -
Relative Suitability).
(vi) Are there areas for combined physical/chemicaltreatment plant and

incinerator in particular that would mitigate potential impacts on agriculture
and/or in industriallydesignatedareas? (CompatibilityScreen).
(vii) Are there site areas for a combined incineratorand physical/chemical

treatment plant which should be eliminatedbecause they are too far from
selected landfills? (System Screen).
This stage in the process resulted in the identificationof 16 potential sites:

10 landfill sites and six sites for a combined physical/chemicaltreatment
plant and incinerator.Of the 10 landfill sites, two were considered as
landfills only and eight were consideredsuitable as either landfills or as
fully integrated sites.
- 137 -
TABLE 3B-2
ExclusionaryFactors for ConstraintMapping
Physical Resources
o Surface granular soils

o Significant stream courses
o Flood plain areas
o Wetlands
o Drumlins
o Morainal features
Land Use
o Indian Reserves
o Residentialbuilt-on
o Residential,designatedand serviced
o Commercial,designated and built-on
o Commercial, designatedand vacant
o Existing rural residential
Recreation and Community Facilities
o Hospitals,homes for the aged, nursing homes

o Colleges and universities
o Special education facilities
o Police HQ
o Theme parks
o Regional shopping centres
o Correctionalfacilities
o Institutionsfor the handicapped
Transportation
o Airports
Agriculture
o Existing specialtycrops
o High grade agriculturalcapability (typicallyClass 1 to 3)
Note: In practice, exclusion criteriawere modified by further factors

including public ownership, industrialzoning, effects of "urban shadow" and
short haulage distance.
- 138 -
(C) From Potential Sites to a Short List of Candidate Sites: Initial

Comparative Evaluation
The third stage in the review of candidate areas was an initial comparative
evaluationof the 16 potential sites, using the factors identified in Table
3B-3. The factors encompass a range of physical, social, resource, biological,
land use, transportationand cost considerationsfor each potential site, the
area around each site and the access roads to the sites.
The comparative analysis of the potential sites addressed the followingthree

questions:
(i) Did the additional investigationsidentifymajor constraints sufficientto

remove some potential sites from further considerationat this time?
(ii) In comparing the differencesamong the potential sites, were there sites
that were relativelyless suitablewhich could be dropped from further
considerationat this time without seriously limitingthe diversity of siting
choices for Phase 4?
(iii) Were there sites which possessedmajor disadvantageswith respect to the

top-rankedgoal (i.e., minimizing risk to human health) such that the site
could not be expected eventuallyto be the preferred site?
This analysis led to a reduction in the number of potential sites to eight

candidate sites.
Step 4 - Comparison of Candidate Sites and Identificationof a Preferred Site
Step 4, the process of evaluatingeach of the siting options was undertaken in

three stages:
o the collection of more detailed data for each site and the developmentof
more detailed factors for site comparison;
o the evaluation of the basic acceptabilityof the sites in the light of the
more detailed data available;and
o the detailed comparativeevaluationof the remaining siting options.
Each of these stages is described in the following.
Data Collection and Factor Identification
The first stage of the detailed comparativeevaluation of siting options was

the collection and compilationof detailed data both on and in the vicinity of
each of the eight candidate sites on the subjectsof hydrogeology,
transportation,agriculture,biology, surfacewater, archaeology,land use,
social and economic factors, air quality and dispersioncharacteristics,and
costs. Informationwas obtained from a number of printed sources, as well as
from interviewswith area residents,farmers, businesses,municipalitiesand
provincial agencies, and from field investigationsand site testing, including
- 139 -
TABLE 3B-3
Initial ComparativeEvaluationFactors
(A) Site
(1) Human Environment
o Existing residences
o Existing resources (agricultural,historical, archaeological,
groundwater)
o Existing community and recreationalfacilities (public,private)
o Existing commercialand industrialuses
o Future residents
o Future resources
o Future commercial and industrialuses
(2) Physical and BiologicalEnvironment (site and site vicinity)
o Hydrogeology
o Biology
o Atmospheric dispersion
(3) Costs/Operations
o Land acquisition
o Site improvements
o Utilities, roads, airports
o Site size and configuration
(B) Site Vicinity
o Existing residences
o Existing resources
o Existing community and recreationalfacilities
o Existing community character and lifestyle
o Future residents
o Future resources
o Existing commercialand industrialuses
o Future commercialand industrialuses
o Proximity to sewage treatment plants/receivingbodies

o Proximity to rail access
- 140 -
(C) Access Road - Local
o transportationsafety
o existing residents
o existing resources
o existing community and recreationalfacilities
o future residents
o future resources
o existing commercialand industrialuses
o future commercial and industrialuses
(2) Physical and Biological Environment
o hydrogeology
o stream crossings
(D) Access Road - Regional
o transportationsafety
o existing residents
o existing resources
(2) Physical and BiologicalEnvironment
o hydrogeology
o stream crossings
o tonne kilometers of waste and solidificationadditives hauled

- 141 -
a deep bore hole drillingprogram. OWMC then establisheda preliminary list of

the factors to be used in evaluatingthe differencesand similaritiesamong the
eight candidate sites. These factors were measures of the potential risks,
impacts and costs of a waste management facility on each site.
The "risk" factors pertain to the potential effects on human health resulting
from the operation of OWMC's proposed facilities. They encompass four
potential means for exposure to toxic chemicals: transportation,air, surface
water and groundwater. Risks to human health will be minimized through the use
of the best proven technology,design, operationsand monitoring procedures.
The choice of a site can also reduce even further the very low levels of risk
anticipated.
The "impactffactors pertain to the potential non-health effects on residents,

agriculture,business, community facilitiesand services, land use, the natural
environment and broader social and economic concerns.
Within each factor, a series of indicatorswas establishedto identify,

measure, describe and predict these risks, impacts and costs. For example,
within the risk factor grouping of hydrogeologicsuitability (groundwater),one
of the factors selectedwas capabilityof providing natural containment,for
which the indicatorswere predictabilityof geologic condition and contaminant
breakthroughline. Similarly,within impact grouping of agricultural
resources,one of the factors selectedwas loss of farmland for which the
indicatorswere soil capability and the drainage. The final list of factors
and indicatorswas established after a series of meetings with government
agencies and public working groups. The public working groups were asked to
review and comment on the comprehensivenessof the factors and indicator s.
The final list of the factors establishedduring Step 4 is provided in Table
3B-3.
The Basic AcceptabilityAnalysis
In the second stage of the comparativeevaluation,each of the eight sites was

assessed in light of the new data which had been collected during Step 4 to
determine if there were any major constraintsthat would result automatically
in the rejection of a site. This was called the basic acceptabilityanalysis
and all OWMC's site selection consultantswere asked to considerwhether or not
a basic acceptabilitycriterion existed for their discipline. In some
disciplines,such as social impact analysis, no clear criterion of this kind
could be established. For others, it was possible to establish such a
criterion.
The site selection team concluded that if the hydrogeologicanalysis of a

candidate site revealed a strong likelihoodof failure to provide natural
containment,that site should be eliminated immediatelyfrom further
consideration. This approachwas consideredpreferable to continuingthe
analysis of a site that did not appear to meet basic acceptability. As a
result of the analysis by the hydrogeologicand engineeringconsultants,two
sites were dropped from consideration,leaving six siting options for further
investigation.
- 142 -
The Detailed ComparativeEvaluationof the Six Siting Options
The comparative evaluationof the remaining siting options began by ranking the
risk and impact factors in order of importanceTable 3B-4. This was followed
by comparing each siting option with other siting options (i.e., a paired
comparison).
(A) The Ranking of Factors
Some of the Phase 4A factors were consideredto be more important than others
in helping OWMC to determine the safety and suitabilityof the siting options.
In ranking "risk" factors, OTWMCconsideredthe potential severity of risk, the

probable frequency of its occurrence,and the possibility of mitigating or
reducing the potential risk. In ranking the "impact" factors,OWMC considered
the likelihoodof an impact occurring,the possible severity of that impact,
the significanceof the impact, the frequencyand duration of a potential
impact, its relationshipto other factors,uncertaintyof impact precondition,
and the possibility of mitigating or reducingthe impacts. "Cost" factors were
establishedby totalling the estimated costs for each siting option and ranking
the siting options according to them.
A preliminary ranking of factors was published in June, 1985 and comment was
subsequentlysought from the public at site selectionworkshops in July. Using
the comments received at these workshops, OWMC refined and finalized the
ranking of its factors. The final list of factors and their ranking appears in
Appendix 2 to the OWMC Phase 4A report (OWMC 1985).
(B) Comparison of the Siting Options
The six remaining siting options were then compared on a factor-by-factorbasis

to identify the major differences or trade-offsbetween them. By reviewing
these trade-offs, it became apparent that each of the options had its own set
of strengths and weaknesses.
For example, in examining transportation,a siting option near the town of

Milton (LF-4N/Pl-lN)was favored over a siting option near the town of West
Lincoln (LF-9C),mainly because the former was closer to where the majority of
Ontario's special wastes are generated and to the major 400 series highways.
But in examining hydrogeology,the West Lincoln siting option was favored over
the Milton siting option, mainly because LF-9C has deeper and more uniform
clay-texturedsoils offering a greater measure of natural containment. The
resulting trade-off between transportationand hydrogeology,which were both
ranked high as risk factors,was one of several trade-offswhich were
identifiedas the siting options were compared.
Based on this comparisonof the siting options, two sites were agreed by all of
OWMC's site selection consultants to be and the other a separate landfill and
physical/chemicaltreatment-incinerator combination. The essential differences
between the two options could be summarizedin terms of lower risks for the
integratedoption, in particulargreater natural containment and greater
certainty of geologicalconditions,versus lower impacts for the separate
facilitiesoption.
- 143 -
TABLE 3B-4
Detailed ComparativeEvaluationFactors
Factor Grouping Factors
(A) Risk
Transportation o Annual province-widehazard-basedspill index

of OWMC generated transport
o Annual province-wideaccident involvementsof
OWMC generated transport
o Transportationrisks on local and regional
access roads due to accident involvementsof
o Transportationrisks on local and regional
access roads due to hazard-based spills of
Air Quality o Risk from direct inhalationof emissions -

chronic
o Risk from direct inhalationof emissions -
acute
o Risks from ingestion of cistern and pond water
o Risks from consumptionof crops and livestock
Hydrogeologic o Capabilityof providing natural

Suitability containment
o Ground water use
Surface Water o Susceptibilityof site to flooding

Suitability o Potential for water use interference
Study Area: Site
(B) EnvironmentalImpacts
Residents o Displacementof residents
Businesses o Displacementof businesses
Community and o Displacementof historical,

RecreationFeatures community and recreationfeatures
o Archaeologicalresources
Land Use o Existing land use

o Proposed and planned land uses
o Land use stability
- 144 -
AgriculturalResources o Displacementof farms with on-site

headquarters
o Loss of farmland
Natural Environment o Rare species

o Natural vegetation displaced
o Potential for occurence of other significant
features
Site Area: Site Vicinity
Residents o Economic stabilityof residents

o Disruptionof use and enjoyment of property
and/or day-to-dayactivities (adjacentto
site)
Businesses o Business activitiesnegatively affected by the

presence of OWMC facilities
o Business activitiespositivelyaffected by the
presence of OWMC facilities
Community and o Disruption of operationsof community and

RecreationFeatures recreationfeatures (adjacentto site)
o Disruption of operationsof community and
recreationfeatures (site vicinity)

o Proposed and planned land use
o Land use stability
o Provincialpolicies and plans
AgriculturalResources o Partial displacementof farms (off-sitefarms

with on-site land)
o Disruptionof adjacent farm operations
o Disruptionof non-adjacentvicinity farm
operations
Natural Environment o SignificantEnvironmentalUnits (SEUs)

o Fish and wildlife features of significance
o Other natural vegetation
o Rare species
Air Dispersion/Air o Restraints to dispersion

Quality o Existing and anticipatedair quality
Site Vicinity: Community and Regional

_ 145 -
Community and Regional o Municipal finance and services

o Social stability
o Social cohesion
o Community character
o Regional and community economic base
o Tourism economy
o Tourism operations

o Proposed and planned land use
o Provincialpolicies and plans
AgriculturalResources o Stabilityof farm population

o Stability of agriculturalland base
o Disruption to the farm economy
Site Area: Access Roads
Residents o Disruptionof day-to-dayactivities and/or the

use and enjoyment of property (adjacent)
o Disruptionof day-to-dayactivities and/or the
use and enjoyment of property (vicinity)
Community and o Disruptionof operationsof community and

RecreationFeatures recreationfeatures (adjacent)
o Disruptionof operations of community and
recreationfeatures (vicinity)
Land Use o Existing land uses

o Planned and proposed land uses
AgriculturalResources o Disruptionto farm traffic and cattle

crossings
o Disruption to crop livestock production
Natural Environment o Fish communities
(C) Engineering Cost
Cost o Capital cost ($000)

o Operating cost ($000)
Site Area for o Site area

FacilitiesPlacement
- 146 -
Since protection of human health (as distinct from non-health related impacts
on the environment)was the highest priority goal of OWMC's site selection
process, the preferred site was the integratedsiting option.
ReferencesAnnex 3B
Ontario Waste Management Corporation (OWMC). 1983a. Facilities Development

Process. Process Phase 2 Report.
Ontario Waste Management Corporation. 1983b. FacilitiesDevelopment Process.

Process Phase 3 Interim Report.
Ontario Waste Management Corporation. 1984. FacilitiesDevelopment Process.

Phase 4A Report.
Ontario Waste Management Corporation. 1985. FacilitiesDevelopment Process.

Phase 4A Report.
Note: For a more recent report, see OWMC. 1988. EnvironmentalAssessment:

For a Waste Management System. Toronto, Canada.
_ 147 -
ANNEX 3C - Development of Methodologiesfor IndustrialHazardousWaste

Inventories - Experiencein Mexico and Italy
Written by Giancarlo Olivetti, Dagh Watson Spa, Italy and Richard
Barnard, Ashact, UK.
Introduction
The preparation of an initial industrialhazardouswaste inventory is not a

difficult exercise; it is the subsequentidentificationand classificationof
hazardous wastes from that inventory that is difficult. This is not easy to
achieve in developed countrieswhere data on industry and their wastes are
usually freely available. In developingcountries the task is often much more
difficult because local infrastructureprobably does not permit access to up-
to-date, accurate informationon industrialactivities and almost certainly
does not facilitate identificationor analysis of industrialwastes.
In this paper, we have shown how an industrialwaste inventorywith a hazardous

waste identificationand classificationprocedurewas developed for Naples,
Italy, and how the methodology is currentlybeing developed,modified and used
in a project covering the MetropolitanArea of Mexico City.
The Naples Experience
History
During the late sixties,pollution in the Gulf of Naples area of Italy was
highlighted by several outbreaks of cholera which focused public attention on
the problems of pollution. The Cassa per I1 Mezzogirono (Italy'sstate- funded
Development Agency for Southern Italy) committed itself to what is arguably one
of the most ambitiouspollution cleanup campaigns ever undertaken.
It was decided to study the problem, formulatepollution control plans and

implement these plans so that the entire population of the Region of Campania
(the county containingthe Gulf of Naples) would be connected to the sewer
system and the collectedwastewater treated to standards sufficientto
eliminate any public health risk. Coupled with this 'liquid'cleanup campaign,
a similar program for urban and industrialsolid waste disposal (which, at the
time, was haphazard and uncontrolled)was implemented. An idea of the
magnitude of the problem can be gained from the size of the area covered (see
Table 3C-1 Naples Study Area).
As part of this program, study of industrialwaste productionin Campaniawas

undertaken in order to formulate a masterplan for its treatment and disposal.
This in itself was a large task. Industry in the area under consideration
varied from heavy steel mills -- like the one at Bagnoli, Naples, one of the
largest and most modern in Europe -- to small, family-runbusinessesof which
tanneries and shoe and leather goods industriesare perhaps the most typical.
The objective of the part of the study which is described here was to identify
and quantify industrialwastes requiring disposal (i.e., principallynon-
aqueous wastes). From this information,suitable disposal facilitieswere to
be developed and hazardous or potentiallyhazardousmaterials requiring
particular treatment and/or disposalmethods were to be identified.
- 148 -
TABLE 3C-1
Naples Study Area
Area 2800 sq km
Coastal Length 260 km
Industrial Areas 17
Local Councils 195
Population - 1986 5.9 Million
- 2016 8.1 Million
Source: Borrelli, S., and L. Peccerillo. 1983. Planning and Development of

the Gulf of Naples 'Clean-up' Project. Ingegneria Ambientale, No. 11:
558-567 in Italian.
- 149 -
The methodology that was developed to gather and interpretdata on the types
and quantities of waste being generated in the region is describedbelow.
Initial Steps
The initial requirementwas to gain an appreciationof the type, size and

location of industrypresent. Backgroundknowledge on industry in Campania
showed that there was a general distributionof industrythroughoutthe Region.
It was also known that several major industrialareas existed at Caserta,
Battipaglia (south the Salerno), along the coast between Naples and Pozzuoli,
in the coastal area between Naples and Portici (the principal industrialarea
of Naples) and the area between Torre del Greco and Castellamaredi Stabia.
Other areas were identifiedwhere there was a tendency for one particulartype
of industry to predominate;the most notable being Solofra with its tanning
industry,Agro Nocerino with tomato production and canning,northern Naples
with shoe and leather goods and Torre del Greco with coral and cameo factories.
It soon became apparent that records giving informationabout industrialwaste
production in Campania did not exist in any useful form. It was therefore
decided to produce a complete inventory of industry in Campania to provide a
basis on which industrialwaste productioncould be evaluated.
Identificationof IndustrialPresence
In any industrialwaste management study the identificationof industrypresent

in the area under considerationmay be consideredto be the most critical
aspect of the work -- clearly, if the existence of a factory is not known, then
any waste it produces will not be identified. For the work in Campania, a
detailed appraisal of industrywas needed.
From information gatheredby various Chambers of Commerce, Trade Associations

and the Instituto Centrale do Statistica (ISTAT - National Census Information)
it was found that there were over 25,000 industrialpremises to be considered
comprisingnumerous different types of industrialactivity. In the ISTAT data,
all industrialpremises had been classifiedinto a main industrial sector.
Principal classes are shown in Table 3C-2.
Each of these classes was also subdividedinto more distinct sub-categories.

For example, class 3 11 is divided into the following sub-categories:
3 11 01 Bicycle manufacture
3 11 02 Vehicle manufacture (cars)
3 11 03 Two or three-wheeledvehicle construction
3 11 04 Lorry construction
3 11 05 Coachworks
3 11 06 Vehicle parts manufacture
3 11 07 Railway rolling stock and locomotivemanufacture
3 11 08 Animal or hand-drawncart manufacture
3 11 09 Aerospace industry
3 11 10 Boat constructionand dockyards
This source also listed the number of factories in each sub-categoryand the
total number of employees engaged in those factories for every local council.
- 150 -
TABLE 3C-2
Main IndustrialClassification
ISTAT
Class IndustrialSector
3 01 Foodstuffs
3 02 Tobacco
3 03 Textiles
3 04 Clothing
3 05 Shoes
3 06 Leather Goods
3 07 Wood
3 08 Furniture
3 09 Metal
3 10 Mechanical
3 11 Construction
3 12 Minerals
3 13 Chemicals
3 14 Rubber
3 15 Cellulose
3 16 Paper
3 17 Publishing
3 18 CinemalMusic
3 19 Plastics
3 20 Various
Source: Instituto Centrale di Statistica.1971. Classificazionedelle

Attivita Economiche. Serie C No.5 (in Italian).
- 151 -
It was decided to use this informationas a basis for the inventory. This
offered three distinct advantages:
(i) This source provided a ready-madeindustrialclassificationsystem.
(ii) It provided a means of extrapolatingwaste production data for any

particular industrialsub-category(quantityof waste per employee).
(iii) It facilitatedeasy division of the whole area into 195 smaller areas
(local councils) which could be examined independentlyor grouped together.
It was found that out of the 25,000 plus industrialpremises in Campania the
majority of them were engaged in small scale crafts or trades that produced
wastes normally disposed of along with domestic garbage. Consequently,to make
the project manageable, the remainderof the study was limited to industrial
premises of 10 employees or greater, comprising some 3000 firms.
A data bank was constructeddetailing,for each local council, the industrial

premises of each industrial sub-categorytogetherwith the total number of
employees engaged in each.
The data bank on industrialpresence took the following form:

Prog. Local Province ISTAT No.
Number Council Class Employees
1 Castellammare NA 3 01 35
2 Vesuviano NA 3 01 15
3 Molinara BN 3 04 36
3276 Battipaglia Sa 3 10 72
Inquiries showed that little or no informationexisted detailing the wastes

produced by these industries. It was concluded that the necessary information
would have to be obtained by a waste survey.
Approach to Waste Identification
It was impossible to visit all industrialpremiseswith 10 employees or more --

over 3000 had been identified. Nor was it practicable to send them a
questionnaire(this practice is best avoided since response is usually slow and
inaccurate,often through willfulness rather than ignorance). A rational
approach to the situationhad to be found. It was decided that a
representativesample of each type of industrywould have to be visited, and
the number of installations,the potential for waste production (if known) and
the size of the industrialpremises present in Campania,would have to be
assessed. It was decided that at least one premise from each sub-category
would be visited.
- 152 -
Data Collection
Between July 1983 and March 1984, over 185 industrialpremiseswere visited and
questions concerning administrativeaspects of the factory and waste production
were put to factory staff. It should be noted that the most obvious parameter
by which unit waste productionwould normally be measured, quantity per unit
volume of product or raw material used, was found to be unreliable as factories
were often reluctant to disclose informationregarding production. By
contrast, data relating to the number of employees obtained from the local
chamber of commerce or from social security records were more reliable. At
the end of the survey, the quantity of wastes produced by that type of industry
per employeewere known for each industrialsub-category.
Another data bank was created containingthis information. Where more than one
premise from any industrialcategorywas visited the average waste production
was calculated. The data bank took the following form:
ISTAT Description of Quantity Months

Class Waste Ton/Emp/ per Yr
_month
3 01 A Sludge 0.1125 11
3 01 A Paper & Plastic 0.113 11
3 09 01 Sludge 0.00027 11
3 09 01 Refractorybricks 0.023 11
3 09 01 Slag 0.7 11
Data Interpretation
By effectively combining one data bank with the other, the total amount of
industrialwaste produced in the area under considerationcould be estimated.
Similarly,applying selectionprocedures to the first data bank, waste
production in a particular area (group of local councils or provinces) or
industry type could be obtained.
Overall it was found that there were approximately845,000 tons/year of

industrialsolid, liquid and sludge waste produced every year in Campania of
which 60Z originated in and around the City of Naples and 20Z in and around the
City of Salerno.
Even though a quantitativeestimate of waste productionhad been made it was

still necessary to assess the qualitativecharacteristicsof the wastes to
facilitateplanning of a waste disposal strategy and the identificationof
hazardous wastes. It was evident that each waste identifiedwould have to be
classified so that suitabledisposal routes could be identifiedand any hazard
or potential hazard would automaticallybe recognized. The manner in which
this is undertaken is the key to a successfulindustrialwaste inventory. Some
systems base qualitative interpretationon an inclusive list of chemical
- 153 -
compounds. Although this may be consideredideal, it is invariably

impracticableas the highly detailed analysisof each waste required to
implement this system is rarely available. Also, unless a very complicated
operating system is set up, hazards regarding the inter-mixingof chemicals
will not be identified.
It was concluded that an easy to instigate,easy to operate, easy to understand

system should be implementedfor immediate short-termbenefits but that the
same system should readily allow future expansion and development. From the
outset it was decided that whatever the methodology,it should be a computer-
based, interactivesystem. The approach that was eventuallyadopted was to
assign each type of waste a simple code based on simple physicochemical
parameters that could be easily derived for each waste. The manner in which
this has been accomplishedhas led to the developmentof a computer program
which asks simple key questions about each particularwaste. These questions
were selected to progressivelyidentify the waste, progressingon to its
chemical constituentsand, in this case, disposal possibilities.
It was decided that all wastes were to be included in the inventory even those
which, because of certain circumstances,might not require disposal
immediately. In this way, any future change could be easily accommodated. An
identificationsystem was therefore incorporatedinto the coding system to show
that certain wastes currently do not enter the disposal pathway. The last
three charactersin the code indicatewhether or not a waste requires disposal
immediately.
The format of the coding methodology is representedin Table 3C-3; although on

the VDU, communicationtechniquesare improvedwith the use of moving cursor
and highlighted areas, etc. The qualitativecharacteristicsof the waste were
thus eventuallycodified by assigning a letter or number to the answer to each
of the key questions. A twenty character code was assigned to each waste of
the form LNLLLLL LLL. For example, residual cutting oil
may well have the code L1ONNN PNY. To allow the
industrialwaste inventory and classificationsystem to be developed, space was
left in the coding system for up to 20 characters.
The codes were then inserted into the waste data bank so the final data bank
took the following form:
ISTAT Description of Quantity Months Waste

Class Waste Ton/Emp/ per Yr Code
month
3 01 A Sludge 0.1125 11 FlBNNP NNS

3 01 A Paper & Plastic 0.113 11 S3PNNC RSS
3 09 01 Sludge 0.102 11 FlIMBN NSS
3 09 01 Refractory bricks 0.023 11 S3INNN NSS
3 09 01 Slag 0.7 11 S2IXNN XXS
- 154 -
TABLE 3C-3
Methodology for the Classification of Wastes
(1) Is waste is solid, liquid or sludge?
Solid (S) Liquid (L) Sludge (F)
(2) Is waste primarily:
Powder (1) Emulsion (1) Wet (1)

Small pieces (2) Oil (2) Dry (2)
Medium size (3) Other hydrocarbon (3) Non-aqueous (3)
Large size (4) Waterbased (4) Unknown (X)
Unknown (X) Unknown (X)
(3) Principal component of waste is?
Organic - chemical or petrochemical origin (0)

Organic - biological origin (B)
Metallic - (M)
Mix of organic materials (P)
Mix of inorganic and organic materials (V)
Mix of inorganic materials (I)
Unknown (X)
(4) Are any of the following present?
Heavy metals (M)

Phenols or their derivatives (F)
Cyanides or isocyanates (C)
Organic halogenated material (A)
Organic (non-halogenated) solvents (S)
Biocides or pharmaceuticals (B)
Tarry residues (R)
Asbestos (P)
Oxidising material (0)
Polycyclic organic materials (Y)
Metal carbonyls (D)
None (N)
Unknown (X)
(5) Is waste acid or basic?

Acid (A)
Basic (B)
Neutral (N)
Unknown (X)
- 155 -
TABLE 3C-3 (continued)
(6) Is the waste combustible?
Highly inflammable (S)

Combustible (C)
Combustiblewith other material or if dried (P)
No (N)
Unknown (X)
Space for questions 7-17 unused at present
(18) Is there a potential for direct reuse of the waste?
Possiblewith no processing (R)

Possiblewith processing (P)
Not possible nor probable (N)
Unknown (X)
(19) Can the waste be mixed with domestic refuse for disposal?
Yes (Y)
No (N)
Unknown (X)
(20) Is the waste to be considered?
Yes (Y)
No (N)
Unknown (X)
The qualitativecharacteristicsof the waste were thus eventually

represented by the answers to these questions -- one letter or number -- so
that a nine character code was assigned to each waste of the form
LNLLLLL LLL.
- 156 -
On compiling these codes from gathered data, it was evident that not enough was
known about the qualitative characteristicsof many of the wastes. When the
codes had been attributedas best as possible, a search of wastes with one or
more Xs in the code was undertaken. This identifiedwastes with part or
completelyunknown qualitative characteristics. On the basis of this a series
of visits were subsequentlyarranged to inspect and sample these wastes. From
the results of these analyses the waste data bank was modified.
When any waste production is calculatedby interactionof the main two data
banks, with or without any selectionprocedures, the waste's code is retained
alongside the quantity. So, when the calculationis complete, a selective
search through the wastes can be made using the code to identify the presence
of quantitiesand types of wastes of one or more code types.
For example, all potentiallyhazardous liquids would be identifiedby searching

for wastes satisfyingthe following:
Code Character Letter or Number

1 L
2 Any
3 Any
4 M F C A S B R PO Y D
5 Any
6 Any
7-17 Not Used
18 Any
19 Any
20 Any
Identificationof specificwaste types is therefore possible. This can be

improved, or tailored to particular circumstances,by modifying the code
creationprocess or utilizing one or more of characters7-17.
The Mexican Experience
Background
The United Nations Development Programme (UNDP) with the World Bank as
executing agency, has undertaken a global IntegratedRecovery Project to
examine and promote the recycling of wastes and the recovery of resources. A
part of the second stage of this project is the developmentand testing of
survey and inventory methodologiesfor classifying,quantifyingand
characterizingindustrialwastes in Mexico City. The initial part of this
project, an evaluation of waste productionand disposalpractices in the
MetropolitanArea of Mexico City, was completed two years ago.
Even during this initial phase of the work, difficultieswere encountered

owing to the sheer magnitude of the problem. An idea of the size of the
problem can be gained from the area covered (see Table 3C-4). The Federal
District of Mexico City is made up of sixteen 'delegaciones'(local
authorities). Due to ever increasingurbanization,the MetropolitanArea of
Mexico City today encompassestwelve municipalitiesof the neighboring State
of Mexico.
- 157 -
Identificationof IndustrialPresence
During the past thirty years there has been a transitionfrom an

overwhelminglyagriculturaland mining base to an industrialeconomy centered
in Mexico City. Heavy industrieshave been established,notably manufacturing
steel, glass, cars, tractors, railway, trucks, diesel engines, petrochemicals
and a wide range of industrialmachinery. Because of the rapid expansion of
the city industrialareas are often intermixedwith residentialproperty
making location and identificationof industrialpremises more difficult.
This is shown in Figure 3C-1.
During the initial survey, informationgathered showed that there are over
30,000 industrialpremises in the Federal District alone. With the major
industrialpremises to the north of the city outside the Federal District, it
is estimated that the number of industrialpremises exceeds 50,000, including
a 40,000 brl/d refinery.
At the outset of the second phase of the work, it was found that very little
informationon industrialwaste existed. In fact, the situationwas exactly
as in Naples -- the only reliable referencewas the census records on
industrialpresence and employment. Data on industry resulting from the
census is stored by the Secretariade Programaciony Presupesto (SPP),
Instituto Nacional de Estadistica. Although the classificationsystem used,
ClasificacionMexicana de Actividadesy Productos (CMAP), is different from
the ISTAT system it is possible to convert from one to the other.
Waste Identification
During the initial survey it was establishedthat the quantitiesof industrial

solid wastes collected and disposed of by the Departamentodel Distrito
Federal (DDF) was approximately2900 t/d in 1983. For the whole of the
MetropolitanArea the quantity is thought to be in the region of 5000 t/d.
The first phase of the study requires the implementationof an industrial

hazardouswaste inventory. However, as in Naples, little data on waste
characteristicshave so far been found to be available. Unlike the Naples
project the scope of this phase of the study does not permit the execution of
a waste survey in order to establish quantitativeand qualitativedata
regarding waste production.
Planned Approach
To gain an appreciationof the potentialwastes originating in Mexico City in

order to set up an industrialwaste inventory system (an inventory for solely
hazardous wastes to be produced from this), it is proposed to create a data
bank of industry in Mexico City (from SPP data), convert the industrialwaste
data bank derived from the Naples and other studies to the CMAP classification
system and interact the resultingtwo data banks.
The informationproduced will be indicativeof the likely waste production in

Mexico City. By carrying out searchesbased on codes or groups of codes, a
first attempt at evaluatingthe hazardouswaste situation in Mexico City will
be possible. It is realized that this approachwill only be very approximate
- 158 -
TABLE 3C-4
Mexico City Study Area
Area 1200 sq km
Industrial 18
Local Authorities 28
Population - 1984 17.0 Million
- 2000 21.3 Million

-159 -
FIGURE 3C-1
IBRD 21302
UNITED STATESOF AMERICA M EX I C O
)\ ~~~~~~~~~~~Principal Industrial Zones in the
AX 4 CuSf of ~~~~~~Metropolitan Area of Mexico City
\lEm X&I C > i-^q 9'40'
\< C~~UATES A* t
99'30' 99'20' A .5
PrinipalIndutri ZnsX
l z *ts>z' S.
-19°10' A' M.0
KIO1
91 TR 5 0 < +1t
a 19 00
M~~ILE,,,S e; 0r, R' _
99.30. 99'20' 99'1 0' 99'00'
JAUAIWY 1989
- 160 -
but it does give a basis on which to work and develop. The most significant
improvementwill be the effective 'calibration'of the waste production data
bank by modifying the productionfigures to those which are representativeof
the Mexican situation. To complete this, an industrialwaste survey covering
the most important industrial sectorswill have to be undertaken.
Conclusion
The implementationof an industrialwaste inventoryhas to be undertakenwith a

good appreciationof the informationand facilitiesavailable and with an
understandingof the capabilitiesand objectivesof the people who are to use
the inventory. It has been shown that the developed system can be used in
other applicationsto provide a tool in assessing the potentialwaste disposal
problems where little or no data on waste productionexists.
An important factor to consider when developingthese types of inventory is to

keep them flexible and simple. It is always better to have a simple system
that works and is used rather than an overly complex one which, although
technicallyexcellent, is rarely used or updated.
The system implemented in Naples as described above, modified on the basis of

experience and now to be implementedin Mexico, gives a good basis on which
waste management authoritiescan build a waste management system to the
standard they desire. It is, of course, open to criticismbut most of these
criticisms can be overcome by accurate 'calibration'for a particular area or
greater selectivityin the coding system. Further developmentof the system is
underway to include a 'starterpack' for waste authorities suitable for IBM
compatiblepersonal computers.
The project in Mexico City is being sponsoredby the UNDP/WorldBank Integrated

Resource Recovery and Waste Recycling Project (GLO/84/007)with co-financing
provided by the Italian Department of DevelopmentCooperation. The views
expressed,however, are solely those of the authors and do not necessarily
reflect the views of the sponsoringagencies. This methodology has been
considerablyimproved for internationalapplicationusing UN ISIC industrial
classificationcodes. The waste databasehas over 7,250 records.
- 161 -
CHAPTER 4 - Waste Minimization- A Key Strategy In Hazardous Waste Management
4.1 Introduction
Waste minimization is a very importanthazardous waste management strategy

in developing countries,as a recent example from a World Bank project in
East Java, Indonesia shows. This example also illustratesthe ability of
engineers and technicians in developingcountries to conceptualizeand
develop waste minimizationtechnologiesappropriate to local conditions.
Prior to the commissioningof a new water treatment plant serving the city
of Surabaya and financed by a World Bank loan, the government of Indonesia
agreed to bring major polluting industrieson Kali Surabaya,East Java
into compliancewith the government'sliquid effluent standards. Since
the governmentof Indonesia subscribesto the 'polluterpays' principle,
the ProvincialGovernmentof East Java placed the burden on the polluting
industriesto finance plant modificationsor add-on pollution control
measures necessary to meet effluent standards.
At one factory processing recycledpaper into cardboard. The effluent

discharge contains fine suspendedpaper pulp with a high BOD load, which
was dischargeddirectly to the Kali Surabaya. During low flow periods
these suspended solids settle in the river bed creating anaerobic
conditionsand are re-suspendedduring periods of higher flow resulting in
a high turbidity and a peak BOD at the inlet to the downstreamwater
treatmentworks. This creates several operationaldifficultiesand
impairment of the quality of treated water.
Following laboratoryinvestigationsthe company found that the fine

suspendedpulp fiber could be separated from the waste stream with
polymeric flocculantsusing a diffused air floatationprocess. Moreover,
it was found that the pulp fiber produced could be readily dewatered and
was in a suitable condition for use as a low quality pulp. Following a
market survey of low quality pulp processors in the region it was
discoveredthat an egg carton manufacturercould utilize the pulp and had
sufficientcapacity to utilize all of the low quality pulp produced.
A one-third scale pilot plant was constructed to treat about a third of

the waste stream. During a two year testing program which optimized the
usage of polymer it was discoveredthat the floatationprocess could be
effectively run even without compressedair. A full-sizedplant has been
constructedusing locally availableconstructionmaterials and methods and
a local labor force. The recoveredbulk is now being sold to the egg
carton manufacturerat a price that covers operating costs as well as
depreciation.
As a result of the government'sdirective to reduce pollution loads, the

factory not only minimized waste through recovery and recycling,but also
modified processes and procedures in the factory itself to reduce
excessivelyhigh raw water and energy usage.
- 162 -
4.2 Waste Minimization Programs
4.2.1 Definition
The concept of waste minimizationcan best be illustratedby means of

Figure 4-1 which subdividesthe topic into three district headings:
source reduction,recycling,and treatment. The definitions of the
important terms utilized throughoutthis chapter are given in Table 4-1.
Examples of successfulwaste minimizationprograms are given in Annex 4B,
while Annex 4C relates the experienceof a state wide program in waste
minimization in North Carolina.
4.2.2 Source Reduction
Source reduction,the most prominent component of waste minimization,

consists of product substitutionand source control as shown in Figure
4-2. Product substitutionmeans the replacementof an original product
with another product suitable for the same end use, or the alterationof
an original product use which results in a decrease or eliminationof
hazardous waste generationassociatedwith the originalproduct's
manufacture. Examples include replacementof treated wood pilings with
concrete pilings in marine construction,replacementof synthetic rubber
with natural rubber, or replacementof paint coating with longer lasting
plastic coating in certain applications. The definitioncan be broadened
also to include researchand developmentactivity associatedwith seeking
low-waste approachesto new products.
Source control means the reductionor eliminationof hazardous waste

generationwithin the process through input material alteration,
technology alterationor procedural/institutional changes (good operating
practices or good housekeeping).
(i) Input Material Alteration
The effectivenessof input material alterationas a source reduction

technique generally differs according to the type of processing involved.
Raw materials that are directly synthesized (converted)into a product can
be purified prior to processing to reduce waste generationbut, since most
primary feed materials used in synthesis are already relativelypure, this
technique generally results in minimal source reduction. For example, the
use of a more costly, purer, propylene feed in the synthesis of
acrylonitriledoes not result in an appreciable decrease in the volume of
waste that is generated.
Where a process is essentiallya purificationstep, the use of a higher

grade (more pure) material or ore yields less waste. The use of a higher
grade crude in petroleum refining, for example, reduces the amount of
impuritiesrequiring removal during processing. Auxiliary raw materials,
which are used in a process but are not converted into product, can
sometimes be replacedwith less toxic, more environmentallysafe
materials. Examples include the substitutionof innocuous biodegradable
detergents for toxic chlorinatedsolvents and the use of less toxic
- 163 -
FIGURE 4-1
Defining the Concept of Waste Minimization
ANYSOURCEREDUCTION,
RECYCUNGOR TREATMENT
ACTMTY
THATREDUCES
THEVOLUME(a)
AND/ORTOXICflY(b)
OFANYHAZARDOuS
WASTE.
SourceReduction Recycling Treatment

ANYACTMTYTHATREDUCES ANYACTMTY THATREDUCES ANYACTIMYTHATREDUCES
OR EUMINATES
THEGENERATION VOLUMEAND/ORTOXICfIYOF VOLUME
AND/ORTOXICIlY
OF
OFHAZARDOUSWASTEWITHIN
A HAZARDOUSWASTE WITH
ATTENDANT HAZARDOUSWAS WTEHOIJ
PROCESS, GENERATIONOFA VALUABLE ATTENDANT
GENERATION
OFA
MATERIALWHICHISSUBSEQUENTLY VALUABLE
MATERIAL
llUZED.
(a)VOWMEREDlCTION
- PREFERABLY
ACCOMPLUSHED
WITHOUT
ANINCREASE
OFTOXIcrfY,
(b)rOXICny
REDUCTION
- PREFERABLY
ACCOMPLSHED
BYMEANS
OTHER
THIAN
DILTION.
Source:TurnTln,C.E Hazardous
WasteContrd ThroughReducflon.
- 164 -
TABLE 4-1
Working Definitions of Waste Minimizationand Related Terms
Waste minimization: The reduction,to the extent feasible, of hazardous waste

that is generated or subsequentlytreated, stored, or
disposed of. It includes any source reduction or
recycling activity undertakenby a generator that results
in either (1) the reduction of total volume or quantity of
hazardous waste or (2) the reduction of toxicity of
hazardous waste, or both, so long as such reduction is
consistentwith the goal of minimizingpresent and future
threats to human health and the environment.
Reduction of total The reduction in the total amount of hazardous waste

volume or quantity: generated,treated, stored, or disposed of, as defined by
volume, weight, mass or some other appropriatemeasure.
Reduction in The reduction or elimination of the toxicity of a

toxicity: hazardouswaste by (1) altering the toxic constituent(s)
of the waste to less toxic or non-toxic form(s) or (2)
lowering the concentrationof toxic constituent(s)in the
waste by means other than dilution.
Source reduction: Any activity that reduces or eliminates the generation of

a hazardous waste within a process.
Source control: Any activity classifiableunder source reductionwith the

notable exception of product substitution.
Product The replacementof any product intended for an

substitution: intermediateor final use with another product intended
and suitable for the same intermediateor final use.
Recycled: A material is "recycled"if it used, reused, or reclaimed

(40 CFR 261.1 (b] (7]).
Used or reused: A material is "used or reused" if it is either (1)

employed as an ingredient (includingits use as an
intermediate)in an industrialprocess to make a product;
however, a material will not satisfy this condition if
distinct componentsof the material are recovered as
separateend products (as when metals are recovered from
metal-containingsecondarymaterials) or (2) employed in a
particularfunction or applicationas an effective
substitutefor a commercialproduct (40 CFR 261.1 [c]
[5)).
Reclaimed: A material is "reclaimed"if it is processed to recover a
usable product or if it is regenerated. Examples are
recovery of lead values for spent batteries and
regenerationof spent solvents (40 CFR 261.1 [cl [4]).
- 165 -
Treatment: (as part of waste minimization)-- Any activity or a

series of activitiesthat reduces the volume andlor
toxicity of hazardous waste without attendant recovery of
valuable material that is subsequentlyemployed in the
manufacture of a commercialproduct (e.g., an incinerator
for disposal of spent chlorinated solventwith scrubbing
and neutralizationof hydrogen chloride from the flue
gas);
Source: U.S. EnvironmentalProtectionOffice. 1986. Minimizationof Hazardous

Waste. No. 530-5W-86-033 (October). Washington, D.C.
- 166 -
FIGURE 4-2
Concept of Source Reduction As a Component of Waste Minimization
PRODUCT
SUBSTITUTION SOURCE
CONTROL
NOTE: EXTERNAL
TO GENERATOR
OF PROD. COMPOSITION
* ALTERATION
OF PROD.USE
* ALTERATION
INPUT
MATERIAL
ALTERATIONTECHNOLOGY
ALTERATION PROCEDURAL
CHANGES'
* MATERLAL
PURIFICATION * PROCESSCHANGES * PROCEDURALMEASURES
* MATERLAL
SUBSTITUTION * EQUIPMENT,PIPINGOR * LOSSPREVENTION
LAYOUTCHANGES * PERSONNELPRACTICES
* ADDlTIONALAUTOMATION * WASTESTREAM
* CHANGESTO OPERATIONAL SEGREGATION
SETINGS * MATERLAL
HANDUNG
* ENERGYCONSERVATION * IMPROVEMENTS
* WATERCONSERVATION
ALSOREFERRED
TOAS "GOODOPERATING
PRACTICES"
OR"GOOD HOUSEKEEPING".
Source:Turman,CE. ControlThroughSourceReduction.
- 167 -
compounds in lieu of chromate corrosion inhibitorsin cooling towers.

Sometimes,however, a manufacturermay substitutea material not because
the waste would be less toxic but because the waste is simply not
regulated.
(ii) TechnologyAlterations
In certain instances,technology substitutionsare also effective in

minimizing waste. A product can sometimesbe manufacturedby two or more
distinct processes. Certain processes, such as the chloride process for
producing titanium dioxide, generate considerablyless waste than
alternative processes, such as the sulfate process. Unfortunately,
modification of existing facilitiescan involve considerableresearch and
development and capital investments,and can require a lengthy
implementationperiod.
Inefficient chemical reactions in a process are a major source of

increasedwaste generation. Improving the efficiencyof the process
through modificationof catalysts,reactor design, and operating
parametershas been shown to reduce significantlythe quantity of waste
generated. For example, in the productionof acrylonitrileby the
catalytic ammoxidationof propylene, switchingfrom an antimony-uranium
catalyst to a ferrobismuthphosphomolybdatecatalyst has boosted the
conversion of acrylonitrileby 35 percent. In another instance, there has
been a significantdecrease in tar formationwhere changes in reactor
design improvedmixing for the manufacture of epichlorohydrin. Attaining
zero waste generation,however, is currently beyond the technical
capabilitiesof most chemical processors.
Modification of equipment is another way to reduce waste generation. The

invention of mechanicalwipers to scrape the sides of paint tanks, for
example, reduces the exposed volume of waste paint that would otherwise
produce fugitivevolatile organic compound (VOC) emissions. Similarly,
process automation,which helps optimize product yields by automatically
adjusting process parameters,has in many cases minimized operator error,
reduced the likelihoodof spills, and discouraged the production of off-
specificationmaterials. As noted earlier, these off-specification
materials can be highly toxic, albeit lower volume, wastes.
Water conservationcan also result in significantwaste reduction.

Efficient product washing results in reduced sludge generationby
minimizing the amount of product lost to the wash water and the quantity
of wastewater that is generated.
Technologymodificationand developmentof low waste techonologiesis

currently a central focus of waste minimization. Generally these changes
are most cost-effectivewhen implementedduring a plant's planning or
design period or when a plant is retooling and replacingworn out
equipment. Retrofittingplants that have already been designed and/or
constructed is often expensive and difficult. Consequently,while
technologymodificationmay be of limited effectivenessin reducingwaste
generation and toxicity from existing sources, it can be effective in
limiting future waste generation.
- 168 -
(iii) ProceduralChanges
"Good operating practices" or "good housekeepingpractices" involve the

alterationof existing procedural, organizational,or institutional
aspects of a manufacturingprocess. The goal is to limit unnecessary
generationof waste attributableto human intervention(or the lack of
it). Employee training,management initiatives,inventory control,waste
stream segregation,improvementsin materials handling, scheduling
improvements,spill and leak prevention,and preventivemaintenance are
all examples of good operatingpractices. Others include the scheduling
of batch operations to limit the frequencyof equipment cleaning and,
consequently,waste generation;the segregationof hazardous wastes from
non-hazardouswastes to minimize the volume of contaminatedwastes; and
the reduction of overspray and runoff from sprayingby the paint booth
operator during paint application.
(iv) Product Substitution
Replacementof an original product with a different product that is

intended for the identicaluse can be an effectivemethod of source
reduction. For example, integratedpest management, an alternativeto
pesticide use in certain applications,reduces pesticide production and,
in turn, the waste generated during pesticide production and application.
The substitutionof concrete pilings for creosote-treatedtimbers
eliminateswastes from the manufactureof the creosote-treatedpilings.
Substitutionof less toxic solvents, such as petroleum solvents for more
toxic solvents such as perchloroethyleneor trichloroethylene,generates a
spent solvent waste that is less toxic.
It is difficult to quantify the current status or effectivenessof these

source reduction techniques. Each substitutionneeds to be evaluated on a
case or application-specific basis. The viability of a substitutecan be
based on:
o whether the substitutecan function adequatelyas a replacement;
o whether the economic cost of a substitutejustifies its use as a

replacement,
o whether the manufacture and disposal of a substitutereduces

environmentalconsequence;
o whether the cost/environmental

benefit of the substitute is
sufficientlyattractive;and
o socio-politicalfactors, such as governmentaction (e.g., procurement

policy) to promote the substitute.
Trade-offshave to be weighed prior to the selection of substitutes. For

example,water-based inks, sometimesused for engraving and flexographic
printing, have the advantage of being less toxic than solvent-basedinks,
- 169 -
but require more energy to dry, possess a low gloss, can cause paper to
curl, and occasionallyrequire brief process stoppages. Petroleum
solvents can be used in dry cleaning, but they are much more flammable
than the more commonlyused but more toxic perchloroethylene.
Available data are insufficientto quantifythe current effectivenessof

source reduction practices in reducingvolume or toxicity. In qualitative
terms, data indicate that industry in developedcountries have already
considerablyreduced the volume of their wastes. Most of these source
control methods, however, have been employed (1) to reduce costs or
improve product quality, and, in turn, increaseprofits and (2) to respond
to existing environmentalregulations. Rarely have these practices been
used solely for the purpose of waste minimization. Current information
suggests that further significantsource reduction does appear feasible
and practicable.
4.2.3 Recycling
Viewed generically,"recycling"encompassesboth re-use and reclamation

activities. The discussionin this section on recycling activities
pertains to hazardous waste recycling for materials recovery as well as
for energy recovery. A recycler'sdecisions as to how to treat a waste is
principally determinedby the character of specificwaste streams or waste
mixtures. Where treatment should take place (either onsite of offsite),
however, is a function of a generator'smanagement practiceswhich
include:
o proximity to offsite recycling facilities,
o economic costs related to the transportationof wastes,
o the volume of wastes available for processing,and
o costs related to storage of waste onsite compared to offsite.
Recycling is characterizedby three major practices: (1) direct use or re-

use of a waste in a process, (2) recoveryof a secondarymaterial for a
separate end use such as the recoveryof a metal from a sludge, and (3)
removal of impurities from a waste to obtain a relativelypure re-usable
substance.
(i) Materials Recovery
Although recycling of selected streams is practiced to a considerable

degree by certain industries,only about 4 percent of the hazardous waste
generated in the United States was recycled in 1981. Of the waste that
was recycled, 81 percent by volume was recycled onsite. Offsite
recycling,however, is becoming increasinglycommon with the advent of
commercial recyclers and direct transfer of wastes from generatorsto
others who can re-use the wastes. Table 4-2 summarizesthese data for the
ten highest volume waste generatingindustries.
- 170 -
TABLE 4-2
Ten Highest Volume Waste Generating Industries+
Generation and Recycling Volumes during 1981
Volume of Total Volume Volume
Waste Volume Recycled Recycled
SIC Industry Generated Recycled Onsite Offsite
M gals* M gals*Percent** M gals*Percent** M gals*Percent**
28 Chemicals and
Allied
Products 28,000 340 1.2 300 1.1 32 0.1
35 Machinery,
Except
Electrical 4,200 26 0.6 18 0.4 7.9 0.2
37 Transportation
Equipment 2,300 900 39.0 880 38.0 22 0.9
42 Motor Freight
Transportation1,700 NR NR NR
29 Petroleum and
Coal Products 1,300 36 2.8 32 2.5 4.2 0.3
33 Primary Metal
Industries 1,000 170 17.0 18 1.8 150 15.0
17 Construction:
Special Trade
Contractors 870 0.2 <0.1 0.1 <0.1 0.1 <0.1
34 Fabricated
Metal Products 820 24 2.9 14 1.7 9.6 1.2
36 Electric and
Electronic
Equipment 670 47 7.0 0.4 <0.1 46 6.9
49 Electric, Gas,
and Sanitary
Services
(includes
POTWs) 470 3.3 0;7 0.1 <0.1 3.2 0.7
Total: 40,000 1543.2 1262.5 271.8
+ These are wastes recycled at the end of the production process.

* Reporting error accounts for onsite and offsite volumes not equalling
total volume recycled.
** Percent of total waste generated (by SIC).
NR: No Recycling of this type reported in RIA Generator Survey.
Source: U. S. EnvironmentalProtectionAgency. 1984. National Survey of
Hazardous Waste Generators and Treatment,Storage, and Disposal Facilities
Regulated Under RCRA in 1981. Washington,D.C.: Office of Solid Waste.
- 171 -
Recycled wastes are used as feedstocksin productionprocesses or as

substitutes for commercialchemical products. Examples include:
o the re-use of solvents for equipmentcleaning;
o the recycling of collected pesticide dusts at pesticide formulators;

and
o the re-use of ferric chloridewastes from titanium dioxide

manufacturingas a wastewater conditionerin water treatment.
The proportion of waste that is recycled is both industry and waste

specific. In general, certain wastes, such as solvents, tend to be
recycledmore often than others, such as pesticides. Factors that
influencewhether an industry recycles its waste include (1) the type of
waste generationprocess used; (2) the volume, composition,and uniformity
of wastes; (3) whether uses and re-uses of the wastes have been
identified, and (4) availabilityand price of virgin materials relativeto
the costs of recycling and storing the wastes. Toxicity of the waste does
not appear to be a direct factor in the recyclabilityof a generated
waste, although, as noted previously,high volume wastes, which are often
less toxic, are more commonly recycled. Based on limited data, some
industry-specificobservationscan be made. See Table 4-2.
Generally, the streams that are recycled in the greatest volumes are
dilute waste streams containinga constituentthat can be re-used in
large-scaleapplicationsby a generator. For example, in the chemical and
allied products sector, spent acids and alkaline solutionsare recycled in
the transportationequipment industry;wastewater treatment sludges from
electroplatingand chromium plating processes are recycled; and in the
primary metals industry, spent pickle liquor is recycled. Chronium
solutions can be reused and recovered in tanneries. These streams are of
varying toxicity, and data are inconclusiveas to whether toxicity plays a
role in a stream'sbeing recycled.
Solvents tend to be recovered in larger proportionthan other wastes.

This is because there is both an existing technologyto allow recoveryand
because a market exists for the recycled solvent. The available
technology (e.g., distillation)is relativelyinexpensiveto operate and
can attain high purity levels (95 percent or higher). In other cases,
however, production processes generatewastes that are not practical for
recovery since the recoveredwastes themselveswould not be useful in
production.
(ii) Energy Recovery
In the 1981 U.S. survey, data indicate that recycling for materials
recovery and re-use appears to be more popular than fuel use or energy
recovery. There are two reasonswhy this is so. First, some wastes that
could be recycled for energy recovery can also be reclaimed and re-used
over and over. Energy recovery in contrast destroys the inputs. Only
when the waste is too "dirty" (contaminatedfrom repeated re-use) do
generators consider energy recovery a desirable option. The 1981 data may
- 172 -
not, however, provide a completelyaccurate picture of current practices

because of recent developmentsin energy recovery technology. Many
technologieswere not available in 1981, and others are only beginning to
be commerciallyavailable today. Solvents tend to be used for energy
recovery because they can possess high energy values. Increasing
quantitiesof high calorificwastes are being used by cement plants and
lime kilns.
(iii) Other recycling technologies
Wastes that have higher constituentconcentrationsare usually selected

for recovery and reclamation. Data suggest that there are threshold
levels that must be reached before wastes can be considered eligible for
the recycling process. Halogenated solvent and nonsolventwastes must be,
on average, in the range of 35 to 40 percent before recovery or re-use
technologiesare practical. For other wastes, such as nonhalogenated
solvents and corrosives,the threshold levels are lower for recovery or
re-use practices. In any case, the average concentrationlevel for the
material being recovered using reclamationtechnologiesis higher than
that for any of the other management practices (such as onsite wastewater
treatment,surface impoundments,wastewater discharge, land disposal, and
treatment of organics).
A number of other typical characteristicsare common to waste streams that

are recycled. To be economicallyand technicallyviable for recycling,a
stream usually must be uniform (i.e., it must not contain more than one
contaminant). Other factors that must be met in order for recycling to be
successfulinclude:
o A market for the recycledmaterial must exist within an economically

viable distance; and
o The recycledwaste must meet purity requirementsfor manufacturing

processes.
Because recyclablewastes must be economicallycompetitivewith the virgin

materials they are replacing,the wastes must often be processed prior to
re-use. Reclamationprocesses include chemical, physical, and
electrochemicalseparation. Some of the major technologiesinclude the
following:
o Distillationof solvent wastes;
o Dechlorinationof halogenated,nonsolventwastes; and
o Metal concentratingtechniquessuch as leaching, solvents extraction,

ion exchange, precipitation,crystallization,and evaporationto treat
dilute metal-bearingwaste streams.
While not as common as onsite recycling,commercialoffsite recycling is

becoming increasinglypopular. It is, in fact, favored by some
industries,most notably primary metals and small quantity generators of
_ 173 -
lead-acidbattery wastes. Offsite recyclingusually occurs at mobile

plants, centralizedrecovery facilities,or other commercialrecycling
plants. An increasinglypopular commercialrecycling service called batch
tolling accepts hazardouswastes from a generator only for treatment and
returns the recovered product to the same generator for re-use. The
recycler charges a fee to the generator for recovery of the reclaimed
material. Some small volume generatorshave actually pooled their
resources and now operate centralizedfacilities,thereby reducing their
capital and operating costs.
Certain wastes that are not useful to a generator may be desired by

another industry as a raw material. Waste exchanges are often helpful in
facilitatingthe transfer and recyclingof these wastes. They serve as
informationclearinghouses(listingwastes that are available or desired),
and can also act as brokers; occasionallythey actually transportwastes
from one plant to another. Available informationsuggests that
approximately20 to 30 percent of all wastes listed by exchanges are
eventuallyrecycled. Some of the wastes that are most often recycled
include acids, alkalis, solvents,metal wastes, and corrosives.
4.2.4 Treatment
This topic is treated in considerabledepth in Chapter 6.
4.3 Incentives and Disincentivesfor Waste Minimizationin Developing

Countries
With very limited governmentenforcementof air and water pollution

control regulations (if these have even been promulgated)and with no
effective regulationsto control hazardous wastes, the costs associated
with the disposal of hazardous waste in developingcountries tend to be
negligible. If the wastes are transportedoff site the disposal cost may
simply amount to the lowest bid received from the local waste hauler who
dumps it on uncontrolledwaste sites or into swamps, streams or ponds as
close as possible to waste generators. Therefore,there is usually little
or no economic incentive for the waste generator to engage in waste
minimizationpractices unless the waste contains a valuable material which
can be readily recovered,for example: gold and silver.
The most important requisite for waste minimizationis active enforcement

of air and water pollution control and hazardous waste management
regulations. Even without specific regulationsrequiringwaste
minimization and utilizationof low waste technologies,the increasedcost
of waste disposal and limitationson certain unacceptabledisposal
practices will provide some incentivesfor waste minimization.
Other barriers to an effectivewaste minimizationprogram at a particular

plant may include (Turman):
o lack of awareness of the benefits of waste minimization;
o lack of technical staff;

- 174 -
o attitude caused by fear of upsetting a

a "hands-off-the-process"
product's quality;
o organizationalinertia, for example, an "if-it-isn't-broken-don't-fix--

it" attitude;
o internalpolitics of the organization,for example, an innovatormay

feel inhibitedby a fear of lack of management's support; and
o an "it-can't-be-done" attitude--peoplemay reject an innovative

approach merely because it is outside their range of experience.
4.4 Waste MinimizationAudits
One procedurewhich can help overcome some of the above barriers to

identificationand implementationof waste reduction plans is a Waste
MinimizatlonAudit (Fromm and Callahan 1986). The objectivesof the audit
are:
o to generate a comprehensivelist of waste minimizationmeasures or

options applicableto a specific industrialprocess, and
o to rank all identifiedwaste reductionoptions and to allow management

to focus on options deserving further in-depth consideration.
A typical wastes minimizationaudit may involve some or all of the

following steps:
o selection of the audit team,
o compilationby the audit team of a waste stream list for the facility
with the associatedflowrates,
o generationby the audit team of waste reduction options for each waste
stream,
o ranking by the audit team of each compiled option in three categories:

effectiveness,extent of current use, and applicationpotential,
o preparationby the audit team of documentationin support of selected

options,
o presentation,discussionand joint review with plant personnel of

options and their rankings,
o analysis by the audit team of revised rankings, and
o final report preparation.
The above procedure is applicableto all three categoriesof waste

minimization (recycling,treatment and source reduction). However, it
originallywas developed and tested for source reduction options only.
Source reduction measures should be consideredeven when recycling or
- 175 -
treatment options are given priority, because reducing the quantitiesof

waste that are recycledor treated often means an increase in revenues
(e.g., due to an increase of product yield and lower cost of treatment).
Tables 4-3, 4-4, 4-5 and 4-6 contain checklistsof water reduction
measures compiled based on many process analyses and on experiencesgained
with waste minimizationaudits in a number of industries. Annex 4A gives
some examples of cost/benefitanalyses of waste minimizationprojects.
4.5 EvaluatingWaste MinimizationProject Costs and Benefits
Ideally, the relativeworth of any proposed capital project is developed

by identifyingand quantifyingall project-relatedcosts and savings.
However, not all savings need be quantifiedin practice to demonstrate
economic practicability.
In practice, the potentialvalue of most capital projects has been

established on the basis of savings in the following areas:
o raw materials costs
o utilities, labor, and maintenance costs, and
o enhanced revenues through creation of marketable by-products
Waste reduction projects can create savings in the same areas. However,
the goal of reducingwaste focuses attention on waste generationcosts
which were previouslyaffected but not taken into consideration:
o disposal fees
o fees/taxeson generatorsper unit of waste(some states)
o transportationcosts
o on-site waste storage and handling costs
o predisposal treatmentcosts
o permitting,reporting,and recordkeepingcosts
o pollution and safety liabilities
For the purpose of evaluatinga project to reduce waste quantities, some

types of costs are larger and more easily quantified. These are disposal
fees, transportationcosts, predisposaltreatment costs, raw materials
costs, and operation and maintenancecosts. It is suggestedthat savings
in these costs be taken into considerationfirst because they will have a
greater effect on project economics and will involve less effort to
estimate reliably.
Disposal fees vary according to whether the wastes are solid or liquid,
the type of container in which the waste arrives (drum or in bulk), and
- 176 -
TABLE 4-3
Waste ReductionMethodology Checklist: All Processes
All Waste Streams 1. Use higher purity materials

2. Use less toxic raw materials
3. Use non-corrosivematerials
4. Convert from batch to continuousprocess
5. Tighter equipment inspectionand maintenance
6. Better operator training
7. Closer supervision
8. Practice good housekeeping
9. Eliminate or reduce water use for spill cleanup
10. Implement proper equipment cleaning techniques
11. Use improvedmonitoring systems
12. Use pumps with double mechanical seals
CommoditiesProduced
ContinuouslyExamples: Acrylonitrile,Epichlorophydrin,Petroleum Refining,
1,1,1 Trichloroethane,
Trichloroethylene/Perchloroethylene,
Vinyl Chloride
Monomer
Heavy and Light Ends 1. Develop more selective catalyst

2. Optimize the reactionvariables/reactordesign
3. Use alternate process routes
4. Combust with heat (and HCI) recovery
Spent and Lost Catalyst 1. Develop tougher catalyst support

2. Use filter inside reactor freeboard
3. Regenerate and recycle spent catalyst
Equipment Cleaning 1. Increase equipment drainage time

Waste 2. Use corrosion resistantmaterials
3. Agitate and/or insulate storage tanks
4. Re-examineneed for chemical cleaning
5. Use nitrogen blanket to reduce oxidation
6. Use in-processHX cleaning devices
Leaks and Spills 1. Use bellow-sealedvalves

2. Use canned (seal-less)pumps
3. Maximize use of welded vs. flanged pipe joints
- 177 -
TABLE 4-4
Waste Reduction Methodology Checklist: CommoditiesProduced in Batches
Examples: Dyes, Inorganic Pigments, Paint, AgriculturalChemical

formulation,PhenolicResins, Wood Preserving
Material Handling 1. Segregate containersby prior contents

2. Use rinseable/recyclabledrums
3. Purchasematerials in bulk or in larger containers
4. Purchasematerials in pre-weighed packages
5. Use pipeline for intermediatetransfer
Reaction/Processing 1. Optimize the reactionvariables/reactordesign

Step 2. Optimize the reaction additionmethod
3. Eliminate the use of toxic catalysts
Filtration and 1. Employ efficientwashing/rinsingmethods

Washing 2. Eliminate the use of filter aids
3. Use countercurrentwashing
4. Recycle spent washwater
5. Maximize sludge dewatering
Baghouse Fines 1. Increaseuse of dust suppressionmethods

2. Use wet instead of dry grinding
3. Schedule baghouse emptying
Off-Spec Product 1. Tighter control of reaction temperature

2. Reformulationof off-spec product
Equipment Cleaning 1. Install high pressure spray wash system

2. Alter production schedule
3. Use mechanicalwipers on mix tanks
4. Clean mix tanks immediatelyafter use
5. Use countercurrentrinse sequence
6. Recycle spent rinse water
7. Increase spent rinse settlingtime
8. Re-examineneed for chemical cleaning
9. Dewater spent rinse sludge
Leaks and Spills 1. Use bellow-sealedvalves

2. Install spill basins
3. Use canned (seal-less)pumps
4. Maximize use of welded vs. flanged pipe joints
- 178 -
TABLE 4-5
Waste Reduction Methodology Checklist: ManufacturingOperations
Examples: Electroplating,LithographicPrinting, Metal Parts

Cleaning, Metal Surface Treatment,Paint Application,
Printed circuit Boards
Material Handling 1. Segregate containersby prior contents

2. Use rinseable/recyclabledrum
3. Purchasematerials in bulk or in larger containers
4. Purchasematerials in pre-weighed packages
Solvent Cleaners 1. Install/operatecleaning tanks properly

2. Avoid cross-contaminationof solvent
3. Avoid water contaminationof solvent
4. Remove sludge continuously
5. Monitor solvent composition
6. Consolidatecold cleaning operations
7. Recycle spent solvent
8. Use plastic bead blasting for paint stripping
Alkaline/AcidCleaners 1. Install/operatecleaning tanks properly

2. Avoid cross-contaminationof solvent
3. Remove sludge frequently
Plating/Etching/ 1. Increase plating solutionbath life

Surface Finishing 2. Use lower concentrationplating bath
Solution 3. Use trivalent Cr in place of hexavalent: Cr
4. Use non-cyanide plating solutions
5. use in-line recovery techniques
6. Regenerate spent bath solutions
7. Segregate all waste streams
8. Inspect all parts for proper cleanliness
Rinse Water 1. Install/operateall rinse tanks properly

2. Use multiple rinse tanks
3. Install drain boards and drip tanks
4. Use fog nozzles and spray units
5. Agitate rinse bath
6. Use deionizedwater for rinsing
7. Recycle and reuse rinse water
8. Segregate all waste streams
9. Reclaim metal from rinse water
Paint Application 1. Use equipmentwith low overspray

2. Inspect all parts before painting
Leaks and Spills 1. Install splash guards and drip boards

2. Prevent tank overflow
- 179 -
TABLE 4-6
Replace ElectroplatingChemicals
Electroplatingis a common process used throughoutthe metals industry. Many

electroplatingprocess typically use chemicals containinghigh levels of
cyanide, and hexavalent chromiumwhich are highly toxic and pose disposal
problems. Eletroplatingchemicals are availablewhich may replace chemicals
containingchromium or cyanide.
Traditional Substitute
Chemical Chemical Comments
Fire Dip (NaCN Muriatic Acid Slower acting than fire dip.
+ H202) with additives
Heavy copper Copper Sulphate Provides excellent throwing power with a

bright, smooth, rapid finish. Requires
good preplate cleaning. Eliminates
carbonate build-up in tanks. Copper
Cyanide likely still necessary for steel
or tin-basedmetals.
Chromic Acid Sulphuric Acid Non-chromiumsubstitution.

Cleaners and Hydrogen Non-fuming.
Peroxide
Chrome-based Benzotriazole Non-chromiumsubstitution.

Anti-tarnish (0.1-1.OZ Extremely reactive, requires ventilation.
solution in
Methanol)
Cyanide Cleaner Trisodium Good degreasingwhen hot and in an

Phosphate or ultrasonicbath. Highly basic. May
Ammonia complexwith solublemetals if used as an
intermediaterinse between plating baths
where metal ion may be dragged into the
cleaner.
Tin cyanide Acid tin Works faster and better

chloride
- 180 -
the quantity of waste disposed of. Table 4-7 gives some disposal fee
ranges for solids and liquids in drum and bulk containers and for "lab
packs." In the U.S., the drum prices shown are for larger quantities;
disposal of small quantitiesof drums can cost up to three times as much
per drum.
The cost of disposal site lab analysis of the waste is included as a

disposal fee and appears in Table 4-7. Each shipmentof waste to a
management facility undergoes an analysis confirmingthe constituentsof
the waste shipment. Therefore, reducingthe number of shipmentswill
result in a savings.
Changes in raw materials cost, and operation and maintenance costs are
process-specific. Maintenance cost may seem a minor item, but it may be
quite substantial.
The remaining elements are usually secondary in their direct impact and
should be included on an as-needed basis in fine-tuningthe analysis. For
example, calculating savings in waste storage and handling requires
imputing a value for the waste inventory area and estimatingthe pre- and
post-project costs of containerizing,labelling,and moving the waste.
Changes in the administrativecosts of regulatorycompliancemay occur
only with a complete or near-completereduction in waste volume.
Once cost savings have been calculated,the standardprofitabilitymeasure

can be computed. One of the more popular measures among engineers is the
payback period. This measure has a strong intuitive appeal, especially
for projects intended for reducingcosts as opposed to increasing
revenues. Capital funding for a project may well hinge on the ability of
the project to generatepositivemargins long after payback and to realize
an acceptable return on investmentas measured by the internal rate of
return.
One way of accounting for a reduction in an identifiedbut not readily

quantifiedrisk is to ease the financialperformance requirementsfor the
project. The acceptablepayback period may be lengthened to five years,
or the required internal rate of return may be lowered. Such adjustments
reflect recognitionof elementswhich affect the risk exposure of the firm
but which cannot be included in the analysis, such as lower potential
liabilities. (These adjustmentsnecessarily reflect the individualbias
of the persons evaluatingthe project for capital funding.)
4.6 RequestingApproval for Funding of Waste Management Projects
Unfortunately,suggestionsfor process improvementsare not always sold on

their technicalmerits alone. As anyone involved in selling a product
will say, presentationis the most importantpart of persuasion. A clear
depiction of both tangible and intangiblebenefitsmay edge a project past
its competitors for funding.
Persons willing to sponsor a waste reduction idea should exhibit a strong

belief in their idea and confidencethat it will work. In the interest of
- 181 -
TABLE 4-7
Typical Costs of IndustrialWaste Management

Disposal
Drum waste
solids $50 - $75/drum
liquids $75 - $160/drum
Bulk waste
solids $150/cubic yard
liquids $0.95 - $2.50/gallon
Lab packs $100/drum
Analysis (at disposal site) $200 - $300
Transportation $65 - $85/hour 845 mph
(round trip)
Source: Jacobs Engineering. 1986. Private Survey. Washington, D.C.

- 182 -
implementingtheir idea, they should be flexible enough to develop

alternativesor modifications. They should also be committed to the point
of doing substantialbackground/supportwork and anticipatingpossible
problemswith the idea's implementation. Above all, they should keep in
mind that an idea won't sell if the sponsors aren't sold on it themselves.
The first step in securing approval is to call attention to the idea.

Identify the problem, noting how long it has persisted and is likely to
persist without action. For example, a lack of efficient control at one
stage of a process could be the source of a waste quantity associatedwith
a constantly increasingdisposal cost. An effective identificationof the
problem would include an outline of the process step, the method currently
used to control it, and the past and present costs to the company (e.g. in
terms of excess raw material usage plus waste management costs)
attributableto the inefficiency. After summarizingthe problem, describe
the proposed solution, and spell out the material benefits to the company
of underwritingthe solution. Also, try to enlist the support of
management at this point, especiallythose with primary profit
responsibilityin your area. Keep in mind that the greater the
organizationalauthority on the part of an idea's main backer(s),the more
likely the idea will be implemented.
Knowing the level within the corporationthat has approval authority for
capital projectswill help in enlisting the appropriate support. For
example, smaller projects may be approved at the plant manager level,
medium-size projects at the divisionalvice-presidentlevel, and larger
projects at the executive committee level.
While solicitingadditional sponsorshipof an idea, it is important to

assemble solid analyticaland documentary support. Evaluate the
performanceof the project under different sets of assumptions,taking
care not to "fix" the results positivelybut to stay close to realistic
expectationsof future costs and prices, productionquantities, tax laws,
etc. Use a number of different performancemeasures (e.g., internal rate
of return, net present value, payback period, the timing and amount of net
cash flow, and so on). In presentingthe analysis, briefly outline how it
was done (i.e., what assumptionshave been made, whether they are
conservative,and how the project generatesnet cash flow). For example,
if the project meets performancerequirementseven though current disposal
fees were used in calculationscovering the entire life of the project,
point out that these fees can realisticallybe expected to rise in the
future, resulting in even greater avoided costs than estimated. In
summarizingyour analysis, present all measures of performance to aid in
the making of an informed decision. Also include a qualitativeassessment
of intangiblecosts or benefits occurring to the company and their effect
on project desirability.
The analysis should include not only how much the project will cost and
its expected performance,but also how it will be done. It is important
to discuss:
o whether the technologyis established,with brief mention of successful

applications;
- 183 -
o the required resources (e.g., technical expertise and labor time)

procurable in-house versus those that must be brought in;
o estimated production downtime;
o estimated constructionperiod, and
o how the performanceof the project can be evaluated after it is

implemented.
In addition, think through the project for possible alternativesor

modifications. Be flexible, as long as the original goal is not obscured.
Discuss your idea in advance with operation and maintenance supervisionto
verify safety and efficient use of manpower. If your idea is for a
change in productionmethods, be prepared to answer questions about the
project's effect on the quality of the final product.
The size of the capital outlay and the level of authorityneeded for
approval determine the extent of the necessary analysis and exploration.
Decisions on larger capital outlays generally require a more thorough
examinationof project economic performancein the face of changing
business conditions, increased competition,etc.
The next step is to develop a suggested course of action. Develop a

detailed schedule for implementingthe project, noting when it is most
feasible for production downtime to occur, or suggest that the project be
referred to an evaluationteam. A team can review the project in the
context of:
o past experiencein this area of operations;
o what the market and the competitionare doing;
o how the implementationprogram fits into the company's overall business

strategy; and
o advantages of the proposal in relation to competing requests for

capital funding.
An evaluation team made up of financial and technical personnel can ensure

that a sponsor's enthusiasmis balanced by objectivity. In like manner,
it can also serve to quell opposing "can't be done" or "if it isn't
broken, don't fix it" attitudeswhich the idea could encounter in the
organizationalstructure.
Waste reduction projects generally involve improvementsin process

efficiency and/or reductionsin operating costs of waste management. Cost
reduction is certainly an objective of any well-run business. However,
the firm's capital resourcesmay be prioritizedtowards enhancing future
revenues (e.g., moving into new lines of business, expanding plant
capacity, or acquiring other companies,rather than towards cutting
- 184 -
current costs). If this is the case, then a sound waste reduction project
could be postponed until the next capital budgeting period. It is then up
to the project sponsor to ensure that the project is reconsideredat that
time.
4.8 Measurement of Waste Reduction
Having implementedwaste minimizationalternatives,it is important to

documenthow successfulthe alternativesare. You may be able to measure
your success by real benefits such as savings in the costs of waste
disposal or raw materials (see Section 4.7). However, a more analytical
approach to monitor waste reduction is to calculate percentage reduction
based on productionas follows:
WR = ( W _ W2 ]/W1 ) X 100Z
P1 P2 P1
where,
WR=percentage of waste reduction

W1= waste generated in year "1"
P1= production output in year "1"
W2= waste generated in year "2"
P2= production output in year "2".
Example:
During 1985 a process generated 50,000 kilograms of waste and produced

500,000 kilograms of product. During 1986, some process modifications
were made to reduce waste and improve efficiency, so that 60,000 kilograms
of waste were generated,but the process produced 800,000 kilograms of
product.
W1= 50,000 kg P1= 500,000 kg

W2= 60,000 kg P2= 800,000 kg
WR= (((50160)- (500(800))t (50/60) X 10O
WR= 25 percent waste reduction
4.9 References 4.1-4.8
Fromm, C. H., and M. Callahan. 1986. Waste reduction audit procedure: A

Methodolgy for Assessment and Screening of Waste MinimizationOptions.
Conference Precedingsat the HazardousMaterials Control Research
Institute,4-6 March, Atlanta, Georgia.
Turman, C. E. Hazardous Waste Control Through Source Reduction.

- 185 -
4.10 Bibliography4.1-4.8
Campbell, Monica E., and William M. Glen. 1982. Profit From Pollution
Prevention - A Guide to IndustrialWaste Reduction and Recycling.
Toronto, Ontario, Canada: Pollution Probe Foundation.
Congress of the United States. 1986. Serious Reduction of Hazardous

Waste. Washington, D.C.: Office of TechnologyAssessment.
Huisingh, Donald, et al. 1985. Profits of Pollution Prevention - A

Compendiumof North Carolina Case Studies in Resource Conversationand
Waste Reduction. Pollution PreventionPays Program. Raleigh, North
Carolina: Department of Natural Resources and Community Development.
Huisingh, Donald, et al. 1985. Proven Profits from Pollution Prevention-

Case Studies in Resource Conservationand Waste Reduction.Washington,
D.C.: Institute for Self-Reliance.
Personal communicationwith Dr. Bill Bibb, Director of Research and Waste

Management Division, Departmentof Energy, Oak Ridge Operations,Oak
Ridge, Tennessee.
Sarokin,David J., et al. 1985. Cutting ChemicalWastes-What 29 Organic

Chemical Plants are Doing to Reduce HazardousWastes. New York: INFORM.
Shanghai Resource Recovery and UtilizationCompany. 1984. Resource

recovery and utilization in Shanghai, edited by C.G. Gunnerson.Paper
presented at the InternationalResource Recovery and Utilization
Seminar, November, Shanghai,Peoples Republic of China.
U.S. Department of Energy. 1986. Waste Minimization: Less is Better.

Draft. Oak Ridge, Tennessee: Waste ManagementTechnologyDivision.
U.S. EnvironmentalProtectionAgency. 1986. Meeting hazardous waste

requirementsfor metal finishers. Seminarmaterials.
- 186 -
ANNEX 4A - Cost/BenefitAnalyses of Waste Minimization
The following two examples illustratehow waste generators treat the

cost/benefitanalysis of waste minimizationsstrategies. In each case, the
treatment of the prospect were developed first, and the analysis focused on the
resulting economic feasibility.
Example 1. Secondary Solvent Recovery
A resin compounding operationuses 1,1,1-trichloroethane solvent for equipment

cleaning. The present configurationuses a single stage atmosphere still for
solvent recovery. The still recovers 92 percent of 3,455 lbs. of spent solvent
per day. The still bottoms, which contain 20 percent solids by weight, are
sent to a facility for solidificationprior to landfilling.
The company is investigatingthe feasibilityof adding a secondary recovery

system to produce a nearly solvent-free,"dry" cake consistingof filler solids
and polymerized resin.
The current and planned solvent recycling scheme is depicted in the lock flow
diagram in Figure 4A-1. For secondary recovery, a scraped-drumevaporatoris
being investigated. The equipment list with pertinent technical and cost
information is presented in Table 4A-1. Important operating cost parameters
are presented in Table 4A-2.
A fixed-costdiscounted cash-flow analysis,which assumes no inflation and no

change in the real relationshipsamong costs, results in an internal rate of
return of 28 percent and a payback period of 3.3 years for this project. The
present Accelerated Cost Recovery Schedulel (ACRS) is assumed to apply for
equipment depreciation. The half of the installed cost is assumed to be met
with retained earnings; the other half is financed over 5 years at a real cost
of capital of 6.67 percent (12 percent nominal rate of interestwith 5 percent
inflation). The unit has an assumed operating life of 10 years and no salvage
value. Project cash flows under these assumptionsare displayed in Table 4A-3.
Table 4A-4 shows project cash flows under the same set of assumptions,but
with no account taken of savings through avoided disposal costs. The internal
rate of return has fallen to 8.7 percent, and the payback period has increased
to nearly six years. On the basis of recovered solvent alone, there is
apparently little justificationfor recoveringthe 8 percent of solvent
remaining after distillation. However, the presence of significantavoided
1/ Under ACRS, the equipment portion of a capital investmentmay be

completelydepreciated over 5 years beginningwith the first (whole or
partial) year of operation. The yearly allowable amounts are 15, 21, 21,
21, and 22 percent.
- 187 -
FIGURE 4A-1
Block Flow Diagram and Mass Balance for Solvent Recovery System
EQUIPMENT
PROCESS
CLEANING
.~~~~~~~~~~~~~~~
r;
STILL)
(ATMOSPHERIC l
|- + EXISTING
PLANNED
SECONDARY
RECOVERY
(SCRAPED
DRUMEVAPORATOR)
TOLANDFILL
Stream 1 2 3 4 5
Solvent 3,455 270 27 243 3,185
Resin 30 30 30 0 0
Rller 76 76 76 0 0
Total,lb/day 3,551 376 133 243 3.185
Source:Butler,D.,CT.Timm,C. Fromm.1986. Justificationof WasteReductionProjectsby Comprehensive

Cost-BenefitAnalysis.Washington,D.C.:Jacobs EngineeringGroup, Inc.
- 188 -
TABLE 4A-l
Secondary Solvent Recovery System

Equipment Data and Cost Information
Service Description Delivered Cost
Feed Pump 10 gph, gear type

1/4 HP, Hastelloy C casing,
Teflon gears $ 620
Scraped Drum Evaporator 10,000 BTU/hr, steam heated

1 HP drive, double 6a0 x 8a
drums (titanium),Teflon coated
housing $34,000
Condenser 10,000 BTU/hr, 3.5 ft2

graphiteblock $ 3,000
Receiver Tank 100 gal capacity $ 1,800
Mixer 1/4 HP $ 600
Discharge Pump 10 gpm, 3/4 HP, Teflon-coated

casing and impeller,magnetic-
coupled $ 950
$40,970
Piping and Instrumentation $ 2,000
Engineering,Design and Procurement (in-house) 8,600
InstallationLabor and Materials 12,000
DEPRECIABLE FIXED CAPITAL INVESTMENT $63,570
Allowance for Unforseen/CashRequirements 6,000
TOTAL CAPITAL COST $69,570
Source: Butler, D., C. Timm, and C. Fromm. 1986. Justificationof Waste

Reduction Projects by ComprehensiveCost-BenefitAnalysis. Washington, D.C.:
Jacobs Engineering Group, Inc.
- 189 -
TABLE4A-2
Secondary Solvent Recovery System

Summary of Operating Parametersand Costs
Element Rate Unit Cost Annual Cost
Solvent Recovered 60,750 lb/yr $ 0.38/lb $23,085
Inhibitor Makeup 1,814 lblyr $ 1.02/lb 1,850
Utilities (includes steam,

cooling water and
electricity) 240
Operating Labor and

Supervision 1.5 hr/day $16,00/hr (burdened) 6,000
Maintenance and Spare Parts 6.0Z of capital cost 4,250
Waste Disposal
without secondary recovery 94,000 lb/yr $ 0.15/lb $14,100
with secondary recovery 33,250 lb/yr $ 0.04/lb $ 1,330

TABLE 4A-3
Scraped-drumEvapOrStor
19s6 1987 1988 1969 1990 1991 1992 1993 1994 1996
(1) (2) (3) _ (4) (s) (e) (7n La) (9) (10)
Gross savings:
Solvent recovered 8 11638 t 23075 S 23075 S 23075 S 23076 S 23075 S 23075 S 23075 3 23075 523076
Avoideddisposal 63ss 12775 12775 12776 12776 12776 12776 12775 12776 12775
Total savings S 17926 * 36850 $ 35860 5 35850 3 36850 3 36860 2 36860 * 36860 3 36860 3 36860
Operatingcosts:
Feedstock/power 3 100 8 200 3 200 S 200 3 200 3 200 * 200 3 200 3 200 S 200
Feedstock/steam 20 40 40 40 40 40 40 40 40 40
Inhibitor 926 1850 1860 1850 1850 1850 1850 1860 1sso 1850
Labor 3000 8000 6000 8000 8000 8000 6000 6000 8000 6000
Maintenance 2126 4250 4260 4260 4250 4260 4260 4260 4260 4260
Total cost S 6170 3 12340 5 12340 3 12340 3 12340 3 12340 3 12340 S 12340 S 12340 S 12340
Operating income S 11766 3 23510 S 23610 S 23610 S 23510 S 23510 3 23610 S 23610 S 23510 S 23610 C
Less:
Cost of working capital 179 369 369 369 369 369 359 369 369 369
Depreciation 9369 13102 13102 13102 13728 0 0 0 0 0
Interestexpense 2131 1710 1287 789 281 0 0 0 0 0
Taxable income S 88 3 8340 S 8783 S 9281 3 9145 S 23152 S 23152 S 23152 3 23152 * 23152
Less:
Tax liability 43 4170 4391 4630 4572 11576 11676 11576 11576 11578
Post tax income S 43 S 4170 s 4391 * 4630 S 4572 3 11576 3 11576 3 11576 S 11676 11576
Add back depreciation 9359 13102 13102 13102 13726 0 0 0 0 0

Add back tax credits 8687 0 0 0 0 0 0 0 0 0
Post tax cast flow * 16989 3 17272 S 17493 * 17732 S 18298 S 11676 S 11576 3 11578 S 11676 * 11676
Cumulativecash flow S 16989 S 33241 S 50734 * 88466 S 88764 3 98340 3109916 3121492 3133067 s144843
TABLE4A-3 (continued)
1986 1987 1968 1969 19 1991 10 190 1994 196

(1) (2) _(3) (4) (S) (a) (7) (a) (9) (101
Less:
Equity payment 34785 0 0 0 0 0 0 0 0 0
Principal repayment 6070 8491 8934 7412 7920 0 0 0 0 0
Net cash flow 3-24885 S 10781 3 106B0 f 10321 S 10379 S 11576 S 11576 S 11578 S 11578 3 11578
Real cumulativecash flow 8-24885 S-14104 3 -3645 3 6776 S 17165 * 28731 S 40308 S 51882 S 83458 3 75034
For the internalrate of

return (IRR)
Operating income S 11755 S 23510 3 23610 2 23610 S23510 * 23510 S 23510 S 23510 3 23510 S 23510
Depreciation 9359 13102 13102 13102 13726 0 0 0 0 O
Taxable income S 2217 3 10060 * 10050 3 10060 * 9426 3 23152 S 23152 S 23162 3 23152 3 23152
Less tax liability 1109 5026 6026 6026 4713 11676 11676 11576 11676 11576
After tax income I 1109 3 6026 3 6026 2 5025 3 4713 * 11576 3 11578 3 11576 3 11578 3 11576

Add back tax crdits 6587 0 0 0 0 0 0 0 0
Post tax net cash flow S 17036 3 18127 3 18127 * 18127 S 18439 * 11576 3 11576 3 11576 3 11576 3 11576
Internal rate of return= 28.48X

Payback period = 3.3 years
Source: Butler, D., C. Timm, and C. Fromm. 1986. Justificationof Waste ReductionProjects by ComprehensiveCost-Benefit
Analysis. Washington,D.C.: Jacobs EngineeringGroup, Inc.
TABLE 4A-4
Evaporator w/o Disposal Saving.
1966 1987 1966 19e9 1990 1991 1992 1993 1994 1996
(1) (2) (3) (4) (6) (e) (?) (8) (9) (10)
Gross savings:
Solvent recovered I 11538 3 23076 3 23076 3 23076 * 23076 3 23076 3 23076 3 23076 3 23076 S 23076
Avoideddisposal 0 0 0 0 0 0 0 0 0 0
Total savings * 11538 3 23076 3 23076 S 23075 3 23076 S 23075 3 23075 S 23075 3 23075 3 23075
Operatingcosts:
Fedstock/power 3 100 S 200 S 200 3 200 3 200 3 200 * 200 S 200 S 200 S 200
Fedstock/steam 20 40 40 40 40 40 40 40 40 40
Inhibitor 926 1850 1860 1850 1sso 1sso 1850 1850 1850 1850
Labor 3000 6000 6000 6000 6000 6000 6000 6000 6000 8000
Maintenance 2126 4260 4250 4260 4260 4250 4250 4250 4250 4250
Total cost 3 6170 * 12340 3 12340 3 12340 3 12340 3 12340 3 12340 3 12340 312340 3 12340
Operatingincome * 5368 3 10736 3 10735 S 10736 3 10736 3 10736 S 10736 3 10735 310735 310735
Loss:
Depreciation 9359 13102 13102 13102 13726 0 0 0 0 0
Taxable income 3 -6237 3 -4308 s -3866 3 -3387 3 -3603 3 10604 3 10504 S 10504 3 10504 3 10504
Less:
Tax liability -3119 -2164 -1932 -1693 -1761 5262 5262 5262 5262 5252
Post tax income 3 -3119 3 -2154 3 -1932 3 -1693 3 -1751 3 5252 3 5252 3 5252 3 5262 3 6262
Add back doprociation 9369 13102 13102 13102 13726 0 0 0 0 0

Add back tax crdits 6567 0 0 0 0 0 0 0 0 0
Post tax cash flow 3 12807 S 10948 3 11170 3 11409 3 11976 3 5262 3 5252 3 5252 S 5252 S 5252
Cumulativecash flow * 12807 S 23766 3 34926 3 46334 3 68308 3 63660 3 68812 3 740e6 8 79317 3 84589
TABLE 4A-4 (continued)
196 1967 1988 1969 1990 1991 1992 1993 1994 1996
(1) (2) (3) (4) (s) (6) (7) (8) (9)_ (10)
Lose:
Equity payment 34786 0 0 0 0 0 0 0 0 0
Principal repayment 6070 8491 8934 7412 7920 0 0 0 0 0
Now cash flow 3-28047 3 4458 3 4236 3 3997 3 4055 3 5252 3 5262 3 6252 S 5262 3 5262
Real cumulativecash flow 3-28047 3-23590 8-19354 3-15367 3-11302 * -8049 S -797 * 4456 3 9707 3 14969
For the internalrate of

return (IRR)
Operating income 3 5368 S 10736 3 10736 3 10736 S 10735 3 10736 3 10735 3 10736 3 107536 3 10735
Depreciation 9369 13102 13102 13102 13726 0 0 0 0 0
Taxable income 3 -4106 3 -2698 3 -2698 3 -2698 3 -3222 3 10604 3 10604 3 10504 3 10604 S 10604
Lesstax liability -2063 -1299 -1299 -1299 -1611 6262 6262 6262 6262 6262
After tax income 3 -2063 3 -1299 3 -1299 3 -1299 * -1811 3 5262 3 5262 S 5252 S 5252 3 5252
Add back drepreciation 9359 13102 13102 13102 13726 0 0 0 0 0

Add back tax credits 8687 0 0 0 0 0 0 0 0 0
Post tax net cash flow 3 13873 3 11803 S 11803 3 11803 3 12116 S 6252 3 6262 3 6252 3 6262 3 5262
Internal rate of return= 8.86x

Source: Butler,D., C. Timm, and C. Fromm. 1986. Justificationof Waste ReductionProjects by ComprehensiveCost-Benefit
- 194 -
disposal costs makes the differencebetween a marginal (probablyunacceptable)

project and a project that can compete with other projects for capital funding.
Example 2. Retubing of Heat Exchanger
A paper mill facility is using a 8200-ft2 tubular-exchangeras an evaporator

for the forced circulationblack liquor evaporatorservice. Severe fouling
conditionsdictate daily water washings and an average of four shutdownsa year
for a hydroblasting (high pressure water jet cleaning) of tubes.
The company has tested electropolishedtubes in this service. The test data
indicate that while daily washings may still be necessary, the cleaning
frequency can be reduced to once a year. The company is now set to evaluate
the economic feasibilityof retubing. Initial analyses are based on cleaning
cost savings alone (i.e., they ignore savings in steam and pumping costs).
Since there is a spare unit, there is no loss of production. Basic parameters
are summarized in Table 4A-5.
As in Example 1, a fixed-costdiscounted cash-flow analysis is conducted to

determine the internal rate of return and payback period for this project.
Assumptions about project financing are the same: half of the money is
borrowed over 5 years at a real rate of interest of 6.67Z and the other half is
covered by the company's retained earnings. Again, the Accelerated Cost
Recovery Schedule (ACRS) is assumed in effect for equipment depreciation,and
the investment tax credit is taken. The new tubes are assumed to last 15 years
before requiring replacements. Salvage value is assumed to be zero.
The cash flows generatedby the proposed retubingproject are found in Figure
3. Under the stated assumptions,the project has an internal rate of return of
9.94Z and a payback period of 6.3 years. The real cumulative cash flow does
not become positive until the ninth year. These are indicationsof a marginal
project. Based on this analysis the acceptabilityof retubing the heat
exchangerwould to some degree depend on the ability of the facility to absorb
the deficit cash generationuntil the project's later years. However,
inclusion of avoided steam and pumping costs should enhance the project
economics considerably. In addition, intangiblessuch as reduced worker
exposurehave not been evaluated. On the basis of avoided cleaning costs
alone, this project comes close to being feasible. (See Table 4A-4, Table 4A-5
and Table 4A-6).
Source for Annex 4A: Butler, D., C. Timm, and C. Fromm. 1986. Justification
of Waste Reduction Projects by ComprehensiveCost-BenefitAnalysis.
Washington, D.C.: Jacobs EngineeringGroup, Inc.
- 195 -
TABLE 4A-5
Retubing of Heat Exchanger

Summary of Technical and Economic Parameters
Parameter Description
Heat Exchanger Long tube vertical evaporator,8200 ft2,

fixed tubesheet,800 tubes, 1.5" OD X 0.059f
wall, 26 ft-long bundle, 316 SS.
Cost to Retube $80,000

Includes cost of material (316 stainless
electropolishedtubes: Tubec tubes - Avesta
Stainless Co.), shop and field labor,
freight.
Cost of Cleaning $4,200

(single occurrence) Includes shutdown,disassemblyand setup,
hydroblasting,re-assemblyand cleanup,waste
handling and generalladministrative
indirect
costs.
The wastes are incineratedon-site using a

conventionalkraft mill recovery furnace.
Savings in Steam See Note
Savings in Pumping Costs See Note
Note: These costs were not included in the analysis in order to isolate the
effect of cleanup costs. Energy cost savings can be substantialand
must be included in a comprehensiveproject analysis.

TABLE4A-6
Retubing with El-ctropolish.d Tube*
1986 1987 1088 1989 1090 1901 1902 1998 1994 1906
(1) (2) t3) (4) (6) (a) (7) (8) (9) (10)
Cross savings:
Disassembly I 838 3 2560 3 2650 3 2650 3 2650 3 2660 S 2660 3 2660 3 2650 S 2660
Hydroblasting 1200 4800 4800 4800 4800 4800 4800 4800 4800 4800
Assembly 6e3 2260 2260 2260 2250 2260 2260 2250 2260 2260
Filtration 188 760 750 760 750 760 760 760 760 750
Disposal 0 0 0 0 0 0 0 0 0 0
Indirects 563 2260 2250 2250 2260 2250 2260 2260 2260 2250
Total Savings * 3150 3 12600 S 12800 3 12600 S 12600 S 12600 3 12600 3 12600 3 12600 3 12800
Operating income 3 3150 3 12600 3 12800 3 12600 3 12600 3 12800 S 12600 312600 3 12800 S 12600
Lese:
Depreciation 11748 18448 18448 18448 17231 0 0 0 0 0
Taxable income 3-10094 3 -8500 3 -5937 S -5330 3 -5488 3 12375 3 12474 S 12474 3 12474 3 12474
Less:
Tax liability -5047 -3250 -2968 -2868 -2733 6188 6237 6237 8237 8237
Post tax income 3 -6047 S -3260 S -2968 3 -2886 S -2733 3 8188 3 6237 S 8237 S 6237 3 8237

Add back tax crdits 8244 0 0 0 0 0 0 0 0 0
Post tax cash flow 3 14948 S 13198 3 13479 3 13783 3 14498 3 8188 3 8237 3 8237 S 6237 36237
Cumulativecash flow 3 14946 3 28144 3 41623 3 56408 3 89903 3 76091 3 82328 3 88566 3 94802 3101039
Loss:
Equity payment 46800 0 0 0 0 0 0 0 0 0
Principal ropayment 3911 8224 8787 9394 10041 5278 0 0 0 0
Net cash flow 8-34566 3 4974 3 4892 3 4389 3 4467 3 911 3 8237 3 6237 3 8237 S 6237
TABLE 4A-6 (continued)
1966 1987 1988 1969 1990 1991 1992 1993 1994 1996
tl) (21 (3) (4) (6) (a) (7n (8) U92 (10)
cash flow 3-34565 3-29S91 S-24899 8-20510 3-16053 8-15142 3 -8905 s -2e88 3 3659 3 9806
Real cumulative
For th- internalrats of

return (IRR)
3 126000 s 128000 s 12800 3 12800 * 12800 3 12800 3 12600 * 12800

Operating income S 3150 * 12600
32 126 126 126 126 126 126 126 128 126
Cost of workingcapital
11748 16448 16448 16448 17231 0 0 0 0 0
Depreciation
3 -8830 3 -3974 * -3974 s -3974 3 -4757 3 12474 s 12474 3 12474 s 12474 3 12474
Taxable income
-4315 -1987 -1987 -1987 -2378 6237 6237 8237 8237 6237
Loss tax liability
S -4315 3 -1987 3 -1987 3 -1987 3 -2378 3 6237 s 6237 3 6237 3 6237 3 6237
After tax income
11748 18448 16448 16448 17231 0 0 0 0 0
Add back depreciation
8244 0 0 0 0 0 0 0 0 0
Add back tax crodits
3 14461 3 14461 S 14461 3 14852 3 6237 3 6237 3 6237 3 6237 s 6237
Post tax net cash flow 3 15678
Internal rate of return= 9.94%

Source: Butler,D., C. Timm, and C. Fromm. 1986. Justificationof Waste Reduction Projects by ComprehensiveCost-Benefit
- 198 -
ANNEX 4B - Examples of SuccessfulWaste MinimizationPrograms
Examples of SuccessfulWaste MinimizationPrograms
o Allied Chemical Corporation of Metropolis, Illinois, recycled its waste

calcium fluoride into the productionof anhydrous hydrofluoricacid at
another facility. The project required a capital outlay of $4.3 million
and resulted in the recyclingof 1,000 cubic yards per month. Annual cost
savings came to $1.0 million, giving a project payback of about 4.5 years
(Huisinghet al. 1985).
o Borden Chemical Co. of Fremont, California,was able to reduce its

phenolic resin waste by 95 percent through filter rinse and reuse of
phenolic resin from the rinsate. The company also implementedtank
rinsing in 2 stages and set up a program to instruct operating personnel
about the importanceof waste reduction. Capital outlay was minimal
(Huisingh et al. 1985).
o Texagulf of Saltville,Virginia, makers of defluorinatedphosphate,

installed a closed-looprecycling system to remove inorganic fluorides
from its process water discharge stream. The system reduced wastewater
volume by 280,000 gallons per day, resulting in an annual cost savings of
$2 million and a payback in one year (Huisinghet al. 1985).
o Intel Corporationof Albuquerque,New Mexico, installed an in-line acid

neutralizationunit for their hydrofluoricacid waste. The company
realized a payback in 8 months by avoiding the generation of 601 tons of
hydrofluoricacid waste which they had previously shipped to California
for treatment and disposal (JacobsEngineering1986).
o Monsanto Corp. in Baxley, Georgia,was able to find a market for their

sodium hydroxide waste as a chemical neutralizer. No longer burdened with
the cost disposal, the company is saving $400,000annually (Sobrino1985).
O United Globe Corporation,a furnituremanufacturerin Lexington, North

Carolina, turned in 1982 to incinerationof process wastewater solids and
solventwastes to produce process steam. The project involved an outlay
of $1.5 million and paid back in less than 3 years on an annual savings of
$905,000 (Huisingh et al. 1985).
o Lumberton Dyeing and Finishing Co., a textile firm in Lumberton,North

Carolina, modified their process by installinga counterflowheat recovery
system to heat process water with exhaust and to precipitate out
hydrocarbon pollutants. The system had a payback of five months (Campbell
and Glenn 1982).
o Numerous solvent-usingcompanieshave installed distillationunits and

carbon adsorption systems to reduce solventwaste and vapor emissions.
Some also burn spent solvents for heat recovery. In all, 22 of the 116
companies examined practiced a form of solvent recovery/reuse. Riker
Laboratoriesof Northridge, California,a pharmaceuticalsdivision of 3M
Corporation,was able to eliminate 24 tons of their organic-basedsolvent
waste per year by modifying their process to accept water-based solvent
- 199 -
for tablet coating (Garrison1985). Companies such as Fisher Body of

Lansing, Michigan, and CaterpillarTractor Co. in Mossville, Illinois,
have significantlyreduced solventwaste by switchingto electrocoating
and water-borne paints (Campbelland Glenn 1982).
O At DuPont's petrochemicalsfacility in Victoria, Texas, the use of a new

process to produce adiponitrile(ADN) eliminatedone intermediate.
Wastewaterwas reduced by 50 percent (400 gallons per minute).
O DuPont's petrochemicalsfacility in Sabine, Texas, practices distillation

of waste for recovery of chemical inputs to other processes and
subsequentlyincineratesthe distillationresidues to achieve an 80
percent reduction in hazardous waste. The facility also recoversand
sells alumina instead of disposing of it off site.
o At DuPont's Cape Fear plant, cobalt is recoveredfrom one process for

reformulationas a catalyst in the dimethyl terephthalate(DMT)
manufacturingprocess. In addition, raw materials are recovered out of
by-product streams from DMT production,and off-gases are burned to
generateheat. The facilityhas also switched to the use of safer
solvents.
* Other measures taken by DuPont include (League of Women Voters of

Massachusetts1985):
- Sale of waste ferric chloride instead of ocean dumping
* Pre-treatmentof waste aluminum oxide for sale to recycler
* Conversion of waste HCl into chlorine
o Type of industry - AutomobileMirror Manufacturer

Name - Dominion Automotive Industries,Inc.
Location - Sevierville, Tennessee
Description - Dominion AutomotiveIndustriesmanufacturesmirrors for

automobilesand small trucks. Prior to an analysis of their production
process and subsequentmodifications,they were prohibited from disposing
of their waste water in the local publicly owned waste water treatment
plant because of the hazardous constituents(organicsand heavy metals).
The company was spending approximately$60,000 US per year to transport
and dispose of waste water.
Waste Reduction Methods - House-keepingmethods were improved to keep the

organic contaminantsout of the waste water stream. Organic solvents,
primarily methylene chloride are shipped offsite for solvent reprocessing.
An ultrafiltrationunit and ion exchange unit were installed to remove
metals and other contaminants.
Waste Reduction Costs - $30,000 US
Payback period - 2 years

- 200 -
Annual Savings - $50,000
Other benefits - Dominion has segregatedits hazardous waste from other

non-hazardouswaste streams. The threat of environmentalcontaminationis
significantlylowered and the long term liability to the company is all
but eliminated.
Source - Personal CommunicationMr. Fred Valentich,EnvironmentalManager,

Dominion Automotive (Garrison1985).
o Type of Industry - Dye and Epoxy Resin

Name - CIBA-GEIGY
Location - Toms River, New Jersey
Description - The Toms River CIBA-GEIGYPlant has the capacity to produce

about 500 different products including dyes and epoxy resins. The plant
has the capacity to produce 220,000 and 105,000 pounds per day of dyes and
resin respectively. The plant used a significantnumber of organic
solvents in its manufacturingprocess as evidenced by over 100 air permits
filed with the New Jersey Departmentof EnvironmentalProtection. In its
anthraquinonedyes manufacturingprocess the company used a standard
process which relied on mercury as a catalyst. About 2,280 pounds of
mercury catalyst ended up in waste streams, the most significantof which
was 39,500 lbs of contaminatedmaterial.
Waste Reduction Methods - The Toms River Plant has institutedmany waste
reductionprojects but one stands out as superior. In 1983 a new process
was institutedat the plant which eliminatedthe need for mercury as a
catalyst in the manufacturingprocess. This process was developed by the
corporation'sresearch staff in Switzerland.
Waste Reduction Costs - Not Reported
Payback Period - Not Reported
Annual Savings - Not Reported
Other Benefits - Mercury is a particularlytoxic and persistent chemical

in the environment. Elimination of the use of the chemical is a major
benefit to the environmentand public health.
Source - INFORM (Campbelland Glenn 1982).
o Type of Industry - Power Tool Manufacturer

Name - Emerson Electric Company
Location - Murphy, North Carolina
Description - The Emerson Electric Company produces stationarypower

tools. Key steps in the finishingof the products are painting and metal
finishing. Manufacturinglines of interest include: an electrostatic
paint line, zinc electroplating,a paint stripping line and parts washing.
- 201 -
Waste ReductionMethods - Emerson Electric installed a modern automated

electroplatingprocess and replacedtheir organic solvent-basedpaint
system with an aqueous-basedanodic electrostaticimmersion system.
Because they installed the water-based system, Emerson has been able to
recover and reuse paint. Cost for raw materials has decreased $600,000US
per year. The company has also improved its house-keepingand general
waste management practices.
Waste Reduction Costs - $1,254,000
Payback Period - 1.2 years
Annual Savings - $998,000
Other Benefits - Emerson has implementeda wide variety of waste reduction

methods. Investedcosts are recovered in little over a year and the
financial benefits will continue to accrue thereafter.
Source - North Carolina PollutionPreventionPays Program (Kohl, Moses,

and Triplett 1984).
o Type of Industry - U.S. Government-OwnedResearch and ProductionFacility

Name - Department of Energy/OakRidge Operations (DOE/ORO)Location - Oak
Ridge, Tennessee.
Description - The Department of Energy Facilitiesat Oak Ridge

historicallyhave produced large volumes of both radioactiveand mixed
radioactiveand hazardous wastes. Rather than continuingto ignore waste
production as had always been the case in the past, the DOE site managers
recently instituteda waste reduction program which penalized generating
organizationsfor producing waste.
Waste Reduction Methods - In 1985 a cost recovery system was institutedby

charging the manufacturingand research organization$1.50 per gallon of
waste. This fee increased to $3.00 in October 1986. The facilityhas
implementednumerous waste reduction techniquesbut the results of only
two are reported here. In 1982 a process was developed to recover silver
from used photographicchemicals. The process has been refined and scaled
up to production level. Second, at one of the machining facilitiesa non-
hazardous water-based coolant (propyleneglycol and borax) was substituted
for an organic solvent-basedcoolant (tetrachloroethylene and mineral
oil).
Waste Reduction Costs - unavailable
Payback Period - unavailable
Annual Savings - $60,000 (for silver recoveryonly)
Other Benefits - The recent emphasis by this US GovernmentDepartment on

waste reduction is an indicationthat the governmentis willing to set an
example particularlyfor small and medium-sizedindustrieswhich are still
unaware of the economic and environmentalbenefits.
- 202 -
Source - Waste Management TechnologyDocument (Draft) (Huisingh,et al.

1985) and personal communicationwith Dr. Bill Bibb, Director of Research
and Waste Management Division DOE/ORO (Kohl, Moses, and Triplett 1984).
o Type of Industry - Leather Tanning

Name - Not Reported
Location - Italy
Description - Leather tanning is an age-old process which has continued to

improve. The applicationof new treatment technologieshas improved the
efficiency of tanning even more. In summary,the tanning process
involves:
1. soaking with salt to prevent bacterial degradation;

2. fleshing to remove unwanted remaining flesh and fat;
3. unhairing using a line and sodium sulphide solution;and
4. tanning using either the vegetable, chrome, or alum process.
Waste Reduction Method - This relates only to the unhairing operation and
recovery of salt and sulphide. Ultrafiltrationis the technology selected
to recover the make-up materials in this bath. The salts and sulphides
pass through a membrane while the contaminantssuch as solids, proteins
and oils do not. The membrane has a projected useful life of about three
years.
Waste Reduction Costs - $80,000 (1979)
Payback Period - 2.93 years (includingaccelerated equipment depreciation)
Annual Savings - New uses are being developed for the waste proteins and
solids generated in the tanning process. Use for these materials range
from foodstuffs to cosmetics.
Source - Pollution Probe Foundation (Leagueof Women Voters of

Massachusetts1985)
o Type of Industry - Auto Engine Remanufacture

Name - Vulcan Automotive Equipment Ltd
Location - Vancouver, B.C., Canada
Description - Vulcan Automotive remanufacturesused auto engines. As part

of the remanufacturingprocess, they clean the old block and parts prior
to reconstruction. The old cleaningprocess which they used involved the
wet application of caustic soda followedby scrubbing and rinsing. The
caustic sludge was stored on-site in tanks prior to off-site disposal.
Costs for disposal ranged from $15,000 to $18,000 per year.
Waste Reduction Methods - The company installed a new parts-cleaning

system. The two step process involvesheating the metal parts to remove
the volatile organic oil and greases. Second, the parts are sprayedwith
a high velocity stream of aluminum shot. The new process is more
efficient and less costly than the alkaline-basedprocess.
- 203 -
Waste Reduction Costs - $75,000 US
Payback Period - 2 years
Annual Savings - $41,000 US
Other Benefits - The installationof the new dry washing process has
eliminated the need for approximately48,000 gal/yr of water as well as
reduced the manpower requirementsfor the washing process.
Source - Institute for Local Self-Reliance(Huisingh,et al. 1985).
o Type of Industry - Electroplating

Name of Process - ProvidenceMethod
Location - Many
Problem - The majority of contaminatedwaste from electro-plating

facilitiesis caused by drag out. This leads to the generationof large
quantities of hazardous waste, but also to high treatment costs and high
raw materials cost. Typically in a batch system, drag-out can account for
between 50 per cent and 90 per cent of the chemical raw material use.
Solution - Process modificationdesigned to remove the majority of the

drag-out in one or two counter-flowtanks not connected to the final
flowing rinse tank resulted in final effluentwhich required at most pH
adjustment and which could then be dischargedto sewer. Volume of waste
requiringbatch treatmentwas reduced by up to 99 per cent.
Reduction in waste treatment costs - US $60,000 assuming conventional

treatmentmethod water flow of 36,000 gpd reduced to 10,000 gpd.
Other benefits - up to 50 per cent saving in process chemicals.
Source - USEPA - Meeting HazardousWaste Requirement for Metal Finishers

(1986).
The cases cited here may now be taken for granted by experiencedchemical
engineers as common yield-improvementmeasures, but each one has
contributedto significantwaste reductionwhile improvingprofitability.
Of the more than 115 cases of waste reductionwhich were examined, 29

included data on payback period. This informationis summarizedin Table
4B-l. As seen in the table, more than 80 percent of the 29 cases had
payback periods of less than 3 years, which indicates fairly rapid capital
recovery and suggests solid profitability. Of course, waste reduction
could be an unprofitableundertaking. One case was found where a process
modification resulted in a net annual cost to the company. However,
because the modificationhelped the company achieve regulatorycompliance
and improve its community relations,management indicated that the cost
was warranted.
- 204 -
TABLE 4B-1
Waste Reduction Project Payback Periods
Payback Period
(Years) Cases Percent
Under 1 16 55
1-2 6 21
2-3 2 7
3-4 3 10
Over 4 2 7
Total 29 100
Source: Jacobs Engineering. 1986. Washington, D.C.

- 205 -
References for Annex 4B
Huisingh, D. et al.. 1985. Proven Profit from Pollution Prevention.

Washington, D.C.: Institute for Local Self-Reliance.
Jacobs Engineering.1986. Private survey. Washington,D.C.
Sobrino, F. 1985. Resource recovery attracts attention of waste

generators. Chemical Market Reporter (November18).
Campbell, M., and W. Glenn. 1982. Profit from Pollution Prevention,

p.298. Toranto: Pollution Probe Foundation.
Garrison, L. S.. 1985. Dupont News 14(9): 1.
Kohl, J., P. Moses, and B. Triplet. 1984. Managing and Recycling

Solvents: North Carolina Practices,Facilitiesand Regulations,
Releigh, North Carolina: North Carolina State University, Industrial
Extension Service.
League of Women Voters of Massachusetts.1985. Waste Reduction: The

Untold Story. Proceedingsof conferenceat the National Academy of
SciencesConference Center, June 19-21, Woods Hole, Massachusetts.
Fromm, C. H., and M. Callahan. 1986. Waste reduction audit procedure:

A methodology for identification,assessmentand screening of waste
minimization options. HazardousMaterials Control Research Institute,
Paper from the 3rd National ConferenceProceedings,March 4-6, Atlanta,
Georgia.
- 206 -
ANNEX 4C - Bringing About Change in HazardousWaste Management
Written by Jerome Kohl, North Carolina State University, Raleigh,

North Carolina
Introduction
This chapter provides informationon North Carolina generatorsand some United

States experience in working with hazardous waste. Most of the experience is
North Carolina experience;however, some informationis presented on
California,Massachusetts,and New York practices.
The basic thesis is: (1) We have developed a hierarchy coveringwaste

management options, in this hierarchy eliminatinggenerationof the wastes is
our first choice and land disposal (burial)is last. Other disposal options
fall in between; (2) As a result of problemswith land disposal we recognize
that we need to bring about a change in the waste handling practices of our
waste generators; and (3) To bring about this change requires that we educate
the generators on alternativesavailable to them and the pros and cons of each
alternative and that we motivate them to make a change. This chapter describes
the options, North Carolina educationalmechanisms, and efforts at motivation
and our recommendations.
First, a little background on North Carolina, our hazardouswastes and their

regulation;and our hazardous waste treatment, storage,and disposal
facilities.
North Carolina,which is shown in perspectiveto Spain in Table 4C-1, manages

generation,treatment, storage, and disposal of its wastes under permits from
the United States EnvironmentalProtectionAgency (USEPA). North Carolina
Regulations cannot be less strict than those of EPA by EPA rule and cannot be
more strict by State Law. So the State Regulations parallel those of the EPA.
Enforcement is by a Solid and Hazardous Waste Management Branch of the
Department of Human Resources. We also have a Pollution PreventionPays (PPP)
group in the EnvironmentalManagementDivision of the Department of Natural
Resources and Community Development (NRCD). NRCD enforces air and water
pollution regulations.
North Carolina has a "Governor'sWaste Management Board" which fosters public

education and has certain authority in case a company seeking to set up a new
treating or disposal facility is in disagreementwith a local authority on
local charges (this situationhas not yet arisen). A two-year-old "Waste
Management Commission' overseas is the establishmentof the needed facilities.
This multiplicity of interestedagencies in different departmentsleads to
confusion and competition.
North Carolina generatorscomprise private industriesoften owned out of state

(and out of country); Federal installationsincludingmany military bases;
state and local institutions,including schools,prisons, and hospitals.
- 207 -
TABLE 4C-1
A Perspective
Area in Sq. Miles Population
Spain 195,000 34,000,000
USA 3,000,000 226,545,000
Vizcaya 853 1,200,000
North Carolina 49,000 6,000,000
Bilbao 433,000
Raleigh 300,000
- 208 -
Bringing About Change
PsychologicalFactors Involved in Change
The purpose of this Annex is to provide information on how we in North Carolina

have helped people and organizations to improve their operations in regard to
production and disposal of their hazardous wastes through better management and
recycling. Improving here meant getting individuals and organizations to do
things differently. It is well known that such changes do not occur easily or
naturally. People and organizations have a strong tendency to continue doing
things the way they are used to doing them. If changes are to be made, it is
necessary that persons and groups be well-informed, be well-motivated, be
cooperative and have a positive attitude toward the new ideas. These are all
psychological factors. Changes are not likely to be brought about by giving
orders or by an appeal to the good intentions of people. Changing the behavior
of people in work organizations is a difficult task that requires considerable
thought and planning even though it seems perfectly clear that such changes
will benefit everyone. Creating change in an organization requires a change
agent, that is, a person who will see to it that the conditions necessary for
change are established. That person cannot bring about change directly. He or
she must do it through people.
Change Agent -----> Supervisors -----> Workers -----> Change
Here are some suggestions that should help in bringing about desired changes.
(1) In influencing people to change their attitudes and behavior, we should

keep in mind the following:
(a) The way people perform or behave results from two major factors --
motivation and ability. They not only must want to do something,
they must know how, if things are to happen. Neither motivation nor
ability by itself is enough. If we wrote this idea in mathematical
form, it might look like this:
P = M X A.
P is performance, M is motivation and A is ability. Note that the

relationship between M and A is multiplicative. If either M or A is
zero, nothing will happen. Neither high ability with low motivation
nor low ability with high motivation is likely to be very productive.
(b) People are goal oriented in their behavior. They do things because
it will make them better off in some sense. The fact that you may
not understand or approve of that reason does not matter except that
if you do not understand their goals, you will probably not be
effective in influencing them. It is also worth remembering that
personal goals are often different from organizational goals.
(c) While we tend to think of people as individuals, the social forces in

their behavior are extremely important. People do things because of
what other people think or do. Hence, we have to plan our operations
- 209 -
so as to affect people as groups and not just individuals. A working

organizationis not merely a collectionof individuals;it is a
social system. That means that any change in operation that one
person makes will affect many other persons and they will react to
that change.
(2) The following are some ways of influencingor changingbehavior with brief
comments on their effectiveness:
(a) Giving orders for desired behavior often causes resentment. This
procedure overlooks levels of motivation and ability and usually
deals with people as individualsand ignores social factors.
(b) The use of incentivesor rewards is a necessary condition. Usually

we think of financial incentivesonly, but other important incentives
are promotion, praise, and social approval. An incentivewill be of
no value if it is not desired by the person. Giving awards to a few
only may result in animosity toward management and other workers.
tc) Procedural changes based on social and group factors are usually more
effective than those directed at individualsonly.
(d) Involving the employee in the decision to make changes and in the
process of making changes increasesthe chance that he will be
cooperativeand will contributeeffectively to improving the process.
People like to have control over their own behavior even at work.
(e) Make full use of the employee'sknowledge and his ability to think;
treating employees like mental incompetentsleads to resentment.
Employees usually are the source of the best ideas.
(f) The cooperation and support of all levels of management is important

and necessary, if changes are to be made. Make sure management is
informed and supportive.
(3) In planning change it is a good idea to make some assessmentof the forces
in your organizationthat are for the change and those likely to be opposed to
it. We call this "Force Field Analysis.' Examine all the forces in your
organization;try to determinewhether they are for or against the new
procedure and the amount of their support or opposition. As an example, these
forces might include -- Plant Manager, Safety Officer, Direct Supervisor,
Workers, Engineering,Purchasing. You might diagram these forces as follows in
Figure 4C-1:
- 210 -
FIGURE 4C-1
Force Field Analisis Diagram
For Change Aainst Change
Engineer Workers
0 <
Plant Manager Direct Supervisor
Safety Officer Purchasing
Consultant
O.-
- 211 -
You can see from this balance of forces, pro and con, that you will have some
problems in bringing about your change. While you seem to have power and
reason on your side, the forces against you might defeat you in the long run.
A careful analysis of all forces will give you guidance on how to proceed and
what tactics to use in achievingyour change.
Economics
One important factor motivating change in the manner of handling wastes is the
economic factor. In the case studies included in this paper, the motivation is
often economic. For each proposed change, an estimate of costs and savings
will need to be made so a payout can be determined.
Some of the lesser-knownincentivesinvolve actions by the State of North

Carolina and by the Federal Governmentto encourage companies to do something
to reduce hazards and to reduce the danger of groundwaterpollution.
Incentivesare offered by the Federal and State governmentsfor the following

reasons:
(i) To encourage compliancewith state and federal pollution abatement

requirements
(ii) To avoid or mitigate economic harm to industriesforced to comply with

pollution clean-up requirements
(iii) To help ensure that complyingcompanies are not at a competitive

disadvantageto non-complyingcompanies
The incentivesoffered by our governmentsinclude:
(i) Rapid amortizationof investments
(ii) Investmenttax credit
(iii) Deduction against franchise tax liability
(iv) Tax-exempt IndustrialDevelopment and Pollution Control Bonds
(v) Penalties as incentives:
(a) RCRA legislationand EPA policiesprohibit the EPA from approving or

recommendingto private parties any facilitiesthat have Category 1
violations.
(b) RCRA legislationand EPA policies require that penalties be large

enough to offset any economic gain from non-compliance.
(c) Normal business expenses through complianceare tax deductiblebut

penalty expenses are not tax deductible. For example, the cost of
buying new drums for a leaky drums penalty is not tax deductible.
- 212 -
(d) The cost of lost goodwill is immeasurablein terms of lost customers,

etc.
The North Carolina state incentivescurrently in existence are:
(i) Tax Exempt IndustrialDevelopmentand Pollution Control Bonds (N.C.

General Statute 159c-2) must meet certain criteria and be approved by
appropriatelocal and state authorities.
(ii) Exclusion from local property tax (N.C. General Statute 105-275) of
property used to abate water pollution or to recycle or provide resource
recovery of solid waste.
(iii) Reduction of franchise tax (N.C. General Statute 102-122) for costs of
property used as in (ii) above.
(iv) Sixty-monthamortization (N.C. General Statute 105-122b) on costs of

property used as in (ii) above.
Federal incentivesare:
(i) Tax-exemptbonds for water pollution control facilitiesand solid waste

disposal facilities.
Other economic incentivesto change include:
(i) The need to maintain and enhance the status of the company in the eyes of
the community and its customers.
(ii) Early payback of investmentor a satisfactoryreturn on the investment.
Hierarchy
There are a variety of options for managing any hazardous waste. As an example
this chapter uses electroplatingsludge. To reduce sludge production three are
options such as recycling,solidifyingor otherwise disposing of the sludge.
The factors determiningthe hierarchy include:
(i) Liability
Liability may be the most important considerationin a decision on how to

handle sludges. The RCRA "cradle to grave' philosophy and the lawsuits being
carried out under Superfund against electroplaters,who in the past legally
disposed of waste that must now be pulled out of a landfill and reburied, are
strong factors motivatingminimizing the use of landfills -- even hazardous
waste landfills. While it is difficult to assess a per day cost of this future
liability, it must be consideredin making decisions regarding dispositionof
sludges.
(ii) Regulations
Any actions are desirable that can be taken to minimize applicableregulations,

reduce the paperwork and record keeping.
- 213 -
(iii) Costs
In trying to assess the costs, for example,of paying someone to reuse a spent
solution or a sludge, one must balance this cost against the total disposal
cost and liability. A factor often not included in cost considerationis that
of liability insurance. This insurancecost should be factored in when the
waste is stored or disposed of in such a way that future liability could be
incurred.
(iv) Conservationof Resources
Chromium, nickel, and copper are all elements of limited supply. It is foolish
to take solids with high concentrationsof these metals and to mix these solids
with many other types of waste materials and then bury the mixture in a manner
that makes it difficult to ultimatelyretrieve the metals. From the long-term
point of view, it is in the best interestof electroplatersto minimize their
purchase of newly mined metals.
In light of the factors described above, we suggest that a hierarchy for

handling electroplatingsludge can be developedwhich will resembleFigure
4C-2. Note that we indicate that the most desirable option with the least
liability is changing the process andlor housekeepingto reduce or eliminate
sludge generation. We suggest that the poorest option with the greatest long-
term liability is the placement of solidifiedwaste in a landfill. Table 4C-2
summarizes the liability and economics of the various sludge handling methods.
Education - Spreading the Word
Due to its lack of treatment facilitiesand inability to overcome local

opposition to siting new facilities,North Carolina is trying to move its
hazardous waste generatorsup the hierarchy shown in Figure 4C-2. Table 4C-3
lists the techniquesused in North Carolina for informing generatorsof the
options available to them and the pros and cons of each option. An Advisory
Committee of Generators is used to help develop workshops and manuals and a
ConsultingBehavioralPsychologistprovides counsel on motivation. Table 4C-4
lists New York techniques. Californiauses the above ideas and has set up a
program to review manifests. If the manifest indicates that sludge was buried
that could have been recycled,the generator is told of his error and
instructedto change his ways to a new technique for which he is given
information. Massachusettsoffers a phone-in-for-helpsystem.
For example, working with S.E. chaptersof the Electroplatingand Surface

Finishing Society, two one-day meetings were organized on "ReducingMetal
Losses and Sludge Production in the ElectroplatingIndustry." For and from
these meetings a manual, "Managingand MinimizingHazardous Waste Metal
Sludges," (December1984, J. Kohl. and B. Triplett)was developed. Funding for
the workshops and manual came from the N.C. Legislature (via the Governor's
Waste Management Board). The Table of Contents of this manual is shown in
Tables 4C-5, and 4C-6, and 4C-7 are case studies taken from the manual.
Exhibitors (vendorsof equipment to electroplaters)were encouragedto
participate in the workshops. The manual includes a list of equipment
suppliers and El list of companies accepting electroplatingsludges and spent or
- 214 -
FIGURE4C-2
Options for Managing Electroplating Sludges
Greatest SolIdIfy
Wasteand Sendto SecureLandfill
Recycle-Recover
MetalValues
Outof Plant
Recycle-Recover
MetalValues
in Plant
ElIminate
Sludge
Production
Least C=
Least Greatest
DESIRABILIIY
- 215 -
TABLE 4C-2
Overview of Various Handling Alternativesfor Metal-ContainingWastes
Option Limitations Liability Economics
Improve housekeep- Management must be Reduced Little or not capi-

ing practices to amenable to proce- tal investment
minimize waste dural changes
generation
Change process to Process and manage- Greatly reduced Depends on

minimize or elimi- ment must be amen- or eliminated particular
nate waste genera- able to change situation
Recycle in-plant Capital for equip- Greatly reduced Depends on

ment, operating and or eliminated particular
maintenance situation
problems and
expenses
Recycle out-of- Concentrationlevels Greatly reduced, Process modifica-

plant of contaminantsin but: transportation expense,
solutions and tion, failure of transportation,
sludges,modifica- recycler, usually cheaper
tion of process may disposal of than landfilling
be necessary residue
Solidify - place Expense for solidi- Reduced, but: $25-$250per ton

in secure landfill fication process as transportation, for solidification,
well as for secure future site $85-$100per barrel
landfill problems for secure land-
filling
Secure landfill No free liquids Transportation; $85-s10Oper

future site barrel
problems
Solidify - place Delisting may be $25-$250per ton

in non-secure withdrawn; site
landfill problems
- 216 -
TABLE 4C-3
Generator Motivation
Motivating Action in North Carolina
Governor'sAward for Excellence in Waste Management
Pollution PreventionPays Matching Grants ($5,000)
RegulationsLimiting Placement of ElectroplatingSludge in

Landfills
Enforcement of Regulations - Fines
Other Motivating Factors
Rising Costs of Metals and Land Filling
Lack of Nearby Disposal Facilities
Concern over Liability from Land Filled Wastes
Fear by Employees of Hazards, Waste Responsibilities
Note: New York taxes generatorson a per ton basis according to the
mode of waste disposal employed.
- 217 -
TABLE 4C-4
Generator Education
New York
EnvironmentalFacilitiesCorp. - Not a regulatoryagency
InformationServices
Waste Exchange (particularlyunderwritescosts)
Assistancewith understandingregulations
Waste Stream Evaluationand Analysis - identificationof most

economicaloptions, evaluationof alternatives
Referral to outside consultants
Assistancewith tax free financing options for industrial

pollution control project
- 218 -
TABLE 4C-5
Managing and Minimizing Hazardous Waste Metal Sludge Manual, December 1984
Table of Contents
page
Introductory Acknowledgement and Notice i
Materials Introduction ii
Chapters 1 WHY CHANGE? 1

A. Psychological Factors Involved in Change 1
B. Liability 3
C. Economics 10
D. Hierarchy 12
2 NORTH CAROLINA RCRA REGULATIONS GOVERNING METAL

WASTES FROM THE ELECTROPLATING INDUSTRY 17
A. Introduction 17
B. Electroplating Sludges and Solutions
as Hazardous Waste 17
C. Basic Guidelines for Electroplating
Metal Waste Generators 17
D. Applicability of the Regulations to Various
Waste Handling Alternatives 20
3 MODIFICATIONS TO REDUCE THE TREATING AND RECOVERY LOAD 23

A. Leaks and Spills Reduction 23
B. Dragout Reduction 24
C. Scrap Reduction 25
D. Filter Choice 25
E. Personnel Training 25
F. Rinsing Techniques 26
G. Alternatives for Stripping and Bright-Dipping
Operations 28
4 RECOVERY EQUIPMENT 31
A. Evaporators 32
B. Ion Exchange 36
C. Electrolytic Metal Recovery 37
D. Electrodialysis Metal Recovery 38
E. Reverse Osmosis 39
F. Ultrafiltration 42
5 SALE OF METAL SLUDGES AND SOLUTIONS 43
Appendices A Delisting Metal Sludges 45

B Research in Progress 47
C Metal Content of North Carolina Electroplating Sludges 49
D Companies Accepting Electroplating Sludges and Spent
Solutions 51
E Hazardous Waste Landfills and Service Organizations 57
- 219 -
F Equipment Suppliers 60
G RCRA Information Sources 62
Tables 1.1 Overview of Various Handling Alternatives for Metal-

Containing Wastes 15
2.1 Hazardous Wastes from the Metal Finishing Industry 18
3.1 Economics of Staged Rinsing for One Set of Conditions 28
4.1 General Characteristics of Recovery Equipment for the
Electroplating Industry 33
5.1 Desirable Characteristics of Electroplating Metal
Wastes from the Recyler's Point-of-View 44
A.1 Overview of Delisting a RCRA Waste 46
C.1 Electroplating Sludges (F006-F008) Shipped Off-Site 50
C.2 Metal Content of 1982 North Carolina Electroplating
Sludges (F006-F008) 50
Figures 1.1 Options for Managing Electroplating Sludges 14

3.1 Effect of Added Rinse Stages on Water Use 27
G.1 Organization Chart-Solid and Hazardous Waste
Management Branch 66
G.2 North Carolina-Hazardous Waste Surveillance and
Enforcement Team 67
Case 4.1 Evaporator Case Study (Easco Hand Tools) 32

Studies 4.2 Evaporator Case Study (Eastern Plating) 35
4.3 Ion Exchange Case Study (Lufkin-Cooper Group) 36
4.4 Cation Exchange Case Study (Easco Hand Tools) 37
4.5 Reverse Osmosis Case Study (Acme-United Corporation) 40
4.6 Reverse Osmosis Case Study (Stanley Tools) 41
- 220 -
TABLE 4C-6
Evaporator Case Study
Company: Eastern Plating
Location: Newport, Tennessee
Contact: Roger Woods
Phone: (615) 623-0062
Purpose: Recover Ni, Cr+3 , Cr+6
Motivation: (1) Economic - less expensive to operator

than any other system
(2) The evaporator can put every thing back

in tank
(3) Eliminates necessity for landfilling or

sewering waste
Equipment
Supplier: Techmatic, Inc.
Payback: 6 weeks - 6 months
Comments: Almost maintenance free; inexpensive to

operator
Reported: Personal communications, August 1984
Source: Kohl, J., and B. Triplett. 1984. Managing and Minimizing Hazardous
Waste Metal Sludges Manual. Prepared for workshop on "Reducing Metal
Losses and Sludge Production in the Electroplating Industry," December,
Raleigh, North Carolina.
- 221 -
TABLE 4C-7
Reverse Osmosis Case Study
Company: Stanley Tools
Location: 100 Stanley Road

Cheraw, South Carolina 29520
Contact: Mike Vannest
Phone: (803) 537-9311
Purpose: Nickel salts recovery
Motivation: Cost reduction
Equipment
Supplier: Osmonics
Payback: 1.3 years
Comments: Low maintenance, very positive experience
Reported: Personal communication, August 1984 to B.

Triplett
Source: Kohl, J., and B. Triplett. 1984. Managing and Minimizing Hazardous
Waste Metal Sludges Manual. Prepared for workshop on 'Reducing Metal Losses
and Sludge Production in the Electroplating Industry," December, Raleigh, North
Carolina.
- 222 -
surplus solutions. Tables 4C-8 and 4C-9 show a section of such a list and a
complementarytable.
Similar meetings have been developed and presented on Managing and Recycling
Solvents,Managing Used Oils, Managing and Recycling Solvents in the Furniture
Industry. Over 100 workshops have been developed and presented to hazardous
waste generatorsand small generatorsthroughoutNorth Carolina. For these
workshops,manuals and video tapes were developed. Industry specificprograms
and video tapes have been developed for dry cleaners, pesticide applicators,
and vehicle repair facilities.
We lack an objective,quantitativeevaluationof the results of applying the

techniquesdescribed in this Annex. Based on experience,small workshops
(30-40 participants)are recommendedwith generatorspresenting case studies as
speakers, and with plenty of time for discussion. Exhibition of equipment is
encouragedand exhibitors are offered 5 minutes on the program to explain their
product and its uses. Manuals should include case studies. The more "local"
the case study, the better. "In-plant"visits are arranged to enable
generatorsto see first hand good housekeepingand advanced recovery
techniques.
For an in-plantworkshop we use a company practicing a good waste management

technique and willing to "show-off"their practice to other companies. This
provides an opportunity for a prospect for change to see for himself what
works, to ask questions,to get pay back information. U.S. experiencewith
bringing about change in agriculturalprocesses has demonstratedthat trial
plots by farmers open for inspectionby their neighbors is the number one means
of bringing about change. Our feedback says that bibliographiesare not much
used and if prepared, should only list readily available publications.
Recommendationsfor a successfulworkshop and manual are shown in Figures 11
and Tables 4C-10 and 4C-11.
Conclusion
We strongly believe that education of generatorson available options is not

enough. Indeed some of our experiences,indicatethat knowledge of an option
such as sludge drying with a pay off under two years still will not lead to the
purchase of a sludge dryer. An additionalboost is often needed beyond
economic advantage or good pay off.
From our discussionswith generatorsand with supplierswe have found that a

waste generator is most likely to change his ways when he knows of a better
option, know that it will pay out in one or two years and when he is convinced
that his present practice could lead to a clash with the regulatorsor to a
possible liability. Figure 4C-3 illustratesthis point. When enforcementof
regulations is consistent,when there are indeed fines and prison sentences,
pollution abatement equipment sales rise. With faltering uncertain
enforcement,we experiencea reluctanceto change.
- 223 -
TABLE 4C-8
Equipment Suppliers
The following list was compiled through personal interviews, telephone

conversations and sales literature. The preparers of this list take no
responsibility for the list's completeness nor for the quality of services
offered by these firms.
Baker Brother/Systems Frederick Gumm ChemicaLlCompany

Post Office Box 707 1280 Wall Street, West Lyndhurst
Raeford, North Carolina 28376 New Jersey 07071
Phone: (919) 875-4169 Phone: (201) 460-7900
Contact: David Gibson, Manager Contact: Joe Cahill, Product Mgr.
Equipment: Electrodialysis Equipment and Supplies: Full line of
equipment and chemica]Lsfor electro and
Barnett-Hormberg, Inc. electroless plating
1709 East Boulevard
Charlotte, North Carolina 28203 Harshaw/Filtrol
Phone: (704) 332-1597 3915 D Valley Court
Contact: H. C. Martin Winston-Salem, North Carolina 27106
Equipment: Corrosion control linings, Phone: (1-800) 321-4802
air pollution control systems, Contact: Louis Gianelos
fiber glass tanks, portable Equipment: Evaporators
and fixed agitators, FRP grating,
structural members, heat ex- Innova Technology, Inc.
changers (steam and electric) 5170 126th Avenue,
Noth Clearwater, Florida 33520
Corning Glass Works Phone: (813) 577-3888
Corning Process Systems Contact: Ted Nohren
BF Plant Equipment: Chrome Napper
Big Flats, New York 14814
Phone: (607) 974-0280 JWI, Inc.
Contact: Raymond Baker 2155 112th Avenue
Equipment: Corning Evaporator Holland, MI 49423
Phone: (616) 772-9011
ECO-TEC Equipment: Sludge Dryers
925 Brock Road South
Toronto, Ontario, Canada LlW 2X9 Lancy International, Inc.
Phone: (416) 831-3400 Post Office Box 490
Contact: Mike Dejak Zelienople, Pennsylvania 16063
Equipment: Ion exchanger Phone: (412) 452-9360
Contact: James Knigh,t
Filtration Technology, Inc. Equipment: Electrolytic metal,
Post Office Box 31442 electrodialysis, ultrafilters,
Raleigh, North Carolina 27622 evaporators, etc.
Phone: (919) 787-3988
Contact: Jim Grantham
Equipment: Fluid filtration
TABLE 4C-9
Desirable Characteristics
of Electroplating
MetalWastesfromthe Recyl-r'sPoint-of-Vies
Capital Northland World

ANlon Atomorgic Assay cor n Macdermid Madison Chmi cal Resoures
Metals Chemicals Labe Ltd. ChemiCal Inc. Industries Company Company
wastes Sludges Sludges and Sludges, ReclaimAl Reclaimspent Sludges, Copper Sludges
Accepted soins, copper solutions, *tchants, solutions:Cu *tchants *tchants from
stripping cyanides acids, ferric etchants.,Cr circuit board
solns and chlorides solns.,Sn and industry
and cyanides aluminum Pb strippers,
materials solder condi-
tioner
Metals Cu, Cr, Sn, Cu, most base Cu, precious Same as Wastes Same as Wastes Cu, Zn Cu Cu, Sn, Ni,
Recovered Ni, precious metals, pre- metals, Accepted above Acceptedabove precious
metals clous metals cyanide metals
Required Generally Item basis, No % require-High Al con- Metal content Metal content 14 oz Cu/gal., No % require-r.,
metal 20% or higherX ment for Cu tent, indivi- not not applica- low level ment; mixture!-
Content higher of better bearing dually based applicable ble; accept parts of OK
Cu; 2-20% isolatedwaste materials; material various other metals
other metals streams a plus mixturesOK content amounts of (100 ppm)
waste
Other Sample size; Low amounts Sample size Sample size; Prefer to deal Wastes only Prefer low Fe, Sample: 2 lbs
Special 2 oz of As, Be, Pb 2 oz sludge, 1 pint with own cus- from circuit As, Pb dry cake or
Require- 100 ml tomers but board 1 gal. liquid
mnts liquid will consider industry; sludge
outside sample size:
sources 1 qt.
S Paymentfor S decisions Paymentfor Payment based Payment 28 Payment for Payment only Payment for
metals, based on Rh, Pt, Au, on Al content cents/gal.for Cu, Zn for Cu metals and
precious profit,cost Ag, Pd Cu, etchants, otchants with precious
metals, factors precious etc. low concentra- metals
penaltyfor metals tion of Fe, As,
undesirable and Pb
compounds
Northland World
Capital
CoW" Maedermid Madison Chemical Reources
Amlon Atomrgic Assay
Chemical Inc. Industries Company Company
Metals Chemicals Labs Ltd.
Seller or Depends on Seller pays Seller pays Charges for "Variable"

Transport Seller pays
recycl-r location and own trucking as to who
quantityof allowing transport and
pays
material credit for Cu 3 factors
Resalable Solid metal Basic Rejuvenated Copper and Copper

Product Ship to
chemicals spent zinc chemicals
overseas technical
grade metal solutions, chemicals
refineries
reclaimed
metals used
in new
plating
solutions
None Part B No RCRA Interim Part B

Permits None Part B Hazard
Permit, permits status
(Broker)
seeking a
delisted
status
- 226 -
TABLE 4C-10
Formula for a SuccessfulWorkshop on Minimizing ElectroplatingSludge
Work with a 10-20 member advisory committee,comprised

of suppliersand prospective attendees or speakers
Include exhibitors: give each 5 minutes on program
Help speakersdevelop good visuals and handouts
Limit presentationsto 10-20 minutes
Encourage and don't limit discussionand questions
Provide hourly breaks with fruit, juices, etc.
Emphasize case studies - preferably local
Include informationon motivating factors and pay back

- 227 -
TABLE 4C-11
Formula for a SuccessfulManual on MinimizingElectroplatingSludge
Work with an Advisory Committee of generators,

treaters, etc.
Emphasize Case Studies,preferably local
Include accurate, up-to-dateinformationon:
suppliers,transporters,recylers, incinerators,
buyers, landfills, services
Provide contacts for informationon regulations
Provide a complete, clear Table of Contents

- 228 -
FIGMRE4C-3
Implementing Change
Economic I
Justfficatlon I
I
Inertia_
Nt,
- 229 -
References Annex 4C
N.C. General Statute 159C-2.
N.C. General Statute 105-275.
N.C. General Statute 102-122.
N.C. General Statute 105-122(b).
For referencematerial on tax and other incentivesfor pollution abatement

equipment,contact Dr. Linda W. Little, Executive Director, Governor'sWaste
Management Board, 513 Albermarle Building, 325 N. Salisbury St., Raleigh, N.E.,
27611, USA, (919) 733-9020.
Note: The N.C. Pollution PreventionPays (PPP) Program offers assistanceto

small businesses and communitiesto find ways to reduce, recycle, and prevent
wastes before they become pollutants. The program offers the following
publications: 1) Pollution PreventionBibliographyby Industrial
Classification;2) Directory of N.C. Resource Recovery Firms; 3) Environmental
Auditing InformationPackage; 4) Accomplishmentsof N.C. Industries;and 5)
United nations Compendium of Low and Non-Waste Technologies. For access to the
PPP program contact:
Mr. Roger Schector, Director - PPP Program

Division of EnvironmentalManagement
Departmentof natural Resources and Community Development
Post Office Box 27687
Raleigh, North Carolina 27611
(919) 733-5083
- 230 -
CHAPTER 5 - Infrastructureof Hazardous Waste Management Systems
5.1' Introduction
The need for a hazardous waste management system begins directly upon
generationof waste and continues through all subsequent stages to final
treatment and disposal. This system is really a series of management
actions to control and contain the waste coordinationamong various
persons and groups of persons. In this simplest form, a hazardous waste
management system consists of three units:
o storage upon generation;
o collection/transportation;
and
o final treatment/disposal.
This chapter reviews the elements of an overall management system that are
applicableto onsite and offsite managementof hazardous waste.
5.2 Storage upon Generation
The first stage in this infrastructureis storingwaste after it is

generated. The waste generator needs to have a system to safely store
waste until it can be transferred for further storage, treatment,or
disposal. Typically, this storage is done in containers or bulk tanks.
Methods like surface impoundmentsare discussed in Chapter 7.3.1 on
disposal technologies. Which is used depends largely on how and where the
waste is generated and the physical state of the waste.
5.2.1 Containers
Containers offer the advantagesof being very portable, suitable for any
physical state of waste, and flexible as to means of filing. They can be
kept next to the waste generatingprocess until full, then easily moved to
a waste storage area awaiting further transfer.
Most containers are suitable for many types of waste, form liquids,
sludges to bulky solids. Containersmay be filled by any available
method, for example,pumping, shovelling,or tipping. Empty containers
which had contained raw material may be suitable for storing waste,
depending on the compatibilityof waste with the container and with any
residueswhich may be left in the container. Compatibilitywith the
container is important so that the container'sintegrity is not impaired.
For example, a plastic container should not be used to store solvent
waste. Care must be taken that residues from the container'sprevious
contentswill not react with the waste; example, a containerwhich had
contained cyanide salts should not be used for waste acid.
Disadvantagesof containersare:
(1) they are easily damaged and toppled;

- 231 -
(2) because they are easily moved and stacked,they accumLulateeasily and
may lead to over-storageat the waste producer's site; and
(3) large groups of stacked containersare difficult to inspect for leaks

and spills.
5.2.2 Tanks
Tanks are useful for accumulatingwastes that are easily handled by bulk
materials handling systems such as pipelines, shutes, or belt conveyors.
Tanks offer more rigid and integral containmentthan containersand are
easier to inspect for leaks and spills.
5.3 Collection/Transportation
5.3.1 Packaging/Labelling
All containersor tanks containingwaste destined for transportation

should be clearly labelledwith the type of waste and its hazards. The
packaging should be secure enough to prevent leaks, spills, and
vaporizationduring transport. Suggestedpackaging includes:
o wastes oils and solvents: 200 litre steel bung drums or steel tankers;
o solid or semi-solidorganic wastes: 200 litres steel clamp-lid drums;
o inorganic liquid wastes: 30,45 or 200 litre plastic cans or

polyethylenetanks; and
o inorganic solids and sludges: 200 litre steel or plastic clamp-lid

drums.
5.3.2 Paperwork Tracking System
Many countries have adopted a paperwork tracking or manifest system to

document the generationof a hazardouswaste, all the later processes that
it may go through, and offsite waste transportation. The paperwork
accompanies the waste shipmentand provides a record of waste movement
from the waste producer through each intermediatemanagement stage to
final treatment and disposal. The paperwork serves as a "chain of
custody" document. Every time the waste shipment changes hands, the
responsiblepersons sign the paperwork. Often the governmentregulatory
agency must receive a copy of the paperwork at crucial stages in the
transfer to monitor the transfer. The system in the State of Victoria,
Australia, is shown in Figure 5-1 (EPA 1985). (See Figures 5-1 and 5-2.)
5.3.3 Direct Transfer/CollectionStation
Waste may be transferredoffsite either directly or via a collectionor

transfer station. Direct transfer is economicalif a large enough
shipment can be sent from a single waste producer, or if a truck picks up
waste from more than one waste producer.
- 232 -
FIGURE 5-1
Australian EPA TransportationScheme
Am6
XL
Waste Producer - Transporter Waste Disposal
Waste Disposal
CERTIFICATE
1 Forwardedto the EPAby the WasteProducer.
CERTIFICATE
2 Retainedby the Waste Producer.
CERTIRCATE
3 Forwardedto the EPAby the DisposalSiteAttendant.
CERTIFICATE
4 Retainedby the DisposalSiteAttendant.
CERTIFICATE
5 Retainedby the WasteTronsporter.
Source:AustralianEnvironmentalProtectionAgency. 1985.Draft IndustrialWasteStrategy.Victoria,Melbourne.

- 233 -
FIGURE 5-2
Transport Certificate - AustralianEnvironmentalProtectionAgency
-PLEASE
COMPLETE
INBLOCKLETTERS-
PARTA. Tobe completed by WasteProducer

Name of Producer Quantity
I I I I. I I I I I I I I ,1 1 1 1
Postcode TelephoneNo. WasteCoUeNo. Units-cross kg=
I.I .I I
.appropriate
III . ,II IIIWs d square:
WasteType(place x in appropriatesquares) INTENDED
DISPOSAL.
ROUTE
[linert Fl Incinerable Fl Odorous Hig hl Infectious = Recycling [ ] Incineration
Poisonous ,, r Land [= ImmobDlisation
(toxic) Corrostv Solid LiquidsIidge =Others =Z Phys./Chern.
Treatment
DescriptionofWasteIncludingIndentificatlonof any HazardousComponents (Referto E.PAph. 6514224for furtheradvice)
NominatedDisposalSite
(pleasenome selectedsite)
urtherComments - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - reterto EPA torlst of curent facilities
SignaitureatWasteProducer SignatureoatDrhter
PART
3 -Tobe completed byTransporter
- - - - - - - - - - --
|NameofTransporter- Loading Date ZEZI1Z Vehicf*leRgNo
| ~~~~~Transport
PermitNo. I i I I I Il I I irL__1I I |I t/i 1/ 1|9|
PART
4 - Tobe completed by Disposal/Treatment
SiteAttendont
NMNE OF DiSPOSAQ/TREATIVENT
SiTE Site Ucence No.
_____________i/i__1___9_|_____9Signature of SteAttendant
ORiGINAL
TOBEFORWARDED
BYTHE
WASTE
PRODUCER
TO THEE.PAWiTHIN7 DAYS
Source: AustraDlan EnAronrnental Protectlon Agency. 1985. Draft Industrial Waste Strutegy. Vlctoria, Melbourre.
- 234 -
The Danish Kommunekemi system is a model for collectionand transfer

station operation,moving chemicalwastes from households, industry and
farms to a central treatmentplant (Palmark1984).
Each municipalityhas at least one collectionstation, designed to receive

chemicalwastes from households. These typically consist of a 4m x 5m x
2m shed with fireproofwalls, concrete floor and in circulation,
preventing the accumulationof toxic and explosive gases. Inside the shed
are two 200 litre drums for liquid wastes, two 200 litre clamp-lid drums
for packaged wastes and a box for storing toxic wastes. Private
households are not obliged to deliver their wastes, but have the right to
do so without charge.
The municipalitytransports from the collection stations to a smaller

number of transfer stations,owned and operated by a group of
municipalities. Industrialwaste producers and farms inform the local
authorities of waste accumulation,and notify them when waste is to be
moved, using forms similar to those shown in Figure 5-2. Transportation,
directly to the transfer stations, is provided by the generators
themselvesor by private contractors. The scheme is illustratedin Figure
5-3.
In Denmark, sites for transfer stationswere selected so that the system

could use the existing railway network. A transfer station consistsof
tanks for bulk liquid storage,and oil separationsystem and covered bays
for the storage of drummed waste and solids. Staffing consists of 1-2 men
working 8 hours per day. Besides handling waste deliveriesand loading
wastes on railcars, etc., some control and administrativework is carried
out. A waste transport certificatesimilar to that in Figure 5-2 and
completed by the generator accompaniesthe waste. After ensuring that the
information contained in it is correct, the transfer station attendant
hands one copy to the transporterand retains one for his records. The
waste is sent by rail from the transfer stations to the central treatment
plant. Firms may also transport the waste themselvesdirect to the site -
the procedure and documentationis similar to that discussed in Chapter
5.3.2. The organizationof a transfer station is shown in Figure 5-4.
The Kommunekemi system also accommodateswaste in small quantities. For

example, redundantmedicines from private households,doctors and
hospitals are received by the pharmacists,who bring them to the
collection stations for subsequenttransportationand disposal. A further
collaborationwith producers and importersof mercury batteries ensures
that stocklistsare suppliedwith boxes for the collectionof used
batteries. These boxes are also dispatchedto the collecting stations.
(See Figures 5-3 and 5-4.)
5.3.4 Transportation
The most common means of transportationof hazardous chemicalwaste is by

road. Hazards associatedwith on and off-loadingactivitiespose a
greater risk than the transport itself. Provided trained drivers in
reliablevehicles are employed, and waste is properly packaged, the risks
to the community are small. But transport risks should be assessed as
_ 235 -
FIGURE 5-3
Waste Collection Scheme - Kommunekemi
STATIONS~~~~ SATON
TRANSFER /
// STATIONS .
FaRM COLILECTION TRE
_ INDUSTRIES ONS
Co LECI
Source:Rasmussen.
.I1984.Paperpresentedat the "2nd InternationalSymposiumon Operating EuropeanCentralizedHazardous
Waste Management Facillties"In Odense,Denmark.
- 236 -
FIGURE5-4
Organization of a Transfer Station
IWEIGHERIDGEL
BASINSFOR 'TASINS
FOR RAR COW NERS
LIhOIDS SW9GES h FORSOLWC
NEUTRLIZATION RETREATMENT
ffi Sr~~
HOO FINAL
fCONTROL
HOMOSENZAMON
WASTEWATERE ECMN
FACILllY
TREATMENT WAECUS
Source:Wcrld Health Organization. 1983. Management of Hazardous Waste. Copenhagen.

_ 237 -
discussed in Chapter 2. The followingcontrols are desirable:
o transportationof hazardous waste should be subject to a permit issued

by the regulatoryauthority to contractorswith approvedvehicles and
trained drivers;
o each vehicle carryingprescribedhazardous waste should be identified

using the appropriatehazard symbols;
o each movement of waste on public roads should require a transport

certificate showing its origin and destination;
o the carrier must ensure that he has the necessary informationon the
material to be transported,and has formulatedan emergency plan in the
event of spillage.
5.4 Management Plans and Programs
Any hazardous waste management facility,whether a complex central

treatment plant or a simple onsite storage facility,needs plans and
programs to guide day-to-day operationsand prevent incidentswhich may
cause a health or environmentproblem. The level of complexityof these
plans will vary according to the type of activity,but the essential
elements are the same.
5.4.1 Waste Characterization
Waste characterizationplays a crucial role in the day-to-dayoperations

of any waste management facility. Before a facility agrees to accept a
waste for management, the facilitymust characterizethe waste. Proper
characterizationbegins with obtaining a sample which is representativeof
the waste. Representativesampling can be difficult since a waste may not
be homogeneous. It may consist of anomalies such as various phases,
particle sizes, concentrationgradients,and "pocketsof contamination".
Any samplingplan should be designed to discover such anomalies and
collect a sample that reflects them. An analysis plan should prescribe
analyticalprocedures, equipment,calibrationmethods, and quality
assurance/qualitycontrol procedures.
Sampling and analysis procedures should satisfy three goals:
o identify the inherenthazards of the waste;
o characterizethe waste enough to effectivelymanage it; and
o find a characteristicto easily identify shipments of waste as

delivered.
Inherent hazards of the waste need to be known so one may take precautions
to prevent accidents caused by the waste. For example: wastes which are
flammable, reactive, corrosive,or incompatiblewith certain materials
require special care and handling; wastes which contain highly soluble
contaminantsshould be protected from rain; wastes which create explosive
- 238 -
dust clouds should be managed so dusting is minimized.
Specificationsof the waste are particularlyimportant to design a program

of effective treatment and disposal of the waste. A waste which contains
heavy metals and cyanide requires a much different treatment scheme than
waste caustic soda.
Waste shipments arriving at a facilitymust be identifiedto ensure that

it is the same waste that the facility has agreed to accept. The facility
should decide upon a test that will easily and readily identify each waste
the facility agrees to accept. The test might be for example, pH,
flashpoint,chloride, sulphate,TOC, calorific value, cyanide,heavy
metals, etc.
5.4.2 Site Security
The facility should maintain adequate securityto prevent unauthorized

access to the site. There are three reasons for maintaining security.
First, to prevent people and livestock from wandering onto the site and
becoming harmed from contact with wastes or equipment. Second, it
protects equipment from damage. Third, it prevents scavengersfrom being
exposed to and from carrying off contaminatedmaterials. Security can be
maintained with fences, natural barriers, or guards.
5.4.3 Equipment Inspection/Maintenance
The facility should establish an inspectionprogram that will check the

condition of process equipment,storage vessels and containers,process
control devices, emergency equipment,and other equipment necessary for
operation of the facility. The inspectionchecklist and frequency depends
on factors such as expected rate of deterioration,sensitivity,and how
accident-pronethe equipment is. For example, process monitoring
equipment crucial to controllingwaste treatment requires more frequent
and detailed inspectionthan a drum storage area. The inspectionprogram
should include a program for repairing items which are found to be
deficient during inspections.
5.4.4 Employee Training
Properly trained employees are necessary for effective operation of any

facility. The facility should have trainingprocedureswhich show, for
every job at the facility, the level and type of training necessary for
that job and how that training is accomplished. The trainingmay take
many forms: from supervisedon-the-jobtraining to formal classroom
training. The objective of training is to ensure that the employees know
how to perform their functions in an effective and safe manner and to
respond to an emergency. The level of training increaseswith complexity
of equipment and process. Training, at minimum, should include: safe job
practices and procedures,the hazards of wastes employeeshandle, and
emergency procedures, both onsite and offsite.
- 239 -
5.4.5 Operating Record
The facility'soperating record should documentwhat the facilityhas done

and reflect the present status of the facility. Examples of what should
appear in an operating record are: process control data, waste types and
quantities, locations of wastes, and environmentalmonitoring data.
Maintaining an accurate operating record is necessary for schedulingwaste
deliveries, treatment operations,and facilityplanning.
5.4.6 Incident Preventionand Preparedness
Hazardous materials, includingwastes, present hazards which can cause

incidents such as spills, fires, and explosions. By identifyingthese
hazards and preparing for the incidents that could happen, you can prevent
many incidents from occurring and minimize the effects of incidents that
do occur. The risk analysis approach outlined in Secticin5.6 is useful
for identifyinghazards and potential incidents. Preparing for incidents
depends on the hazards and potential incidents identified. If fire from
flammablewastes is identifiedas a potential incident, a preparedness
measure could be installationof appropriatefire fighting equipment near
the locationwhere fires could occur. The necessary fire protection
measures should be designed for each site by appropriateexperts and
tested frequently. If liquid spillage is a potential problem, curbing in
the area may prevent a contaminationincident.
5.4.7 Emergency Planning
Facilities should have a set of proceduresfor employees to follow if an

emergency occurs. These procedures should identifythe type of emergency,
the type of waste, and what to do to minimize the effect.of the incident.
Safety analysis is a useful tool in designing these procedures. The
following should be emphasized:
(1) how to protect employees during the incident;
(2) how to minimize effect of the incident on the environment;
(3) protection of facility equipment;
(4) interactionwith community services (police, fire department, etc.)

to develop full scale emergency planning. Also drills and tests
need to be conducted at regularly scheduled intervals to test the
plan and ensure employee preparedness.
5.4.8 Closure Planning
Experiencehas shown that the best time to plan for final closing of waste
management facility is during the design of the facility,which should be
updated as experienceis gained during operation. The objective is to
have a clear, orderly method of closure so that after closure the facility
poses minimum risk and requiresminimum post-closuremaintenance.
- 240 -
The closure of a waste facility involves one of two approaches,depending

on the nature of the facility:
o final treatment and disposal of all wastes and residues and

decontaminationof equipment; or
o onsite containmentof waste.
The first approach applies to treatment and storage facilities,the second

applies to waste that will be left onsite in disposal facilities.
The plan should outline what will be done, what steps will be followed,
how the facilitywill be decontaminated,and how wastes and residueswill
ultimatelybe disposed of.
5.5 Example: Central Waste Treatment Plant
5.5.1 Basic Concepts
The central treatment plant discussed here is the Kommunekemi plant in

Denmark, which chemicallytreats inorganicwastes and incineratesa wide
range of organic wastes. This plant is illustratedin Figure 5-5.
Since the aim of central treatment plants is to protect the environmentby

providing safe disposal facilities,the design and operation of such a
plant must incorporatesafeguardsagainst all forms of environmental
pollution which could result from such an operation. In particular
(Coleman1975):
o aqueous effluent derived from process operationsmust conform to the

relevant discharge specifications;
o gaseous effluents from incinerationoperationsmust also conform to

emission standards. Gas cleaning equipment is an essential component
of incineratordesign;
o solid residues resulting from the treatment processesmust be

sufficientlyinert, to be safely landfilled;
o within the treatment plant, the possibility of ground contaminationdue

to waste transfer operations,pipe and tank fracture, site flooding,
etc. must be minimized by the adoption of safe working practices and
systems of treatment;
o measures should be adopted for the adequate treatment of spillages,and

emergency plans formulatedin anticipationof an incident such as fire,
explosion,etc.
5.5.2 Siting
The hazards associatedwith waste treatment are similar to those of

chemical manufacture and processing, and therefore similar siting criteria
FIGURE 5-5
Central Treatment Plant Layout - Kommunekemi
lapalnC entrge T0 Poison Storage
ment
0000~~stc Cmusin'Pan
Sources
Ptoagerk Moes sonaTanksagemeFornSoPan
394 aprpeetda Fclnt Plant
in the 2nd Itoernatona 0
on prating Europea
Symposium Centralized Haarou (Cemcl)Wat
ManagementFacilities
in September,Odense, Deimenmark.(
- 242 -
are appropriate. Because such facilitiesdeal with hazardous substances,

they must be located so that possible malfunction and emissions do not
adversely affect the environment.
Siting of waste treatment facilities is discussed in Chapter 3.9.
5.5.3 Design Philosophy
The design philosophyof central treatment plants catering for chemical

treatment of inorganicwastes and incinerationof organic wastes is
illustratedin Figure 5-6.
The sequence of waste through the facilitywill typically be:
o Receiving
o Inspection
o Assay
o TreatabilityTest, etc.
o Storage/Blending
o Solid/LiquidSeparation
o Incineration
o Chemical Treatment
o Residue Disposal.
The need for strict laboratorycontrol at all stages of the operation is

emphasizedby the prominent position of laboratorycontrols in the
characterizationof wastes, process schedulingand environmentalcontrols.
It may be noted that while both forms of treatment are located on one
site, they are essentially independententities, the only common points
being the laboratory,maintenance and administrationfacilities. The
design philosophy thereforealso applies to plants catering for just one
form of treatment.
5.5.4 Process Descriptions
The descriptionsbelow are taken from Coleman (1975).
(i) Chemical Processingof InorganicWastes
The first commitmenton the plant is the reception of waste materials into
pre-processingstorage. Receipt may be in bulk via road tanker or in
packaged lots comprisingany combinationof conventional30, 45 or 200
litre containers. Solid waste may be received by vehicle in various types
of removable container;for smaller consignments,kegs and clamp-lid drums
may be used. Here the laboratoryis involved in chemical assaying to
ensure that the material conforms to the in-coming schedule and to provide
records of waste characteristics. Waste characteristicssuch as
contaminant concentrationdetermine the type and amount of processing
chemicals to treat the waste.
After assaying, the waste is scheduled into the chemical processing

FIGURE 5-6 Design Philosophy of a Central Treatment Plant
| I~ABORATORY|
MaterialAssay Material Assay
Spililage
SiteSafetyControl-Perimeter
r -- - - - - -- -- -- -_- -- - - - ---
i Catc hment
hment I _ti
Incoming i I
Material r i
| ~~~~~~~~Material l >Material
I ~~~~~~~~Reception Reeto
o
|aRecepti n l P I Process Control Storage _
I Outgoina Storage nvironment Control Blending

i.
|
MIer
Recovered -r r
.l
-----------------
FumeExtraction a
Blending
_
i r cn
p~~~~~~ChOcemsi Process Control i ia) ;.,..
I # t I Environmental Control |nert Residue yal|
|uailter
Co t I ......... I
~
to Tlp |It | 1 1 Chamber
nProces Contrl ProcessControl
IDischarge to Sewer Environmental Control EnvironmentalControl

~~~~(Dlscharge Speclflcation) fi||(Exhaust Gas Speclflcatio)
Source: Coleman, AK. 1975. Chemlst & Industry (5 July), ProcEffluentgto
L -_ - _ _ Chemical . .. ____.._.._.._.._..J
Source: Coleman, A K. 1975. Chemsry&Iduty(5 July), 534. Processing
- 244 -
programme and the necessary chemical treatment is carried out on a batch

basis. At this stage, the laboratoryexercises the appropriateprocess
control by monitoring the reaction stages. This monitoring is either by
direct instrumentationor by selectivechemical analysis. To eliminate
smells from this area, the fumes are extracted from the processingvats
and passed either to the incineratorfor combustion,or into a separate
scrubber system.
If the chemical processinghas produced a product for recovery, the

product receives a quality control check from the laboratoryand is then
schedule for dispatch to the purchaser.
The non-recoveredmaterial passes through a solid/liquidseparation

(effluent filtration)stage, where the water insoluble solids in
suspensionare removed from the water. This usually comprises a sludge-
thickening stage where solids are settled out under gravity, followedby a
pressure filtrationstage in which the thickened sludge is physicallyde-
watered. The resultant inert sludge filter cake is removed from the
filter press into disposalbins. After the laboratorytests certifies
that the material is water insoluble,the material is dispatchedto
landfill site.
The water phase from the filter system is sampled for analysisby the
laboratory. If unacceptablyhigh levels of toxic components are found to
be present, the batch is subjected to a 'polishing'chemicalprocess to
remove the contamination. Any resultant solid phases are passed back to
the filter cake disposal bins.
The quality of the final effluent is subject to a discharge consent

specificationimposed by the receiving local authority. It is therefore
essential that the laboratorycertifies each batch of effluent before it
is discharged.
(ii) Incineration
As Figure 5-6 shows, the first stage of the incinerationplant is

reception of waste material into storage. As in the case of inorganic
waste, organic is accepted in bulk via road tanker or in a variety of
packaged lots including containervehicles for solids such as baled
plastics. Again the laboratoryis involved in material assay for
essentiallythe same reasons. The materials are programmed from storage
to provide the requisiteblending in terms of viscosity, calorific values,
water content and material types. The liquid and sludge wastes, after
blending, are passed to the incineratorfeed systems and ignited in the
appropriatechamber, according to previouslyprepared loading schedules.
Drums of organic waste are punctured just before loading into the rotary
drum incinerator.
The combustiongases pass into an after-burnerchamber to ensure complete

combustionand thence into a gas washing chamber designed to remove acidic
gases, such as hydrochloricacid produced in the combustion of chlorinated
hydrocarbonsand chlorinatedplastics, and particulatematter from the
- 245 -
exhaust gas stream. The acidity of the washwater is monitored by the

laboratory. From the gas-washingchamber the cleaned gases pass through
into the discharge stack. At this stage the laboratorymonitors the
quality of the discharge gases.
Inert residues are removed from the incinerator,transferredinto waste

storage bins and, after being certified as inert by the laboratory,are
dispatchedto a landfilledsite. The gas washing liquor is neutralized,
passed though a settlementchamberlsandfilter to remove lparticulates, and
dischargedalong with the liquid effluent from chemical treatment.
(iii) Odour Control
The drum opening area associatedwith material handling operationsis

equipped with air extraction systems to collect and control fumes. Fumes
are collected and fed into the incineratorthus preventing odour problems
within the confines of the site. Similarly, air extraction systems are
installed on certain storage tanks to control odours from the unloading
and storage of certain obnoxiousmaterials in those tanks.
(iv) Site Drainage and SpillageControl
Finally, from the diagram it will be observed that both facilitiesare

surroundedby a spillage catchment drain, which is linked to a catchment
sump for each function. In the event of any spillage, the area can be
cleaned,washed down and the combined spillage and wash liquors pumped
from the respective sump into the material-storagearea for processing in
the correct manner.
(v) Support Facilities
The site also houses the offices of support functions such as: sales,
accounting,administrationand maintenance.
5.5.5 Plant Layout
Two examples of the layout of a central treatmentplant are provided. The

Kommunekemi facility in Denmark is shown in Figure 5-5. The plant covers
approximately6.5 ha. The main sections are:
o wastes receiving and emptying section;
o tank farm;
o waste oil recovery plant;
o chemical treatment plant for inorganicwastes;
o incinerationplants for organic wastes.
Warehouses for solid packagedwastes, administration/labioratory building,

maintenance building, gatehouse and weighbridge, etc. are also located on
- 246 -
the site. Plant capacity is 33,000 t/yr for incinerationand 2,500 t/yr
for chemical treatment.
The layout of a smaller facility,more appropriateto developing

countries, is that of ReChem Internationalin UK shown in Figure 5-7. The
site occupies 1.5 ha. All the relevant informationis provided in the key
accompanyingthe layout, and the design philosophydescribed in this
section is applicable.
Chemical treatment and incinerationoperationsare independent,each

having separate tank farms, drum storage and bunded areas for acids,
alkalis, support fuel, and general organic wastes. Chemical treatment is
performed on a batch basis, in five stirred, stainless steel lined
reaction vessels, each of 10m3 capacity. The maximum annual throughputof
inorganicwaste is 10,000 tonnes. The incineratorhas a throughputof
2t/h. (See Figure 5-7).
5.5.6 Administrative Procedures
(i) Introduction
The procedures involved in the operationof a central treatment plant are

broadly similar to those employed in a manufacturingfacility, and
include:
o input-receiptof (waste)material;
o material storage/stockcontrol;
o schedulingof processes;
o process control;
o output-release (discharge)of (waste)products after checking that they

conform to regulatorycriteria.
Records are kept at each stage of the waste consignment'sprogress through

the plant. Some aspects of these proceduresare discussed below, and a
booking/recordingprocedure is described.
(ii) Waste Review/Costing
Figure 5-8 is a form that the treatment plant uses to review wastes and
offer the waste producer a quotation of the cost of treatment. The waste
producer describeswaste characteristicsand known analyses in Part A of
the form and submits a sample of the waste. The form and sample are given
to the central treatment plant's laboratorywhich reviews the Part A
information and performs any additionalanalysesnecessary to design a
treatment scheme of the waste and records its work in Part B. The form is
then sent to the processingmanager who describes in Part C how the waste
will be treated. The form then is sent to administrationpersonnel who
calculate a treatment cost based on the informationon the form. Among
FIGURE S-8
Example of a LaboratoryAnalysisReport Form
Applicationfor Analysisand Waste Producer Informationn Form Ref. No. Serial No.
Quotationfor Disposalof Waste by -
Informationprovidedby Waste
Producer (A) LaboratoryAnalysis (B) Plant
General Type of Industry Sample No. Transport Requirement

(NAMEAND ADDRRESSOF Process producingwaste Date into lab. Type of vehicle
CENTRALTREATMENTPLANT) Main chemical and biological
components Size
Physical nature Lining

Viscosity/mobility Receiptinto plant
Suspendedsolids, comon Precautions
Odour/reason
S. 0. _ Proposed Final
pH Storage area
Inorganic Fuel tank
COLLECTIONADDRESS/WASTEPRODUCER Acids/Alkalis Residues Tank
Name Content C.T.tank / which X
Anions present/content Drum area
Address (e.g.Cyanide, Other
sulphide, sulphate)
Metals/content Plant processing
Organic
Halogens (Fluorine,Chlorine,
Contact Bromine, Iodine)content Chemical treatment
Position hr, NMogan, ru.;
Telephone Ext. Phosphorus content Bulk residues
Telex Water content Willet system
Calorific value - Special residues
CONTRACTOR
(if applicable) Ash content Hearth solid
Name Metal contentof ash Pallet
Address Flashpoint/flammability Other
Compatibilitywith other
liquids Rate of processing
Other Information
- 247 -
FIGURE 5-7
Central Treatment Plant Layout - ReChem International Limited
f/ / ~~/ / / /- / / / /
,= I , / DXJ 1/ t 'L-J
V
00~~~~
/~~~~~~~~~~~~~~~~~~~~
17/ / / / 17 Incinerator
18 Ash Skip
19 Sludge Tank Farm
1 Gate House 20 Separator
2 Weigh Bridge 21 Solids & Sludge Hoppers
3 Offices, Canteen, etc. 22 Skip Storage
4 Car Park 23 Drum Storage
5 Lorry Park 24 IncineratorSolid Feed System
6 Alkali Bund 25 SedimentationTank
7 Acid Bund 26 Soot Ash Handling System
B Polishing Plant 27 Fume Duct
9 FIlter Presses 28 Pipe Bridge
10 Reaction Vessels 29 Pipe Bridge
11 Bunded Store 30 Sewage Treatment Plant
12 Laboratory,Stores, etc. 31 Oil Storage Tank
13 Emergency Fire Pump 32 Reception Screen
14 Reservoir 33 Centrifuge
15 Control Room - Sub Station
.16 Support Fuel Tank Farm
Source: ReChem International Limited. 1986. Personal Communication.

Southampton.
FIGURE S-8 (continued)
Example of a LaboratoryAnalysisReport Form
Application for Analysis and Waste ProducerInformationn Form Ref. No. Serial No.
Quotationfor Disposalof Waste by -
Informationprovidedby Waste
Producer (A) LaboratoryAnalysis (B) Plant
Contact
Position Toxicity Rate of intake
Telephone Ext. Precautionarymeasures Comments
Present quantityof waste/where

and how stored Data sheets (if available) Signed Signed
attached Date Date
Bulk Stored in Is waste classifiedas Special Charge: Disposa £ Transprt £
Waste Yes/No QUOTATION _
Type of tank Letter/Telex/VerbalFollow Planned Actual Outcome 4
Drums/Pack Numbersby size, type Signed for waste producer Date given up
Position To whom (if verbal) Date Order Date
Date To competitor
Rate of arising By whom By whom Who
Price
Why
- 250 -
the factors affecting the treatment cost are: the quantity and cost of
chemicals to be used for treatment,the degree and complexityof the
treatment scheme, and the handling difficulty of the waste. (See Figure
5-8).
(iii) Receipt of Waste
When the quotation is accepted, the procedures of recording the waste

begin. A Job Ticket is raised for each consignmentof waste. This can
comprise of four colours on the form which identify the waste. The
information required on the form is filled in with copies to the
gatehouse,the laboratory,and the Plant Manager. The gatehouse,having
prior knowledge of an incoming consignment,directs the load to the
weighbridge and then to the appropriatetank farm/drum storage area. It
is a safe and wise practice to verify the contents of the load (waste
characteristics)before emptying the contents into storage tanks. A wrong
pH or other error could cause an unexpected reaction. The empty vehicle
is weighed again as it leaves the plant. A weight ticket is attached to
Copy 1 of the Job Ticket, which is returned to administration. Copy 2,
with the weight recorded, is sent to the laboratory. Here, an additional
analysis is performed on a sample of the consignment,to confirm that it
matches the previous description,and recordedon Copy 2. Copies 2 and 3
are then returned to the Plant Manager. A register is maintained at the
gatehouse,detailing job numbers and the names of the waste producers, as
a permanent record of incomingwastes. Wastes are labelledwith the Job
Ticket code when they are stored.
(iv) Treatment Schedule
A daily meeting is held with Incineration,Chemical Treatment,Laboratory

and Plant Manager, to determine the treatment schedule. A list is drawn
up, detailing job numbers (i.e., the code on the Job Ticket), the storage
area of the consignments,and the mode and rate of treatment.
Incinerationscheduleswill include details of blending operations, and
any special requirements,for example, maintaininghigh temperaturesfor
PCB incineration.
(v) Process Control and Record Keeping
Chemical treatment and incinerationprocess control is exercised by the

laboratory (if chemical analysis is required) and by the operators.
Incineratoroperating conditions such as temperature,induced-draughtfan
pressure drop, and scrubberwater pH are measured with on-line analyzers
and recorded on chart recorders. These measurementsare also manually
logged at half-hour intervalson a daily form. This form also lists feed
rates of wastes and identifiestheir storage origin (tank number, drum
number etc.) and job number, followingthe schedule laid down for that
day.
Chemical reactions in the chemical treatment plant are monitored by the

operators, and logged to provide a permanent record of the fate of a
particular consignmentof waste, again identifiedby its job number.
Alarm systems are important. All chemical reactions should have automated
monitors for pH, temperature,pressure, etc. All necessary safety
- 251 -
equipment should be provided and regularlymaintained in case of runaway

reactions and other emergencies.
Permanent records are also kept of the emissions from the central
treatment plant. Chemical treatment effluents are only released to the
receiving system after an analysis has establishedthat they conform to
regulatorycriteria. A weekly composite form is prepared from the daily
records, for both chemical treatment and incinerationeffluents. These
are shown in Figures 5-9 and 5-10.
Finally, a record is made on copies 1,2 and 3 of the Job TiLcket,of the
date of treatment for the consignment. The copies are then filed.
5.6 Site Safety Analysis
5.6.1 Introduction
A hazardous waste management facility generally caters for a wide range of

chemicals and processes. The inherent uncertaintiesin feed material
composition,the potential for human errors, and the failures of
equipment, all pose an element of danger to employees and the surrounding
community. As an illustration,some possiblemalfunctions of a
incinerator plant are listed in Table 5-1.
Safety analysis is a technique used for identifyingpossible malfunctions

and their consequences. The analysishelps a plant look at potential
dangers and take appropriateaction to minimize risks. Risk-minimizing
actions might include improving operatingprocedures, redesigningthe
layout to reduce incidentpotential and incorporatingadequate safety
systems.
Safety Analysis involves the following steps (World Bank 1988):
o problem characterization;
o identificationof potential hazards and failure modes (faults);
o quantificationof probability of occurrences (events);
o quantificationof consequences;
o assessmentof the range of risks;
o recommendationsfor hazard mitigation, improved safety and emergency

response.
Plant data relating to equipment,organizationand procedures, and

statistical failure data for standard components,are used to assess the
risks associatedwith failures. The analyticaltools range from simple
check-list to computer simulationsof failure sequences and consequences
such as fire and atmosphericdispersionof toxic substances. The
calculated consequencesare interpretedin relation to health effects,
material damage, or environmentaleffects.
FIGURES-9
Example of a Chemical Treatment WeeklyReport Form

Week
Liquid Effluent Filter Cake
CN- Cr SO= Ni Cu Zn Pb Cd COD S/Solids Remarks CN- Cr S= Ni Cu Zn Pb Cd Remarks

4
Day Sample pH ppm ppm gl ppm ppm ppm ppm ppm ppmO2 ppm pH ppm ppm ppm ppm ppm ppm ppm ppm Skip No
Monday
Tuosday
Wednesday
Thursday
Friday
FIGURE 5-10
Example of an Incineration Weekly Data Form
Incineration Weekly Data Week

Monday Tuesday Wednesday Thursday Friday
Stock Gas Acidity HCl gns/mr3
Weir Water: pH
T.D.S. Z W/w
Scrubber System Feed Water: pH
T.D.S. Z W/w
S/Solids ppm
Ash X W/w
Slurried pH
Organics
Incinerator Ash S ______ _
ppm Levels
Ni 2n ..
Pb Cd
Cu Cr
Tank No.
pH
Residues Feed CV KJ/Kg .
Ash Z W/w
Heavy Metals Z W/w
Loads to Residue Tank no.

Tanks To residues
feed
- 254 -
TABLE 5-1
Potential OperationalMalfunctionsat an IncinerationFacility
Operation PossibleMalfunction Consequence
Tank filling 1. Overall on level interlock Waste spill

2. Leakage due to pump seal,
valve packing material
corrosion,etc. Small waste spill
3. Inclusion of unauthorized
waste by subversionof Possible incineration
quality control procedures difficulties.
Waste trans- 1. Leakage due to pump seal,

fer through material corrosion,etc. Small waste spill
pump and 2. Filter plugging None if filters switched on
filter high pump discharge pressure
measurement
Waste 1. Nozzle plugging (low flow

injection to detection) Temporary shut down
incinerator 2. Atomization air loss on Failure to combust, toxic
air blower failure vapour discharge, liquid
accumulation
Incineration 1. Burner flame loss (flame- Transcienttoxic vapour discharge

out) due to loss of fuel prior to automatic shutdown on
pressure, loss of primary flame loss detection (or low com-
combustion air, coking, bustion temperature. A water
or water slug in feed layer in the tank can be isolated
by conductivitymeasurement inter-
lock to the waste feed pump
2. Improper fuel rate Excess waste productiondischarge
3. Improper air/fuel ratio Inefficientcombustion
4. Injection into a cool com- Inefficientcombustion
bustion zone on start up
Stack Gas 1. Scrubbing solutioncircu- High HC1 concentrationin stack

scrubbing lating pump fails gases
2. Weak scrubbing solution Not much change, even water
scrubbing is very effective for
HC1 removal
3. Pump, valve, or tank leaks Scrubbing solution spill (no con-
sequence if water is used for
scrubbing)
Waste water 1. Chemical addition pump Low pH discharge

treatment fails
2. Pump, valve, or tank leaks Small waste water spill
Source: Shih, C. C. et al. 1978. Paper number 600/2-78-190August.

EnvironmentalProtectionAgency.
- 255 -
5.6.2 Safety Goals
The following safety goals were proposed in a safety analysis of the

Kommunekemi central treatment plant (Rasmussen1984). The underlying
principle was that the safety level should be as high as that of a
current, high standard chemical plant processinghazardous chemicals. The
goals were translatedinto quantitativefatality risk levels:
o individualrisk for nearest neighbor: probability less than 10-7 per

year, or in a year there will likely be less than one fatality among
ten million people;
o collectiverisk for community: probability inversely proportionalto

the number of fatalities;
o occupationalrisk (employees): probability less than 4 per 108 working

hours with no single hazard contributingmore than 1OZ of the total,
and with an allowance of 50Z for general industrialaccidents.
As a supplementto the quantitativegoals, good standard practice goals

were established to cover such factors which have a general background
effect on failure probabilities. These included safe systems of work,
operating procedure,maintenance schedules,etc.
5.6.3 Basic Approach
A brief descriptionof the procedures involved in conducting a risk

analysis is given below. Detailed informationwith worked examplesmay be
obtained from references (COVO SteeringCommittee,Rijnmond Council).
5.6.4 Identification of Failure Cases
The first requirementis to generate a list of possible failure cases

which fully represent the spectrum of all possible accidents. Two methods
may be used.
(i) The Check-listMethod
In this method, failure cases are derived from a list based on knowledge
of actual previous accidents. An inventory of the hazardous materials is
made, and their intrinsichazards reviewed. The various possible means of
escape are then identifiedusing the check-list (flange leaks, rupture or
tanks, pipe breakages,etc.), and each termed a failure case. (World Bank
1988).
(ii) Hazard and Operability Study
The study involves the detailed examinationof each component,considering

in turn all the possible variations from the design conditionwhich that
component could undergo. Some deviationswill be found to be physically
possible and potentiallyhazardous under conceivable fau]Ltconditions.
The deviationwill therefore suggest possible failure cases.
- 256 -
5.6.5 Fault-treeAnalysis
Starting from each failure case, a tree is constructed downwards in a step

by step fashion, by determiningat each stage the causative events
associatedwith the previous stage. The tree is complete when the basic
causative events remainingare all simple and quantifiableevents. All
the basic events are then assigned probabilityvalues for events higher up
the tree calculatedby appropriatecombinationof the basic events.
Ultimately, the total probabilityof the failure case is calculated.
5.6.6 Event-treeAnalysis
An event-treeis a logic diagram in which all of the possible outcomes of

a single initiatingevent are listed. The probabilitiesof a set of
outcomes are calculated for each failure case.
5.6.7 Calculation of Consequencesand Assessment of Risk
Using models to describe the release,dispersion and ultimate health

effect of a chemical on employees and the community,a consequence in
terms of fatalities is calculated for each outcome. The summation of
(probabilityx consequence)for all outcomes gives a measure of the
severity of the failure case, in terms of average rates of death among
employees and the general population.
These risks are viewed in relation to the safety goals listed in Chapter
5.6.2. Failure cases associatedwith unacceptablerisks are then
reviewed, and improved equipment/workprocedures/safetyequipment is put
into operation to lower the risk to acceptable levels.
5.6.8 Recommendations
As an example of how risk analysis is used to locate and correct for

possible malfunction, four potential hazards identifiedin the Kommunekemi
study are listed below (Rasmussen1984):
o evaporationof light compounds from waste oil contaminatedwith

solvents, leading to relief valve opening, followedby ignition.
Recommendationswere made concerning improved reliabilityof pumping
pressure control;
o chlorine generationas a result of pumping errors to a hypochlorite

plant. Recommendationswere for separatepiping with coding of
connectionsto improve the reliabilityof the transfer operation;
o chlorine generationcaused by the passage of hypochloriteto a basin of

acid waste, via a drain. Recommendationwas for relocationof the
drain.
o Sudan analysis is also useful for making siting decisions and for
specifyingthe extent of safety exclusion zones around the facility.
- 257 -
5.6.9 Site Safety
The health and safety of the plant employees and the public is of prime
importancein hazardous waste management. The following it:emsare
considered to be essential for the safe operation of the facility.
(i) Plant Safety and Training Officer
The role of a safety and training officer is to perform regular safety

audits, bring to the attention of plant management deficienciesin
operating procedures that might result in a dangerous occurrence injury,
and ensure that operators are properly trained and have adequate
protection (imperviousclothing, breathing apparatus, etc.) against
chemicals.
(ii) Operating Proceduresand Systems of Work
These are manuals containingdetailed informationof specificplant

activities, such as maintenance procedures,transfer and pumping of
wastes and processing of waste. The manual contains, for each item, a
summary of the potential hazards associatedwith the activity, safety
precautions such as clothing, decontaminationand emergency procedures,
and a detailed system of work. It is the responsibilityof the Managers
to ensure that operators adhere to these procedures, and to regularly
update them in the light of the best available information.
(iii) Trained Operators
Operators should be trained to perform plant functions in a sage and

responsiblemanner, adhering at all times to a specified system of work,
and safe work practices.
(iv) Housekeepingand Maintenance
Good housekeepingis essential to prevent the dispersionof hazardous

chemicals. Immediate clean-up of spills using establishedprocedures,the
preventionof fire, the diversion of stormwaterfrom storage and
processing areas, are all operationsthat require constantvigilance.
Lack of maintenance can result in a fracturedpipe, leaking pump seals

etc., possibly leading to a dangerous occurrence. A regularmaintenance
programme should be initiated.
(v) Emergency Procedures
Procedures for the evacuationof the site in the event of an incident,

should be drawn up and rehearsed. The site should mainta-inadequate fire-
fighting equipment,hydrants, emergency showers,protectiveclothing and
breathing apparatus.
- 258 -
(vi) Operator Hygiene
Operators should be trained to observe basic rules of hygiene, such as

changing out of dirty overalls and use of washing facilitiesbefore
entering the canteen or leaving the site. Smoking and eating should be
prohibited in all areas, except the canteen and administrationbuildings.
5.7 Measurementsto be Taken in Case of UnintentionalExposure to Hazardous

Waste
It is important that in any case where potential exposure is discovered

from hazardous waste the public authoritiesand public are informed
swiftly and adequatelyabout the source of exposure and the potential
risks involved. An informationcommunicationsystem should be set up to
ensure that the progress of ongoing investigationsis being reported
adequatelyand all necessary precautionsto protect the public are
implemented. Such informationis necessary in order to prevent public
over-reactionand political exploitationof fears and concern.
Measures should be taken to limit or eliminate exposure and to confine the

waste to a controlled area or site.
5.7.1 Health and Safety of Personnel Handling Hazardous Waste
Individualsat most risk from exposure to hazardous waste are those who
are involved in handling the waste either during collection,
transportation,storage,treatment or disposal. To prevent exposure of
these workers to hazardous agents through inhalation,ingestion or
absorptionthrough skin contact (throughinjuries or through splashes into
the eyes) safety procedures should be instigatedas part of a general
safety programme. To be adequate, such a programme should incorporatethe
following aspects: Information,training,work organization,personal
protection, personal hygiene, medical surveillance,and environmental
monitoring.
(i) Information
All personnel should be given detailed informationregarding risks

involvedwith different types of waste, togetherwith possible routes or
exposure, methods of avoidance and measures to be taken should exposure
occur. Personnel should be made fully aware of the consequence if they do
not follow the prescribed safety precautions. Any change in the
composition of waste or working procedures should be adequately and
effectivelybrought to the attention of all worker before changes are
implemented.
(ii) Training
All persons handling hazardouswaste should be given training in the

handling procedures by experiencedpersonnel. They should also be given
written instructionsabout normal procedures,safety precautions and about
actions to be taken if complicationsarise. When procedures are changed,
special training courses should be organized for personnel involved.
- 259 -
(iii) Work COrganization
(a) StandardizedOperating Procedures
An importantway to reduce the possibility of harm to

personnel is to work out standardizedoperatirLg procedures.
Such procedures should be based on the best available
knowledge, operationalprinciplesand technical guidance. The
initial procedures should be properly tested, reviewed and
revised from time to time by competent safety professionals.
The procedures should be practical and applicablewithout
sacrificingthe level of safety. They should be described in
understandableinstructionsand made available to all relevant
personnel.
(b) Plant Layout
The workplace should be properly organized. Appropriatework

areas should be establishedidentifyingareas where access is
forbidden,where entry is restricted,where support services
and equipment should be located and where decontaminationcan
be carried out. Where appropriate,a decontamination
procedure should be establishedfor workers prior to leaving
the plant site. When appropriate,wind indicatorsshould be
set out to provide indicationsfor upwind escape in case of an
emergency.
Mixing differentwastes of unknown compositionsshould as a rule not be

permitted unless tests and chemical expertise have shown or adjudged that
this can be performedwithout any hazard.
When wearing self-containedbreathing apparatus or fully encapsulated

suites, or when operating in confined spaces, personnel in the hazardous
waste area should work in pairs at all times. Pairs should pre-arrange
hand signals for communicationof if availableestablish radio contact.
Use of self-containedbreathing apparatus or fully encapsulatedsuits
requires one or two additionalpersons suitablyequipped as a safety back-
up. Communicationbetween all members must be maintained at all times.
It is important to emphasize that the number of personnel and the amount
of equipment in the hazardous area should be minimized.
Safety plans for all potentially dangerous incidents should be developed,

regularly updated and made available to all personnel.
(iv) Personal ProtectionEquipment
Personnel may be protected from inhalationof hazardous dust and gases, by

the use of breathing apparatus. Protectionof eyes and skin can be
achieved with protectiveglasses and clothing. If splashing is a
possibility,eye rinsing and sometimeswhole body shower equipment should
be made available at suitable locations. Depending on the type of
hazardous waste and on the level of protectionrequired, various
combinationsof such equipmentmay be required.
- 260 -
(v) RespiratoryEquipment
The choice of respiratoris determinedby the type and extent of the

hazard. Respiratoryhazards fall into the following groups:
(a) Oxygen deficiency,and
(b) Air contaminationby: particulates,vapours and gases or a

combination of these.
The purpose of any respiratoris to protect the respiratory system from

harmful physical or chemical airborne agents either by removing the
contaminant from the air before it is inhaled or by supplying an
independent source of respirableair. If a device removes contaminants,
it is an air purifying respirator. It does not supply oxygen and
thereforemust never be used in an oxygen deficient atmosphere. In most
cases, unless the specifichazard is known and an air purifying respirator
has been determinedto be appropriate,this type of respiratorwould not
be used in an emergency response situation.
Breathing supply respiratorsare the basic responseapparatus and are

normally referred to as a self-containedbreathing apparatus (SCBA).
SCBA's are classifiedas "closed'or 'open' circuit systems. A closed
system is a rebreathingdevice in which the exhaled air has been scrubbed
and oxygen content restored. An open circuit SCBA emits the exhaled air
to the atmosphere. Air is inhaled from a compressedair tank which passes
through a two stage regulatorwhich reduces the pressure for delivery to
the face piece. Two types of open circuit SCBA's are available, "demand'
and "pressure-demand'.With the demand system, air flows into the face
piece only upon the inhalationor "demand"or the water. The danger of a
demand system is that the negative pressure in the face piece caused by
inhalation (felt by the wearer as suction),not only triggers air flow
from the regulatorbut could draw contaminatedair in through leaks around
the face piece.
The pressure-demandsystem causes a small continuousflow of air to be

passed into the face piece through the regulator. Even with or without
inhalation there will be air and positive pressure in the face piece, and
contaminatedair will not be drawn in through leaks around the face piece.
A face piece whose exhalationvalve is designed for demand operation
should never be used with a pressure-demandsystem, as air will flow
continuallyout of the exhalationvalve, quickly exhaustingthe air
supply.
A demand type SCBA should never be used in an atmosphere consideredto be

immediatelydangerous to life or health. In this case a pressure-demand
SCBA must be used.
All SCBA's must be worn with full face pieces. Many are designed to fit
inside a particulartype of fully encapsulatedsuit. In such arrangements
there may be vision problems due to condensationon visors.
- 261 -
(vi) ProtectiveClothing
The hazardous properties of chemical substancesnecessitate the use of

protective clothing. The degree of protection required is dictatedby the
inherent physical, chemical, or toxic property of the material. For
example, protection required for a corrosive compound is different from
that of a compoundwhich releases a highly toxic vapour. The type of
activity,must also be consideredwhen assigningprotective clothing. As
with the selection of proper protective respiratoryapparatus,a thorough
assessment of the encounteredhazards must be completed before making a
decision.
Several factors must be consideredin the selection of clothing. The most

important is the safety of the individual. The level of protection
assignedmust be in accordancewith the severityof the hazard. It is
also very important that the individualis well trained in the use of
protective apparel and is familiarwith the necessary standard operating
procedures for site activities. Other factors include cost, availability,
compatibilitywith other equipment, suitability,and most important,
performance.
Protective clothing ranges from safety glasses, helmet, and safety shoes
to a fully encapsulatingsuit with a breathing supply. A variety of
clothing includes disposableoveralls, fire-retardantclothing,
splashsuitsand many other types of clothing utilizing a range of
materials providing specializedprotection against a variety of hazards.
The primary safeguard of any protectiveclothing is the material from

which it is manufactured. There are six main characteristicsof a
material to be consideredfor acceptableperformance:
strength: resists damage
chemical resistance: resists degradationand permeation;
thermal resistance: protects under adverse heat conditions;
dexterity/flexibility: facilitatesactivity, ease of movement;
cleanability: facilitatescleaning and decontamination;

and
ageing resistance: durable over time.
The three general classes of materials used to manufacture protective

clothing are cellulose-based,natural and syntheticfabrics, and
elastomers. Each is useful for specificpurposes.
(vii) The Heat Factor
With any clothingwhich provides protectionagainst hazardous substances

it is important to recognize the hazards created by wearing such clothing.
- 262 -
Because the body is shieldedfrom normal circulationof air it is

prevented from carrying out its normal cooling functions. Perspiration
generatedwithin an elastomer suit does not evaporate,thus inhibitingthe
body's major mechanism of losing heat. Without this mechanism, the body
is prone to heat stress which can exhibited as heat stroke of heat
exhaustion. This is most likely to occur when the ambient temperature is
above 18-21C. Work schedules in fully encapsulatedclothing must be
regulated very carefully as heat stress may become more of a threat than
the chemical hazard itself. Response personnel should be trained to
recognize the symptoms and provide first aid for these conditions.
(viii) Personal Hygiene
Although personal protective equipmenthelps to minimize the hazard, the

main determining factor when handling hazardous waste is personal hygiene
and behaviour habits. Eating, drinking, chewing tobacco or smoking are
activitieswhich should not be carried out in the vicinity of waste
material where there is a possibility for contaminationby micro-organisms
and toxic chemicals. Personnel should frequentlychange clothing and
shower whenever they leave the work place. Facilities should be provided
at a suitable distance from the work place where personnel can eat and
rest and where washing facilitiesare provided. In these areas no work
clothes should be allowed. Smoking is an effective method of transferring
hazardous material from the hands to the lungs and gastrointestinaltract
and must therefore be avoided during working hours. During work,
personnel should avoid contactwith potentially contaminatingsubstances
and not walk through puddles, pools, muds etc., and avoid whenever
possible, kneeling on the ground, leaning or sitting on waste drums and
machinery. If respiratoryequipment is required, facial hair (e.g.,
beards), interferingwith the correct fitting of masks, should be removed.
(ix) Medical Surveillanceand Safety Programme
Personnel working with hazardous waste should be kept under constant

medical surveillance. A proper immunizationprogramme should be
administeredwhere appropriateand a programme of regular medical
monitoring relevant to the type of exposures should also be carried out.
Necessary first aid equipment and relevant antidotes to toxic substances
should always be close at hand. Special personnel,including staff safety
representativeand safety officers should be assigned to ensure compliance
with proposed safety measures.
(x) EnvironmentalMonitoring
When certain hazardous wastes are handled, it will be desirable to monitor

the environment of the workplace to ensure that dangerouslyhigh levels of
contaminationare not reached. Monitoringmay be carried out by either
personnel or static sampling; and by the use of techniquesranging from
relatively simple ones using detector tubes and hand-held pumps to highly
sophisticatedoperatorswhich requiresprofessionallyqualified personnel
to both operate and interpret.
- 263 -
5.8 Economic, Institutional,and Financial Considerations
5.8.1 Cost
Costs associatedwith hazardouswaste management can be classifiedas

avoidance costs, abatement costs, damage costs, compensationcosts, and
transaction costs. A national program in hazardouswaste management
should determinewhat institutionalarrangementsand what economic
policies are necessary to assure that all of these costs receive attention
and can be adequatelyfinanced. One goal could be to minimize the sum of
avoidance, abatement,compensation,and transactioncosts falling on
potential cost bearers.
Avoidance costs are costs of hazardouswaste managementwhich could

include efforts toward waste minimization,treatment to reduce risk, or
disposal. Abatement costs are the remedialcosts of removal and clean-up
following improperhazardous waste management. Damage costs are the cost
of damage to human health and the environment. Damage costs can be viewed
alternativelyas the benefits of proper hazardouswaste management.
Compensationcosts are the funds transfered to injured indlividualsor
society to compensate for hazardouswaste damages. TransaLction costs
include governmentaladministrativeand enforcementcosts and the cost of
acquiring informationfor the parties to a hazardous waste management
transaction,includingmeeting a burden of proof in a court case.
There may be considerablemerit in incurring avoidance costs sufficientto

minimize future risk. This tends to eliminate future abatement and damage
or compensationcosts from hazardous waste management. As an example, the
cost of proper disposal at the Love Canal site in New York is estimated at
$4 million. This compareswith abatement costs of $125 million and
compensationcosts resulting from $2.5 billion in claims for personal
injury (HarvardLaw Review 1981).
As a practical matter, one can readily see that managing liquid hazardous
waste, which is in a 55-gallon drum, is easier than dealing with the same
waste which leaks through and contaminatessoil and subsequently
contaminatesground water and the water bearing rock (aquifer)through
which it travels. The cost of decontaminatingthe soil, ground water and
aquifer would be abatement costs. A monetary value for the damage to
human health and the environmentcaused by the contaminatedsoil or ground
water would be damage costs. Finally, the monetary transfers to injured
parties, including compensationto society for ecologicaldamage, would be
compensationcosts.
5.8.2 Complexityand Uncertainty
Avoidance costs include:
o capital costs for procurementof land, facilities,and equipment;and
o operating and maintenance costs associatedwith hazardous waste

management systems.
- 264 -
These costs are clearer,more certain, and more immediatelyapparent than

abatement, compensationand transactioncosts. Yet, even estimationof
avoidance costs, which would provide an acceptable level of risk to human
health and the environment,involvesconsiderationcomplexityand
uncertainty for a given waste generator:
o What wastes are hazardous? In what way?
o What sampling and analysis techniquesare appropriate to verify that

determination?
o What avoidancemeasures are most appropriate: changing raw material;

changing productionprocess; reuse, recovery, or recycling;treatment
to reduce risk; disposal?
o What degree of human exposureor environmentalvulnerabilityapplies in

this situation?
Abatement costs pose greater complications. For example,when are soils,

ground water or aquifers (rock formationscontaining ground water)
adequatelycleaned-up? Damage costs involve putting monetary values on
sometimes irreversibleimpairmentsto human health and the environment.
Compensationcosts involve difficult questions of causality and equity.
Transaction costs involve policy decisions on the degree of government
involvementas well as individualdecisions by potential cost bearers
regardinghow much they are willing to spend for more informationabout
hazardous waste management and its impacts.
Because of the complexity and uncertaintyassociatedwith hazardous waste

management, government interventionis necessary to lower overall costs.
In the absence of effective governmentaction, emphasis is likely to fall
on minimizing avoidance costs -- the cost of doing the job right in the
first place -- thereby maximizing abatement and damage or compensation
costs which can be many times greater than avoidance costs. The expert
judgments needed from a wide variety of disciplines,including law,
economics,toxicology,chemistry,engineering,and management, to achieve
a proper governmentalrule in hazardouswaste management, must be properly
coordinated in order to keep transactioncosts manageable.
5.8.3 Liability
Liability laws can be a major factor in refocusingthe attention of those

responsiblefor managing hazardouswaste from a narrow concentrationon
out-of-pocketavoidance costs to include potential abatement and
compensationcosts. To minimize the aggregate costs of avoidance,
abatement, compensation,and the transactioncosts of effecting hazardous
waste management cost allocation, it is desirable to consider liability
laws that are joint and several, strict, and continuing (HarvardLaw
Review 1981).
Hazardous waste generators,treaters, receivers,recyclers, reclaimers,

and disposers will respond to economic incentivesto reduce abatement,
- 265 -
compensation,and avoidance costs. Joint and several liability gives

firms this incentive by allowing them to bargain among themselves in order
to reduce the total costs of hazardous waste management (Calabresi1970).
Strict liability is appropriatefor several reasons. First, costs

stemming from hazardous wastes belong to the waste generatingand waste
management activitiesand should not, for example, be consideredcosts of
living near a disposal site. Second, because in almost all cases it
costs society less to prevent releasesthan to allow them, liabilitywould
usually be found even under a negligence standardwhen a re!leasedoes
occur. Strict liability avoids the high transactioncosts required to
prove this point on a case-by-casebasis (HarvardLaw Review 1981).
Thirdly, it reinforcesthe generally accepted 'PollutionPays Principle",
which is frequently incorporatedinto national environmentallaws.
Continuing liability allows a waste generator's liability for costs

stemming from its activities to be coextensivewith the hazardous life of
the waste plus the time reasonablynecessary to discover any injuries
caused by the waste. Any other approach is inconsistentwith the
principle that the polluter pays for damages caused and undermines
deterrence to improperhazardous waste management (HarvardLaw Review
1981).
The issue of liabilityhas been consideredby the United Nations General

Assembly and by the United Nations Commission on InternationalTrade Law
(Schapp 1980). Although passage of national legislationon liability may
appear to put that country at a relative disadvantagefor industrial
investment, recent events suggest that multi-nationalcorporationswould
benefit from full considerationof all potential costs associatedwith
hazardousmaterials, includinghazardous wastes (Morehouseand Subramaniam
1986).
5.8.4 Relation to Emergency Response, OccupationalHealth and Safety,

Consumers, and Toxic SubstancesControl
Much of the professionaljudgment, knowledge and expertise needed for a

national program in hazardous waste management is also needed in national
programs for emergency response to accidental spills of hazardous
materials, protection of employeeswho handle hazardous material in the
workplace, protectionof consumers of hazardous products, and control of
the manufacture of toxic substances. A scarcity of such resources in
developing countries reflectsthe need for careful coordinationin the
development and operation of these programs, as well as a program of
liquid and gaseous effluent solutioncontrol.
5.9 Economic Considerations
From the standpointof economic theory, society has allocated the optimal
degree of resources to hazardouswaste managementwhen the marginal cost
of management of hazardouswaste is equal to the marginal benefits of
damages prevented by that expenditure (Haas 1984-85). Included in the
assumptions underlying this view are that there are many sellers
- 266 -
(purchasersof hazardous waste management) and many buyers (bearersof the

damages), all of whom are well informedabout the implicationsof the
transaction. Perhaps because of the complexityand uncertainty associated
with hazardous waste management, the unaided free market has sometimes led
to undesirable consequencesand governmentinterventionhas been
undertaken.
An interesting question is who pays for hazardouswaste management. Two

possibilitiesare that the polluter pays and society pays. The polluter-
pays principal suggests that the full cost of an economic activity should
be reflected in the decisions of the producer of that economic good.
Thus, all the costs from any hazardous waste management associatedwith an
economic activity should be represented,including compensationfor
damages to human health and the environmentand outlays for appropriate
levels of clean-up. If these costs are included, then optimal levels of
output are achieved. The society-paysconcept recognizesthe difficulty
of anticipatingdamages and establishingcausality between injured parties
and hazardous waste managers. This is especiallytrue if the injured
parties are future generations. As a practicalmatter, society may wish
to eliminate damages and the transactioncosts of appropriating
compensationby simply paying for proper hazardous waste management
(HarvardLaw Review 1981). It may also be appropriate to develop a
combined approach which incorporatesboth concepts in an equitable
balance.
5.10 Direct Regulation
One approach to achieving a better national balance among the costs of

hazardous waste management is direct regulation. A body or bodies of the
governmentprescribe measures (regulations)which must be followedby
generators and other managers of hazardous waste. Penalties are
prescribed for failure to comply, reporting requirementsand right of
entry are established,and an inspectionand enforcement function is
undertaken. Governmentbodies establishingregulationsbalance increased
protection for human health and the environmentagainst factors such as
potential plant closures, loss of employment,and import/exportimpacts.
Because developed countries have already invested considerablemoney and
effort in establishinghazardous waste management regulations,it may be
desirable to consider using them. However, to the extent possible, it
would be desirable to review the basis for these regulationsand make
suitable adjustments for local factors in human health, environmental
sensitivity,and economic considerations.
5.11 Economic Incentives
Another approach to achieving a better national balance among the costs of

hazardous waste management is economic incentives. Economistshave argued
that market-based approachescan produce the socially desirable amount of
pollution control and do so more cheaply than direct regulation. Such
approaches include effluent charges, taxes on outputs,marketable
discharge permits, subsidizationproportionalto waste reduction from a
base level, and deposit-refundprograms (See Note).
- 267 -
An effluent charge (Kneese and Bower 1968, and MacKintosh 1973) would be a
tax per unit amount of hazardous waste discharged. The charge should be
set so that the marginal cost of avoidance equals the marginal benefit of
that avoidance (cost of abatement plus damage plus any compensationin
excess of actual damages, ignoring transactioncosts). This approach
allows the generator to decide how much waste to control,with what
technology, and how much to simply discharge and pay the fee. For toxic
pollutants, direct regulationmay be more appropriatethan effluent
charges or other economic incentives (Andersonet al. 1977). For less
toxic hazardous waste where avoidance technology is not well
characterized,economic incentivesmay be appropriate (Haas 1984-85).
Implementingan effluent charge scheme involvesquantifying the benefit of

controllinghazardous waste. This may involve estimatingintangiblessuch
as the value of human life, better health, more desirable recreation
sites, and breathing comfort. Experts do not agree on the methodology to
make such estimates (Revesz1984, and Bailey 1980).
Many environmentalistbelieve that in balancing tangible costs against

intangiblebenefits, the valve of the latter are down-played. In
addition, it is psychologicallycostly for our society to assign a price
to goods like a human life (Calabresiand Bobbitt 1978).
Marketable discharge permits (Kneese and Bower 1986, and MacKintosh 1973)
are an economic incentive that avoids or minimizes these problems. Once
an acceptable level of hazardous waste discharge is determined,perhaps by
a legislativebody, the available discharge amount is allocated by open
competition among hazardous waste producers for discharge permits.
Subsidizationproportionalto waste reduction from a base level (Kneese
and Bower 1968, and MacKintosh 1973) encouragesproper practice by paying
hazardous waste generatorsand managers for improvedpractices. Setting
subsidy amounts involves the same problems of setting effluent charges.
Base levels might be set by a legislativebody. This program suffers the
drawback that hazardouswaste generatorsand managers with the worst
practices get the greatest rewards. Funding of such a system also poses
difficult problems in developingcountries.
Deposit-refundprograms require deposits from hazardous waste generators

which are returnedwhen proof is given that a desirable technologyhas
been used to manage the waste (Coase 1960, and Revesz 1984). Deposit-
refund programs might be easier to implement for hazardous waste
management than waste taxes (Solow 1971, and Bohm 1981).
- 268 -
5.12 References 5.0 - 5.11
Anderson, F. R. et al. 1977. EnvironmentalImprovementThrough Economic

Incentives. Baltimore,Maryland: Johns Hopkins University Press.
Bailey, M. 1980. Reducing Risks to Life: Measurement of the Benefits.

Washington, D.C.: American Enterprise Institute for Public Policy
Research.
Bohm, P. 1981. Deposit - Refund Systems: Theory and Applications to

Environmental,Conservation,and Consumer Policy. Baltimore,Maryland:
Johns Hopkins UniversityPress.
Calabresi, G. and P. Bobbitt. 1978. Tragic Choices, 32. New York:

Norton.
Calabresi, G. 1970. The Costs of Accidents: A Legal and Economic

Analysis, 135-140. New Haven: Yale UniversityPress.
Coase, R. 1960. The problem of social costs. Journal of Law and

Economics,Vol. 3.
Coleman, A. K. 1975. New concepts in the handling of industrialwastes.

Chemistry & Industry (5 July): 534.
COVO Steering Committee,Rijnmond Council. 1982. Risk Analysis of Six

Potentially Hazardous IndustrialObjects in the Rijnmond Area, a Pilot
Study. Dordrecht: D. Reidel PublishingCo.
Haas, Charles N. 1984-85. Incentive options for hazardous waste

management. Journal of EnvironmentalSystems 14(4).
Harvard Law Review. 1981. Allocating the costs of hazardous waste

disposal. 94(3) (January):584-604.
Kneese, A. V., and B. T. Bower. 1968. Managing Water Quality: Economics,

Technology, Institutions. Baltimore,Maryland: Johns Hopkins
University Press.
MacKintosh, D. R. 1973. The Economics of Airborne Emissions: The Case

for an Air Rights Market. New York: Praeger.
Morehouse, W., and M. Arun Subramaniam. 1986. The Bhopal Tragedy: What
Really Happened and What it Means for American Workers and Communities
at Risk.
Palmark, M. 1984. The Danish System. In the 2nd internationalsymposium

on operating centralizedhazardous waste management facilities,Odense,
Denmark.
Paula Schapp. 1980. The case for strict liability in the infant formula
industry. Brooklyn Journal of InternationalLaw (Spring):88-110.
- 269 -
Rasmussen, I. 1984. Paper presented at the 12nd InternationalSymposium

on Operating European CentralizedHazardousWaste Managenment
Facilities" in Odense, Denmark.
Solow, R. M. 1971. The economists'approach to pollution control.

Science, Vol. 172.
World Bank. 1988. Techniques for Assessing IndustrialHazards. No. 55.

Washington, D. C.
Note: See, for example:
Ackerman, B., et al. 1974. The Uncertain Search for Environmental

Quality. New York: The Free Press.
Anderson, F. R., et al. 1977. EnvironmentalImprovementThrough Economic

Incentives. Baltimore,Maryland: Johns Hopkins UniversityPress.
Baumol, W., et al. 1979. Economics,EnvironmentalPolicy and the

Quality of Life. Englewood Cliffs, New Jersey: Prentice-Hall.
Haas, C. N. 1985. Incentiveoptions for hazardouswaste management,

Journal of EnvironmentalSystems 14(4).
Kneese, A., and C. Schultze. 1975. Pollution,Prices and Public Policy.

Washington, D. C.: Brookings Institution.
Lahy, W. L. 1984. Economiccharges for environmentalprotection:

Ocean dumping fees. Ecology Law Quarterly11(3).
Revesz, R. L. 1984. Book Review: Incentivesfor environmental

protection. Ecology Law Quarterly 11(3).
Schelling, T. C. ed. 1983. Incentivesfor EnvironmentalProtection.

Cambridge,Massachusetts: MIT Press.
RECENT WORLD BANK TECHNICAL PAPERS (continued)
No. 77. Gunnerson, WastewaterManagement for Coastal Cities: The Ocean Disposal Option
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Financed Projects (also in Spanish, 80S)
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No. 83. Ewing and Chalk, The Forest Industries Sector: An Operational Strategy for Developing
Countries
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Developing Countries
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No. 86. Munasinghe, Integrated National Energy Planning and Management: Methodology and
Application to Sri Lanka
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No. 88. Vuylsteke, Techniques of Privatization of State-Owned Enterprises, vol. I: Methods and
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Case Studies
No. 90. Candoy-Sekse, Techniques of Privatization of State-Owned Enterprises, vol. III: Inventory of
Country Experience and Reference Materials
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ISSN 0253-7494
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Public Disclosure Authorized

WORLD BANK TECHNICAL PAPER NUMBER 93

The Safe Disposal of Hazardous Wastes

Roger Batstone, James E. Smith, Jr., and David Wilson, editors

= W-- 3Z!sgr *11

(List continues on the inside back cover)

The Special Needs and Problems of Developing Countries

The World Bank World Health United Nations

The Safe Disposal of HazardousWastes

Roger Batstone, James E. Smith, Jr., and David Wilson, editors

The World Bank

All rights reserved

Library of Congress Cataloging-in-Publication Data

World Bank technicalpaper, 0253-7494; no. 93)

The World Bank, World Health Organization,and United Nations Environment

A particularlyuseful section of this manual includes the examples of

1.1 What are Hazardous Wastes7 1

CHAPTER 2. The Health and EnvironmentalEffects of HazardousWastes 11

Annex 2 Waste Types for Proposed ClassificationScheme 45

CHAPTER 3. Planning for Hazardous Waste Management 60

3.2 A Framework for Planning 60

Annex 3A A Typical Wastes Generation Questionnaire For Use

CHAPTER 4. Waste Minimization - A Key Strategy in Hazardous Waste

4.1 Introduction 161

Annex 4A Cost/Benefit Analyses of Waste Minimization 186

CHAPTER 5. Infrastructure of Hazardous Waste Management Systems 230

5.1 Introduction 230

5.2 Storage upon Generation 230

5.3 Collection/Transportation 231

5.4 Management Plans and Programs 237

5.5 Example: Central Waste Treatment Plant 240

5.5.2 Siting 240

5.6 Site Safety Analysis 251

5.7 Measurements to be Taken in Case of Unintentional Exposure to

5.8 Economic, Institutional and Financial Considerations 263

5.9 Economic Considerations 265

5.10 Direct Regulation 266

5.11 Economic Incentives 266

5.12 References 5.0 - 5.11 268

CHAPTER 6. Hazardous Waste Treatment Technologies 270

6.1 Introduction 270

6.2 Discussion of Typical Treatment Technologies 270

6.3 Treatment Technology Considerations 276

6.4 Precipitation/Flocculation 277

6.5 Sedimentation 287

6.6 Oily Wastes 297

6.7 Chemical Oxidation 311

6.8 Stabilization/Solidification 331

6.9 Neutralization 358

6.9.2 Representative Types and Modifications 358

6.10 Solvent Extraction 377

6.11 Sludge Processing 383

6.12 References 6.1 - 6.11.5 439

CHAPTER 7. Technical Requirements for the Safe Disposal of Hazardous

7.1 Landfills 448

Annex 7.1A Leachate from a Hazardous Waste Landfill--Technical

Annex 7.1B Disposal and Management of Pesticide

7.2 Land Treatment 606

7.3 Other Land Disposal Processes and Monitoring 632

7.4 Incineration 653