SNF SAS

ZAC de Milieux
42163 Andrzieux Cedex
FRANCE
Tel : + 33 (0)4 77 36 86 00
Fax : + 33 (0)4 77 36 86 96
[email protected]

The information in this brochure is provided in good faith. To our knowledge it reflects the truth.
SNF Products
in the Sugar
Industry
SNF Products in the Sugar Industry
Introduction
SNF Floerger has 25 years of experience in the manufacturing of hydrosoluble polymers, mainly
flocculants and coagulants used for water and wastewater treatment. SNF has expanded its range
of products to include scale and corrosion inhibitors, anti-foam, deviscosifiers and biocides.

All these products are used by the sugar industry, in the process itself as well as in the wastewater
treatment.

Uses
Product Brand Application

FLOCCULANT FLOPAM For sugar juice and mud-water

COAGULANT FLOQUAT Filtration aid

DESCALING FLOSPERSE In juice evaporation and heat exchangers

ANTI-FOAM FLOFOAM For beet cleaning

Diffusion and purification juice
in fermentation and distillation processes

BIOCIDE Diffusion juice and press waters

Equipment disinfection
SNF Products in the Sugar Industry
FLOQUAT Coagulants
1 FLOPAM Flocculants
Organic hydrosoluble polymers regroup both the flocculants and the organic coagulants.
anionic flocculants and polyamines used by the sugar industry :
The flocculants used by the sugar industry are drinking water grade powder anionic polymers with
a suitable molecular weight for the process
The organic coagulants most suited for the sugar process are polyamines.
SNF has the largest range of flocculants available in the market today (FDA certified and Kosher
grade).
These flocculants are used at three levels in the sugar process:
In order to recycle the beet cleaning water. Wether decanters or settling ponds are used, the floc-
culant enhances greatly the quality of the recycled water, even at the end of the season.
In the CLARIFICATION step, after grinding sugar canes.
The juice obtained has a sugar content of 12% to 15%
(BRIX degree). Depending on the season (rain), wether
the grinding of the stalks is manual or mechanical, this
juice contains more or less impurities: both soluble and
insoluble, organic and inorganic.
FLOPAM flocculants are used in order to enhance the
settling of the fine solid particles in suspension, such as
fibers, clays and lime.
In the SETTLING step of the beet process, some refi-
neries are equiped with DORR and PUTSCH settling
tanks after the purifier. The use of FLOPAM flocculants
in this step will increase the settling speed and minimi-
se the size of the settlers.
2 FLOFOAM Defoamer
Foam is a gas dispersion in a liquid or solid continuous phase. Foam is created and stabilized by
the surfactants which are at the air/liquid interface.

SNF produces specific defoamers for every situation (Kosher Quality or FDA).
- Beet cleaning stage. SNFs defoamers are organic. The injection points are usually at
the water input of the washers where FLOFOAM H 344 is recommended. In the settling tanks,
FLOFOAM HC 244 is more suitable.
- Diffusion stage. There are four
main types of diffusers: RT, DES MET, BMA
and DDS. In all these diffusers a defoamer
is necessary. The most efficient type of
defoamer will depend on the type of dif-
fuser and wether it is for hot juices, where
FLOFOAM AS 2 et AS 9 are recommended
or for cold juices, where FLOFOAM AS 8B
is oiften the most efficient.

SNFs technical ass i s t a n ce tea m

will provide you with the necessary exper-
tise to optimise the use of the chemicals
and select the injection points.

- Crystallization stage. Defoamers

are used in this step in order to lower the
viscosity of the juices when these are pla-
ced under vacuum where they will thicken
and become unpumpable.

- Distillery. SNF has

in its range several defoamers devolopped specifically to prevent foaming
in the fermenters. Products such as FLOFOAM AS 8B, FLOFOAM AS 11 are
designed for the distillation columns and FLOFOAM AS 25 for the wine
sludge concentration.
SNF Products in the Sugar Industry
3 FLOSPERSE Scale Inhibitors
The sugar harvest last from three to six months depending on the country and the plant. Three to
six months for beets and six months for cane.
In the juice evaporation process, all the conditions are present to create scaling: Evaporation of
water, increasing pH and increasing temperature will crystallize the salts present in the juices and
favor organic deposition.
In the beet process, scaling in the evaporation chambers will decrease the heat transfer. This will
increase the energy demand.
In the cane process, this phenomenon is increased by the presence of large quantities of Silica and
by the length of the campaign itself (6 months). Several maintenance cleaning have to be done
during the campaign.
A continuous use of a scale inhibitor such as FLOSPERSEis therefore necessary. This dispersant will
slow down scaling and decrease the numbers of cleaning.

The nature of the salts is variable: Calcium Carbonate; Calcium

Oxalate; Silica; partially burned organic matter.
The deposits are mainly found in the hottest sections of the
evaporation tubes. On the exchangers and other apparatus
having different concentrations, the deposits take place also in
the hottest zones and where the salts are most concentrated.
SNFs FLOSPERSE are based on polyacrylates, phosphonates
and other specific dispersants. They remain efficient over a
wide range of pH and temperature.
A regular analysis on a representative sample (usually every 8
hours) is enough to control the incoming and outgoing lime
salts. This analysis is also used to regulate the dosage pump that
feeds the FLOSPERSE injection.
4 Biocides
In several steps of sugar refining, bacteria and biofilms (bacteria+yeast+mold) are formed.
These micro-organisms, by fermentation, generate gas, create odors, color the juice and, overall,
lower productivity.

SNFs, FDA approved, biocide and biostatic range of products provide an answer to all the needs
for treatment in the sugar industry.

The main biological developments encountered are as below:

Sugar Biodegredation:

Yeast Alcohol
Lactic Bacterium Lactic Acid
Butyric Bacterium Butyric Acid
Acetone-Butanolic Bacterium Acetone-Butanolic Acid
Leuconostocs Dextran

Biocide treaments are mainly applied in the following steps of the process:
1- Beet Hopper: Germ disinfection before diffusion.
2- Press Water: Depending on the refinery itself (pressability and lactic acid).
3- Diffusion of the hot and/or cold juices.

Biocides are more or less used to complement formaldehyde. In this case the dosages of bio-
cides are much lower.

In order to determine the efficiency of a biocide treatment, several analytical techniques can
be used:

- The most usual technique is to measure the lactic acid level automatically.
- Counting leuconostoc in Petri dish
- Bacteria counting by microscope.
- pH follow-up by diffusion.

SNFs Technical Assitance team is at

your disposal for the choice in
injection points.
SNF Products in the Sugar Industry
Beet Sugar Process
Antifoam Biocide*
FLOFOAM

Slicer
Beet
Washer
Flocculant sliced
FLOPAM beet

Antifoam Biocide
FLOFOAM

Pulping aid*
FLOPAM or FLOFOAM
Raw
pressed Hot Water Juice
pulp

Antifoam* Pulp Press Diffusion

FLOFOAM
Biocide
Press wastewater

CO2
Antifoam*
FLOFOAM
Flocculant
Lime Lime FLOPAM Coagulant*
FLOQUAT

Filters

Liming Liming Carbonatation Settling Filtration

Mud

Biocides*
Antiscalant FLOSPERSE
Molasses
Crystallizing aids*
FLOFOAM Dewaterin
g

Drying

Sirop Crystallization
Syrup Sugar
Evaporation
*: Usage depends on the sugar factory
Cane Sugar Process
Biocide

Mixed
Juice
Cane
stalk

Grinding and Juice Mill

Decolorizing agents*
FLOQUAT Flocculant
FLOPAM

Lime
Clarified
juice

Coagulant*
FLOQUAT

Liming
Clarification
Filtrate recycling

Sludge
Filtration

Biocide*
Antiscalant FLOSPERSE
Crystallizing aids* Molasses
FLOFOAM
Dewaterin
g

Drying

Sirop Crystallization
Syrup Sugar
Evaporation
*: Usage depends on the sugar factory
SNF Products in the Sugar Industry
Distillation Process
Substrates:
Molasses
Cane Juices
Beet Juices
Syrup

Antifoam
FLOFOAM

Fermentation

Rhum
alcohol Alcohol for drinking
Alcohol for perfume
Bio-fuel
Antiscalant* Antifoam
FLOSPERSE FLOFOAM

Wine concentrated
sludge wine sludge

Wine sludge concentrator

Distillation
Antifoam
FLOFOAM

agriculture
fertilizer

*: Usage depends on the sugar factory