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PLIBRICO COMPANY LLC Safety Data Sheet

1010 N. Hooker Street, Chicago, Illinois 60642
Phone: (312) 337-9000
Fax: (312) 337- 9003 Revised Date: 10/19/2015
www.plibrico.com Supersedes: 1/27/2015

SECTION 1 - MATERIAL IDENTIFICATION

Trade Name and Synonyms: Plicast C/G LWI Product Number: 18012
Al 2 O3 - % -
40.6 SiO2 46.0 % Manufacturers Code I.D. : L - 3064
Chemical Name and Synonyms: High Temperature Cement Chemical/Mineral Family: Alumino Silicate
Recommended Use: Refractory/Construction/maintainence/repair material
Manufacturer: Plibrico Company LLC Supplier: Plibrico Company LLC
1010 N. Hooker Street, Chicago, Illinois 60642 1010 N. Hooker Street, Chicago, Illinois 60642
Phone 312-337-9000; Fax 312-337-9003 Phone 312-337-9000; Fax 312-337-9003
www.plibrico.com www.plibrico.com
Contact Person: Tom Ervin, [email protected]
EMERGENCY PHONE: 312-337-9000,
After 4:30PM weekdays, Weekends, and Holidays:
740-820-8746, 740-604-1033
SECTION 2- HAZARDOUS IDENTIFICATION

HMIS Rating
Health * 1
Signal Word: Danger 0
Flammability
Hazard statement: H315: Causes skin irritation, H320: Causes eye irritation
H335: May cause respiratory irritation H351: Suspected of causing cancer Physical Hazard 0
H373: May cause damage to lung through prolonged or repeated inhalation. Personal Protection E

This product contains crystalline silica, a substance that has been listed by: NFPA Rating scale 0-4
1. IARC: sufficient evidence for the carcinogenicity of crystalline silica to humans. (Group 1) Flammability
2. Canadian WHMIS : D2A - Materials Causing Other Toxic Effects 0
Health *1 0 Instability
3. ACGIH: A2-Suspected Human Carcinogen. --
4. NTP: a substance known to be a human carcinogen. Special

Special Notes: *** Greater amounts of Quartz and Cristobalite may be formed after firing.
Major portion of the crystalline silica present in the product as manufactured is not fine enough to normally be considered
respirable.
Precautionary Statements:
P260+P261 - Avoid breathing dust/fume/gas/mist/vapors/spray
P280 - Wear eye protection/face protection
P285 - Wear respiratory protection
P305+P351+P338 - If in eyes: Rinse cautiously with water.
P302+P352 - If on skin: Wash with plenty of soap and water.
P501- Dispose of material in accordance with local regulation.
Primary Route of Entry: Inhalation, Ingestion, Skin Contact
Target Organs: respiratory tract (nose & throat), eyes, skin
Potential Health Effects:
Eyes: May cause irritation. Abrasive action of dust can damage eye.
Skin: May cause irritation
Ingestion: May cause gastrointestinal disturbances. Symptoms may include irritation, nausea, vomiting, abdominal pain and diarrhea.
Inhalation: Effects of overexposure:
1. Acute: Exposure to nuisance dust may cause temporary irritation or discomfort to skin, eyes, nose, throat or lungs and may
aggravate bronchial disorders.
2. Chronic: Long term inhalation of respirable quartz, cristobalite, fused silica and/or amorphous silica may cause silicosis (delayed
lung injury) and other respiratory disorders. In addition there is sufficient evidence for the carcinogenicity of crystalline silica to
humans.
Trade Name and Synonyms: Plicast C/G LWI Revised Date: 10/19/2015 Page 2 of 4

SECTION 3- HAZARDOUS INGREDIENTS

Ingredients (checked) TLV ACGIH OSHA PEL
C.A.S. No. Weight % EINECS
mg/m 3 mg/m 3
X Quartz*** 14808-60-7 7.30 0.025(resp.dust) 10 mg/m 3 /%SiO 2+2 (resp) 238-878-4
X Cristobalite*** 14464-46-1 5.47 0.025(resp.dust) 1/2(10 mg/m 3 /%SiO 2+2 (resp)) 238-455-4
X Amorphous Silica*** 69012-64-2 4.0 0.025(resp.dust) Not Established 273-761-1
Fused Silica*** 60676-86-0 0.025(resp. dust) 80 mg/m 3 /%SiO 2 262-373-8
Zirconium Silicate*** 14940-68-2 10 15(total), 5(resp.) 239-019-6
Aluminum Phosphate 13530-50-2 - 2 mg/m 3 TWA(as Al) 2 mg/m 3 TWA(as Al) 236-875-2
Alumina 1344-28-1 - 1(resp.dust) 15(total), 5(resp.) 215-691-6
X Aluminosilicate(Mullite) 1302-93-8 38. - 48. 2(resp.dust) 15(total), 5(resp.) 215-113-2
X Aluminosilicate(Kyanite) 1302-76-7 9.6 - 19. 2(resp.dust) 15(total), 5(resp.) 215-106-4
Bauxite 1318-16-7 - 10 15(total), 5(resp.) -------
Silicon Carbide 409-21-2 - 10 15(total), 5(resp.) 206-991-8
Pyrophyllite 12269-78-2 - 10 15(total), 5(resp.) -------
Spinel 1302-67-6 - 10 15(total), 5(resp.) 215-105-9
Andalusite 12183-80-1 - 10 15(total), 5(resp.) 235-352-6
Zirconiumdioxide 1314-23-4 - 10 15(total), 5(resp.) 215-227-2
X Calcium Aluminate Cement 65997-16-2 15. - 25. 10 15(total), 5(resp.) 266-045-5
Calcium Silicate Cement 65997-15-1 - 10 15(total), 5(resp.) 266-043-4
X Clay 1332-58-7 1.0 - 9.7 2(resp.dust) 15(total), 5(resp.) 265-064-6
Aluminum Sulfate 10043-01-3 - 2(resp.dust) 15(total), 5(resp.) 233-135-0
Barium Sulfate 772-74-37 - 10 10(total), 5(resp.) 231-784-4
Bentonite 1302-78-9 - 10 15(total), 5(resp.) 215-108-5
X Perlite 93763-70-3 7.8 - 17. 10 15(total), 5(resp.) 310-127-6
Sodium Silicate 1344-09-8 - 10 15(total), 5(resp.) 215-687-4
X Titanium Oxide 13463-67-7 1.7 10 15(total), 5(resp.) 215-280-1
Organic Fiber 9003-07-0 0.05 - 0.5 10(total), 3(resp.) 15(total), 5(resp.) ---------

SECTION 4- FIRST AID MEASURES

Eyes: Immediately flush eyes with plenty of water and get medical attention.
Skin: Wash with soap and water. Get medical attention if irritation develops or persists.
Ingestion: If swallowed, seek medical attention.
Inhalation: Remove to fresh air. If not breathing, give artificial respiration. Get immediate attention.
If symptoms persist, seek medical attention.

SECTION 5- FIRE FIGHTING MEASURES

Unusual Fire and Explosive Hazards: The product will not burn. Improper mixing and bake-out of materials may result in steam
spalling during initial heating. Refer to mixing instructions and bake-out schedules for proper procedures.
Fire Fighting Equipment: Fire fighters should wear full protective gear and self-contained breathing apparatus-SCBA.

SECTION 6- ACCIDENTAL RELEASE MEASURES

Steps to be taken in case material is released or spilled: Wear protective clothing as described in Section 8 of this sheet. Use
routine housekeeping procedures, avoid dusting, collect material in closed containers or bags.
Waste Disposal Method: According to the EPA (40CFR 261.3) wastes are not hazardous wastes. Wastes may be disposed of in a
landfill, however, in accordance with federal, state, and local regulations.

SECTION 7 - HANDLING AND STORAGE

To ensure product quality, store material in a dry place. Minimize dust generation and avoid inhalation and contact with refractory
dusts during processing, installation, maintenance and tear-out. After handling of refractory dusts from processing, installation,
maintenance or tear-out, wash exposed skin areas thoroughly. Wash clothing contaminated with dusts.
Trade Name and Synonyms: Plicast C/G LWI Revised Date: 10/19/2015 Page 3 of 4

SECTION 8 - EXPOSURE CONTROL/PERSONAL PROTECTION

Ventilation: Local and Mechanical: follow OSHA STD 29 CFR 1910.94.
Respiratory Protection: Good ventilation should be provided if dust is created when working with materials. Used material, which is
being removed, should be dampend to reduce dust. In addition, when dust is present, workers should employ repirator protection.
Recommended: NIOSH approved respirator for dusts and mists, including silica, in compliance with OSHA STD 29.CFR1910.134.
Protection Gloves: Protective gloves recommended.
Eye Protection: Safety glasses/goggles.
Other Protective Equipment: As required to meet applicable OSHA standards.
Note: See Section 3 for occupational exposure limit values.

SECTION 9- PHYSICAL AND CHEMICAL PROPERTIES

Appearance, Color & Odour: Granular aggregate & fine solid mix, brown or grey in color, earthly smell
Solubility in Water: Negligible pH: Alkaline Vapor Pressure: Not applicable
Boiling Point (o ): N/A Vapor Density: Not applicable
Melting Point (o ): 2400F / 1315C Evaporation Rate: Not applicable

Specific Gravity: 1 % Volatile by Weight: Not applicable

SECTION 10- STABILITY AND REACTIVITY DATA
Stability: Stable Hazardous Polymerization: May not occur Incompatibility: Materials to avoid: N/A
Hazardous Decomposition: N/A

SECTION 11 - TOXICOLOGICAL INFORMATION

Effects of overexposure:
1. Acute: Exposure to nuisance dust may cause temporary irritation or discomfort to skin, eyes, nose, throat
or lungs and may aggravate bronchial disorders.
2. Chronic: Long term inhalation of respirable quartz, cristobalite, fused silica and/or amorphous silica may
cause silicosis (delayed lung injury) and other respiratory disorders.
3. Prolonged contact with skin may cause irritation.
For crystalline silica (quartz /cristobalite):
CARCINOGENICITY: Product contains crystalline silica which may cause delayed respiratory disease (silicosis) if inhaled
over a prolonged period of time. IARC concludes that "there is a sufficient evidence for the carcinogenicity of crystalline
silica to humans." (Group 1).
For aluminum silicate: Aluminum silicate minerals have been found to cause lung fibrosis in the absence of crystalline silica.

SECTION 12 - ECOLOGICAL INFORMATION

No ecological concerns have been identified.
Not applicable for as-manufactured refractory product. Dusts of as-manufactured refractory product have a low order of aquatic
toxicity (rating TLm96: over 1000 ppm), are insoluble, and are not very mobile. Based upon this information, it is not believed to be
a significant threat to the environment if accidentally released on land or into water. However, dusts generated during maintenance
and tear-out operations may be contaminated with other hazardous substances (e.g. metal). Evaluation of dusts from specific
processes should be performed by a qualified environmental professional to determine if an environmental threat exists in the case
of a release.

SECTION 13 - DISPOSAL CONSIDERATIONS

Waste Disposal Method: According to the EPA (40CFR261.3) wastes are not hazardous wastes. Wastes may be disposed of in a
landfill, however, in accordance with federal, state, and local regulations. However, dusts generated during maintenance and tear-out
operations may be contaminated with other hazardous substances (e.g. metals). Therefore, appropriate waste analysis may be
necessary to determine proper disposal. Waste characterization and disposal/treatment methods should be determined by a qualified
environmental professional in accordance with applicable federal, state and local regulations.
Trade Name and Synonyms: Plicast C/G LWI Revised Date: 10/19/2015 Page 4 of 4

SECTION 14 - TRANSPORT INFORMATION

Canadian Transportation of Dangerous Goods Regulation: Hazard Class & PIN: Not Regulated
DOT Proper Shipping Name (29 CFR 172.101): Not regulated
DOT Hazard Class (29 CFR 172.101): Not regulated
UN/NA Code (49 CFR 172.101): Not applicable
DOT Labels Required (49 CFR 172.101): Not applicable
DOT Placards Required (49 CFR 172.504): Not applicable
Land Transport ADR/RID (cross-border): Not regulated
Maritime Transport IMDG : Not regulated
Air Transport ICAO-TI and IATA-DGR: Not regulated

SECTION 15 - REGULATORY INFORMATION

CANADIAN WHMIS: D2A

CANADIAN EPA: Components of this product are listed on the Domestic Substance List (DSL).
U.S. FEDERAL REGULATIONS:
OSHA: Hazardous by definition of Hazard Communication Standard (29 CFR 1910.1200).
SARA TITLE III: EPCRA Section 302 (EHSs):
This product does not contain ingredients subject to reporting requirements of 40 CFR Part 355, Appendices A and B (Extremely
Hazardous Substances).
CERCLA Section 304:
This product does not contain ingredients subject to state and local reporting under Section 304 of SARA Title III as listed in 40
CFR Part 302, Table 302.4
SECTION 311/312 HAZARD CATEGORIES:
Product (airborne particulates) is categorized as an immediate (acute) health hazard and a delayed (chronic) health hazard as defined
by SARA Title III Section 311/312 (40 CFR 370).
SECTION 313 TOXIC CHEMICALS: None
TSCA: Components of this product are listed on the TSCA Inventory.

SECTION 16 - OTHER INFORMATION

Only Trained personel should use this material.

Abbreviations:
ACGIH: American Conference of Governmental Industrial Hygienists
CAS: Chemical Abstracts Service
CERCLA: Comprehensive Environmental Response, Compensation and Liability Act
DOT: Department of Transportation
EPA: Environmental Protection Agency
IARC: International Agency for Research on Cancer
NFPA: National Fire Protection Association
NIOSH: National Institute for Occupational Safety and Health
NTP: National Toxicology Program
OSHA: Occupational Safety and Health Administration
SARA: Superfund Amendment and Reauthorization Act
WHMIS: Workplace Hazardous Materials Information System (Canada)

DISCLAIMER
The information presented herein is presented in good faith and believed to be accurate as of the effective date of this Safety Data
Sheet. Occupational exposure limits are under constant review and may be changed at any time. Employers may use this SDS to
supplement other information gathered by them in their efforts to assure the health and safety of their employees and the proper use
of this product. This summary of the relevant data reflects professional judgment. Employers should note that information perceived
to be less relevant has not been included in this SDS. Therefore, given the summary nature of this document, Plibrico Company LLC
does not extend any warranty (expressed or implied), assume any responsibility or make any representation regarding the
completeness of this information or its suitability for the purposes envisioned by the user. No warranty guarantee or representation
is made to its accuracy, reliability or completeness. It is the user's responsibility to satisfy himself as to the suitability of such
information for his own particular use. In addition, Plibrico Company LLC shall not be liable for injury arising by either misuse of
materials, or failure to follow safety procedures as outlined in the safety data sheet.