Penguard HB II Comp A
Penguard HB II Comp A
Penguard HB II Comp A
Penguard HB II Comp A
(In accordance with Article 41, Paragraph 1, of Industrial Safety and Health Act)
: Penguard HB II Comp A
Label No.
: 5340
Product description
: Paint.
Product type
: Liquid.
C. Supplier/Manufacturer
Emergency telephone
number
5340;6621;6620
5340
^(ValidationDate).
Approved
Signal word
: Danger.
Hazard statements
Precautionary statements
Prevention
: Wear protective gloves. Wear eye or face protection. Keep away from heat, hot
surfaces, sparks, open flames and other ignition sources. No smoking. Use
explosion-proof electrical, ventilating, lighting and all material-handling equipment.
Use only non-sparking tools. Take precautionary measures against static discharge.
Keep container tightly closed. Avoid release to the environment. Do not breathe
vapour or spray. Wash hands thoroughly after handling. Contaminated work
clothing should not be allowed out of the workplace.
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Storage
: Get medical attention if you feel unwell. IF ON SKIN (or hair): Take off immediately
all contaminated clothing. Rinse skin with water or shower. IF ON SKIN: Wash
with plenty of soap and water. Take off contaminated clothing. If skin irritation or
rash occurs: Get medical attention. IF IN EYES: Rinse cautiously with water for
several minutes. Remove contact lenses, if present and easy to do. Continue
rinsing. Immediately call a POISON CENTER or physician.
: Store in a well-ventilated place. Keep cool.
Disposal
: Dispose of contents and container in accordance with all local, regional, national
and international regulations.
C. Other hazards which do : None known.
not result in
classification
: Mixture
Ingredient name
talc (non-asbestos form)
fatty acids, c18-unsatd., dimers, polymers
with bisphenol a and epichlorohydrin
xylene
aluminium stabilized
epoxy resin (MW 700-1200)
1-methoxy-2-propanol
Synonym
Fatty acids, C18-unsatd.,
dimers, polymers with
bisphenol A and
epichlorohydrin; Bisphenol
A, epichlorohydrin, dimer
fatty acids polymer; Fatty
acids, C18-unsaturated,
dimers, polymer with
(chloromethyl)oxirane and
4,4'-(1-methylethylidene)bis
[phenol]; Oxirane,
(chloromethyl)-, polymer
with fatty acids and 4,4'(1-methylethylidene)bis
(phenol); Fatty acids,
C18-unsaturated dimers,
polymers with bisphenol A
and epichlorohydrin
Benzene, dimethyl-; Xylol;
xylene, mixed isomers,
pure; Benzene, dimethyl-,;
Xylene (mixed); Xylenes;
Dimethylbenzene;
XYLENES (Isomer Mixture)
aluminium powder
(stabilised)
4,4'-Isopropylidendiphenol,
Polymer mit 2,2-Bis(p-(2,
3-epoxy; 4,4'Isopropylidenediphenol,
oligomeric reaction
products with 1-chloro-2,
3-epoxypropane; Bisphenol;
Bisphenol A-bisphenol A
diglycidyl ether polymer
monopropylene glycol
methyl ether;
1-methoxypropan-2-ol;
2-Propanol, 1-methoxy-;
Propylene glycol
monomethyl ether;
Dowtherm 209; Propylene
glycol methyl ether;
1-Methoxy-2-propanol,
2-Methoxy-1-methylethanol;
1-Methoxy-
CAS number
14807-96-6
67989-52-0
20-30
20-30
1330-20-7
10-20
7429-90-5
2.5-10
25036-25-3
2.5-10
107-98-2
2.5-10
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butan-1-ol
formaldehyde
2-hydroxypropane; PGME;
methoxyisopropanol
naphtha (petroleum),
64742-82-1
hydrodesulphurized heavy;
Low boiling point hydrogen
treated naphtha; Naphtha,
petroleum,
hydrodesulfurized heavy;
Naphtha, (petroleum),
heavy, hydrodesulfurized
n-butanol; 1-Butanol; n71-36-3
BUTYL ALCOHOL; nBUTYL ALCOHE; n-Propyl
carbinol; 1-Hydroxybutane;
Butyl alcohol; 1-Butanol (I);
n-Butyl alcohol (I); Normal
butyl alcohol
Formalin; Formic aldehyde; 50-00-0
Methaldehyde; Methanal;
Oxomethane;
Oxymethylene; Methylene
oxide; Methyl aldehyde
2.5-10
2.5-10
0-0.1
There are no additional ingredients present which, within the current knowledge of the supplier and in the
concentrations applicable, are classified as hazardous to health or the environment and hence require
reporting in this section.
Occupational exposure limits, if available, are listed in Section 8.
B.
C.
D.
E.
Ingestion
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Eye contact
Over-exposure signs/symptoms
Inhalation
: No specific data.
Ingestion
: Not available.
Notes to physician
Hazardous thermal
decomposition
products
C. Special protective
equipment for firefighters
Special precautions for
fire-fighters
: No action shall be taken involving any personal risk or without suitable training.
Evacuate surrounding areas. Keep unnecessary and unprotected personnel from
entering. Do not touch or walk through spilt material. Shut off all ignition sources.
No flares, smoking or flames in hazard area. Do not breathe vapour or mist.
Provide adequate ventilation. Wear appropriate respirator when ventilation is
inadequate. Put on appropriate personal protective equipment.
: Avoid dispersal of spilt material and runoff and contact with soil, waterways, drains
and sewers. Inform the relevant authorities if the product has caused environmental
pollution (sewers, waterways, soil or air). Water polluting material. May be harmful
to the environment if released in large quantities.
Date of issue/Date of revision : 12.01.2016.
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Large spill
: Stop leak if without risk. Move containers from spill area. Use spark-proof tools and
explosion-proof equipment. Dilute with water and mop up if water-soluble.
Alternatively, or if water-insoluble, absorb with an inert dry material and place in an
appropriate waste disposal container. Dispose of via a licensed waste disposal
contractor.
: Stop leak if without risk. Move containers from spill area. Use spark-proof tools and
explosion-proof equipment. Approach the release from upwind. Prevent entry into
sewers, water courses, basements or confined areas. Wash spillages into an
effluent treatment plant or proceed as follows. Contain and collect spillage with noncombustible, absorbent material e.g. sand, earth, vermiculite or diatomaceous earth
and place in container for disposal according to local regulations (see Section 13).
Dispose of via a licensed waste disposal contractor. Contaminated absorbent
material may pose the same hazard as the spilt product. Note: see Section 1 for
emergency contact information and Section 13 for waste disposal.
: Eating, drinking and smoking should be prohibited in areas where this material is
handled, stored and processed. Workers should wash hands and face before
eating, drinking and smoking. Remove contaminated clothing and protective
equipment before entering eating areas. See also Section 8 for additional
information on hygiene measures.
Exposure limits
xylene
aluminium stabilized
1-methoxy-2-propanol
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formaldehyde
Recommended
monitoring procedures
Hand protection
Eye protection
Skin protection
Hygiene measures
: If workers are exposed to concentrations above the exposure limit, they must use
appropriate, certified respirators. Use respiratory mask with charcoal and dust filter
when spraying this product.(as filter combination A2-P2). In confined spaces, use
compressed-air or fresh-air respiratory equipment. When use of roller or brush,
consider use of charcoalfilter.
: There is no one glove material or combination of materials that will give unlimited
resistance to any individual or combination of chemicals.
The breakthrough time must be greater than the end use time of the product.
The instructions and information provided by the glove manufacturer on use,
storage, maintenance and replacement must be followed.
Gloves should be replaced regularly and if there is any sign of damage to the glove
material.
Always ensure that gloves are free from defects and that they are stored and used
correctly.
The performance or effectiveness of the glove may be reduced by physical/chemical
damage and poor maintenance.
Barrier creams may help to protect the exposed areas of the skin but should not be
applied once exposure has occurred.
For right choice of glove materials, with focus on chemical resistance and time of
penetration, seek advice by the supplier of chemical resistant gloves.
The user must check that the final choice of type of glove selected for handling this
product is the most appropriate and takes into account the particular conditions of
use, as included in the user's risk assessment.
: Use safety eyewear designed to protect against splash of liquids.
: Personnel should wear antistatic clothing made of natural fibres or of hightemperature-resistant synthetic fibres.
: Wash hands, forearms and face thoroughly after handling chemical products, before
eating, smoking and using the lavatory and at the end of the working period.
Appropriate techniques should be used to remove potentially contaminated clothing.
Contaminated work clothing should not be allowed out of the workplace. Wash
contaminated clothing before reusing. Ensure that eyewash stations and safety
showers are close to the workstation location.
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: Liquid.
: Various
: Characteristic.
: Not available.
E. Melting/freezing point
: Not applicable.
: Not applicable.
F. Boiling point/boiling
range
G. Flash point
Burning time
: Not applicable.
Burning rate
: Not applicable.
H. Evaporation rate
I.
Flammability (solid,
gas)
: 0.8 - 13.74%
K. Vapour pressure
: Highest known value: 2.7 kPa (20.3 mm Hg) (at 20C) (Hydrocarbons, C9-C12, nalkanes, isoalkanes, cyclics, aromatics (2-25%)). Weighted average: 1.22 kPa (9.
15 mm Hg) (at 20C)
: Insoluble in the following materials: cold water and hot water.
L. Solubility
M. Vapour density
N. Relative density
: Highest known value: 3.7 (Air = 1) (xylene). Weighted average: 3.36 (Air = 1)
: 1 to 1.54 g/cm
: Not available.
P. Auto-ignition
temperature
Q. Decomposition
temperature
: Not available.
SADT
R. Viscosity
S. Molecular weight
: Not available.
: Dynamic: Highest known value: 2.95 cP (butan-1-ol) Weighted average: 1.27 cP
Kinematic (40C): >22.5 cSt
: Not applicable.
B. Possibility of
hazardous reactions
C. Conditions to avoid
: Under normal conditions of storage and use, hazardous reactions will not occur.
D. Incompatible materials
E. Hazardous
decomposition
products
: Avoid all possible sources of ignition (spark or flame). Do not pressurise, cut, weld,
braze, solder, drill, grind or expose containers to heat or sources of ignition.
: Keep away from the following materials to prevent strong exothermic reactions:
oxidising agents, strong alkalis, strong acids.
: Under normal conditions of storage and use, hazardous decomposition products
should not be produced.
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Skin
Eyes
B. Delayed and immediate effects and also chronic effects from short and long term exposure
Acute toxicity
Product/ingredient name
Result
Species
Dose
Exposure
xylene
Rat
Rat
Rabbit
Rat
6700 ppm
4300 mg/kg
13 g/kg
6600 mg/kg
4 hours
-
1-methoxy-2-propanol
Irritation/Corrosion
Product/ingredient name
Result
Species
Score
Exposure
Observation
1-methoxy-2-propanol
Rabbit
Rabbit
24 hours
500
milligrams
500
milligrams
Sensitisation
Not available.
Potential chronic health effects
General
Inhalation
Ingestion
Skin contact
Eye contact
: Once sensitized, a severe allergic reaction may occur when subsequently exposed
to very low levels.
: No known significant effects or critical hazards.
Carcinogenicity
Mutagenicity
Teratogenicity
Developmental effects
Fertility effects
Chronic toxicity
Not available.
Carcinogenicity
Not available.
Mutagenicity
Not available.
Teratogenicity
Not available.
Reproductive toxicity
Not available.
Specific target organ toxicity (single exposure)
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Category
Route of
exposure
Target organs
1-methoxy-2-propanol
Hydrocarbons, C9-C12, n-alkanes, isoalkanes, cyclics,
aromatics (2-25%)
butan-1-ol
Category 3
Category 3
Not applicable.
Not applicable.
Narcotic effects
Narcotic effects
Category 3
Not applicable.
Respiratory tract
irritation and
Narcotic effects
Name
Category
Route of
exposure
Target organs
Category 1
Not determined
Not determined
Aspiration hazard
Name
Result
C. ATE value
Route
Result
Oral
Dermal
Inhalation (vapours)
16365,5 mg/kg
10481,1 mg/kg
104,8 mg/l
Product/ingredient name
Result
Species
Exposure
aluminium stabilized
48 hours
96 hours
Algae
Fish
72 hours
96 hours
3 days
48 hours
B. Persistence/degradability
Product/ingredient name
Aquatic half-life
xylene
Hydrocarbons, C9-C12, n- alkanes, isoalkanes, cyclics,
aromatics (2-25%)
Photolysis
Biodegradability
Readily
Not readily
C. Bioaccumulative potential
Product/ingredient name
LogPow
BCF
Potential
xylene
1-methoxy-2-propanol
Hydrocarbons, C9-C12, nalkanes, isoalkanes, cyclics,
aromatics (2-25%)
butan-1-ol
formaldehyde
3,12
<1
-
8.1 to 25.9
10 to 2500
low
low
high
1
0,35
low
low
D. Mobility in soil
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: Not available.
: No known significant effects or critical hazards.
B. Disposal precautions
: Paint
UN Number
: 1263
Class
: 3
Packing group
: III
Label
Additional information
ADR / RID
IMDG
ISHA Article 38
: Not applicable
TCCA Observational
chemicals
TCCA Article 32
(Banned)
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: The following components are listed: Xylene; Barium and its compounds; Aluminium
and its compounds; Ethylbenzene
: Not determined.
Korea inventory
C. Dangerous Materials
: Class: Class 4 - Flammable Liquid
Item: 4. Class 2 petroleums - Water-insoluble liquid
Safety Management Act
Threshold: 1000 L
Danger category: III
Signal word: Contact with sources of ignition prohibited
D. Wastes regulation
: Dispose of contents and container in accordance with all local, regional, national
and international regulations.
E. Regulation according to other foreign laws
Europe inventory
: Not determined.
United States
inventory (TSCA 8b)
: Not determined.
Japan inventory
: Not determined.
: Not available.
B. Date of issue/Date of
revision
: 12.01.2016.
C. Version
: 3
Date of printing
: 12.01.2016.
D. Other
Indicates information that has changed from previously issued version.
Notice to reader
The information in this SDS is based on the present state of our knowledge and on current laws. The product
is not to be used for purposes other than those specified under section 1 without first obtaining written
handling instructions. It is always the responsibility of the user to take all necessary steps to fulfil the
demands set out in the local rules and legislation. The information in this SDS is meant to be a description of
the safety requirements for our product. It is not to be considered a guarantee of the product's properties.