Prediction of The Reid Vapor Pressure of Petroleum Fuels: M. R. Riazi, T. A. Albahri and A. H. Alqattan

PREDICTION OF THE REID VAPOR PRESSURE OF
PETROLEUM FUELS
M. R. Riazi*, T. A. Albahri and A. H. AlQattan
Chemical Engineering Department, Kuwait University,
P.O.Box 5969, Safat 13060, Kuwait
*Tel: (+965) 4817662; Fax: (+965) 4811772
*Homepage: http://139.141.199.1/~riazi
[email protected]
Introduction
The volatility characteristics of petroleum fuels are very
important especially for gasolines. Motor and aviation gasolines are
manufactured as liquids but they are consumed in the vapor phase.
Consequently, gasoline volatility must be high enough to assure
acceptable engine start-up, warm-up, acceleration and throttleresponse under normal driving (or flying) conditions. On the other
hand, the maximum volatility of a gasoline must be restricted to
avoid vapor lock, vaporization losses, air pollution, and unsafe
storage and handling. The volatility considerations for other
transportation fuels like kerosene and diesel are, to some extent,
similar to those for gasoline.
The Reid vapor pressure (RVP) is frequently used as an
indication of volatility of liquid hydrocarbons. The RVP is defined as
the absolute pressure (i.e., psia or bar) exerted by a mixture,
determined at 100 F (37.8 C) and at a vapor to liquid ratio of 4.
This is different than the true vapor pressure which is defined as the
pressure of a vapor in equilibrium with its condensed phase at a
specific temperature. Although the RVP provides a convenient
approximation of the absolute vapor pressure of a partly vaporized
sample at 100 F, it is not equivalent to the true vapor pressure. In
general, RVP is lower than the true vapor pressure due to some small
sample vaporization and the presence of water vapor and air in the
confined space. The apparatus and procedures for determining the
RVP are standardized and specified in ASTM method D-323 and IP402 [1]. The Reid vapor pressure test is widely used as a criterion for
blending gasoline and other petroleum products. Once RVP of a fuel
is known the methods provided in the API-TDB [2] can be used to
estimate true vapor pressure of a fuel or a crude oil at any desired
temperature. True vapor pressure is an important thermodynamic
property related to volatility and phase equilibrium calculations.
There are a number of methods for estimating the vapor pressure
of petroleum fractions but very few for Reid vapor pressure. The
method presented in the API-TDB [2] for estimation of RVP is based
on rigorous vapor-liquid equilibrium calculations. A number of
simple methods have been developed to estimate the Reid vapor
pressure of finished petroleum products [3]. In the Bird-Kimball
method the gasoline is divided into 28 cuts or boiling ranges
characterized by their average boiling point. A blending RVP of each
cut is then calculated by the following equation [3]:
Bi=
7.641
exp (0.03402 T bi +0.6048)
i=28
(1)
P a = Bi x v i
i=1
f = 1.0 + 0.003744 (VAPB - 93.3)

RVP = f Pa
where Bi = RVP blending number for cut i and Tbi = normal boiling
point of cut i in C. xvi is the volume fraction of cut i and VABP is
the volume average boiling point in C. RVP is calculated in bars.
The constants were obtained from the original constants given in
English units. Use of this method requires full distillation curve of

the fuel to be known. Another simple method is to use a relation for
the true vapor pressure (TVP) of petroleum fractions and to assume
that RVP is the same as TVP at 100 F (311 K). The vapor pressure
relation given by van Nes van Westen [4] can be converted into the
SI unit at 311 K as:
T 41
log(TVP)100 = 3.204 1 4 b
1393 Tb
(2)
where Tb is the normal boiling point in K and TVP100 is the true

vapor pressure at 100 F (311 K) in bars. Once TVP is calculated it
may be used instead of RVP in case of lack of sufficient data. This
method only requires mid-boiling point (or ASTM temperature at 50
volume% vaporized). This give an approximate value for RVP as the
difference between RVP and TVP is ignored. The main objective of
this work was to develop a simple predictive method for RVP of
petroleum fuels from crude oils from around the world which
requires minimum laboratory data as input parameters.
Technical Development
A bank of data on RVP and basic characteristics of 52 gasoline
and naphtha samples from crude oils around the world was prepared
from OGJ Data Book [5]. One simple and relatively accurate
equation for correlation of true vapor pressure of hydrocarbons is the
Miller equation [6]. We apply this equation at 311 K (100 F),
however, the constants in the equation have been determined from
RVP of petroleum fractions and have been related to boiling point
(Tb) and specific gravity (SG) of the fraction in the following form:
RVP = Pc exp(Y)
T SG
5
Y = X b
(1 Tr )
T
r
(3)
X = 276.7445 + 0.06444Tb + 10.0245SG 0.129Tb SG

+
9968.8675
+ 44.6778ln Tb + 63.6683ln SG
Tb SG
Tr = 311/ Tc
where Tc and Pc are the pseudocritical temperature and pressure of

the fraction in degrees Kelvin and bar, respectively. RVP is in bars
and Tb mid-boiling point of mixture in degrees Kelvin . This equation
is based on data with RVP in the range of 0.0007-1.207 bar (0.01
17.5 psia), normal boiling point range of 305 494 K and specific
gravity range of 0.65-1.08. This method may be used for quick
estimation of RVP when only boiling point and specific gravity of a
fuel are known. This equation does not give reliable values for RVP
of wide boiling range fractions such as the whole crude oil. Tc and Pc
needed for use in the above equation may be estimated from the
relations given by Riazi and Daubert [7] that are also included in the
API-TDB [2] using Tb and SG as input parameters. Therefore, with
the minimum knowledge of mid-boiling point and specific gravity
one can get estimate of RVP from Equation (3). A summary of
evaluation of these three methods is given in Table 1. Equations (1)
and (2) nearly give similar result, although Equation (2) is much
simpler than Equation (1). However, the average error for Equation
(3) is 0.06 bar (0.88 psia) which is nearly half of the other two
methods. Predicted versus experimental values of RVP from the
Fuel Chemistry Division Preprints 2003, 48(1), 478
proposed method is also shown in Figure 1. Demonstrated results

indicate that when minimum data on a petroleum fuel is available the
method proposed in this work can be used to estimate RVP of a fuel.
References
(1)
Table 1. Summary of Results for Prediction of RVP of 52 Fuels
(2)
Item
(3)
RVP (bar)
Method
Eqn.
AAD
MD
Proposed model
0.06
0.24
Nes and Van Westen [4]
0.13
0.38
Bird and Kimball [3]
0.12
0.42
(4)
(5)
(6)
(7)
ASTM, Annual Book of Standards, American Society for Testing and

Materials, Philadelphia, Pennsylvania, 1995.
American Petroleum Institute (API) Technical Data Book Petroleum
Refining. Chapter 5, 6th Edition, American Petroleum Institute.,
Washington DC, 1997.
Baird, C.T. Crude Oil Yields and Product Properties, Ch. De la Haute
Belotte 6, 1222 Vezenaz, Geneva, Switzerland, 1981.
Van Nes, K., and Van Western, H.A., Aspects of the Constitution of
Minerals Oils, Elsevier, Amsterdam, 1951.
Oil and Gas Journal Data Book, 2000 Edition, PennWell, Tulsa,
Oklahoma, 2000.
Reid, R. C., Pransnitz, J. W., and Poling, B. E. The Properties of Gases
and Liquids. 4th Edition., McGraw-Hill, Inc., New York, 1987.
Riazi, M.R., Daubert, T.E., Characterization Parameters for Petroleum
Fractions, Ind. & Eng. Chem. Research, 1987, Vol. 26, pp. 755-759.
API Gravity range: 51 87 API, Tb Range: 305 494 K

RVP Range: 0.0007-1.207 bar,
AAD% = (1/no of data) (pred. exp.)/exp.100,
MD%= maximum % deviation
20
18
16
14
Calculated RVP
12
10
8
6
4
2
0
-2
-2
10
12
14
16
18
20
Experimental RVP (psi)
Figure 1. Parity plot for the Reid vapor pressure (RVP) using
Equation (3).
Fuel Chemistry Division Preprints 2003, 48(1), 479

Prediction of The Reid Vapor Pressure of Petroleum Fuels: M. R. Riazi, T. A. Albahri and A. H. Alqattan

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PREDICTION OF THE REID VAPOR PRESSURE OF

f = 1.0 + 0.003744 (VAPB - 93.3)

English units. Use of this method requires full distillation curve of

where Tb is the normal boiling point in K and TVP100 is the true

X = 276.7445 + 0.06444Tb + 10.0245SG 0.129Tb SG

where Tc and Pc are the pseudocritical temperature and pressure of

Fuel Chemistry Division Preprints 2003, 48(1), 478

proposed method is also shown in Figure 1. Demonstrated results

Table 1. Summary of Results for Prediction of RVP of 52 Fuels

Nes and Van Westen [4]

Bird and Kimball [3]

ASTM, Annual Book of Standards, American Society for Testing and

API Gravity range: 51 87 API, Tb Range: 305 494 K

Experimental RVP (psi)

Fuel Chemistry Division Preprints 2003, 48(1), 479

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