TV 17 2010 4 403 410
TV 17 2010 4 403 410
TV 17 2010 4 403 410
ISSN 1330-3651
UDC/UDK 655.22:621.78
1
Introduction
Uvod
Flexography is a printing technology generally used in
packaging. It is a relief printing process meaning that the
image areas on the printing plate are raised above the nonimage areas. During the reproduction process, image areas
receive the printing ink which is transferred directly to the
print substrate when the substrate is pressed with support of
the impression cylinder against the printing plate. The
pressure between the anilox roll (carrier of the printing ink)
and the printing plate, and then between the printing plate
and the substrate, must be carefully adjusted to give a
uniform print with no areas of over impression. The printing
process requires only a slight contact pressure to enable
reliable ink transfer from printing plate to substrate. Soft,
flexible printing plates facilitate quality imprints even with
a low and gentle contact pressure within the printing plate
and printing substrate [1-4]. Printing process is
characterized by flexible printing plates and low viscosity
printing inks. It is possible to print at almost every substrate
[5], i.e. on very thin, flexible, and solid materials, virtually
all papers, thick cardboard, rough-surfaced packaging
materials and fabrics. Flexographic plates vary in their
hardness and thickness which has to be adapted to the
particular substrate and specific process characteristics.
They are mainly made of rubber or photopolymers.
Basically, they consist of elastomeric vehicles, unsaturated
monomers and UV photo-initiators which are soluble in
water or in organic solvents.
Flexographic printing plates can be produced by
photographic/chemical processes or by one of the digital
laser-based computer to plate (CtP) technologies [4, 6].
There are different imaging systems available for CtP in
Technical Gazette 17, 4(2010), 403-410
2
Thermal technology
Termalna tehnologija
Thermal development process is one of the newest
technologies in the field of flexography. It is the process
which allows the removal of untreated (unexposed)
polymer through a strictly mechanical process, without
using any solvents. It has many advantages in regard to
other digital technologies used in the flexographic plate
making process. It is environmentally friendly with no
solvents and aqueous solutions to handle, store or recycle
workflow [7]. It is designed to meet the needs of high
quality imprints with fine halftones, lineworks and solids.
The structure of the CtP flexographic untreated plate for
digital image transfer by CtP systems is shown in Fig. 1. It
consists of protective layer on the top of the plate, followed
by laser energy absorbent layer, photopolymer relief layer
and base material.
CtP flexographic plate making process, based on
thermal development, consists of a series of successive,
mutually dependent stages presented in Fig. 2: back
exposure, laser imaging, main exposure, thermal
development process, post exposure and light finishing
processes (UVAand UVC).
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3
Experimental part
Eksperimentalni dio
3.1
Materials and methods
Materijali i metode
In the study DuPont TM Cyrel DFH 45 printing
plates were tested. The experimental part of the work was
performed in standardized production conditions [9].
Printing plates were stored under the prescribed
Tehniki vjesnik 17, 4(2010), 403-410
3.2
Designing the digital test form
Oblikovanje digitalne testne forme
1 IR source
2 Cylinder (carrier of fabric)
3 Cylinder (carrier of used fabric)
4 Drum (carrier of printing plate)
5 Pressure cylinder
6 Removal of untreated polymer
Figure 3 Thermal development unit
Slika 3. Termalna jedinica
3.3
Back exposure test
Test donje ekspozicije
In order to define the impact of exposure time on relief
depth, different duration of back exposure was tested.
Appropriate back exposure has to be defined because
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3.4
Main exposure and thermal development test
Test glavne ekspozicije i termalne obrade
Testing of the main exposure was made in accordance
with the optimal back exposure, defined in the previous
testing stage. In this phase, the influence of drum rotations
number (thermal development of printing plate sample) was
observed in relation to the main exposure. The test was
carried out with 8, 10, 12 and 14 minutes of main exposure
and 8 and 10 rotations of the drum. The post exposure
(UVA) and light finishing (UVC) was conducted for 7 min
[8]. Optimum duration of the main exposure could be
controlled on the finished printing plates by observing the
halftone patches of 1 and 97 % of surface coverage and by
observing the sharpness of the positive lines of 0,05 mm,
positive and reverse cross lines from 0,03 mm to 0,04 mm.
SEM analysis was performed on those selected areas.
3.5
Characterization of the thickness and hardness of the
printing plates
Karakterizacija debljine i tvrdoe tiskovnih formi
According to the recommendations, the thickness of
flexo plate should not deviate more than 0,010 to 0,015
mm from its nominal value [11]. The same tolerant area is
recommended for the plate thickness within the package
box, while the thickness of the plates between two packages
should not differ more than 0,025 mm.
Regarding the hardness of the flexographic printing
plates it is possible to measure two different values. The first
one is the hardness of the raw plate and the second one is the
hardness of the printing plate after processing. The hardness
of the raw printing plate is usually not controlled, because
this information generally is not useful for plate
functionality. This is the reason why printing plate hardness
must be considered after processing because it has the direct
influence on transferring the printing ink from the plate to
the printing substrate. Suppliers indicate that printing plate
of 1,14 mm of thickness should have hardness of 75 Sh A
with possible tolerances of 2 ShA.
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4
Results and discussion
Rezultati i rasprava
4.1
Defining the back exposure optimal relief depth
Odreivanje donje ekspozicije optimalne dubine reljefa
Results of back exposure test are presented graphically
in Fig. 5.
Based on the results the corresponding dependence
between back exposure and relief depth can be expressed as
follows: longer duration of the back exposure results in
shallower relief. Shorter back exposure (10 s) resulted in
cross linking process in the surface areas of photopolymer
and caused the relief depth of 0,721 mm. Longer back
exposure (80 s) resulted in shallower relief of 0,04 mm.
Based on the results adequate duration of back exposure
was defined on 50 seconds.
Relief depth / mm
0,8
0,6
0,4
0,2
0
0
20
40
60
80
100
Back exposure time /s
4.2
Defining the main exposure and thermal development
Odreivanje glavne ekspozicije i termalne obrade
The main exposure test was conducted through
monitoring further parameters: sharpness of halftone dots of
1 to 98 % of coverage, clearness in reproductions of 0,03
and 0,04 mm positive lines, sharpness of the positive and
reverse line ratios and relief depth.
The main exposure test was conducted in relation to the
thermal development conditions. According to the
manufacturer thermal development should be repeated by
10 to 12 rotations of the drum to remove all the melted
material and the main exposure can vary from 10 min to 15
min. In order to observe shorter duration of thermal
development, it was carried out with 8 and 10 rotations of
the carrying drum. Testing was made for the main exposure
of 8, 10, 12 and 14 minutes for both thermal processing
conditions. After thermal development, each plate was
treated with UVA and UVC light for a period of 7 minutes
(manufacturer's recommendations). As defined in previous
test back exposure was 50 seconds.
Measuring of the relief depth has been carried out in the
same way as the back exposure test and the results are
displayed graphically in Fig. 6. It can be seen that increasing
of main exposure from 8 to 14 min causes the decreasing of
relief depth from 0,383 to 0,31 mm for 8 rotations of the
drum, i.e. from 0,4 mm to 0,31 mm for 10 rotations of the
drum. It can be seen that the observed number of drum
Tehniki vjesnik 17, 4(2010), 403-410
Relief depth / mm
0,5
10 rot
8 rot
0,4
2
0,3
0,2
5
10
15
Main exposure time / min
4.3
SEM analysis
SEM analiza
SEM micrographs of the characteristic elements on a
reproduced test form have been made. Fig. 7 shows SEM
images of 1 % of coverage obtained with main exposure of
12 minutes and processed with 8 and 10 rotations of the
drum. One can see uniformly distributed, stable dots (image
areas) at 1 % of coverage processed with 8 rotations of the
drum (Fig. 7a). Every dot has a clearly formed body shape
and fully cured polymer along the entire polymer plate
surface. From these images it is possible to see that shaped
dots have been formed correctly in exposed photopolymer
areas. Longer thermal processing (10 rotations of the drum)
presented in Fig. 7b indicates that dot of 1 % of coverage has
similar quality and characteristics, and furthermore,
through both processing conditions, untreated polymer has
4.4
Control of the thickness and hardness of the printing
plates
Kontrola debljine i tvrdoe tiskovnih formi
Characterisation of the thickness and hardness of the
printing plates was made in order to control the observed
Figure 7 SEM images of 1 % of coverage (a) main exposure 12 minutes; thermal processing carried out with the 8 rotations of the drum and
(b) main exposure 12 minutes; thermal processing carried out with the 10 rotations of the drum (magnification 100 and 500, respectively)
Slika 7. SEM slike za 1 % pokrivenosti povrine (a) glavna ekspozicija 12 min; termalna obrada sa 8 okretaja bubnja
(b) glavna ekspozicija 12 min; termalna obrada sa 10 okretaja bubnja (poveanje 100 i 500, redom)
Technical Gazette 17, 4(2010), 403-410
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Figure 8 SEM images of 98 % of coverage (a) main exposure 12 minutes; thermal processing carried out with the 8 rotations of the drum and
(b) main exposure 12 minutes; thermal processing carried out with the 10 rotations of the drum (magnification 100 and 500, respectively)
Slika 8. SEM slike za 98 % pokrivenosti povrine (a) glavna ekspozicija 12 min; termalna obrada sa 8 okretaja bubnja
(b) glavna ekspozicija 12 min; termalna obrada sa 10 okretaja bubnja (poveanje 100 i 500, redom)
Figure 9 SEM micrographs of the positive and reverse cross lines of 0,03 and 0,04 mm.
Main exposure 12 minutes; thermal development: (a) 8 and (b) 10 rotations of the drum (magnification 500)
Figure 9. SEM slike pozitivskih i krinih linija debljine 0,03 i 0,04 mm.
Glavna ekspozicija 12 min; termalna obrada: (a) 8 and (b) 10 okretaja bubnja (poveanje 500)
Figure 10 SEM images of halftone fields (50 % coverage), main exposure 12 min; development 8 rotations of the drum
(magnification 100 and 500 respectively)
Figure 10. SEM slike polja (50 % pokrivenosti povrine), glavna ekspozicija 12 min; termalna obrada 8 okretaja bubnja
(poveanje 100 i 500, redom)
Box 2
Printing plate
Thickness, mm
Plate 1
Plate 2
Plate 3
Plate 1
Plate 2
Plate 3
1,145
1,140
1,140
1,140
1,145
1,145
Mean
value, mm
1,142
1,141
5
Conclusion
Zakljuak
Photopolymer printing plates intended for thermal
development have to be processed by a number of
independent but strictly controlled and harmonized stages,
i.e. back exposure, laser ablation, main exposure, thermal
development, post exposure and light finishing. These
production phases have to be in adequate balance for
providing the printing plates of high quality. On the other
hand, the manufacturers' recommendations are commonly
given for characteristic parameters with certain tolerances
which implies that every plate making stage must be
individually defined according to the reproduction
conditions. The aim of this paper was to define optimal
duration of every processing stage with further
improvement: decreasing of duration of certain stages in
order to accelerate the plate making process with a goal to
obtain the plates with optimal quality.
Technical Gazette 17, 4(2010), 403-410
6
References
Literatura
[1] Rentzhog, M. Characterisation of Water-Based Flexographic
Inks and their Interactions with Polymer-Coated Board,
Licentiate Thesis, Royal Institute of Technology, Institute for
Surface Chemistry, Sweden, 2004.
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Authors' addresses
Adrese autora
Dragoljub Novakovi, Prof.
Faculty of Technical Sciences
University of Novi Sad
Trg Dositeja Obradovia 6
21000 Novi Sad, Srbija
E-mail: [email protected]
Sandra Dedijer, Assistant
Faculty of Technical Sciences
University of Novi Sad
Trg Dositeja Obradovia 6
21000 Novi Sad, Srbija
E-mail: [email protected]
Sanja Mahovi Poljaek, Assistant Prof.
Faculty of Graphic Arts
University of Zagreb
Getaldieva 2
10000 Zagreb, Croatia
E-mail: [email protected]
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