World Journal of Engineering and Technology, 2015, 3, 116-126

Published Online August 2015 in SciRes. http://www.scirp.org/journal/wjet

http://dx.doi.org/10.4236/wjet.2015.33013

Investigating the Effect of Various

Nanomaterials on the Wettability of
Sandstone Reservoir
El-Abbas Moustafa1, Ahmed Noah2, Karam Beshay2, Lamees Sultan2,
Mina Essam2, Omar Nouh2
1

Egyptian Petroleum Research Institute (EPRI), Cairo, Egypt

Petroleum and Energy Engineering Department, Faculty of Science and Engineering, The American University,
Cairo, Egypt
Email: [email protected], [email protected], [email protected]
2

Received 14 April 2015; accepted 1 August 2015; published 4 August 2015

Copyright 2015 by authors and Scientific Research Publishing Inc.
This work is licensed under the Creative Commons Attribution International License (CC BY).
http://creativecommons.org/licenses/by/4.0/

Abstract
Wettability is the ability of a fluid to stick to a solid surface in the presence of other immiscible
fluids. Wettability alteration is crucial as it affects the amount of oil recovered from a given reservoir. The majority of enhanced oil recovery mechanisms purposefully alter the wettability of the
reservoir rock from oil-wet to water-wet; to increase the amount of oil recovered from it. This
study investigates the effect of various nanomaterials on the wettability, and particularly the brine
phase contact angle, of a sand stone reservoir. The nanomaterials used are Magnesium/Aluminum
Layered Double Hydroxide, Silica/Zirconia, and a combination of 80.0% Magnesium/Aluminum
Layered Double Hydroxide (Mg/Al-LDH) and 20.0% Silica/Zirconia (Zi/Zr). The results suggest
that a concentration of 4.0 g/L of Magnesium/Aluminum Layered Double Hydroxide (Mg/Al-LDH)
decreases the brine phase contact angle, in the presence of oil, from 66 to 60 in 0.033 minute as
opposed to Silica/Zirconia which increases the brine phase contact angle to 68 in the same time
interval. The combination of both nanoparticles results in a decrease of 1.0 in the brine phase
contact angle indicating that Silica/Zirconia (Zi/Zr) lowers the efficiency of Magnesium/Aluminum
Layered Double Hydroxides adsorption to the sandstone surface.

Keywords
Nanomaterials, Wettability Alteration, Oil Recovery Mechanism

How to cite this paper: Moustafa, E.-A., Noah, A., Beshay, K., Sultan, L., Essam, M. and Nouh, O. (2015) Investigating the
Effect of Various Nanomaterials on the Wettability of Sandstone Reservoir. World Journal of Engineering and Technology, 3,
116-126. http://dx.doi.org/10.4236/wjet.2015.33013

E.-A. Moustafa et al.

1. Introduction

Wettability of rocks is classified into five categories, which are Water Wettability, oil wettability, neutral or intermediate wettability, fractional wettability, and finally, mixed wettability. In water-wet reservoirs, the reservoir rock is preferentially wetted with water which occupies the small pores and contacts most of the rock surface forming a thin film of water that coats the formation matrix [1] [2]. For effective oil transport and recovery,
the water-wet condition is a favourable one [3].
In this study, contact angle measurement and analysis are rigorously explained and applied. The contact angle
is one of the quantities that measure the wettability of a rock/fluid system. It is the angle measured through the
liquid where a solid interface is in contact with a liquid/vapour interface. There are several existing methods for
contact angle measurement such as tilting plate method, the capillary rise method, and the sessile drop method.
The contact angle is defined as the edge of a droplet of fluid placed on a flat surface. The edge of the droplet
when in contact with a surface is divided into three different regions, which are a free surface, a planar interface
and a transition region. The planar interface is the region where the droplet adheres to the solid surface and is
different from the nature of the liquid. The transition region connects the spherical cap to the droplet planar portion. The radii and the tangent are varying accordingly from zero at the planar interface to pi-theta at the spherical cap. This will change the energy with changes in separation when they get close to each other [4].
This contact angle measurement method involves depositing a water, which is brine in the majority of the
cases so as to simulate the reservoir saline condition, drop on the rock surface and adding volume to the drop
until the maximum volume allowed is reached without increasing the three-phase line. The advancing angle is
the maximum possible angle measured resulting from the volume increase. The increase in volume step is followed by a volume removal one where the maximum volume that can be extracted before disturbing the drop
profiles geometry is removed and the resulting contact angle is measured [5]. This angle is the receding angle
which when subtracted from the advancing contact angle yields a value referred to as the contact angle hysteresis The difference between the advancing angle and the receding angle is the hysteresis contact angle H = a
r [6].

Structure of Nanomaterials and Their Applications in the Oil Industry

Nanotechnology is the technology that has enabled us to synthesize material at the nano-structural form. One
nano-meter (nm) is one billionth of a meter or approximately 5 silicon atoms aligned in one line, Figure 1
shows the nano-meter scale compared to other material sizes [7]. Nanotechnology is a complex interdisciplinary
science that has many categories like nano-chemistry, nanophysics, Nanomaterial, nano-electronics and nanobionics.
Applications of Nanotechnology. The use of Nanomaterial in the petroleum field is extremely essential, as
now we need new technology to be able to deplete our reservoir or enhance the material being used to make
more than one function at the time and this is possible through the use of Nanomaterial. The use of Nanomaterial in the petroleum field is wide; we can use it in the drilling operation, in completion and production in most of
the process made.

Figure 1. Classification of nanomaterials.

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Classification of Nanomaterials. The principle sorts of nanostructured materials focused around the measurements of their structural components are: zero-dimensional (0-D), one-dimensional (1-D), two-dimensional
(2-D) and three-dimensional (3-D) nanomaterials. Zero-dimensional nanomaterials incorporate nano-cluster
materials and nano-dispersions, i.e. materials in which nanoparticles are detached from one another. One-dimensional Nano-materials are nano-fiber (nano-rod) and nano-tubular materials with fiber (rod, tube) length
from 100 nm to several microns [8]. Two-dimensional nanomaterials are thin films (coatings) with nano-meter
thickness. Structural components in 0-D, 1-D and 2-D nanomaterials can be appropriated in a fluid or robust
perceptible framework or be connected on a substrate. Three-dimensional Nanomaterials incorporate powders,
sinewy, multilayer and polycrystalline materials in which the 0-D, 1-D and 2-D structural components are in
close contact with one another and structure interfaces. A vital kind of three-dimensional nanostructured material is a minimized or merged (mass) poly-crystal with nano-size grains, the whole volume of which is loaded
with those nano-grains, free surface of the grains is for all intents and purpose missing, and there are just grain
interfaces. The arrangement of such interfaces and vanishing of the nanoparticle (nano-grain) surface is the
essential distinction between three-dimensional smaller nanomaterials and nano-crystalline powders with different degrees of agglomeration that comprise of particles of the same size as the minimized nanostructured materials [9]. Figure 2 shows the difference of the shapes and structure of 0D, 1D, 2D and 3D.
Nanomaterials and Reservoir Wettability. The use of nanomaterial in the field of wettability alteration has
made some promising results in the enhancement of oil production. The use of nanomaterial made these promising results as its size is in the nanometer scale, which enables it to move through the tight pore spaces and fully
flush the reservoir to reach maximum depletion which Having a nanomaterial that would enable altering the
wettability of the reservoir from oil-wet to water-wet means that the ultimate oil recovery could be reached.
Initially, before the nanofluid alters the wettability, the oil droplet has a 180-degree contact angle with the
surface, but when the nanofluid is presents it contracts this angle to nearly 1-degree, and the result is a wedge
film [10]. If there is a one layered wedge film its force will be higher than a two layered wedge film. This wedge
film will be the main acting reason to separate the oil from the formation surface. This will impart the oil particles that are adhered to the rock surface to be removed from the rock and flow and then the nanoparticles adhere to the rock surface. The complete spreading of the nanofluid will make the oil droplet separate completely
from the surface of the rock, when the angle reaches zero [11]. Thus, at this point, we can safely say that there is
a successful alteration of the wettability as we changed the contact angle of the oil from 180-degree to zero degree that is a complete separation cycle.

2. Nanomaterials Used in Experimentation

2.1. Magnesium/Aluminium Layered Double Hydroxide, (Mg/Al-LDH)
As Figure 2 illustrate that Structure of Layered Double Hydroxides. The (Mg/Al-LDH) has the ability to combine two-dimensional layered material and intercalation technique, which gives us a new area for developing
new material with desired functionality [12]. The (Mg/Al-LDH) has a chemical composition general formula of
MII1xMIIIx(OH)2Anx/nyH2O, where MII and MIII are divalent and trivalent metal Cations and An- is an n-vacant
anion. They possess a crystal like structure composed of positively charged hydroxide layers. Mg/Al-LDH is an
effective material in this experiment as it has great potential in adhering or adsorbing on to surfaces which is main
focus of the material being used in the enhancement of oil recovery.

Figure 2. Structure of layered double hydroxides.

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2.2. Silica/Zirconia (Si/Zr)

Silicon and zirconium oxides have been studied extensively in the past years due to their superior physicochemical properties. These properties are classified as follows: higher thermal and chemical stability, hardy
mechanical strength, catalytic activity and strong surface acidity [13]. When dispersed in distilled water or brine,
Aluminium oxide nanoparticles proved their efficacy in reducing oil viscosity and thus, enhancing oil recovery.
Furthermore, hydrophobic silicon oxide nanoparticles change the wettability of rocks upon dispersion in ethanol.
Using ethanol solely as an enhanced oil recovery agent reduces the oil-water interfacial tension. Magnesium
oxide exhibited low capability in enhancing recovery as it causes permeability impairment when dispersed in
brine or distilled water. The use of brine-dispersed Aluminium oxide and ethanol-dispersed Silicon oxide nanoparticles for improving oil recovery is recommended [14].
Initially, all rocks are believed to be water wet, prior to the migration of oil to them from the source rock.
Following migration, oil got trapped and saturated the rock in tight spots, thus replacing the water and becoming
oil wet. After the development of nanomaterial, we are now able to reach tight spots that we not could reach before, as this technology had not yet been applied. The wettability alteration of the rock mainly depends on the
separation of the oil from the surface of the rock and this is called the disjoining pressure, and will be thoroughly
explained in the coming section, which is related to the contact angle of the oil droplet with the surface and the
interfacial tension of the fluid.
The objective of this study to investigate the effect of various nanoparticles on the wettability of a sandstone
reservoir where Magnesium/Aluminum Layered Double Hydroxide (Mg/Al-LDH), Silica/Zirconia (Si/Zr), and
a mixture of both containing 80% Magnesium/Aluminum Layered Double Hydroxide and 20% Silica/Zirconia
by weight are deposited on sandstone rock plates and the corresponding contact angles are measured and recorded. The concentration is kept constant at 4.0 g/L and the changes in contact angles are to be taken as indications of changes in wettability.

3. Methodology
The aim of the research is to investigate the effect of various nanomaterials on the wettability of a sandstone reservoir and particularly the effect of these nano-materials on the water phase contact angle with the surface of
the rocks. Changes in the reservoir rock wettability are of interest in the oil field industry as they reflect on the
amount of oil recovered from the reservoir. When the reservoir wettability is altered from water-wet to oil-wet,
severe impairment is caused to the productivity, therefore, treatments that lead the reservoir to a more water-wet
condition are favourable ones.
The nanomaterials under investigation are Magnesium/Aluminum Layered Double Hydroxide (Mg/Al-LDH),
Silica/Zirconia (Si/Zr), and a mixture of containing 80.0% Magnesium/Aluminum Layered Double Hydroxide
(Mg/Al-LDH) and 20.0% Silica/Zirconia (Si/Zr) by weight. The use of the Mg/Al-LDH is justified by the fact
that none of the previous researchers tested its efficacy in the oil industry in contrast to oxides that have been
extensively used in the field of oil recovery.
The concentration of the above mentioned nano-materials was kept constant at 4.0 g/L in the study making
the type of material the variable. The study is conducted at ambient condition except for the saturation of core
plugs that was conducted at a pressure of 2000 psi. The different instruments used throughout the study are explained in the experimental section.
The contact angle meter was used for measuring the contact angle that each nano-fluid makes with the rock
in an attempt to settle on the one with the greatest positive impact on oil productivity.
The following are the wettability categories that surfaces lie in depending upon the range in which their contact angle falls:
0 < 90

Water-wet

= 90

Neutral or Intermediate wet

90 < 180

Oil-wet

The relation between the contact angle and the interfacial energies is governed by Youngs equation:

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=
cos
oos ows
oow

(1.1)

= Contact angle measured through the water phase at Rock/Oil/Brine interface;

= Interfacial energy between Solid and Oil, (dyne/cm)
oos
= Interfacial energy between Solid and Water, (dyne/cm),
ows

oow = Interfacial energy or tension between Oil and Water, (dyne/cm) (Engler, (2010)).
Contact Angle Measurement. Several contact angle measurement techniques are present such as the tilting
plate method, the capillary rise method, and the sessile drop method. The method that is most widely used in the
petroleum industry is the sessile drop method [15]. The sessile drop measurement is conducted by placing a drop
of water on a mineral surface that is suspended below the oils surface horizontally [1]. The measurement takes
place by taking a photograph of the system where the angle is measured through water, that is, the denser phase
[15]. This is the basic principle of the sessile measurement technique. Modifications carrying different natures
were introduced to the sessile drop method. This work explains the Sessile - Add and Remove Volume Method
as it is the method of measurement adopted by the contact angle meter device that is used for measuring contact
angles in the experimental section.
Limitations Associated with Contact Angle Measurement. One of the problems encountered during contact angle measurements is contact angle hysteresis where a liquid drop can make several stable contact angles
with the rock surface. Hysteresis is a result of surface heterogeneity and roughness [16]. Another cause of hysteresis while measuring contact angles is surface immobility where the surface does not allow the necessary motion for the fluid to reach an equilibrium contact angle value [15]. Surface roughness influences the oil/brine/
solid contact line, such that the contact angle is fixed only on smooth surfaces. Figure 3 illustrates that Water
advancing and receding contact angles measured by the sessile drop method.

4. Experimental Work and Procedures

4.1. Materials
The materials used in the experiment were core samples from a sandstone reservoir obtained from a well producing in the Western Desert, synthetic brine prepared in the Lab. with salinity of 50,000 ppm, the composition
of the brine used in experiment was 5.0 wt% of NaCl. The density of brine was 1.047 gm/cm3, oil that has a
density of 0.9554 g/mL, and API gravity of 17. Nanomaterials obtained were Si/Zr, Mg/Al-LDH and a mixture
of 80.0% Mg Al-LDH and 20.0% Si/Zr by weight. A concentration of 4.0 gm/L of each nanomaterial was prepared by dispersing it in brine using an ultra-sonic bath. The ultrasonic bath was carried out with the aim of ensuring that the nano-solution is stable and homogeneous.

4.2. Setup and Procedures for Experimental

Core plugging was done to the sample rock using the plugging machine in the university Lab.7 cores sample
were cut off from the sample rock where four core plates samples had average diameter 38.07 mm, lengths
ranging from 8.24 to 11.77 mm.
The core samples were trimmed using the Trim Saw and then they were left into the Dean stark device to be
cleaned from any undesirable fluids in the pores. Then the core samples were put into the oven to be dried and it

Figure 3. Water advancing and receding contact angles measured by the sessile drop method.

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was heated at 64C as above this temperature the clays in the samples might break down affecting porosity and
permeability of the cores. Routine core analysis was done to get porosity and absolute permeability using Helium Porosi-meter and Air Permeameter, then the four core plugs (Plates) was put inside the manual saturator to
be saturated with brine and measure its saturation at pressure 2000 psi and ambient temperature for eight or ten
hours. Table 1 show that the routine core analysis results for core plate samples used in this study.
Each of the four core plates were injected with brine and different nanomaterial at constant concentration (4.0%
by wt) and were achieved the measurement of contact angles for their and surface tension measured between air,
brine and/or different nanomaterial phases using a contact angle meter and K100 Tensiometer into the Central
Metallurgical Research institute. Figure 4(a) and Figure 4(b) show that Contact Angle Meter, CMRDI and
Nano-fluid droplet being deposited on the rocks surface as detected by the contact angle meters software.

4.3. Surface and Interfacial Tension

The change in surface or interfacial tension between oil, brine and several of nano-fluid, and air are the main
mechanism when wettability reversal to water-wet condition, reduction of interfacial tension will lead to a reduction of the capillary pressure within the pores. Surface tension is measured in the laboratory by a TensiometerK100, which can be used by DuNouy ring. Figure 5 illustrate that the surface tension apparatus used to
measure of the surface tension values (mN/m) for each distilled water, brine, oil and version of nano-fluids for
different materials.

(a)

(b)

Figure 4. (a) Contact angle meter, (CMRDI); (b) nanofluid droplet being deposited on the rocks surface as
detected by the contact angle meters software.

Figure 5. Surface tension apparatus measured and procedures.

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Table 1. Routine core analysis results for core plate samples.

Sample Weight Diameter
No
gm
mm

Pore
Porosity
Volume

Cal.
Initial
Absolute
Oil
Pore
Water
Permeability Saturation
Volume
Saturation

Length

Bulk
Volume

Grain
Density

mm

mm

gm/cm3

mm

md

Plate 1

20.90

38.14

9.04

10.33

2.41

1.64

15.88

1.53

2201.76

93.7

6.3

Plate 2

18.72

38.04

8.24

9.36

2.39

1.48

16.35

1.53

2378.90

97.2

2.8

Plate 3

21.33

38.08

9.57

10.90

2.39

1.99

18.26

1.67

2595.97

84.3

15.7

Plate 4

24.00

38.02

11.77

13.36

2.42

3.44

25.75

2.01

2698.79

58.4

41.6

The main difference between these two is the places where it occurs. Surface tension is defined to a single
liquid surface, whereas the interfacial tension is defined to the interface of two immiscible liquids. Surface tension is actually a derivation of interfacial tension where force from the second surface is negligible or zero.
In addition to, we can be determined the interfacial tension after measuring of contact angles for several solutions of nano-fluids and versus oil and surface tension measured for their solutions. Its calculated by used the
follows as means equation [17]:

sl =

la sa

1 0.015 la sa

This equation is called geometric of determined of interfacial tension for solutions versus oil.
where:
sl = Interfacial Tension calculated for oil-rock/nano-fluids, mN/m;

sa = Surface Tension measured for oil-rock and air, mN/m;

la = Surface Tension measured for nano-fluids and air, mN/m.

5. Results and Discussion

Nanomaterials are being used in the oil industry in the domain of Enhanced Oil Recovery where they are injected into core samples in the laboratory and the resulting increase in oil recovery is recorded. Metal oxides in
the nanoscale such as aluminum oxide, silica, iron oxide, and nickel oxide are being used; however, hydroxides
were never attempted with this purpose. As far as the contact angle principle is concerned, [18] postulate that a
concentration of 4.0 g/L of SiO2 nanoparticles suspended in water can alter the wettability of a carbonate reservoir from strongly oil-wet to strongly water-wet. The oil phase contact angle changed from 35 to 135. Their
results prove that significant amounts of oil can be recovered after water is injected into the core plug aged with
SiO2 nanofluids.
Moreover, the concentration of the nanoparticles enhances the oil recovery as when we increase the concentration of the nanoparticles in brine mix solution (nanoparticles in aqueous phase) the interfacial tension and the
contact angle decreases [19]. The effect of -Al2O3 nanoparticles on the wettability of an Iranian carbonate reservoir was explored by [20]. He suggests that -Al2O3 nanoparticles could adsorb on a carbonate surface altering its wettability from oil-wet to water-wet. The most significant change in oil phase contact angle corresponded to a 0.5 wt% concentration of -Al2O3 nanofluid. A 0.5 wt% concentration of -Al2O3 nanoparticles
caused the maximum change in contact angle. At this concentration raised the amount of oil recovered by 11.25%
upon injection into the core sample.
Roustaei and Bagherzadeh postulate that a 4.0 g/L concentration of SiO2 nanoparticles could introduce considerable alteration to the rock wettability from oil-wet to water-wet [18]. To settle on the optimum concentration of SiO2 nanoparticles to be injected into a carbonate core sample, the researchers applied their study on a
concentration range of 1.0 - 6.0 g/L. Seven carbonate plates were cleaned polished, trimmed; to minimize contact angle hysteresis, and saturated with crude oil. Oil droplets were deposited on the carbonate surfaces and the
oil phase contact angle, in the presence of brine, was measured.

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A graph of oil phase contact angle (degrees), in the presence of brine, versus several nano-fluid concentrations (g/L) was plotted and so the optimum concentration appeared to be 4.0 g/L. The 4.0 g/L concentration
changed the oil phase contact angle from 35 to 135 indicating a wettability shift from oil-wet to water-wet.
The change in angle was a consequence of the increase in the interfacial tension between oil and water according to Youngs equation. The wettability alteration reflected on oil recovery by an increase to 76.0% in the
amount of oil recovered after nano-fluid injection. Table 2 shows that the average contact angle measurement
for brine solution, Mg/Al-LDH phase solution, Si/Zr phase solution and mixture with 80% by wt of Mg/AlLDH phase and 20% by wt of Si/Zr phase solution. All of one, these phases used at constant concentration 4.0
g/L of nanomaterials.
Four core plates of a length of approximate 1.0 mm each and cleaning samples using a trimming machine and
polished to achieve a flat and relatively smooth surface which used to measure of contact angle are accuracy
values results, then these sample plates were saturated with oil at room temperature and a pressure of 2000 psi.
Four different solutions were prepared such that each solution is to be deposited on one of the rock plates using
a syringe.
The four solutions were: brine (used as a control to test the initial reservoir rock wettability), Mg/Al-Layered
Double Hydroxide suspended in brine, Silica/Zirconia suspended in brine, and the mixture of both nanoparticles
was also suspended in brine.
The entire time interval taken to measure contact angles for each sample of the four was 2000 milliseconds
(0.033 minute). For all samples, the maximum recorded deviation between contact angle readings was found to be
16. As a result, the contact angle readings reported contain a maximum error of 8. It entails depositing a water
droplet on the rocks surface and adding volume to it and measuring the contact angle, which is in this case referred to as the advancing contact angle. The volume increase step is followed by a volume decrease one where
volume is extracted from the drop and the contact angle is measured.
For the brine sample, the brine phase contact angle, in the presence of oil, was 65.56 indicating an initially
water-wet condition of the sandstone rock sample. Then, measured for the Mg/Al Layered Double Hydroxide
(Mg/Al-LDH), the brine phase contact angle, its decreased to 59.7; so indicating that the rock is becoming
more water-wet. In case of Silica/Zirconia, the brine phase contact angle increased to 67.9 suggesting a decrease in water-wetness and consequently, an inclination towards oil-wetness. Finally, for the mixture of both
nanoparticles, the brine phase contact angle decreased slightly to 65 implying that Silica/Zirconia renders the
Mg/Al Layered Double Hydroxide inefficient. Figure 6 shows that the contact angle values for brine and several
of nanomaterials.

Contact Angle at ambient temperature

Contact Angle Value,

80.0
76.0
72.0
68.0
64.0

67.90
65.56

60.0

65.00
59.70

56.0
52.0
48.0
44.0
40.0
Brine

Mg/Al-LDH

Si/Zr

Brine and Different Nanomaterial

Figure 6. Contact angle measurement for brine and various nanomaterials.

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80% Mg/Al-LDH
and 20% Si/Zr

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Table 2. Average contact angle measured for each nano-material used.

Material Used

Nano = Fluid/Oil-Rock Contact Angle Measuring (Degrees)

Brine

65.56

Mg/Al-LDH

59.70

Si/Zr

67.90

80.0% Mg/Al-LDH + 20.0% Si/Zr (by Weight)

65.00

Interfacial Tension
The difference between interfacial tension and surface tension is the liquid-liquid interface instead of the liquidair interface. Interfacial tension can be used to describe immiscibility of these two liquids. Consider the interface
between the phases. The molecules on the first surface have forces acting upon it from the first liquid and from
the surface molecules of the second liquid and vice versa. If the force on the surface molecules from the first
liquid (cohesive forces) equals the force from the second surface (adhesive forces) these two liquids will mix. If
these forces are unequal these liquids will not mix.
As Table 3 and Figure 7 illustrated the behaviour of oil-distilled water-brine and several of nanomaterial for
measured the surface tension and calculated for interfacial tension at ambient temperature. The oil with air was
observed to demonstrate decreasing surface and interfacial tension than distilled water and brine with air at room
temperature. The laboratory work can be simplified by show the less value of surface tension measured or Calculated of Interfacial Tension were observed at the solution of Si/Zr with air and Si/Zr solution with oil than the
other nanomaterial either Mg/Al-LDH with air or mixed Si-Zr & Mg/Al-LDH with air and with oil.
For example, nanoparticles can be directed to self-assemble into thin films at an oil/brine interface by manipulating the solid/brine or solid/nano-fluid and solid/oil surface tensions. However, if the attractive forces had
been occur at the interface between two phases (interfacial tension). So the interfacial tension is an important
factor in tertiary or enhanced oil recovery processes and in calculating of reserves oil reservoir.

6. Conclusion and Recommendations

The use of Mg/Al-Layered Double Hydroxide (Mg/Al-LDH) as nanoparticles dispersed in brine is highly
supported. For a sandstone reservoir, it decreased the brine phase contact angle, in the presence of oil, by 6
in a period of 2000 milliseconds (0.033 minute).
Silica/Zirconia nanomaterial (Si/Zr) dispersed in brine is not to be used for the purpose of wettability alteration from oil-wet to water-wet as it yields an increase in the brine phase contact angle by 2.34 in 2000 milliseconds (making the rock less water-wet). Silica/Zirconia causes wettability to shift towards oil-wet which
is an unfavourable condition in the oil industry as it has adverse effects on oil recovery.
When mixed with Silica/Zirconia nanoparticles (Si/Zr), the effect of Mg/Al Layered Double Hydroxide
nanoparticles (Mg/Al-LDH) in increasing water-wetness decreases significantly.
It can be inferred from the results that Mg/Al Layered Double Hydroxide nanoparticles (Mg/Al-LDH) dispersed in brine adsorb on the surface of the rock decreasing the contact angle, thereby, resulting in an increased water-wetness condition. Silica/Zirconia nanoparticles (Si/Zr) dispersed in brine cause oil to decrease the cohesive forces between brine and the rocks surface, thus the surface becomes less water-wet.
This explains why when Mg/Al Layered Double Hydroxide (Mg/Al-LDH) is mixed with Silica/Zirconia its
efficiency of increasing water-wetness decreases where it reduces the water phase contact angle only by
0.56.
Mg/Al Layered Double Hydroxide forces (Mg/Al-LDH), the sandstone rock surface to become more hydrophilic as opposed to Silica/Zirconia (Si/Zr) which forces it to give up its affinity for water and to become
hydrophobic.
The results of this study recommend the adoption of Mg/Al Layered Double Hydroxide (Mg/Al-LDH) in the
field of Enhanced Oil Recovery to alter the wettability of a sandstone reservoir rock from oil-wet to water-wet or to increase the water-wetness of an already water-wet sandstone reservoir.
The effect explained was achieved in 0.033 minute, thereby, if the duration is extended for a whole day (24
hours), recognizable results are expected to be attained. These effects will reflect on the wettability measurement and subsequently on the amount of oil recovered from the reservoir.

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Interfacial Tension Calculated, mN/m

Surface Tension measured, mN/m

Surface Tension measured at ambient Temperature

80.00
70.00
60.00
50.00
40.00
30.00
20.00
10.00
0.00

E.-A. Moustafa et al.

Distiiled water, Oil, Brine and

various Nanomaterical Solution

Interfacial Tension Caculated at ambient Temperature

10.00
9.00
8.00
7.00
6.00
5.00
4.00
3.00
2.00
1.00
0.00

Distiiled water, Oil, Brine and

various Nanomaterical Solution

Figure 7. Surface tension measured and interfacial tension calculated versus distilled water, oil, brine and various
Nanomaterial solutions.
Table 3. Average surface tension and calculated of interfacial tension versus distilled water, oil and type of solution.
Type of Solution

Average Surface Tension Value mN/m

Interfacial Tension Calculated mN/m

Distilled Water

70.30

-----

Oil with air

29.00

-----

Brine with air

61.23

6.595

Mg/Al-LDH with air

51.90

3.650

Si-Zr with air

60.00

6.171

Si-Zr & Mg/Al-LDH with air

60.30

6.274

In contrast, the application of Silica/Zirconia (Si/Zr) in the industry with sandstone reservoirs is not recommended as it results in decreasing the affinity of the reservoir for water making it less water-water, thus
yielding adverse effects on productivity.

Acknowledgements
Authors would like to express our gratitude and appreciation to petroleum engineering staff members at the
American University in Cairo and Geologist. Marawan for allowing us to use the core lab under his supervision.
We also would like to thank him for helping us carry out to complete our research work.

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