Corrosion Inhibition Studies of Mild Steel in Acid Medium Using Musa Acuminata Fruit Peel Extract
Corrosion Inhibition Studies of Mild Steel in Acid Medium Using Musa Acuminata Fruit Peel Extract
Corrosion Inhibition Studies of Mild Steel in Acid Medium Using Musa Acuminata Fruit Peel Extract
net
Introduction
An antique fruit crop of the world, known as Apple of the paradise botanically named as
Musa acuminata (Nendran), cheapest and plentiful fruit, used widely as food without
apparent toxic effect, having antimicrobial and antioxidant activity contains starch,
fructosans, phenolic acids, anthocyanins, terpenoids, sterols, polyphenols, gallocatechin and
dopamine1-5. The peel of the fruit contains beta sitosterol, stigmasterol, campesterol,
cycloeucalenol, cycloartanol and 24-methylene cycloartanol6,7. The natural flavonoid present
in banana exhibits an antioxidative activity that stops oxidation and corrosion, the
deterioration process and discoloration8.
488
S. C. MURUGAVEL et al.
Experimental
Inhibitor preparation
The peels of Musa acuminata fruit were collected from the chips manufacturing shops of
Coimbatore city, dried and powdered. About 12.5 g of the powder was refluxed with 250
mL of 1 N HCl for about 3 hours and was allowed to stand overnight. The resultant solution
was filtered and the filtrate was made up to 250 mL. From this 5% stock solution of the
extract, different concentrations of the inhibitor solution like 0.005, 0.01, 0.05, 0.10, 0.50,
1.0, 1.5, and 2.0 % v/v were prepared.
Specimen preparation
For weight loss method mild steel coupons of dimension 1 x 5 x 0.2 cm with a small hole on
the upper part to facilitate suspension of the coupons in the test solutions were used. The
specimens were degreased with acetone and pickled with concentrated hydrochloric acid. The
surface of the specimens were mechanically polished using SiC emery papers of grades 400
and 600, washed with distilled water, dried at room temperature and stored in a desiccator.
For electrochemical polarization and impendence measurements mild steel rod of 15 x
0.5 cm were used. These rods were mechanically polished using different grades of SiC
emery paper, repeatedly rinsed with distilled water and dried before use.
489
Effect of temperature
The polished and pre-weighed specimens in duplicate were suspended in 100 mL of the test
solution without and with the addition of different concentrations of the peel extract for 1 h
in the temperature range of 30-80 C using thermostat. After the corrosion test, the
specimens were washed with distilled water, dried and weighed. From the weight loss the
inhibition efficiency (IE %) was calculated.
Electrochemical measurements
A three electrode cell assembly of borosil glass consisting of a mild steel rod of size 15
X 0.5 cm as working electrode (WE), a large area platinum mesh of negligible
impedance as counter electrode (CE), and a saturated calomel electrode as reference
electrode (RE) containing 100 mL of the test solution was used for electrochemical
measurements at 30 C.
x 100
Where, Icorr and Icorr (inh) are corrosion current density without and with inhibitor respectively.
Where, Rct
490
S. C. MURUGAVEL et al.
2
56.48
74.27
86.18
90.85
92.92
94.30
94.47
94.65
3
42.70
64.06
88.73
92.60
94.53
94.74
94.96
95.06
7
44.05
64.11
84.92
86.53
91.85
94.64
94.05
94.10
12
50.30
63.45
78.87
85.67
89.42
91.51
92.91
94.13
24
53.47
62.54
84.01
88.00
88.76
89.97
90.29
89.40
Inhibition efficiency, %
Conc. of
extract, % v/v
0.005
0.01
0.05
0.10
0.50
1.00
1.50
2.00
Concentration, %v/v
Effect of temperature
To study the effect of temperature on the corrosion inhibition properties of peel extract,
experiments were carried out in absence and presence of varying concentration of the inhibitor
491
Inhibition efficiency, %
in the temperature range from 30-80 C. The results are summarized in Table 2 and Figure 3. The
data indicated that the peel extract was effective up to 40 C and decreased slightly thereafter.
12
24
Immersion time, h
Inhibition efficiency, %
Concentration, %v/v
Figure 3. Effect of temperature on mild steel in 1 N HCl in presence and absence of MNP
extract
The maximum efficiency of 96.91% at 40C indicates that the inhibitor can be
effectively used up to 40 C. The decrease in inhibition efficiency with increase in
temperature may be due to desorption of inhibitor molecules at faster rate at higher
temperature13,27.
492
S. C. MURUGAVEL et al.
Where, CR and CR' are the corrosion rate with and without inhibitor respectively
obtained from the weight loss method.
The surface coverage increased with increase in the concentrations of extract. This may be due
to increased number of inhibitor molecules getting parallely adsorbed on the surface of mild steel 26.
Adsorption isotherm
log (1- )
The mechanism of corrosion inhibition and degree of adsorption of inhibitor depend on the
chemical structure of the molecule, chemical composition of the solution, the nature of metal
surface, the temperature and the electrochemical potential at the metal / solution interface.
The surface coverage () values help in understanding adsorption characteristics. The
values for different concentrations of the extract were tested by fitting various isotherms
such as Langmuir and Temkin.
Straight line obtained by plotting log ( / 1- ) vs. log C (Langmuir adsorption) (Figure
4) and vs. log C (Temkin adsorption) (Figure 5) indicated that the process of inhibition is
due to physical adsorption13,27,28.
log C
Surface coverage,
Figure 4. Langmuir adsorption isotherm of MNP extract on mild steel in 1 N HCl at various
temperature
log C
Figure 5. Temkin adsorption isotherm of MNP extract on mild steel in 1 N HCl at various
temperature
Electrochemical method
Potentiodynamic polarization studies
The effect of the extract on the electrochemical behaviour of mild steel was studied by
carrying out cathodic and anodic polarization experiments. The electrodynamic parameters
493
of the inhibitor such as corrosion potential Ecorr, corrosion current density Icorr, anodic and
cathodic Tafel slopes, ba and bc, in absence and presence of inhibitor are listed in Table 3
and depicted in Figure 6. Further the result reveals that Icorr values of acid in presence of
inhibitor are lower than that of acid in absence of inhibitor indicating that increase in
inhibition property was due to adsorption of inhibitor molecules on the electrode surface.
This shows that the peel extract of Musa acuminata in 1N HCl acts as very good corrosion
inhibitor for mild steel. The steady value of Ecorr suggest that the inhibitor is mixed type
inhibitor and this infers that the inhibitor reduces the hydrogen evolution and anodic
dissolution of mild steel25, 29.
Table 3. Potentiodynamic polarization parameters for mild steel in 1 N HCl in the absence
and presence of MNP extract
Conc
% v/v
Blank
0.005
0.01
0.10
0.50
1.00
1.50
2.00
-Ecorr
V
0.463
0.455
0.454
0.464
0.466
0.459
0.468
0.472
Icorr
mAmp/cm2
7831.0
2439.0
1235.0
118.7
124.8
130.1
64.1
65.7
bc
mV/dec
774.19
244.47
219.13
170.84
196.33
191.83
176.57
167.35
ba
mV/dec
317.84
161.70
121.99
101.56
75.57
68.18
71.79
77.64
Rp
Ohm cm2
8.204
8.342
8.948
18.010
18.651
20.283
26.503
26.526
Tafel
68.86
84.23
98.48
98.41
98.34
99.18
99.16
% IE
Linear
1.65
8.31
54.45
56.01
59.55
69.05
69.07
Potential
-0.4
-0.6
-0.8
-1.0
0.0000001
0.00001
0.001
0.1
A/cm2
Figure 6. Potentiodynamic polarization curves for mild steel in 1 N HCl without and with
different concentrations of MNP extract
494
S. C. MURUGAVEL et al.
with increase in the concentration of the inhibitor which are in accordance with the results
obtained by weight loss method30.
Table 4. EIS parameters for the corrosion of mild steel in 1 N HCl containing MNP extract
at 30C
Zim, ohms
Conc of extract
% v/v
Blank
0.5
1.0
1.5
2.0
Cdl
F cm-2
2.298 x10-9
1.075 x10-5
1.308 x10-5
1.139 x10-5
1.593 x10-5
Rct
Ohmcm2
11.52
88.11
76.80
144.70
141.40
%IE
86.93
85.00
92.04
91.85
80
60
40
20
20
40
60
80
100
120
140
160
180
Zre, ohms
Figure 7. Impedance plots recorded for mild steel in 1 N HCl solutions without and with
various concentrations of MNP extract
Conclusions
The peel extract of Musa acuminata was found to be effective inhibitor at concentration of
2% v/v in 1 N HCl solution. The inhibition efficiency of mild steel in 1 N HCl increases
with increasing the concentration of MNP extract. The performance of the extract as
corrosion inhibitor decreased with increasing temperature. AC impendence plots of mild
steel in the acid medium show that polarization resistance increases with the increase of
extract concentration. The results indicate that inhibition effect of the plant extract was due
to physical adsorption of the nutrients present in the extract onto the active sites on the
surface of the metal.
495
Acknowledgement
The authors are grateful to the Principal, Nirmala College for Women, (Autonomous),
Coimbatore and Principal, PSG College of Technology, Coimbatore, for the constant
support and for providing the necessary facilities for this research work.
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