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    Korantin BH 50 MSDS

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    SalsabilaAzis
    1. The document is a safety data sheet for a chemical product called Korantin BH 50. 2. It contains but-2-yne-1,4-diol, methenamine, prop-2-yn-1-ol, methanol, and formaldehyde as hazardous ingredients. 3. The product is harmful in contact with skin, toxic if inhaled or swallowed, and causes burns. It may cause sensitization from inhalation or skin contact and prolonged exposure may cause serious damage to health.

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    © All Rights Reserved
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    Korantin BH 50 MSDS

    Uploaded by

    SalsabilaAzis
    2K views9 pages
    1. The document is a safety data sheet for a chemical product called Korantin BH 50. 2. It contains but-2-yne-1,4-diol, methenamine, prop-2-yn-1-ol, methanol, and formaldehyde as hazardous ingredients. 3. The product is harmful in contact with skin, toxic if inhaled or swallowed, and causes burns. It may cause sensitization from inhalation or skin contact and prolonged exposure may cause serious damage to health.

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    1. The document is a safety data sheet for a chemical product called Korantin BH 50. 2. It contains but-2-yne-1,4-diol, methenamine, prop-2-yn-1-ol, methanol, and formaldehyde as hazardous ingredients. 3. The product is harmful in contact with skin, toxic if inhaled or swallowed, and causes burns. It may cause sensitization from inhalation or skin contact and prolonged exposure may cause serious damage to health.

    Copyright:

    © All Rights Reserved
    Download as PDF, TXT or read online from Scribd
    Download as pdf or txt
    2K views9 pages

    Korantin BH 50 MSDS

    Uploaded by

    SalsabilaAzis
    1. The document is a safety data sheet for a chemical product called Korantin BH 50. 2. It contains but-2-yne-1,4-diol, methenamine, prop-2-yn-1-ol, methanol, and formaldehyde as hazardous ingredients. 3. The product is harmful in contact with skin, toxic if inhaled or swallowed, and causes burns. It may cause sensitization from inhalation or skin contact and prolonged exposure may cause serious damage to health.

    Copyright:

    © All Rights Reserved
    Download as PDF, TXT or read online from Scribd
    Download as pdf or txt
    of 9
    At a glance
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    The document outlines the composition, hazards, first aid measures, firefighting measures, accidental release measures, handling and storage, exposure controls/personal protection, physical and chemical properties, stability and reactivity, toxicological information, ecological information, disposal considerations and regulatory information regarding the chemical product Korantin BH 50.

    The document identifies that the product is harmful in contact with skin, toxic by inhalation and if swallowed, causes burns, and may cause sensitization by inhalation and skin contact. It also states there is limited evidence of carcinogenic effects.

    If difficulties occur after dust has been inhaled, remove to fresh air and seek medical attention.

    Safety data sheet

    Page: 1/9
    BASF Safety data sheet according to 91/155/EEC
    Date / Revised: 14.10.2005
    Product: Korantin* BH 50

    Version: 3.0
    (30075505/SDS_GEN_EU/EN)
    Date of print 17.10.2005

    1. Substance/preparation and company identification

    Korantin* BH 50
    Use: chemical for industrial metal-working

    Company:
    BASF Aktiengesellschaft
    67056 Ludwigshafen
    Contact address:
    Performance Chemicals for Detergents and Formulators
    Telephone: 0621-60-72783/ 42228
    Telefax number: 0621-60-41517
    E-mail address: [email protected]
    Emergency information:
    Fire brigade BASF Ludwigshafen
    Telephone: 0621-60-43333
    Telefax number: 0621-60-92664

    2. Composition/information on ingredients
    Chemical nature
    but-2-yne-1,4-diol, in water
    Hazardous ingredients
    but-2-yne-1,4-diol
    Content (W/W): 50 %
    CAS Number: 110-65-6
    EC-Number: 203-788-6
    INDEX-Number: 603-076-00-9
    Hazard symbol(s): C, T
    R-phrase(s): 21, 23/25, 34, 43, 48/22

    Page: 2/9
    BASF Safety data sheet according to 91/155/EEC
    Date / Revised: 14.10.2005
    Product: Korantin* BH 50

    Version: 3.0
    (30075505/SDS_GEN_EU/EN)
    Date of print 17.10.2005

    methenamine
    Content (W/W): 3 %
    CAS Number: 100-97-0
    EC-Number: 202-905-8
    INDEX-Number: 612-101-00-2
    Hazard symbol(s): F, Xn
    R-phrase(s): 11, 42/43
    prop-2-yn-1-ol
    Content (W/W): 0.5 % - 1.5 %
    CAS Number: 107-19-7
    EC-Number: 203-471-2
    INDEX-Number: 603-078-00-X
    Hazard symbol(s): T, N
    R-phrase(s): 10, 23/24/25, 34, 51/53
    methanol
    Content (W/W): 0.5 % - 1.5 %
    CAS Number: 67-56-1
    EC-Number: 200-659-6
    INDEX-Number: 603-001-00-X
    Hazard symbol(s): F, T
    R-phrase(s): 11, 23/24/25, 39/23/24/25
    formaldehyde
    Content (W/W): 0.5 % - 1.5 %
    CAS Number: 50-00-0
    EC-Number: 200-001-8
    INDEX-Number: 605-001-00-5
    Hazard symbol(s): T
    R-phrase(s): 23/24/25, 34, 43, 40
    The wording of the hazard symbols and R-phrases is specified in chapter 16 if dangerous ingredients
    are mentioned.

    3. Hazard identification
    Harmful in contact with skin.
    Toxic by inhalation and if swallowed.
    Causes burns.
    May cause sensitization by inhalation and skin contact.
    Harmful: danger of serious damage to health by prolonged exposure if swallowed.
    Limited evidence of a carcinogenic effect.

    4. First-aid measures
    General advice:
    Immediately remove contaminated clothing.

    Page: 3/9
    BASF Safety data sheet according to 91/155/EEC
    Date / Revised: 14.10.2005
    Product: Korantin* BH 50

    Version: 3.0
    (30075505/SDS_GEN_EU/EN)
    Date of print 17.10.2005

    If inhaled:
    If difficulties occur after dust has been inhaled, remove to fresh air and seek medical attention.
    On skin contact:
    Immediately wash thoroughly with plenty of water, apply sterile dressings, consult a skin specialist.
    On contact with eyes:
    Immediately wash affected eyes for at least 15 minutes under running water with eyelids held open,
    consult an eye specialist.
    On ingestion:
    Rinse mouth immediately and then drink plenty of water, induce vomiting, seek medical attention.
    Note to physician:
    Treatment: Treat according to symptoms (decontamination, vital functions), no known specific
    antidote, administer corticosteroid dose aerosol to prevent pulmonary odema.

    5. Fire-fighting measures
    Suitable extinguishing media:
    water, dry extinguishing media, foam
    Specific hazards:
    harmful vapours
    Evolution of fumes/fog. The substances/groups of substances mentioned can be released in case of
    fire.
    Special protective equipment:
    Wear a self-contained breathing apparatus.
    Further information:
    The degree of risk is governed by the burning substance and the fire conditions. Contaminated
    extinguishing water must be disposed of in accordance with official regulations.

    6. Accidental release measures


    Personal precautions:
    Use personal protective clothing.
    Environmental precautions:
    Contain contaminated water/firefighting water. Do not discharge into drains/surface
    waters/groundwater.
    Methods for cleaning up or taking up:
    For large amounts: Pump off product.
    For residues: Pick up with suitable absorbent material. Dispose of absorbed material in accordance
    with regulations.

    Page: 4/9
    BASF Safety data sheet according to 91/155/EEC
    Date / Revised: 14.10.2005
    Product: Korantin* BH 50

    Version: 3.0
    (30075505/SDS_GEN_EU/EN)
    Date of print 17.10.2005

    7. Handling and storage


    Handling
    Avoid aerosol formation.
    Protection against fire and explosion:
    Take precautionary measures against static discharges.
    Storage
    Segregate from strong acids. Segregate from strong bases. Segregate from heavy-metal salts.
    Segregate from strong oxidizing agents.
    Further information on storage conditions: Keep container tightly closed and dry; store in a cool
    place.

    8. Exposure controls and personal protection


    Components with workplace control parameters
    50-00-0: formaldehyde
    67-56-1: methanol
    107-19-7: prop-2-yn-1-ol

    Personal protective equipment


    Respiratory protection:
    Suitable respiratory protection for lower concentrations or short-term effect: Particle filter EN 143
    Type P3 (high efficiency (solid and liquid particles of toxic and very toxic substances)).
    Hand protection:
    Chemical resistant protective gloves (EN 374)
    Suitable materials also with prolonged, direct contact (Recommended: Protective index 6,
    corresponding > 480 minutes of permeation time according to EN 374):
    nitrile rubber (NBR) - 0.4 mm coating thickness
    Supplementary note: The specifications are based on own tests, literature data and information of
    glove manufacturers or are derived from similar substances by analogy. Due to many conditions
    (e.g. temperature) it must be considered, that the practical usage of a chemical-protective glove in
    practice may be much shorter than the permeation time determined in accordance with EN 374.
    Manufacturer's directions for use should be observed because of great diversity of types.
    Eye protection:
    Tightly fitting safety goggles (cage goggles) (EN 166) and face shield.
    Body protection:
    Body protection must be chosen based on level of activity and exposure., acid- resp. lye-proof apron,
    e.g. of rubber (according DIN-EN 467), protection boots, e.g. of rubber (according to DIN-EN 346),
    acid-proof chemical protection suit (according to DIN-EN 467)

    Page: 5/9
    BASF Safety data sheet according to 91/155/EEC
    Date / Revised: 14.10.2005
    Product: Korantin* BH 50

    Version: 3.0
    (30075505/SDS_GEN_EU/EN)
    Date of print 17.10.2005

    General safety and hygiene measures:


    Handle in accordance with good industrial hygiene and safety practice.

    9. Physical and chemical properties


    Form:
    Colour:
    Odour:

    liquid
    light yellow
    product specific

    pH value:

    approx. 7
    (20 C)
    (measured with the undiluted
    substance)

    solidification temperature:
    -1 C
    Boiling range:
    100 - 250 C
    Flash point:
    Ignition temperature:

    > 65 C
    > 200 C

    Vapour pressure:

    21 mbar
    (20 C)
    104 mbar
    (50 C)

    Density:

    1.091 g/cm3
    (20 C)

    (DIN 51758)
    (DIN 51794)

    Solubility in water:
    fully soluble
    Solubility (qualitative) solvent(s): polar solvents
    soluble

    10. Stability and reactivity


    Substances to avoid:
    nitric acid
    Hazardous reactions:
    Reacts with strong acids and alkalies. Reacts with heavy metal salts. Reacts with oxidizing agents.

    Hazardous decomposition products:


    No hazardous decomposition products if stored and handled as prescribed/indicated.

    11. Toxicological information


    LD50/oral/rat: 25 - 200 mg/kg

    Page: 6/9
    BASF Safety data sheet according to 91/155/EEC
    Date / Revised: 14.10.2005
    Product: Korantin* BH 50

    Version: 3.0
    (30075505/SDS_GEN_EU/EN)
    Date of print 17.10.2005

    by inhalation: / 8 h(IRT)
    No mortality within the stated exposition time as shown in animal studies.
    LD50/dermal/rat: 400 - 2,000 mg/kg
    Primary skin irritation/rabbit: Irritant. (OECD Guideline 404)
    Primary irritations of the mucous membrane/rabbit: non-irritant (OECD Guideline 405)
    Sensitization:
    If handled constantly, there is a risk of skin allergy.
    Further information:
    Information on: formaldehyde
    Limited evidence of a carcinogenic effect.
    After lifelong inhalation exposure to concentrations that were severely damaging to the nasal
    epithelium, nasal tumors were induced in rats; in other species these findings were not found or were
    considerably less pronounced.
    The International Agency for Research on Cancer (IARC) has classified formaldehyde as a Group 1
    (known) human carcinogen based on epidemiological evidence linking formaldehyde exposure to
    occurrence of nasopharyngeal cancer.
    Current regulatory information is provided in this MSDS.
    No adverse health effects are anticipated if recommended personal protective equipment and
    industrial hygiene practices are used.
    ---------------------------------Additional information:
    The product has not been tested. The statement has been derived from the properties of the
    individual components.

    12. Ecological information


    Ecotoxicity
    Toxicity to fish:
    Leuciscus idus/LC50 (96 h): 10 - 100 mg/l
    Aquatic invertebrates:
    EC50 (48 h): 10 - 100 mg/l
    Aquatic plants:
    EC50 (72 h): > 100 mg/l
    Microorganisms/Effect on activated sludge:
    Inhibition of degradation activity in activated sludge is not to be anticipated during correct
    introduction of low concentrations.

    Page: 7/9
    BASF Safety data sheet according to 91/155/EEC
    Date / Revised: 14.10.2005
    Product: Korantin* BH 50

    Version: 3.0
    (30075505/SDS_GEN_EU/EN)
    Date of print 17.10.2005

    Persistence and degradability


    Elimination information
    Test method:
    Method of analysis:
    Degree of elimination:
    Evaluation:

    OECD 301E; 84/449/EEC, C.3


    DOC reduction
    > 80 %
    Readily biodegradable.

    Additional information
    Other ecotoxicological advice:
    Do not release untreated into natural waters.
    The product has not been tested. The statement has been derived from the properties of the
    individual components.

    13. Disposal considerations


    Must be dumped or incinerated in accordance with local regulations.

    Contaminated packaging:
    Uncontaminated packaging can be re-used.
    Packs that cannot be cleaned should be disposed of in the same manner as the contents.

    14. Transport information


    Land transport
    ADR

    : Class
    Packaging group
    UN-number
    Designation of goods

    8
    III
    2922
    CORROSIVE LIQUID, TOXIC, N.O.S.
    (Contains: 2-BUTIN-1,4-DIOL)

    RID

    : Class
    Packaging group
    UN-number
    Designation of goods

    8
    III
    2922
    CORROSIVE LIQUID, TOXIC, N.O.S.
    (Contains: 2-BUTIN-1,4-DIOL)

    Inland waterway transport

    Page: 8/9
    BASF Safety data sheet according to 91/155/EEC
    Date / Revised: 14.10.2005
    Product: Korantin* BH 50

    Version: 3.0
    (30075505/SDS_GEN_EU/EN)
    Date of print 17.10.2005

    ADNR

    : Class
    Packaging group
    UN-number
    Designation of goods

    8
    III
    2922
    CORROSIVE LIQUID, TOXIC, N.O.S.
    (Contains: 2-BUTIN-1,4-DIOL)

    IMDG/GGVSee : Class
    Packaging group
    UN-number
    Marine pollutant
    Exact technical name

    8
    III
    2922
    NO
    CORROSIVE LIQUID, TOXIC, N.O.S.
    (contains 2-BUTIN-1,4-DIOL)

    Sea transport

    Air transport
    ICAO/IATA

    : Class
    Packaging group
    UN-number
    Exact technical name

    8
    III
    2922
    CORROSIVE LIQUID, TOXIC, N.O.S.
    (contains 2-BUTIN-1,4-DIOL)

    15. Regulatory information


    Regulations of the European union (Labelling) / National legislation/Regulations
    Directive 1999/45/EC ('Preparation Directive'):
    Hazard symbol(s)
    C
    T
    R-phrase(s)
    R23/25
    R34
    R21
    R42/43
    R48/22
    R40
    S-phrase(s)
    S23.3
    S36/37/39
    S26
    S45

    Corrosive.
    Toxic.

    Toxic by inhalation and if swallowed.


    Causes burns.
    Harmful in contact with skin.
    May cause sensitization by inhalation and skin contact.
    Harmful: danger of serious damage to health by prolonged exposure if
    swallowed.
    Limited evidence of a carcinogenic effect.

    Do not breathe vapour/spray.


    Wear suitable protective clothing, gloves and eye/face protection.
    In case of contact with eyes, rinse immediately with plenty of water and
    seek medical advice.
    In case of accident or if you feel unwell, seek medical advice
    immediately (show the label where possible).

    Page: 9/9
    BASF Safety data sheet according to 91/155/EEC
    Date / Revised: 14.10.2005
    Product: Korantin* BH 50

    Version: 3.0
    (30075505/SDS_GEN_EU/EN)
    Date of print 17.10.2005

    Hazard determinant component(s) for labelling: 2-BUTIN-1,4-DIOL, FORMALDEHYDE


    Other regulations

    16. Other information


    Unsuitable for use: aerosol

    Not to be used as an aerosol.


    Full text of hazard symbols and R-phrases if mentioned as hazardous components in chapter 2:
    C
    Corrosive.
    T
    Toxic.
    F
    Highly flammable.
    Xn
    Harmful.
    N
    Dangerous for the environment.
    21
    Harmful in contact with skin.
    23/25
    Toxic by inhalation and if swallowed.
    34
    Causes burns.
    43
    May cause sensitization by skin contact.
    48/22
    Harmful: danger of serious damage to health by prolonged exposure if
    swallowed.
    11
    Highly flammable.
    42/43
    May cause sensitization by inhalation and skin contact.
    10
    Flammable.
    23/24/25
    Toxic by inhalation, in contact with skin and if swallowed.
    51/53
    Toxic to aquatic organisms, may cause long-term adverse effects in the
    aquatic environment.
    39/23/24/25
    Toxic: danger of very serious irreversible effects through inhalation, in
    contact with skin and if swallowed.
    40
    Limited evidence of a carcinogenic effect.
    Vertical lines in the left hand margin indicate an amendment from the previous version.
    The data contained in this safety data sheet are based on our current knowledge and experience and
    describe the product only with regard to safety requirements. The data do not describe the product's
    properties (product specification). Neither should any agreed property nor the suitability of the product for
    any specific purpose be deduced from the data contained in the safety data sheet. It is the responsibility
    of the recipient of the product to ensure any proprietary rights and existing laws and legislation are
    observed.

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