Safety Data Sheet: According To EC Directive 91/155/EEC

Safety Data Sheet
According to EC Directive 91/155/EEC

Date of issue:
Supersedes edition of
1.
31.03.2005
20.10.2003
Identification of the substance/preparation and of the company/undertaking

Identification of the product
Catalogue No.:
101042
Product name:
Aluminium potassium sulfate dodecahydrate EMPROVE Ph Eur,BP,USP
Use of the substance/preparation

Pharmaceutical production and analysis
Company/undertaking identification
2.
Company:
Merck KGaA * 64271 Darmstadt * Germany * Phone: +49 6151 72-0
Emergency telephone No.:
Please contact the regional Merck representation

in your country.
Composition/information on ingredients
Synonyms
Potassium aluminium sulfate, Alum potassium, Potassium alum
CAS-No.:
M:
Formula Hill:
Chemical formula:
3.
7784-24-9
474.39 g/mol
AlKO8S2 * 12 H2O
KAl(SO4)2 * 12 H2O
EC-No.:
233-141-3
Hazards identification
No hazardous product as specified in Directive 67/548/EEC.
4.
First aid measures

After inhalation: fresh air.
After skin contact: wash off with plenty of water. Remove contaminated clothing.
After eye contact: rinse out with plenty of water with the eyelid held wide open.
After swallowing: make victim drink plenty of water. Consult doctor if feeling unwell.
The Safety Data Sheets for catalog items are also available at www.chemdat.info
Page 1 of 6
Merck Safety Data Sheet

Catalogue No.:
Product name:
5.
101042
Fire-fighting measures
Suitable extinguishing media:
In adaption to materials stored in the immediate neighbourhood.
Special risks:
Non-combustible. Ambient fire may liberate hazardous vapours. The following may develop in event of
fire: sulfur oxides.
Special protective equipment for fire fighting:
Do not stay in dangerous zone without self-contained breathing apparatus.
Other information:
Contain escaping vapours with water. Prevent fire-fighting water from entering surface water or
groundwater.
6.
Accidental release measures

Person-related precautionary measures:
Avoid inhalation of dusts.
Environmental-protection measures:
Do not allow to enter sewerage system.
Procedures for cleaning / absorption:
Take up dry. Forward for disposal. Clean up affected area. Avoid generation of dusts.
7.
Handling and storage

Handling:
No further requirements.
Storage:
Tightly closed. Dry. Storage temperature: no restrictions.
8.
Exposure controls/personal protection

Personal protective equipment:
Protective clothing should be selected specifically for the working place, depending on
concentration and quantity of the hazardous substances handled. The resistance of the
protective clothing to chemicals should be ascertained with the respective supplier.
Respiratory protection:
required when dusts are generated.
Eye protection:
required
Page 2 of 6

Catalogue No.:
Product name:
101042
Hand protection:
In full contact:
nitrile rubber
0.11 mm
> 480 Min.
Glove material:
Layer thickness:
Breakthrough time:
In splash contact:
nitrile rubber
0.11 mm
> 480 Min.
Glove material:
Layer thickness:
Breakthrough time:
The protective gloves to be used must comply with the specifications

of EC directive 89/686/EEC and the resultant standard EN374, for
example KCL 741 Dermatril L (full contact), 741 Dermatril L (splash
contact). The breakthrough times stated above were determined by
KCL in laboratory tests acc. to EN374 with samples of the recommended
glove types.
This recommendation applies only to the product stated in the safety
data sheet and supplied by us as well as to the purpose specified by
us. When dissolving in or mixing with other substances and under
conditions deviating from those stated in EN374 please contact the
supplier of CE-approved gloves (e.g. KCL GmbH, D-36124 Eichenzell,
Internet: www.kcl.de).
Industrial hygiene:
Change contaminated clothing. Wash hands after working with substance.
9.
Physical and chemical properties

Form:
Colour:
Odour:
solid
colourless
odourless
pH value
(20 C)
at 100 g/l H2O
Melting point
Boiling point
Ignition temperature
Flash point
Explosion limits
92.5
not available
not applicable
not flammable
lower
not applicable
upper
Density
Bulk density
Solubility in
water
Thermal decomposition
3.0-3.5
not applicable
(20 C)
(20 C)
~ 900
g/cm3
kg/m3
139
g/l
60-200
780
C
C
1.75
(release of crystalline water)

(anhydrous substance)
Page 3 of 6

Catalogue No.:
Product name:
101042
10. Stability and reactivity

Conditions to be avoided
Heating.
Substances to be avoided
strong oxidizing agents.
Hazardous decomposition products

in the event of fire: See chapter 5.
Further information
releases water of crystallization when heated.
11. Toxicological information

Acute toxicity
Quantitative data on the toxicity of this product are not available.
Subacute to chronic toxicity

Bacterial mutagenicity: Escherichia coli: negative. (anhydrous substance) (Lit.)
Further toxicological information

Substance properties: adstringent.
Property which must be anticipated on the basis of structure- effect considerations:
After skin contact: Slight irritations.
After eye contact: Slight iritations.
After swallowing: irritations of mucous membranes in the mouth, pharynx, oesophagus and
gastrointestinal tract.
Other notes:
The following applies to aluminium compounds in general: After swallowing: only slightly
absorbable via the gastrointestinal tract. Serious disorders in man (from about 4000 mg
aluminium up): phosphate metabolism, calcium metabolism.
Further data
The product should be handled with the care usual when dealing with chemicals.
Page 4 of 6

Catalogue No.:
Product name:
101042
12. Ecological information

Biologic degradation:
Methods for the determination of biodegradability are not applicable to inorganic substances.
Ecotoxic effects:
Quantitative data on the ecological effect of this product are not available.
Further ecologic data:
The following applies to aluminium compounds in general: for acidic aluminium compounds:
biological effects: toxic for water organisms. Fish: toxic as from 0.55 mg/l ; in very soft
water toxic as from 0.1 mg/l ; crustaceans: D. magna toxic as from 136 mg/l ; algae: Sc.
quadricauda toxic as from 1.5 mg/l (all values referring to dissolved Al). In the case of
alkaline aluminium compounds, flocculation may cause mechanical damage in aquatic organisms.
The following applies to sulfate in general: biological effects: fish: toxic as from 7 g/l ;
bacteria: toxic as from 2.5 g/l .
No ecological problems are to be expected when the product is handled and used with due care and
attention.
13. Disposal considerations

Product:
Chemicals must be disposed of in compliance with the respective national regulations. Under
www.retrologistik.de you will find country- and substance-specific information as well as
contact partners.
Packaging:
Merck product packaging must be disposed of in compliance with the country-specific regulations
or must be passed to a packaging return system. Under www.retrologistik.de you will find special
information on the respective national conditions as well as contact partners.
14. Transport information

Not subject to transport regulations.
15. Regulatory information

Labelling according to EC Directives
Symbol:
R-phrases:
S-phrases:
-------
16. Other information

Reason for alteration
Chapter 1:change in product name.
General update.
Regional representation:
This information is given on the authorised Safety Data Sheet
for your country.
Page 5 of 6

Catalogue No.:
Product name:
101042
The information contained herein is based on the present state of our knowledge. It
characterizes the product with regard to the appropriate safety precautions. It does not
represent a guarantee of the properties of the product.
Page 6 of 6

Safety Data Sheet: According To EC Directive 91/155/EEC

Uploaded by

Copyright:

Available Formats

Safety Data Sheet: According To EC Directive 91/155/EEC

Uploaded by

Document Information

Original Description:

Original Title

Copyright

Available Formats

Share this document

Share or Embed Document

Sharing Options

Did you find this document useful?

Is this content inappropriate?

Copyright:

Available Formats

Safety Data Sheet: According To EC Directive 91/155/EEC

Uploaded by

Copyright:

Available Formats

Safety Data Sheet

According to EC Directive 91/155/EEC

Identification of the substance/preparation and of the company/undertaking

Aluminium potassium sulfate dodecahydrate EMPROVE Ph Eur,BP,USP

Use of the substance/preparation

Merck KGaA * 64271 Darmstadt * Germany * Phone: +49 6151 72-0

Emergency telephone No.:

Please contact the regional Merck representation

First aid measures

Merck Safety Data Sheet

Accidental release measures

Handling and storage

Exposure controls/personal protection

required when dusts are generated.

Merck Safety Data Sheet

The protective gloves to be used must comply with the specifications

Physical and chemical properties

at 100 g/l H2O

(release of crystalline water)

Merck Safety Data Sheet

10. Stability and reactivity

Hazardous decomposition products

11. Toxicological information

Subacute to chronic toxicity

Further toxicological information

Merck Safety Data Sheet

12. Ecological information

13. Disposal considerations

14. Transport information

15. Regulatory information

16. Other information

Merck Safety Data Sheet

You might also like