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    IR Spectral Table

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    IR Spectral Table

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    IR

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    IR

    Copyright:

    © All Rights Reserved
    Download as PDF, TXT or read online from Scribd
    Download as pdf or txt
    69 views6 pages

    IR Spectral Table

    Uploaded by

    dewinoorjannah
    IR

    Copyright:

    © All Rights Reserved
    Download as PDF, TXT or read online from Scribd
    Download as pdf or txt
    of 6

    Richard F. Daley and Sally J.

    Daley
    www.ochem4free.com

    Organic
    Chemistry
    Appendix B
    Reference tables for interpreting infrared spectra

    Organic Chemistry - Appendix B

    Daley & Daley

    Copyright 1996-2005 by Richard F. Daley & Sally J. Daley


    All Rights Reserved.
    No part of this publication may be reproduced, stored in a retrieval system, or transmitted in any form or
    by any means, electronic, mechanical, photocopying, recording, or otherwise, without the prior written
    permission of the copyright holder.

    www.ochem4free.com

    5 July 2005

    Organic Chemistry - Appendix B

    Daley & Daley

    Appendix B
    Infrared Spectral Tables
    Group

    Intensitya

    Range
    (cm-1)b

    Group

    Hydrocarbons

    Alkene, nonconjugated

    CH Stretching

    Monosubstituted
    Disubstituted, cis
    Disubstituted, trans
    Disubstituted, gem
    Trisubstituted
    Tetrasubstuted
    Diene

    Alkane
    Alkene, monosubstituted

    m-s
    m
    and m
    m
    m
    m
    m
    s
    v

    2960-2850
    3040-3010
    3095-3075
    3040-3010
    3040-3010
    3095-3075
    3040-3010
    ~3300
    ~3030

    Alkane, CH
    Alkane, CH2

    w
    m

    ~1340
    1485-1445

    Alkane, CH3

    m
    and s
    s
    and s
    m
    and s
    s
    s
    and s
    s
    m
    and s
    s
    and s
    s
    s
    v,s
    and v,s
    v,s
    v,m
    v, m
    v,w
    s
    s
    s
    w
    and w

    1470-1430
    1380-1370
    1385-1380
    1370-1365
    1395-1385
    1370-1365
    1420-1410
    995-985
    915-905
    ~690
    1310-1295
    970-960
    1420-1410
    895-885
    840-790
    ~630
    ~750
    ~700
    ~750
    ~780
    ~830
    ~880
    1705-1680
    1680-1660
    1715-1695
    2900-2820
    2775-2700

    Alkene, disubstituted, cis


    Alkene, disubstituted, trans
    Alkene, disubstituted, gem
    Alkene, trisubstituted
    Alkyne
    Aromatic

    CH Bending

    Alkane, gem-dimethyl
    Alkane, tert-butyl
    Alkene, monosubstituted

    Alkene, disubstituted, cis


    Alkene, disubstituted, trans
    Alkene, disubstituted, gem
    Alkene, trisubstituted
    Alkyne
    Aromatic, five adjacent H
    Aromatic, four adjacent H
    Aromatic, three adjacent H
    Aromatic, two adjacent H
    Aromatic, one H
    ,-Unsaturated, acyclic
    ,,,-Unsaturated, acyclic
    Aryl
    Aldehyde C-H

    CC Stretching

    Alkyne, monosubstituted
    Alkyne, disubstituted
    Allene
    Aromatic

    Intensitya

    Range
    (cm-1)b

    m
    m
    m
    m
    m
    w
    w
    and w
    m
    v,w
    m
    and m
    v
    v
    m
    and m

    ~1645
    ~1658
    ~1675
    ~1653
    ~1669
    ~1669
    ~1650
    ~1600
    2140-2100
    2260-2190
    ~1960
    ~1060
    ~1600
    ~1580
    ~1500
    ~1450

    1725-1705

    s
    s
    s
    s

    1725-1705
    1750-1740
    ~1775
    1685-1665

    1685-1665

    1725-1708

    s
    s
    s
    s
    s
    s
    s

    1670-1663
    1700-1680
    1670-1660
    1730-1710
    1640-1540
    1690-1660
    ~2150

    s
    s
    and m

    1740-1720
    1780-1750
    1750-1720

    Carbonyl Groups
    Ketone
    Acyclic
    Cyclic, 6-member ring or
    larger
    Cyclic, 5-member ring
    Cyclic, 4-member ring
    ,-Unsaturated, acyclic
    ,-Unsaturated, cyclic, 6member ring or larger
    ,-Unsaturated, acyclic, 5member ring
    ,,,-Unsaturated, acyclic
    Aryl
    Diaryl
    -Diketones
    -Diketones (enolic)
    1,4-Quinones
    Ketenes

    Aldehydes
    Acyclic
    ,-Unsaturated and aryl

    Ester

    www.ochem4free.com

    5 July 2005

    Organic Chemistry - Appendix B

    Group
    Acyclic
    Cyclic, -lactones
    Cyclic, -lactones
    Cyclic, -lactones
    Vinyl esters
    ,-Unsaturated and aryl
    ,-Unsaturated -lactone
    ,-Unsaturated -lactone
    ,-Unsaturated -lactone
    -Ketoester
    -Ketoester (enolic)
    Carbonates

    Intensitya
    s
    s
    s
    s
    s
    s
    s
    s
    s
    s
    s
    s

    Range
    (cm-1)b
    1750-1735
    1750-1735
    1780-1760
    ~1820
    1800-1770
    1730-1717
    1730-1717
    1760-1740
    ~1800
    1755-1740
    ~1650
    1780-1740

    Carboxylic acids
    Acyclic
    ,-Unsaturated
    Aryl
    Hydroxyl stretching (several
    bands)
    Carboxylate anion

    s
    s
    s

    1725-1700
    1715-1690
    1700-1680

    w
    s
    and s

    2700-2500
    1610-1550
    1400-1300

    ,-Unsaturated and aryl,


    acyclic
    Saturated 5-membered ring
    ,-Unsaturated 5membered ring

    s
    and s

    1850-1800
    1790-1740
    1830-1780

    Imides, cyclic, 6-membered


    ring
    Imides, cyclic, ,unsaturated 6-membered
    ring
    Imides, cyclic, 5-membered
    ring
    Imides, cyclic, ,unsaturated 5-membered
    ring

    Primary, H-bonded
    Secondary, free
    Secondary, H-bonded

    s
    and s

    1850-1800
    1830-1780

    Alcohol OH stretch

    s
    s
    s

    ~1850
    ~1795
    ~1810

    Alcohol OH bending

    ~1650
    ~1690

    s
    s
    s
    s
    s
    s

    1680-1630
    1700-1670
    1670-1630
    ~1680
    ~1700
    1750-1700

    s
    s

    1760-1730
    1780-1770

    ~1660

    ~1640

    Range
    (cm-1)b

    s
    s
    s
    and s

    ~1720
    1740-1690
    ~1710
    ~1700

    s
    and s

    ~1710
    ~1700

    s
    and s

    ~1730
    ~1670

    s
    and s

    ~1770
    ~1700

    s
    and s

    ~1790
    ~1710

    m
    and m
    m
    and m
    m
    m

    ~3500
    ~3400
    ~3350
    ~3180
    ~3430
    3320-3140

    s
    s

    1620-1590
    1550-1510

    v, sh
    s,b

    3650-3590
    3400-3200

    s
    and s
    s
    and s
    s
    and s
    s
    and s

    1350-1260
    ~1050
    1350-1260
    ~1100
    1410-1310
    ~1150
    1410-1310
    ~1200

    m
    and m
    m
    m
    m

    ~3500
    ~3400
    3500-3310
    3400-3300
    3130-3030

    s-m
    w
    s
    and s

    1650-1590
    1650-1550
    1600-1575
    ~1500

    Amide NH bending
    Primary, dilute solution
    Secondary
    Free OH
    H-bonded
    Primary alcohols
    Secondary alcohols

    s
    s

    Intensitya

    Amide NH stretch

    1770-1720
    1870-1820
    1800-1750

    Amide Carbonyls
    Primary, solid or
    concentrated solution
    Primary, dilute solution
    Secondary, solid or
    concentrated solution
    Secondary, dilute solution
    Tertiary
    Cyclic, -lactam
    Cyclic. -lactam
    Cyclic. -lactam, fused to
    another ring
    Cyclic, -lactam
    Cyclic. -lactam, fused to
    another ring
    Ureas, acyclic
    Ureas, cyclic, 6-membered
    ring

    Ureas, cyclic, 5-membered


    ring
    Urethanes
    Imides, acyclic

    s
    and s
    s
    and s

    Acyl halides
    Acyl fluorides
    Acyl chlorides
    Acyl bromides

    Group

    Primary, free

    Anhydride
    Acyclic

    Daley & Daley

    Tertiary alcohols
    Phenols

    Amine NH stretch
    Primary
    Secondary
    Imine (C=NH)
    Amine salts

    Amine NH bending
    Primary
    Secondary
    Amine salts

    www.ochem4free.com

    5 July 2005

    Organic Chemistry - Appendix B

    Group

    Intensitya

    Range
    (cm-1)b

    Amine CH vibrations
    Aromatic, primary
    Aromatic, secondary
    Aromatic, tertiary
    Aliphatic

    s
    s
    s
    w
    and w

    1340-1250
    1350-1280
    1360-1310
    ~1410
    1220-1020

    Unsaturated
    Nitrogen
    Compounds
    Alkyl nitriles
    ,-Unsaturated alkyl
    nitriles
    Aryl nitriles
    Isocyanates
    Isocyanides
    Alkyl oximes and imines
    ,-Unsaturated oximes and
    imines
    Azo stretching
    Diimide (N=C=N)
    Stretching
    Azide stretching
    Nitroso (CN=O)
    Aromatic nitro compounds
    Aliphatic nitro compounds

    Daley & Daley

    2260-2240

    m
    m
    m
    m
    v
    v

    2235-2215
    2240-2220
    2275-2240
    2220-2070
    1690-1640
    1660-1630

    1630-1575

    s
    s
    and w
    s
    s
    and s
    s

    2155-2130
    2160-2120
    1340-1180
    1600-1500
    1570-1500
    1370-1300
    1570-1550

    Group

    Nitrates (ONO2)
    Nitrites (ON=O)

    Intensitya
    and s
    s

    Range
    (cm-1)b
    1380-1370
    1650-1600

    and s
    s
    and s

    1300-1250
    1680-1650
    1625-1610

    s
    s
    s
    s

    1400-1000
    800-600
    600-500
    ~500

    s
    s
    s
    s
    and s
    s
    s
    s
    and s
    s
    and s
    s
    s
    and s

    2600-2550
    1200-1050
    1070-1030
    1350-1300
    1230-1150
    1430-1350
    1230-1150
    1370-1340
    1185-1165
    1350-1300
    1180-1140
    1210-1150
    1060-1030
    ~650

    Halogen compounds
    stretching
    Fluorides
    Chlorides
    Bromides
    Iodides

    Sulfur compounds
    Thiol SH stretching
    C=S stretching
    Sulfoxides
    Sulfones
    Sulfites
    Sulfonyl chlorides
    Sulfonamides
    Sulfonic acids

    a Abbreviations: s= strong, m = medium, w = weak, v = variable, b = broad, sh = sharp.


    b Abbreviation: ~ = approximately

    www.ochem4free.com

    5 July 2005

    Organic Chemistry - Appendix B

    www.ochem4free.com

    Daley & Daley

    5 July 2005

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