What Is Soil Acidification

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WHAT IS SOIL ACIDIFICATION

Soil acidification is the buildup of hydrogen cations, also called protons, reducing the soil pH. This
happens when a proton donor gets added to the soil. The donor can be anacid, such as nitric
acid and sulfuric acid (these acids are common components of acid rain). It can also be a compound
such as aluminium sulphate, which reacts in the soil to release protons. Many nitrogen compounds,
which are added as fertilizer, also acidify soil over the long term because they
produce nitrous and nitric acid when oxidized in the process of nitrification.
Acidification also occurs when base cations suchas calcium, magnesium, potassium and sodium are
leached from the soil. This leaching increases with increasing precipitation.Acid rain accelerates
the leaching of bases. Plants take bases from the soil as they grow, donating a proton in exchange
for each base cation. Where plant material is removed, as when a forest is logged or crops are
harvested, the bases they have taken up are permanently lost from the soil.

Causes of soil acidity


Producers commonly ask this question of staff soil fertility and crops
specialists. There are four major reasons for soils to become acidic: rainfall
and leaching, acidic parent material, organic matter decay, and harvest of
high-yielding crops. Wet climates have a greater potential for acidic soils. In
time, excessive rainfall leaches the soil profile's basic elements (calcium,
magnesium, sodium, and potassium) that prevent soil acidity. Soils that
develop from weathered granite are likely to be more acidic than those
developed from shale or limestone. Organic matter decay produces hydrogen
ions (H+), which are responsible for acidity (an ion is a positively or
negatively charged element). Like that from rainfall, acidic soil development
from decaying organic matter is insignificant in the short term. Harvest of
high-yielding crops plays the most significant role in increasing soil acidity.
During growth, crops absorb basic elements such as calcium, magnesium,
and potassium to satisfy their nutritional requirements. As crop yields
increase, more of these limelike nutrients are removed from the field.
Compared to the leaf and stem portions of the plant, grain contains minute
amounts of these basic nutrients. Therefore, harvesting high-yielding forages
such as bermudagrass and alfalfa affects soil acidity more than harvesting
grain does.

Nitrogen fertilizer has been blamed for the increase in soil acidity problems
throughout the region. Yes, when ammoniacal fertilizer materials are applied
to the soil, acidity is produced, but the form of nitrogen removed by the crop
is similar to that found in fertilizer. In reality, nitrogen fertilizer increases soil
acidity by increasing crop yields, thereby increasing the amount of basic
elements being removed.
How is soil acidity corrected?
Soil acidity can be corrected easily by liming the soil, or adding basic
materials to neutralize the acid present. The most commonly used liming
material is agricultural limestone, the most economical and relatively easy to
manage source. The limestone is not very water-soluble, making it easy to
handle. Lime or calcium carbonate's reaction with an acidic soil is described
in figure 1, which shows acidity (H) on the surface of the soil particles. As
lime dissolves in the soil, calcium (Ca) moves to the surface of soil particles,
replacing the acidity. The acidity reacts with the carbonate (CO3) to form
carbon dioxide (CO2) and water (H2O). The result is a soil that is less acidic
(has a higher pH).

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