SPM Trial 2014 Chemistry Qa Kedah SetA
SPM Trial 2014 Chemistry Qa Kedah SetA
SPM Trial 2014 Chemistry Qa Kedah SetA
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1.
Diagram 1
Rajah 1
Which of the following is the physical state of X?
Antara berikut keadaan fizikal X?
Liquid
Cecair
Solid
Pepejal
Gas
Gas
2.
Compound
Sebatian
Molecule
Molekul
Atom
Atom
Ion
Ion
3.
Hydrogen-1
Hidrogen-1
Carbon-12
Karbon-12
Oxygen-16
Oxygen -16
Nitrogen-14
Nitrogen -14
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4.
formula of a molecule
formula satu molekul bahan
Which of the following pairs of group and name is correct in the Periodic Table?
Antara berikut yang manakah pasangan yang betul bagi kumpulan dan nama di dalam Jadual
Berkala?
Group
Kumpulan
A
B
C
D
Name
Nama
Alkali earth metal
Alkali metal
Logam alkali
Halogen
17
Halogen
Transition elemant
18
Unsur peralihan
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Magnesium chloride
Magnesium klorida
Lead(II) chloride
Plumbum(II) klorida
Calcium oxide
Kalsium oksida
Karbon dioxide
Karbon dioksida
Magnesium chloride
Magnesium klorida
Sulphur dioxide
Sulfur dioksida
Iron(III) oxide
Ferum(III) oksida
Lead(II) oxide
Plumbum(II) oksida
Prevention of corrosion
Mencegah kakisan
Electroplating metals
Penyaduran logam
Extraction of metals
Pengekstrakan logam
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10 Metal P displaced zinc from zinc nitrate solution but does not displace magnesium from
magnesium nitrate solution. Metal P could be
Logam P menyesarkan zink daripada larutan zink sulfat tetapi tidak menyesarkan magnesium
daripada larutan magnesium sulfat. Logam P mungkin
Lead
Plumbum
Copper
Kuprum
Calsium
Kalsium
Aluminium
Aluminium
It conducts electricity
Mengkonduksikan elektrik
12 Which of the following reactants will produce salt and water only?
Antara berikut, bahan tindak balas yang manakah akan menghasilkan garam dan air
sahaja?
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13 The following equation shows the reaction to produce a blue solution.
Persamaan berikut menunjukkan tindak balas untuk menghasilkan larutan biru.
H2S04 + X sulphate salt + H20
garam sulfat
What is X?
Apakah bahan X?
A Potassium hydroxide
Kalium hidroksida
B
Lead(II) oxide
Plumbum(II) oksida
C
Barium hydroxide
Barium hidroksida
D Copper(II) oxide
Kuprum(II) oksida
14
A
B
C
D
15
Steel
Keluli
Pewter
Piuter
Bronze
Gangsa
Brass
Loyang
Hydrogenation
Penghidrogenan
Ostwald
Ostwald
Contact
Sentuh
Haber
Haber
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16
17
The collision theory states that for a chemical reaction to occur, the reacting
particles must
Teori perlanggaran menyatakan bahawa bagi tindak balas kimia boleh berlaku,
zarah-zarah yang bertindak balas mesti
A
B
C
D
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18
Diagram 2
Rajah 2
Berdasarkan rajah 2, apakah jumlah tenaga pengaktifan bagi tindak balas di atas?
Based on the diagram, what is the amount of activation energy?
A
B
C
D
19
(X - Y) kj mol-1
(Y - X ) kj mol-1
X kj mol-l
Y kj mol-1
CnH2n+1COOH
CnH2n+1OH
CnH2n+2
CnH2n
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20
21.
Carbon
Karbon
Butanol
Butanol
Polivinil chloride
Polivinil klorida
Hydrogen gas
Gas hidrogen
H O
| ||
H C C OH
|
H
Diagram 3
Rajah 3
The empirical formula of etanoic acid is
Formula empirik bagi asid etanoik ialah
A
B
C
D
CHO2
CH2O
C2H402
C3H6O3
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22
13 14 15 16 17 18
Diagram 4
Which of the following element has the greatest ability to release electron(s)?
Antara yang berikut, manakah unsur yang mempunyai keupayaan yang paling
tinggi untuk melepaskan elekron?
A
B
C
D
S
T
U
V
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23
Y
Diagram 5
24
12
Diagram 6
What is the electron arrangement of ion T?
Apakah susunan electron bagi ion T?
A
B
C
D
2.8
2.8.2
2.8.8
2.8.8.8
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25 Table 1 belows shows the proton number of elements X and Y.
Jadual 1 menunjukkan nombor proton unsur X dan Y.
Element
Unsur
Proton number
Nombor proton
8
Table 1
What type of bond and the chemical formula of the compound formed between X
and Y?
Apakah jenis ikatan dan formula kimia bagi sebatian yang terbentuk antara atom X
dan Y?
A
B
C
D
Type of bond
Jenis ikatan
Ion
Ion
Ion
Ion
Covalent
Kovalen
Covalent
Kovalen
Chemical formula
Formula kimia
YX2
XY2
XY2
YX2
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26 Diagram 7 shows the apparatus set-up used for the purification of copper metal
through electrolysis.
Rajah 7 menunujukkan susunan radas yang digunakan untuk penulenan logam
kuprum melalui elektrolisis.
Y
Solution Z
Larutan Z
Diagram 7
Which of the following substances is suitable to be used as electrode and electrolyte.
Manakah antara bahan-bahan berikut yang sesuai digunakan sebagai elektrod dan
elektrolit.
A
B
C
D
Electrode X
Elektrod X
Pure copper
Kuprum tulen
Impure copper
Kuprum tak tulen
Pure copper
Kuprum tulen
Impure copper
Kuprum tak tulen
Electrode Y
Elektrod Y
Impure copper
Kuprum tak tulen
Pure copper
Kuprum tulen
Impure copper
Kuprum tak tulen
Pure copper
Kuprum tulen
Solution Z
Larutan Z
Copper(II) sulphate
Kuprum(II) sulfat
Copper(II) nitrate
Kuprum(II) nitrat
Copper(II) carbonate
Kuprum(II) karbonat
Copper(II) carbonate
Kuprum(II) karbonat
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27 Table 2 shows the observations of electrolysis using carbon electrode and electrolyte
W.
Jadual 2 menunjukkan pemerhatian bagi elektrolisis menggunakan elektrod karbon
dan elektrolit W.
Electrode
Elektrod
Anode
Anod
Cathode
Katod
Observation
Pemerhatian
A greenish-yellow gas released
Gas berwarna kuning kehijauan terbebas
A colorless gas which burns with a pop sound is released
Gas yang tidak berwarna dan terbakar dengan bunyi pop terbebas
Table 2
Aqueous solution
Larutan akueus
pH value
Nilai pH
Table 3
Which of the solution will react with calcium carbonate to release carbon dioxide?
Larutan manakah akan bertindak balas dengan kalsium karbonat untuk
membebaskan karbon dioksida?
A L
B M
C N
D O
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29 Glacial ethanoic acid does not change blue litmus paper to red.
The litmus paper turns red when added with
Asid etanoik glacial tidak menukarkan kertas litmus biru ke merah. Kertas litmus
bertukar kepada merah apabila ditambah dengan
A
B
C
D
propanol
propanol
ethyl ethanoate
etil etanoat
chloroform
klorofom
water
air
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30 Diagram 8 shows chemical tests of compound G.
Rajah 8 menunjukkan ujian kimia bagi sebatian G.
G
Added with dilute hydrochloric acid and
filtered
Tambah dengan asid hidroklorik dan
dituraskan
Precipitation
Mendakan
Solution
Larutan
Diagram 8
G is a mixture of two types of salts. Which of the following is found in G?
G ialah campuran dua jenis garam. Antara berikut manakah terdapat dalam G?
A
B
C
D
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H
H
C
C
CH3 H
H H
H
H H
C
C C
C C
CH3 H CH3 H CH3
Diagram 9
A
B
C
D
CHCH=CH2
CHCH=CH3
CHCH3=CH2
CH3=CH3
32 The following equation represents the reaction between zinc and hydrochloric acid.
Persamaan berikut mewakili tindak balas antara kasium karbonat dan asid
hidroklorik.
Zn(s) + 2HCl(aq) ZnCl2(aq) + H2(g)
Predict the changes of the rate of reaction if the hydrochloric acid is replaced with
sulphuric acid ?
Ramalkan perubahan yang berlaku pada kadar tindak balas jika asid hidroklorik
diganti dengan asid sulfurik ?
A
B
C
D
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33 The following equation shows the reaction between excess zinc powder and dilute
hydrochloric acid:
Persamaan berikut menunjukkan tindak balas antara serbuk zink berlebihan dengan
asid hidroklorik cair:
Zn + 2HCl ZnCl2 + H2
Which of the following graphs represents the volume of hydrogen gas ,V released
against time , t?
Antara graf berikut yang manakah mewakili isipadu gas hidrogen ,V yang
dibebaskan melawan masa,t?
A
C
3
/cm3
/cm
/s
/s
B
D
3
/cm3
/cm
/s
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/s
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34
Diagram 10
What is the name of compound Q?
Apakah nama sebatian Q?
A
B
C
D
Ethyl methanoate
Etil metanoat
Ethyl ethanoate
Etil etanoat
Methyl ethanoate
Metil etanoat
Methyl propanoate
Metil propanoat
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35
The following equation represents the reaction between propene and chlorine.
Persamaan berikut mewakili tindak balas antara propena dan klorin.
Propene + Cl2 S
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36.
Carbonate salt
Garam karbonat
limewater
air kapur
heated
panaskan
Diagram 11
37.
Which of the following gases contains 0.4 mol of atoms at room temperature and
pressure?
[1 mol of gas occupies the volume of 24 dm3 at room temperature and pressure]
Antara gas berikut, yang manakah mengandungi 0.4 mol atom pada suhu dan tekanan
bilik?
[1 mol gas menempati isipadu sebanyak 24 dm3 pada suhu dan tekanan bilik]
A
B
C
D
4.8 dm3 He
4.8 dm3 CO2
4.8 dm3 S03
4.8 dm3 H2
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38 Atom R reacts with atom W to form a compound with a formula RW4.
Given that the relative atomic mass of R is 12 and the relative atomic mass of W is
35.5.
Find the relative molecular mass of the compound formed by R and W.
Atom R bertindakbalas dengan atom W untuk menghasilkan sebatian dengan
formula RW4.
Diberi jisim atom relatif R ialah 12 manakala jisim atom relatif W ialah 35.5.
Tentukan jisim molekul relative bagi sebatian yang terbentuk di antara R dan W.
A
B
C
D
39
154.0
130.5
95.0
47.5
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40 Table 4 shows the information about three voltaic cells.
Jadual 4 menunjukkan maklumat tentang tiga sel voltan.
Pairs of metals
Pasangan logam
W, Y
X, Y
W, X
Terminal positif
Positive terminal
Z
Y
X
Potential difference / V
Beza keupayaan / V
3.1
0.3
1.8
Table 4
What is the potential difference of a voltaic cell using metal Y and Z as electrodes?
Apakah beza keupayaan bagi sel voltan yang menggunakan logam Y dan Z sebagai
elektrod?
A
B
C
D
1.0 V
1.3 V
2.1 V
2.8 V
41 0.1 mol sulphuric acid neutralizes completely 0.2 mol of an alkali which has the
formula M(OH)n.
What is the value of n in the formula?
0.1 mol asid sulfurik meneutralkan dengan lengkap 0.2 mol suatu alkali yang
mempunyai formula M(OH)n.
Apakah nilai untuk n dalam formula ini?
A
B
C
D
1
2
3
4
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42 25 cm3 of 0.5 mol dm-3 potassium hydroxide, KOH, is titrated with hydrochloric
acid.
What is the volume of 1.0 mol dm-3 hydrochloric acid required to neutralise the
alkaline solution?
25 cm3 kalsium hidroksida, KOH , 0.5 mol dm-3 dititratkan dengan asid hidroklorik.
Apakah isi padu asid hidroklorik 1.0 mol dm-3 yang diperlukan untuk meneutralkan
larulan alkali tersebut?
A
10 .0 cm3
12.5 cm3
25.0 cm3
50.0 cm3
43 4.5 g of calcium carbonate powder is reacted with excess dilute hydrochloric acid.
What is the mass of calcium chloride formed in the reaction?
[ Relative atomic mass : Ca,40; C,12; O,16; H,1; Cl,35.5]
4.5 g serbuk kalsium karbonat bertindak balas dengan asid hidroklorik secara
berlebihan. Berapakah jisim kalsium klorida yang terbentuk dalam tindak balas ini?
[ Jisim Atom Relatif : Ca,40; C,12; O,16; H,1; Cl,35.5]
A
2.498 g
3.398 g
4.995 g
9.990 g
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44 Table 5 shows the results of two chemical tests on a salt solution
Jadual 5 menunjukkan dua keputusan ujian kimia terhadap satu larutan garam
Test
Ujian
I
II
Procedure
Kaedah
Observation
Pemerhatian
Excess sodium
hydroxide solution is
added.
Larutan natrium
hidroksida ditambah
secara berlebihan
Excess ammonia
solution is added
Larutan ammonia
ditambah secara
berlebihan
Based on the information. There are two cations present in the solution.
How to confirm the cations in the solution?
Berdasarkan maklumat tersebut, terdapat dua kation hadir dalam larutan itu.
Bagaimanakah untuk menentusahkan kation-kation itu?
A
B
C
D
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45 The following are the formulae of several fertilisers.
Berikut adalah formula bagi beberapa jenis baja.
Urea, CO(NH2)2
Ammonium nitrate,
ammonium nitrat, NH4N03
Ammonium phosphate, ammonium fosfat (NH4 )2 HPO4
Ammonium sulphate,ammonium sulfat, NH4SO4
Urea
Urea
Ammonium nitrate
Ammonium nitrat
Ammonium phosphate
Ammonium fosfat
Ammonium sulphate
Ammonium sulfat
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46 Diagram 12 shows profile diagram for the reaction P + Q S.
Rajah 12menunjukkan rajah profil untuk tindak balas P + Q S.
Energy
Tenaga
350 kJ
S
130 kJ
P+Q
Diagram 12
A
B
C
D
130 kJ mol-1
350 kJ mol-1
480 kJ mol-1
830 kJ mol-1
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47 Table 6 shows the total volume of gas collected at regular intervals in a reaction.
Jadual 6 menunjukkan jumlah isipadu gas yang terkumpul pada sela masa tertentu
dalam suatu tindak balas.
Time/s
Masa/s
30
60
90
120 150
180 210
Volume of gas / cm
Isipadu gas / cm
2.0
3.7
5.2
6.4
8.6
7.3
8.6
Table 6
What is the average rate of reaction in the second minute?
Berapakah kadar tindak balas purata dalam minit kedua?
A
B
C
D
0.040 cm s 1
0.045 cm s 1
0.053 cm s 1
0.062 cm s 1
48 If you want to cook 50 eggs within a short time, which is the most suitable method?
Sekiranya anda ingin memasak 50 biji telur dalam masa yang singkat, apakah
langkah paling sesuai di lakukan?
A
B
C
D
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49
2.24 dm3
1.12 dm3
4.48 dm3
8.96 dm3
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50
Diagram 13
What property of vulcanized rubber makes it suitable to be used for making these
car tyres?
Apakah sifat getah tervulkan yang menyebabkannya sesuai digunakan dalam
pembuatan tayar kereta?
A
B
C
D
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INFORMATION FOR CANDIDATES
question, choose one answer only. Blacken your answer on the objective answer sheet
provided.
Tiap-tiap soalan diikuti oleh empat pilihan jawapan, iaitu A. B. C dan I). Bagi setiap
soalan, pilih satu jawapan sahaja. Hitamkan jawapan anda pada kertas jawapan
objektif yang disediakan.
4. If you wish to change your answer, erase the blackened mark that you have made.
Rajah yang mengiringi soalan tidak dilukis mengikut skala kecuali dinyatakan.
6. You may use a scientific calculator.
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1
NAMA:..
TINGKATAN:..
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Section A
Bahagian A
[60 marks]
[60 markah]
Answer all questions in this section.
Jawab semua soalan dalam bahagian ini.
23
11
35
17
37
17
20
10
Diagram 1
Rajah 1
(a)
(i)
[ 1 mark]
[ 1 mark]
(b)
(i)
[ 1 mark]
[ 1 mark]
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(c)
[ 2 marks]
(d)
[ 2 mark]
(ii) State one use of element S.
Nyatakan satu kegunaan unsur S.
..
[ 1 mark]
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Diagram 2.1 shows parts of the Periodic Table of Elements. A, B, D ,E and G do not
represent the actual symbols of the elements.
Rajah 2.1 menunjukkan sebahagian daripada Jadual Berkala Unsur. A, B, C, D dan E
tidak mewakili simbol sebenar unsur-unsur berkenaan.
D
G
Diagram 2.1
Rajah 2.1
Using the letters in diagram 2.1, answer the following question;
Dengan menggunakan huruf-huruf dalam rajah 2.1, jawab soalan-soalan berikut;
(a)
(b)
[ 1 mark ]
(c)
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(d)
[ 1 mark ]
(fe
Diagram 2.2 shows the set-up of the apparatus to investigate the reaction between
element A with oxygen gas.
Rajah 2.2 menunjukkan susunan radas untuk mengkaji tindak balas antara unsur
A dengan gas oksigen.
(i)
Gas jar
Balang gas
Oxygen gas
Gas oksigen
Element A
Unsur A
Diagram 2.2
Rajah 2.2
State one precautionary step that must be taken when carrying out this
experiment.
Nyatakan satu langkah berjaga-jaga yang perlu diambil ketika
menjalankan eksperimen ini.
.
[ 1 mark ]
(ii)
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(iii)
[ 2 marks ]
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Types
Jenis
Examples
Contoh
Compositions
Komposisi
Glass
Borosilicate
Kaca
Borosilikat
Polymer
Vinyl chloride
Z
Polimer
Vinil klorida
Alloy
Bronze
Aloi
Gangsa
Composite
material
Bahan
komposit
Table 3
(a)
[1 mark]
(b)
[ 2 marks]
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(c)
(i)
Cl
Cl
Cl
Diagram 3
Rajah 3
Draw the structural formula of monomer of compound Z.
Lukiskan formula struktur bagi sebatian Z.
1 mark]
(ii)
Compound Z is often used as a water pipe. State one advantage of this type
of pipe as compared to metal pipes.
Sebatian Z sering digunakan sebagai paip air. Berikan satu kebaikan bahan
ini sebagai paip berbanding dengan paip logam.
[1 mark]
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(d)
W can withstand high pressure and can support very heavy loads.
What is W?
W boleh tahan terhadap tekanan yang tinggi dan boleh menampung beban yang
sangat berat. Apakah W?
..
[1 mark]
(e)
(i)
[2 mark]
(ii)
[ 3 marks]
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V
Zinc
zink
Zinc sulphate
Zink sulfat
CELL A
SEL A
Copper(II) sulphate
Kuprum(II) sulfat
CELL B
SEL B
Diagram 4
Rajah 4
(a)
Cell A :
Sel A:.
(ii)
Cell B:
Sel B:..
[2 marks]
(b)
(c)
Write the ionic equation for the reaction that occurred in cell A.
Tulis persamaan ion untuk tindak balas yang berlaku dalam sel A.
[2 marks]
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(d)
cathode of cell A:
katod sel A:
(ii)
anode of cell B:
anod sel B:
[2 marks]
(e)
(i)
[1 mark]
(ii)
[2 marks]
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Diagram 5.1 shows the apparatus set-up of experiment to investigate the effect of heat
on lead(II) carbonate salt.
Rajah 5.1 menunjukkan susunan radas bagi eksperimen yang dijalankan untuk mengkaji
kesan haba ke atas garam plumbum(II) karbonat.
PbCO3
Heat
Panaskan
Lime water
Air kapur
Diagram 5.1
Rajah 5.1
(a)
(i)
[1 mark]
(ii)
Tick () in the box below for the observations that occur in the above
experiment.
Tandakan ( ) dalam kotak dibawah bagi mewakili pemerhatian yang
berlaku dalam eksperimen di atas.
White solid turns brown when hot and yellow when cold
Pepejal putih bertukar perang semasa panas dan kuning semasa sejuk
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(b)
Diagram 5.2
Rajah 5.2
[2 marks]
(ii)
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(iii)
Describe how to obtain the solid lead(II) carbonate from the mixture of the
solutions.
Terangkan bagaimana mendapatkan pepejal plumbum(II) karbonat dari
campuran larutan tersebut.
[2 marks]
(c)
[2 marks]
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Process X
Proses X
H
But-1-ene
Hydrocarbon Y
Hidrokarbon Y
Diagram 6
Rajah 6
(a)
Name process X.
Namakan proses X.
[1 mark]
(b)
(c)
[3 marks]
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(d)
[3 marks]
(e)
Isomerism is the phenomenon where a compound has the same molecular formula
but different structural formula. Butene has three isomers.
Draw all the isomers of butene.
Isomerism ialah fenomena di mana suatu sebatian mempunya formula molekul
yang sama tetapi formula struktur yang berbeza. Butena mempunyai tiga isomer.
Lukis semua isomer bagi butena.
[3 marks]
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Section B
Bahagian B
[20 marks]
[20 markah]
Answer any one question from this section
Jawab mana-mana satu soalan daripada bahagian ini.
(a)
Table 7 shows the pH for solutions of acid P and acid Q with the same
concentration.
Jadual 7 menunjukkan pH bagi larutan asid P dan asid Q dengan kepekatan sama.
Acid
Asid
pH value
Nilai pH
Table 7
Jadual 7
By using one example of acid P and acid Q each, explain why the pH values of the
acids are different.
Dengan menggunakan satu contoh bagi setiap asid P dan asid Q, terangkan
perbezaan nilai pH asid-asid tersebut.
[8 marks]
(b)
Aaron was bitten by an ant and his skin becomes itchy. He uses
calamine lotion to relief the pain.
Aaron digigit semut dan kulitnya menjadi gatal. Dia menyapu
losen kalamin untuk menghilangkan kesakitan.
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18
(c)
(i)
50 cm3 of 0.5 mol dm-3 sulphuric acid, H2SO4 reacts completely with 25 cm3
of sodium hydroxide, NaOH solution.
Write the chemical equation for the reaction.
Calculate the molarity of the sodium hydroxide, NaOH solution needed to
neutralize the acid.
50 cm3 asid sulfurik, H2SO4 0.5 mol dm-3 bertindak balas dengan lengkap
bersama 25 cm3 larutan natrium hidroksida, NaOH.
Tuliskan persamaan kimia bagi tindak balas.
Hitung kemolaran larutan natrium hidroksida, NaOH yang diperlukan untuk
meneutralkan asid tersebut.
[6 marks]
(ii)
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19
A group of pupils carried out three experiments to investigate the factors affecting the
rate of reaction.
Table 8 shows information about the reaction in each experiment.
Sekumpulan pelajar menjalankan tiga eksperimen untuk mengkaji faktor yang mempengaruhi
kadar tindak balas.
Jadual 8 menunjukkan maklumat yang digunakan dalam setiap eksperimen
Experiment
Eksperimen
Reactants
Bahan tindak balas
3
-3
60 cm of 0.25 mol dm hydrogen peroxide solution
II
III
Table 8
Jadual 8
50
III
II
15
30
Diagram 88
Rajah 8
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55
Time/s
Masa/s
20
(a)
(b)
(c)
(d)
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21
Section C
Bahagian C
[20 marks]
Answer any one question from this section
Jawab mana-mana satu soalan daripada bahagian ini.
9.
Element
Unsur
V
W
X
Proton number
Nombor proton
6
11
8
Table 9
Jadual 9
(a)
Based on table 9, choose two different elements can formed either ionic
compound or covalent compound and answer these question:
Daripada jadual 9, pilih dua unsur yang berlainan yang boleh membentuk
samada sebatian ion atau sebatian kovalen dan jawab soalan berikut:
(i)
State the type of bond and the molecular formula of the compound formed
Write a balanced chemical equation for the reaction that occur between the
elements.
Nyatakan jenis ikatan dan formula molekul bagi sebatian yang terbentuk
Tuliskan persamaan kimia seimbang bagi tindakbalas yang berlaku antara
unsur-unsur tersebut.
[4 marks]
(ii)
Draw the electron arrangement of the compound formed. Explain how the
compound is formed. Give one physical property of the compound.
Lukiskan susunan elektron bagi sebatian yang terbentuk. Terangkan
bagaimana sebatian itu terbentuk Berikan satu sifat fizik bagi sebatian
tersebut.
[ 11 marks]
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22
(b)
+ water
+ air
+ solvent Z
+ pelarut Z
Solution I
Can conduct electricity
Change the colour of litmus
paper
Solution II
Cannot conduct electricity
Does not change the colour of
litmus paper
Diagram 9
Rajah 9
(i)
(ii)
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23
10
Alcohol is an example of an organic compound with various uses. The general formula
of alcohol is CnH2n+1 OH.
Alkohol adalah satu contoh sebatian organik dengan pelbagai kegunaan.
Formula am alkohol adalah CnH2n+1 OH.
(a)
(b) Diagram 10 shows the flow chart on how ethanol can be prepared in the school
laboratory and industry using glucose and ethene respectively.
Rajah 10 menunjukkan carta alir bagaimana etanol dapat disediakan di makmal
sekolah dan industri menggunakan glukosa dan etena masing-masing.
Glucose
Glukosa
Ethanol
Etanol
Ethene
Etena
Diagram 10
Rajah 10
Briefly describe the preparation of ethanol from glucose and ethene.
Your description must include:
The name of the process and the steps required.
The chemicals to be used and the suitable conditions for the conversions
The chemical equation for the reactions that occur
Huraikan dengan ringkas penyediaan etanol daripada glukosa dan etena.
Huraian anda haruslah merangkumi:
Nama bagi proses dan langkah yang terlibat
Bahan kimia yang digunakan dan keadaan yang sesuai bagi pertukaran
Persamaan kimia bagi tindak balas yang berlaku
[10 marks]
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24
(c) Alcohols react with carboxylic acids to form esters and water.
By using one named example of an alcohol and one named example of a
carboxylic acid, describe the preparation of an ester in the laboratory.
Alkohol bertindak balas dengan asid karboksilik untuk menghasilkan ester dan air.
Dengan menggunakan satu alkohol yang dinamakan dan satu asid karboksilik yang
dinamakan, huraikan penyediaan ester di dalam makmal.
[6 marks]
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25
SULIT 4541/2
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26
2.
3.
4.
5.
6.
7.
8.
9.
10.
11.
4541/2
SULIT
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Markah
Diperolehi
Kertas soalan ini mengandungi 8 halaman bercetak .dan 1 halaman tidak bercetak.
[Lihat halaman sebelah
SULIT
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2
1
Diagram 1 shows the apparatus set-up of experiment to compare the hardness of copper
and its alloy. The 1 kilogram weight at 500 cm height is dropped onto a stainless steel ball
bearing stick on the block of copper. The step is repeated three times on different surfaces
of the copper block. The dents formed are shown in Table 1. The diameter of the dents are
recorded. The experiment was repeated using brass block.
Rajah 1 menunjukkan susunan radas eksperimen untuk membandingkan kekerasan kuprum dan
aloinya. Pemberat 1 kilogram pada ketinggian 500 cm dijatuhkan ke atas bebola keluli yang
dilekatkan ke atas blok kuprum. Langkah tersebut diulang sebanyak tiga kali keatas permukaan
blok yang berlainan. Lekuk yang terbentuk ditunjukkan dalam Jadual 1. Diameter lekuk
direkodkan. Eksperimen diulang menggunakan blok loyang.
1 kg weight
Pemberat 1 kg
Copper block
Blok kuprum
Diagram 1
Rajah 1
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3
Surface
Copper block
Brass block
...........................................cm
................................................cm
...............................cm
................................................cm
..............................................cm
.................................................cm
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[3 marks]
(b) Construct a table to record the diameter and the average diameter of dents on copper and
brass blocks.
Bina satu jadual untuk merekod diameter lekuk dan purata diameter lekuk bagi bongkah
kuprum dan bongkah loyang.
[3 marks]
(c) State one hypothesis for the experiment.
Nyatakan satu hipotesis bagi kedua eksperimen.
..................................................................................................................................................
..................................................................................................................................................
..................................................................................................................................................
[3 marks]
(d) State the variables for this experiment.
Nyatakan pemboleh ubah bagi eksperimen ini.
(i) Manipulated variable: -.......................................................................................
Pemboleh ubah dimanipulasikan:
(ii) Responding variable:-.......................................................................................
Pemboleh ubah bergerak balas:
(iii) Fixed variable:-................................................................................................
Pemboleh ubah dimalarkan:
[3 marks]
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What can you observe at the diameters of dents when alloy block is used to replace the
pure metal block?
Apakah yang dapat diperhatikan pada diameter bagi lekuk terbentuk apabila blok aloi
diguna bagi menggantikan blok logam tulen?
.....................
..
.
[3 marks]
(g) What is the inference based on the observation?
Apakah inferens berdasarkan pemerhatian?
....
[3 marks]
(h) If a steel bar and an iron bar are left in at moist area for three days, what will happen for
the steel bar and an iron bar?
Sekiranya satu kepingan keluli dan kepingan besi dibiarkan di kawasan lembab selama
tiga hari, apakah yang akan terjadi kepada kepingan keluli dan kepingan besi tersebut?
[3 marks]
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(i)
A student repeat this experiment using copper block, but she dropped the weight from 400
cm height. Predict the value of diameter of dents produce.
Seorang pelajar telah mengulangi eksperimen ini dengan menggunakan bongkah kuprum,
tetapi dia telah menjatuhkan pemberat pada ketinggian 400cm. Ramalkan nilai diameter
lekuk yang terhasil.
(j)
[3 marks]
Classify all the substances below into alloy and pure metals.
Kelaskan semua bahan-bahan di bawah kepada aloi dan logam tulen.
Duralumin
Duralumin
Magnesium
Magnesium
Alloy
Aloi
Pewter
Piuter
Tin
Timah
Manganese
Mangan
Gold
Emas
Pure Metal
Logam Tulen
[3 marks]
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Fresh milk stored in the refrigerator lasts longer than that placed in the cabinet.
Susu segar yang disimpan di dalam peti sejuk didapati tahan lebih lama berbanding
diletakkan di dalam kabinet.
Referring to the above situation, plan a laboratory experiment to investigate the effect of
temperature on the rate of reaction between sodium thiosulphate solution and
hydrochloric acid.
Merujuk kepada maklumat di atas, rancang satu eksperimen dalam makmal untuk
menyiasat kesan suhu keatas kadar tindak balas antara larutan natrium tiosulfat dengan
asid hidroklorik.
Your planning must include the following aspects:
Perancangan anda hendaklah mengandungi aspek-aspek berikut :
(a)
Problem statement
Pernyataan masalah
(b)
(c)
Hypothesis
Hipotesis
(d)
(e)
Procedure
Prosedur
(f)
Tabulation of data
Penjadualan data
[17 marks]
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8
INFORMATION FOR CANDIDATES MAKLUMAT UNTUK CALON
1. This question paper consists of two questions: Question 1 and Question 2
Kertas soalan ini mengandungi dua soalan: Soalan 1 dan Soalan 2.
2. Answer all questions. Write your answers for Question 1 in the spaces provided in this
question paper.
Jawab semua soalan. Tulis jawapan anda bagi Soalan 1 pada ruang yang disediakan
pengawas peperiksaan. Anda boleh menggunakan persamaan, rajah, jadual, graf dan
cara lain yang sesuai untuk menjelaskan jawapan anda.
4. Show your working, it may help you to get marks.
Tunjukkan kerja mengira, ini membantu anda mendapatkan markah.
5. The diagrams in the questions are not drawn to scale unless stated.
Rajah dalam soalan tidak dilukis mengikut skala kecuali dinyatakan.
6. The marks allocated for each question or sub-part of a question are shown in brackets.
Markah yang diperuntukkan bagi setiap soalan atau ceraian soalan ditunjukkan
dalam kurungan.
7. If you wish to change your answer, cross out the answer that you have done. Then write down
the new answer.
Jika anda hendak menukar jawapan, batalkan jawapan yang telah dibuat. Kemudian
tulis jawapan yang baru.
8. You may use a scientific calculator.
Anda dibenarkan menggunakan kalkulator saintijik.
9. You are advised to spend 45 minutes to answer Question 1 and 45 minutes for Question 2.
Anda dinasihati supaya mengambil masa 45 minit untuk menjawab Soalan 1 dan 45
minit untuk Soalan 2.
10. Detach Question 2 from this question paper. Tie the 'helaian tambahan' together with this
question paper and hand in to the invigilator at the end of the examination.
Ceraikan Soalan 2 daripada kertas soalan ini. Ikat helaian tambahan bersama-sama
kertas soalan ini dan serahkan kepada pengawas peperiksaan pada akhir
peperiksaan.
SULIT
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26.
2.
27
3.
28
4.
29
5.
30
6.
31
7.
32
8.
33
9.
34
10.
35
11.
36
12.
37
13.
38
14.
39
15.
40
16.
41
17.
42
18.
43
19.
44
20.
45
21.
B
B
46
22.
47
23.
48
24.
49
25.
50
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ANSWER SCHEME
MODUL 1 PAPER 2
No
1
(a)
(i)
(b)
(ii)
(i)
(ii)
(c)
(d)
(i)
Sample answer
The number of protons in the nucleus of an atom.
Mark
1
17
2.8.1 // 2, 8, 1
Reacts with water to produce hydrogen and metal hydroxide//
Reacts with oxygen to form metal oxide.//
Reacts with chlorine gas to produce metal chloride.
1
1
1
Q and R
because they have the same proton number but different nucleon
number// same number of proton but different number of neutrons
Correct no of shells
Correct e arrangement
XX
X
X
X
1
1
1
X
X
X
XX
(ii)
(a)
(b)
(c)
(d)
(e)
(i)
(ii)
(iii)
1
9m
Element D
Atom D has achieved octet electron arrangement / 8 valence
electrons // atom D does not receive, release or share electrons with
other atom
A
G
D, B, A, G, E
Use a small piece of A // use a filter paper to dry A //The gas jar
spoon is quickly placed into a gas jar
4 A
+ O2
2 A2O
4 moles of A : 2 moles of R2O
1
1
1
1
1
1
1 moles of A : 0.5 moles of R2O
Mass of R2O = 0.5 x [2(7) + 16 ]
= 15 g
[r: answer without unit]
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2
Total
(a)
(b)
Boron oxide
In pure copper, the atoms can slide easily.
Dalam kuprum tulen, atom-atom boleh mengelungsur dengan
mudah.
9m
1
1
(i)
1
H
Cl
CC
(ii)
(d)
(e)
(i)
(ii)
Do not rust//oxidised
Reinforced concrete
Konkrit yg diperkukuhkan
2NH3 + H2SO4
(NH4)2SO4
Correct formulae 1
balance 1
1
urea
% of N in CO(NH2)2 =
=
% of N in (NH4)2SO4 =
=
14x 2 / (14x2)+6+32+(16x4)
21.5%
Total
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11 m
(a)
(i)
(ii)
(b)
1
(c)
(i)
Zn + Cu2+
Zn2+ + Cu
(d)
(e)
1
1
(i)
become thicker
(ii)
become thinner
1
1
(i)
(ii)
Total
(a)
(i)
1
10 m
(ii)
White solid turns brown when hot and yellow
when cold
Pepejal putih bertukar perang semasa panas
dan kuning semasa sejuk
Black solid turns brown
Pepejal hitam bertukar perang
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1+1
4
Lime water remain unchanged
Air kapur tidak berubah
Lime water turns chalky
Air kapur menjadi keruh
(b)
(i)
(ii)
1
1
Filter the solution mixture using filter funnel and filter paper
Rinse the residue
1
1
1. Add 2 cm3 of KI/NaI solution into the test tube contain 2 cm3 of
Pb(NO3)2 solution and the test tube is shaken
(iv)
Total
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11 m
(a)
Hidrogenation // Addition
(b)
C4H8 + H2 C4H10
(c)
1
1
1
or
1. Put 2 3 drops of acidified potassium manganate(VII)
solution into two different test tubes
2. Fill 2 cm3 of but-1-ene and 2 cm3 of hydrocarbon Y into the
test tubes with stopper.
4. Shake the test tubes
3. But-1-ene decolourise purple acidified potassium
manganate(VII) solution but in hydrocarbon Y purple colour
remain unchanged
(d)
0.5 x 4
1
= 2 mol
Or
1 mol Y : 4 mol CO2
0.5 mol : 2 mol CO2
Mass of CO2
2 x 44 g // 88 g
[r: answer without unit]
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(e)
Isomer
Total
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11 m
1
1
1
1
H2SO4 + 2NaOH
Na2 SO4
2H2O
1
1
Calculation:
Mole of H2SO4
MV = 0.5 X 50
1000
1000
= 0.025 mole
Ratio
1 mole of H2SO4 : 2 mole of NaOH
0.025 : 0.05
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8
mol dm-3/ halved / decrease halved / less halved
hydrochloric acid is monoprotic/monobasic acid.
sulphuric acid is a diprotic acid / dibasic acid
Total
(a)
1.
average rate =
50
55
1
1
1
20 m
2.
= 0.909//0.91 cm3 s-1
[r: answer without unit]
(b)
Energy
Experiment II
Ea
2H2O2
Experiment III
Ea
2H2O + O2
1
1
1
1
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1
1
1
1
9
II
7. Catalyst that is Manganese(IV) oxide present in experiment
III
8. Manganese(IV) oxide lower the activation energy of the
reaction in experiment III
9. More colliding hydrogen peroxide molecules easily
overcome the lower activation energy in experiment III
10. Frequency of effective collision between Hydrogen
peroxide molecules of experiment III become higher
(d)
0.5 x 30
1000
// 0.015
1
1
1
1
1
3. number of mole of O2
= 0.015
2
// 0.0075
20 m
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10
(a)
(i)
1+1
(ii)
Ionic compound
1
1
1
Explanation
Ionic compound
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7
marks
1 mark
11
Covalent bond
7
marks
1 mark
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12
b i
1
1
Solution I
Substance Y dissolve in water
1
1
1
1
Max 5
20 m
Total
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13
Question No
10 (a)
Mark Scheme
elements
C : H :O
mass/g
64.9 : 13.5 : 21.6
no of mole
5.4 : 13.5 : 1.35
ratio
4 : 10 : 1
C4 H9OH
butanol
(b)
Marks
1
1
1
1
From glucose:
Process
Fermentation
Step
50 cm 3 glucose solution is added with yeast into a conical flask
Left for 3 days
The product is then purified by fractional distillation
1
1
Chemical equation
C6H12O6 2C2H5OH + 2CO2
From ethene:
Process
Hydration // addition reaction
Step
A mixture of ethene and water vapour/ steam are passed over
phosphoric acid as the catalyst
At temperature of 300 C and pressure of 60 atm
1
1
1+1
Chemical equation
C2H4 + H2O C2H5OH
1
(c)
1
1
1
1
1
1
Total 20 m
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ANSWER
[able to measure diameter of dents accurately and correctly]
Sample answer:
Q
1
ANSWER
[able to construct table with correct label and unit]
Sample answer:
Type of blocks
Copper
Brass
ANSWER
[able to state hypothesis correctly]
Sample answer
2
1
0
SCORE
Q
1
2
1
0
SCORE
Q
1
SCORE
2
1
0
ANSWER
[able to state all the variables]
Sample answer
SCORE
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Q
1
ANSWER
[able to state operational definition correctly]
Sample answer
2
1
0
SCORE
3
Q
1
ANSWER
[able to state inference correctly]
Sample answer
SCORE
3
2
2
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Sample answer
Brass is the harder
[able to state idea of inference]
Sample answer
2
1
1.65 cm
Antara 1.55 hingga 1.75 cm
Antara 1.45 hingga 1.55cm // 1.75 hingga 1.85 cm
Wrong responr // no respon
3
2
1
0
Pure metal
Tin
Gold
Manganese
Magnesium
2
1
0
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Question
Rubric
Able to give the statement of the problem correctly
Sample answer :
How does the temperature of sodium thiosulphate solution affect the rate
of reaction?
Able to give the statement of the problem incorrectly
3(a)
Sample answer :
How does the temperature of solution affect the rate of reaction?
Able to give an idea of statement of the problem
Sample answer :
To determine the rate of reaction by the temperature of solution
No response or wrong response
Question
3(b)
Question
3(c)
Rubric
Able to state all variables correctly
Sample answer :
Manipulated variable :The temperature of sodium thiosulphate solution
Responding variable : Rate of reaction//The time taken for the X mark to
disappear
Constant variable : Volume and concentration (sodium thiosulphate) /
(hydrochloric acid) // sodium thiosulphate // acid//
size of conical flask
Able to state any two variables correctly
Able to state any one variable correctly
No response or wrong response
Rubric
Able to state the relationship between the manipulated variable and the
responding variable correctly
Sample answer :
The higher the temperature of sodium thiosulphate solution , the higher the
rate of reaction
Able to state the relationship between the manipulated variable and the
responding variable incorrectly
Score
1
0
Score
2
1
0
Score
Sample answer :
The rate of reaction increases when the temperature of solution increase
Able to state an idea of hypothesis
Sample answer :
The temperature of reactant affect the rate of reaction
No response or wrong response
Question
Rubric
4
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1
0
Score
Able to give the list of the apparatus and materials correctly and
completely
Answer:
Apparatus:
conical flask, measuring cylinder, thermometer, stopwatch, white paper,
wire gauze, tripod stand, Bunsen bunner
Material:
[0.1 1.0] mol dm-3 sodium thiosulphate solution,
[ 0.1-1.0] mol dm-3 hydrochloric acid
Able to give the list of the apparatus and materials correctly but not
completely
3(d)
Answer:
2
Apparatus:
conical flask, thermometer, stopwatch, white paper, Bunsen bunner
Material:
Sodium thiosulphate solution, hydrochloric acid
Able to give two materials and at least one apparatus
Sample answer :
1
Material:
Sodium thiosulphate solution, hydrochloric acid
Apparatus:
[container]
No response or wrong response
Question
3(e)
Rubric
Able to state all procedures correctly
Sample answer :
1. Draw an X on a white paper.
2. Pour [20-100] cm3 of [0.1 1.0] mol dm-3 sodium thiosulphate
solution into a conical flask.
3. Record the temperature of solution.
4. Place the conical flask on the X.
5. Pour [5 10] cm3 of [0.1 1.0] mol dm-3 hydrochloric acid
solution.
6. Swirl the conical flask and start the stopwatch immediately.
7. Stop the stopwatch when the X is no longer visible. Record the
time taken.
8. Repeat steps 2 to 7 using 35oC, 40oC, 45oC and 50oC temperature
of sodium thiosulphate solution.
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Score
Rubric
Able to exhibit the tabulation of data that includes the following
information.
Score
1. Headings
2. With unit
Sample answer :
2
o
3(f)
Temperature/ C
Time/s
30
35
40
45
50
Able to tabulate the data incompletely
1. Titles without unit
Sample answer :
Temperature
Time
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