Narayana Phase-I JEE-Main GTM-7 Final Q'Paper

NARAYANA IIT ACADEMY
INDIA
Sec: Sr.IIT ALL STREAMS PHASE-I Date: 13-02-14
GRAND TEST -7 Max Marks: 432
JEE-MAIN_2010 MODEL

IMPORTANT INSTRUCTIONS:
1. The question paper consists of 90 questions. The maximum marks are 432
2. There are three parts in the question paper. The distribution of marks subject
wise in each part is as under for each correct response.
3. Part-A: Physics (144 marks) question no 1 to 2 and 9 to 30 consists of Four (4) Marks each and question
No. 3 and 8. consist of Eight (8) marks each for each correct response.
Part-B: Mathematics (144 marks) question no 31 to 39 and 46 to 60 consists of Four(4) Marks each and
question No. 40 to 45. consist of Eight (8) marks each for each correct response.
Part-C: Chemistry (144 marks) question no 61 to 82 and 89 to 90 consists of Four (4) Marks each and
question No. 83 to 88. consist of Eight (8) marks each for each correct response.
4. Candidates will be awarded marks as stated above in instruction No. 5 for correct response of each
question. 1/ 4 (one forth) marks will be deducted for indicating incorrect response of each question. No
deduction from the total score will be made if no responce is indicated for an item in the answer sheet.

13-02-14_SR.IIT-ALL STREAMS_JEE-MAIN_GTM-7_PAPER SETTERS& VERIFIERS
Subject
Paper Setters
(VIJ-CVRB3)
Paper Verifiers
(VSP-Vedavyas)
MATHS
Mr. KS-9440506070 Mr. PARDHASARADHI-9848582705
PHYSICS
Mr. NAGANJANEYULU-
9347009197
MR. GOVARDHAN PRASAD-9491126596
CHEMISTRY
Mr. LOKESH GUPTA-9293113099
Mr. RAMESH BABU-9505599336
Mr. GOPAL KRISHNA(Phy)-9912403030

Narayana IITAcademy 13-02-14_Sr.IIT-ALL STREAMS_Phase-I_JEE-Main_ GTM-7
Sr.IIT ALL STREAMS_JEE-MAIN Space for rough work Page 2
PHYSICS
1. The rate of decay of a radioactive element at t=0 instant
3
10 disintegrations per second.
If the half life of the elements is 1 s, then the rate of decay after 1 s will be
1) 500 disintegrations per s 2) 1000 disintegrations per s
3) 250 disintegrations per s 4) 2000 disintegrations per s

2. A force F=t is applied to a block A as shown in figure, where t is time in seconds. The
force is applied at t=0 seconds when the system was at rest. Which of the following
graph correctly gives the frictional force between A and horizontal surface as a
function of time t [Assume that at t=0, tension in the string connecting the two blocks
is zero]

1) 2) 3) 4)

3. A cylinder rests in a supporting carriage as shown. The side AB of carriage makes an
angle
0
30 with the horizontal and side BC is vertical. The carriage lies on a fixed
horizontal surface and is being pulled towards left with an horizontal acceleration a.
The magnitude of normal reactions exerted by sides AB and BC of carriage on the
cylinder be
AB
N and
BC
N respectively. Neglect friction everywhere. Then as the
magnitude of acceleration a of the carriage is increased, pick up the correct
statement;
B

1)
AB
N increases and
BC
N decreases
2) Both
AB
N and
BC
N increase
3)
AB
N remains constant and
BC
N increases
4)
AB
N increases and
BC
N remains constant
4. The P-V diagram of the Isothermal curve as shown in fig. one mole of an ideal gas is
taken from the same initial state A to different paths , , A B A C A D , the
quantities of heat supplied A B is
1
, Q A C is
2
, Q and A D is
3
Q then the correct
realation between
1 2
, Q Q and
3
Q is (B, C, D points are on the isothermal curve)
D
C
B
A
p
r
e
s
s
u
r
e

o
f

g
a
s

P
volume of gas V

1)
1 2 3
Q Q Q > > 2)
2 1 2 3
, Q Q Q Q > > 3)
3 2 1
Q Q Q > > 4)
1 3 2
Q Q Q > >
5. In the figure shown the potential energy U of a particle due to another particle
conservative interaction is plotted against its position x from origin. [Assume that
two particles taken as a system] Then which of the following statement is correct.

1)
1
x is in stable equilibrium 2)
2
x is in stable equilibrium
3)
3
x is in stable equilibrium 4)
2
x is in unstable equilibrium
6. A spherical surface of radius of curvature R separates air (refractive index 1.0) from
glass (refractive index 1.5) the center of curvature is in the glass. A point object P
placed in air is found to have a real image Q in the glass. The line PQ cuts the surface
at a point O and PO =OQ. The distance PO is equal to [Assume PQ line coincidence
with the principal axis]
1) 5R 2) 3R 3) 2R 4) 1.5R

7. Earth is rotating with a constant angular velocity ' ' about its polar axis. A man of
mass m present on the earth surface at a latitude angle ' ' , man is at rest w.r.t. earth.
The frictional force experienced by the man, the acceleration due to gravity at the
poles is g earth is taken as solid sphere and its radius is R and is the coefficient of
the friction and neglect the height of the man when compared to the radius of the
earth.
1)
i )
2
cos mg mR - 2)
i )
2 2
cos mR e |
3)
2
sin2
2
mR
4)
i ) i )
2 2
( cos ) mg mR e |
8. AB is an L shaped obstacle fixed on a horizontal smooth table. A ball strikes it at A,
gets deflected and restrikes it at B. If the velocity vector before collision is v and
coefficient of restitution of each collision is e, then the velocity of ball after its
second collision at B is (Neglect friction between contact surfaces and neglect the
gravitational effect.)

1)
2
e v
2)
2
e v -

3) ev -

4) Data insufficient
9. A small block of mass m is rigidly attached at P to a ring of mass 3m and radius
r. The system is released from rest at
0
90 = and rolls without sliding. The angular
acceleration of hoop just after release is __ about the centre of the ring.

u

1)
4
g
r
2)
8
g
r
3)
3
g
r
4)
2
g
r

10. A conical pendulum consists of a simple pendulum moving in a horizontal circle as
shown in the figure. C is the pivot, O the centre of the circle in which the pendulum
bob moves and the constant angular velocity of the bob. If L
is the angular
momentum about point C, then

1) L
is constant 2) only direction of L
is constant
3) only magnitude of L
is constant 4) both magnitude and direction of L
changes
11. The coefficient of friction between blocks of mass m and 2m is 2tan = . There is no
friction between block of mass 2m and fixed inclined plane. The maximum amplitude
of two block system for which there is no relative motion between the blocks.
[Assume At the time of releasing the system of two blocks released from rest suddenly
and the ideal spring is in its natural length]

1)
3 sin
2
mg
k
u
2)
sin mg
k
3)
3 sin mg
k
4)
2 sin mg
k
u

12. A bead of mass m is located on a parabolic wire with its axis vertical and vertex at
the origin as shown in figure and whose equation is
2
4 x ay = . The wire frame is fixed
and the bead can slide on it without friction. The bead is released from the point y=4a
on the wire frame from rest. The tangential acceleration of the bead when it reaches
the position given by y=a is : (Acceleration due to gravity is g)

1)
2
g
2)
3
2
g
3)
2
g
4)
5
g

13. The figure shows at time t=0 second, a rectangular pulse and triangular pulse on a
uniform wire are approaching each other. The pulse speed is 0.5 cm/s. The shape of
resultant pulse at t=2 second is

1)

2)

3)

4)

14.
1
S and
2
S are two coherent sources of sound separated by distance 100.25 , where is
the wave length of sound
1
S leads
2
S in phase by
2
. A and B are two points on the

line joining
1
S and
2
S as shown in figure. The ratio of amplitudes of source
1
S and
2
S
are in ratio 1:2. The ratio of intensity at A to that of
A
B
I
B
I
( `
(
(
'
is

1) 2)
1
9
3) 0 4) 9
15. One mole of an ideal gas is taken from state A to state B by three different processes,
(a) ACB (b) ADB (c)AEB as shown in the P-V diagram. The heat absorbed by the gas
is

1) greater in process (b) than in (a) 2) the least in process (b)
3) the same in (a) and (c) 4) less in (c) than in (b)
16. The graph which represents the variation of mean translational kinetic energy of
molecules with temperature
o
c t is
1)

2)

3)

4)

17. Figure shows a solid hemisphere with a charge of 5nC distributed uniformly
throughout its volume. The hemisphere lies on a plane and point P is located on the
plane, along a radial line from the centre of curvature at distance 15 cm. The electric
potential at point P due to the hemisphere, is: ( )
9
0
1
9 10 . .
4
S I units
tc
| |
=
|
\ .

1) 150 V 2) 300 V 3) 450 V 4) 600 V
18. An electron in a hydrogen atom makes a transition from first excited state to ground
state. The equivalent current due to circulating electron
1) becomes 2 times 2) becomes 4 times
3) becomes 8 times 4) remains the same
19. In the figure shown the current flowing through the resistor of resistance 2 R is :

1) from left to right 2) from right to left
3) no current 4) frist left to right and and then right to left

20. The plates of a capacitor are charged to a potential difference of 320 V and are then
connected across a resistor. The potential difference across the capacitor decays
exponentially with time. After 1s from starting the potential difference between the
plates of the capacitor is 240V. Then after 2s and 3 s from starting the potential
difference between the plates will be
1) 200 and 180V 2) 180 and 135 V
3) 160 and 80 V 4) 140 and 20 V

21. The voltage time (V-t) graph for triangular wave having peak value.
0
V is as shown in
figure.

The rms value of V in time interval from t=0 to
4
T
is :
1)
0
3
V
2)
0
2
V
3)
0
2
V
4)
0
2V
t

22. In an ac dynamo, the number of turns in the armature are made four times and the
angular velocity nine times. Then the peak value of induced emf will become.
1) 36 times 2) 12 times 3) 6 times 4) 18 times

23. A uniform magnetic field exists in region which forms an equilateral triangle of side a.
The magnetic field is perpendicular to the plane of the triangle. A charge q enters into
this magnetic field perpendicularly with speed v along perpendicular bisector of one
side and comes out along perpendicular bisector of other side. The magnetic field
strength in the triangle is
1)
mv
qa
2)
2mv
qa
3)
2
mv
qa
3)
4
mv
qa

24. The grid (each square of 1m x 1m), represents a region in space containing a uniform
electric field. If potentials at points O, A, B, C, D, E, F, G & H are respectively 0, -1,
-2, 1, 2, 0, -1, 1, and 0 volts, then find the unit vector along the direction of electric
field intensity.
1m
O A B
C
D
E F
G H
y
x
1m

1)
i )

( ) /
2
i j V m +
2)
i )

( ) /
2
i j V m
3)
DD
( ) /
2
i j V m +
4)
DD
( ) /
2
i j V m

25. A wooden stick of length 3 is rotated about an end with constant angular velocity
in a uniform magnetic field B perpendicular to the plane of motion. If the upper one
third of its length is coated with copper, the potential difference across the whole
length of the stick is

1)
2
9
2
B
2)
2
4
2
B
3)
2
5
2
B
4)
2
2
B

26. The following figure represents a plane wave front AB which passes from air to
another transparent medium and produces a new plane wave front CD after refraction.
The refractive index of the medium is (PQ is the boundary between air and the
medium).

1)
1
4
cos
cos
2)
4
1
cos
cos
3)
1
4
sin
sin
4)
2
3
sin
sin

27. In the circuit shown in figure the base current
B
I is 10 A and the collector is 5.2 mA.
The value of
BE
V is

1)0.1V 2) 0.3V 3) 0.5 V 4) 0.7V

28. Two hydrogen atoms are in excited state with electrons residing in n=2. First one is
moving towards left and emits a photon of energy
1
E towards right. Second one is
moving towards right with same speed and emits a photon of energy
2
E towards right.
Taking recoil of nucleus into account during emission process (Assume that direction
of motional atom unaltered)
1)
1 2
E E > 2)
1 2
E E < 3)
1 2
E E = 4) information insufficient

29. A Youngs double slit experiment is conducted in water
i ) 1
as shown in the figure,
and a glass plate of thickness t and refractive index
2
is placed in the path of
2
S . The
magnitude of the phase difference at O is : (Assume that is the wavelength of light
in air)

1)
2
1
2
1 t

( `
(
-
(
'
2)
1
2
2
1 t

( `
(
-
(
'

3)
i ) 2 1
2
t

- 4)
i ) 2
2
1 t

-
30. An insulating rod of length carries a charge q uniformly distributed on it. The rod is
pivot at its mid point and is rotated at a frequency f about a fixed axis perpendicular to
rod and passing through the pivot. The magnitude of magnetic moment of the rod
system is
1) Zero 2)
2
24
qf t
3)
2
1
12
qf 4)
2
1
3
qf

MATHEMATICS
31. If e
X
+e
f(x)
=e, then domain of the function of f is
1) [- ] 2) (- ) 3) (1, ) 4) [1, )
32. The value of
2
2 2 2
cos
1 1 1
cos cos cos
2
1 2 .........
x
x x x
x
lt n
t
(
+ + +
(

is
1) 0 2) n 3) 4)
33. The function f(x) =
3 2
16 20
2
x x x
x
+ +
when x = 2. In order to make f(x) is

continuous at x=2, f(2) should be defined as
1) 0 2) 1 3) 2 4) 3
34. A function f(x) is such that ( ) ( )
n
f x =f(nx) x and if f
1
(x) denotes derivative of
f(x) w.r.t x, then f
1
(x). f(nx)=
1)f(x) 2) 0 3) f(x). f
1
(nx) 4) nx
35. The two curves 3
x
y = and 5
x
y = intersect at an angle
1)
1
log3 log5
tan
1 log3.log5
| |
|
+
\ .
2)
1
log3 log5
tan
1 log3.log5
| | +
|
\ .

3)
1
log3 log5
tan
1 log3.log5
| | +
|
+
\ .
4)
4
t

36.
log( 1) log
( 1)
x x
dx
x x
+
+
}
is equal to
1)
2
1 1
log
2
x
c
x
( + | |
+
| (
\ .
2) ( ) { } ( )
2 2
log 1 log c x x
(
+
(

3)
1
log log
x
c
x
( + | |
+
| (
\ .
4)
2
1
( 1)
C
x x
| |
+
|
+
\ .

37.
| | ( )
2
6
0
sec , x d x x
t
}
where [.] is greatest integer part function, is equal to
1) 3 2)
1
3
3) 1 4) 0

38. If
( )
18 18
2
1 1
( 8) 9 8 45
i i
i i
x and x
= =
= =

then the standard deviation of
1 2 18
, ,...., x x x is
1) 4/9 2) 9/4 3) 3/2 4) 9
39. If the relation R : A B where A = { } 1,2,3,4 and { } 1,3,5 B = is defined by
{ }
1
( , ): , , R x y x y x A y B then ROR is
= < e e
1) { } (1,3)(1,5)(2,3)(2,5)(3,5)(4,5) 2) { } (3,1)(5,1)(5,2)(5,3)(5,4)
3) { } (3,3)(3,5)(5,3)(5,5) 4) { } (1,1)(2,2)(3,3)(4,4)
40. If the lines ax +y +1=0, and x+by+1=0 and x+y+c=0 (a, b and c being distinct and
different from 1) are concurrent, then
1 1 1
1 1 1 a b c
+ + =

1) 1 2) -1 3) 0 4) 2
41. In a certain city, all telephone numbers have six digits, the first two digits always
being 41 or 42 or 46 or 62 or 64. The number of telephone numbers having all six
digits distinct is
1) 8400 2) 7200 3) 9200 4) 360
42. If two of the lines ax
3
+bx
2
y+cxy
2
+dy
3
=0 (a ) make complementary angles with x-
axis in anticlockwise sense then
1) a(a-c)-d(b-d)=0 2) d(a-c)+a(b-d)=0
3) a(a-c)+d(b-d)=0 4) a+b+c+d=0
43. The base AB of a triangle is fixed and its vertex C moves such that sinA =k sinB
(k ). If a is the length of the base AB, then the locus of C is a circle whose radius
is equal to
1) 2) 3)
2
2
1
ak
k
4)
2
2
1
1
k
a
k
| | +
|
\ .

44. If b and c are the lengths of the segments of any focal chord of a parabola y
2
=4ax
then the length of the semi latusrectum is
1)
bc
b c +
2) bc 3)
2
b c +
4)
2bc
b c +

45. If any tangent to the ellipse
2 2
2 2
1
x y
a b
+ = intercepts lengths h and k on the x and y axes,
respectively then
1)
2 2
2 2
1
a b
h k
= 2)
2 2
2 2
1
a b
h k
+ = 3)
2 2
2 2
1
a b
k h
= 4)
2 2
2 2
1
a b
k h
+ =
46. An ellipse slides between two lines at right angles to one another. The locus of its
centre is
1) a parabola 2) an ellipse 3) a circle 4)straight line
47. If
3 2
0, iz z z i + + = then z =
1)1 2) 2 3) 3 4) 0
48. If , o | be the roots of the equation
2
0 x px q + = and 0, 0 o | > > then the value of

1 1
4 4
o | + is

1
4
6 4 2
k
p q q p q
| |
+ + +
|
\ .
, then k is equal to
1) 1 2) 1/2 3) 1/3 4) 1/4
49. The polynomial
6 5 4 3
4 3 2 1 x x x x x + + + + + is divisible by
1) x e + 2)
2
x e + 3) ( )
2
( ) x x e e + + 4) ( )
2
( ) x x e e
Where e is one of the imaginary cube roots of unity
50. The value of k for which the line
4 2
1 1 2
x y z k
= = lies in the plane 2 4 7 x y z is + =
1) 7 2) 6 3) -7 4) no such k
51. The coefficient of x
n
in the expansion of
( )( )( )
1
1 1 2 1 3 x x x
is
1)
2 3
1
(2 3 1)
2
n n + +
+ 2)
( )
2 3
1
3 2 1
2
n n + +
+
3)
3 2
1
(2 3 1)
2
n n + +
+ 4) 0

52. If x,y,z are in A.P with common differences d and the rank of the matrix
4 5
5 6
6
x
y
k z
(
(
(
(

is 2 then the values of d , k are
1)
4
x
,arbitrary number 2) arbitrary number,7
3) x ,5 4) ,6
2
x

53. If x =-9 is a root of the following equation, then the other roots are
3 7
2 2 0
7 6
x
x
x
=
1) 2,7 2) -2,7 3) 2,-7 4) -2, -7
54. If
2 2 2 2 2 2 2 2
cos sin sin +b cos , u a b a = + + where R u e then the difference between
the maximum and minimum values of
2
u is given by
1) ( )
2
a b + 2)
2 2
2 a b + 3)
( )
2 2
2 a b + 4) ( )
2
a b
55. The least positive non-integral solution of the equation
( )
2 2
sin sin x x x t t + = is
1) rational
2) irrational of the form p
3) irrational of the form
1
4
p
, where p is an odd integer
4) irrational of the form
1
4
p +
, where p is an even integer
56. If
1
tan , ,
3
x
x N
t
t
< e then the maximum value of x is

1) 2 2) 5 3) 7 4) 11
57. In any A ABC,
2
cot cot cot
2 2 2
A B C
r =
1) A 2) 2A 3) 3A 4)
58. An unbiased die is tossed until a number greater than 4 appears. The probability that
an even number of tosses is needed is
1) 1/2 2) 2/5 3) 1/5 4) 2/3
59. If , a b

are two unit vectors and u is the angle between them, then
cos
2
is
1)
1
2
a b +

2)
1
2
a b

3)
1
.
2
a b

4)
1
2
a b

60. If , , a b c

are non-coplanar unit vectors such that
( )
2
b c
a b c
+
=

then the angle between
a
and b
is
1)
3
4
t
2)
4
t
3)
2
t
4)
6
t

CHEMISTRY
61. In simple cubic unit cell of a metal lattice, radius of cubic void is
1) 0.732 r
metal
2) 0.6 r
metal
3) 0.68 r
metal
4) 0.155 r
metal

62. Wavelength of high energy transition of H atom is 91.2 nm. Calculate the
corresponding wavelength of He
+
ion.
1) 32.8 nm 2) 22.8 nm 3) 26.3 nm 4) 39.7 nm
63. Which of the following d orbitals is not involved in
3
d s hybridization ?
1)
xy
d 2)
yz
d 3)
2 2
x y
d
4)
xz
d
64. One mole of N
2
O
4
was found to decompose 80% at a particular temperature and a
total pressure of 1.5 atm. The
p
K for the reaction
2 4 2
N O (g) 2NO (g)
is
1)
64
1.5
81
( `
(
(
'
atm 2)
64
1.5
9
( `
(
(
'
atm 3)
8
1.5
9
( `
(
(
'
atm 4)
1
1.5
9
( `
(
(
'
atm
65. The percentage of dissociation of a weak acid HA is 0.3% when concentration of the
acid is 1 M. Hence % dissociation of 100 times diluted solution is
1) 0.3% 2) 3% 3) 30% 4) 100%
66. Which of the following metals can be purified by distillation?
1) Cu 2) Zn 3) Ag 4) Au

67. The cell potential of the given cell
Pt , H
2
(1 atm) ( ) ( )
2
4 3 HCl pH HCl pH H = = ( ) 1 , atm Pt is
(1) 0.0 V (2) 0.03V (3) 0.059V (4) 0.118V
68. The conductivity of pure water at 298K is K Scm
-1
. Limiting molar conductivity of
H
+
and OH
-
ions are x and y Scm
2
mol
-1
respectively. Degree of dissociation of
water and ionic product of water at 298K are respectively
1)
( )
( )
6 2
2
18 10
,
K K
x y
x y
+
+
2)
( )
2
2
,
K K
x y
x y
+
+

3) ( ) ( )
2
2
, K x y K x y + + 4) ( ) ( )
2
6 2
18 ,10 k x y k x y + +

69. In blue vitriol, number of coordinated water molecules is/are
1) 5 2) 4 3) 2 4) 1
70. In which of the following octahedral complexes,
0
^ magnitude is highest
1) ( )
3
2
6
Co H O

l
l
l
2) ( )
3
3
6
Co NH

l
l
l
3) ( )
3
6
Co CN

l
l
l
4) ( )
3
2 4
3
Co C O

l
l
l

71. Colloid with which one of the following zeta potential is more stable
1) 25mV = 2) 35mV = 3) 45mV = 4) 60mV =
72. In CaMgSi
2
O
6
, how many oxygens per each tetrahedron are shared by others
1) 4 2) 3 3) 2 4) 1
73. Treatment of cyclobutylmethanamine with nitrous acid doesnt give

2
CH OH
I
2
CH
II

III

IV
OH

V

1) I, II, IV 2) II, V, I 3) I, II, IV, V 4) III only
74. Among the conjugate bases of oxoacids of chlorine, the correct bond angle order is
1)
3 4 2
ClO ClO ClO
- - -
< < 2)
2 3 4
ClO ClO ClO
- - -
< <
3)
2 4 3
ClO ClO ClO
- - -
< < 4)
4 3 2
ClO ClO ClO
- - -
< <
75. For dissolution of gases in liquids, correct statement(s) among the following is / are as
per Henrys law.
a) At a certain temperature, the ratio of the molar concentrations of the gas in solution
and in the gas phase is constant.
b) The volume of a gas dissolved in a solvent at a given temperature is independent of
the pressure.
c) The mole fraction of the gas dissolved in the solution is proportional to the pressure
of a gas over a solution in which the gas is dissolved.
1) a, b and c 2) only c 3) only a, c 4) only a, b
76. Chlorine oxidizes iodine to
1) hypoiodite 2) iodite 3) iodate 4) periodate
77. The product formed in maximum proportion in the following reaction is

3
3 3
( )
anhydrous
AlCl
CH CCOCl + ----------

1)
i ) 6 5 3
3
C H COC CH 2)
i ) 6 5 3
3
C H C CH
3)
i ) 6 5 2 3
3
C H CH C CH 4)
i ) 3
3
OC CH
CHO

78. Emerald is
1) Alumina with Cr
3+
impurity 2) Silica with Cr
3+
impurity
3) Alumina with Cu
2+
impurity 4) Beryl mineral with Cr
3+
impurity

79. Formation of yellow stains on fingers while working with conc. HNO
3
in laboratory is
due to reaction of conc. HNO
3
with
1) Carbohydrates 2) Nucleic acids
3) Proteins 4) Vitamins
80. Which one of the following complexes is optically inactive
1)
i )i )i )i )
2
3 2 5 6 4
As CH C H S C H COO
-
(

tetrahedral
2)
i )i )i ) 3 2
Pt py NH NO Cl Br I

3)
i )i )
3
3
4
C en NH o
+

(

4)
i )i ) 3 2
4
Co en NH Cl
+

(

81. For any gas ( )
0
m
p
PV
value at 273.15K is (in dm

3
bar)
1) zero 2) infinity 3) 22.711 4) 22.414
82. Each pair has been matched with the suitable reagent used for making distinction.
Which pair has been matched wrongly?
Pair Reagent
1) R C CH and
2
R CH CH =
3 4
/ AgNO NH OH
2) R CHO and RCOOH 2,4 DNP
3) RCOOH and
2
RCONH
3
NaHCO
4)
2
R NH and
2
Ph NH
3
/ CHCl NaOH
83. The entropy change at 373K for the transformation
( ) ( )
2 2
,1.013225 ,0.101325 ,
vap
H O bar H O g bar H A of H
2
O is 40.6 KJ /mol
1) 109 J /K/mol 2) 19.15 J /K/mol
3) 128.17 J /K/mol 4) 150 J /K/mol
84. Tertiary butyl alcohol
0
,300 Cu C
A .
A is subjected to ozonolysis. The products of ozonolysis are reduced with
4
LiAlH .
The final products is/are
1) 2-methylpropane-2-ol 2) mixture of methanol and ethanol
3) propan-2-ol and methanol 4) mixture of ethanol +formic acid
85. 12 g of AB (mol. mass =60) is dissolved in 0.5 kg of water. The solution freezes at
0.74C below the freezing point of water. What is the degree of dissociation of the
electrolyte is nearly?
1
[ 1.86 ]
f
K Km
-
=
1) 0 2) 0.25 3) 0.75 4) 1.0

86. Under the same reaction conditions initial concentration of 1.386 mol
3
dm
-
of a
substance becomes half in 40 seconds and 20 seconds through first order and zero
order kinetics respectively. Ratio
1 0
( / ) k k of the rate constant for first order
1
( ) k and
zero order
0
( ) k of the reaction is
1) 0.5 2)
3
1.0mol dm
-
3)
3
1.5mol dm
-
4)
1 3
0.5mol dm
+

87. If phenol is heated with
4
CCl and KOH a product is formed which on treatment with
dil. HCl gives the compound X, X is
1) Salicylaldehyde 2) Salicylic acid
3) Salol 4) Aspirin

88. Heat of combustion of ethane, ethene and ethyne are -1561kJ /mol, -1410kJ /mol and
-1326kJ /mol. Flame temperature of which fuel is highest when remaining conditions
are identical (
p
C value of
( ) 2 g
H O and
( ) 2 g
CO are 33.5 J /k/ mol, 36.3 J /k/mol)
1) Ethane 2) Ethene 3) Ethyne 4) Equal for all

89. An aromatic compound having molecular formula
8 10
( ) C H A on treatment with hot
4
KMnO gives (B) which can easily be converted to an anhydride by heating it . The
compound (A) is
1) Toluene 2) Ethyl benzene 3) Para - xylene 4) Ortho xylene

90. Among the following solutions with given p
H
values, in which solution solubility of
CH
3
COO Ag is maximum.
1) 4 2) 6 3) 7 4) 9

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NARAYANA IIT ACADEMY

is constant 2) only direction of L

is constant 4) both magnitude and direction of L

. A and B are two points on the

when x = 2. In order to make f(x) is

< e then the maximum value of x is

value at 273.15K is (in dm

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