Handbook: Lighting

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4-24 I E S LIGHTING HANDBOOK

Spectrophotometry
Spectrophotometry is the measurement of spectral reflectance and trans-
mittance.
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Colorimetric data may be obtained from spectrophotometric
measurements which have been converted to I.C.I, notation. (See page
4-16.)
The modes of illumination and collection differ in various spectrophotome-
ters. Since the results depend on the slit width, the illumination and col-
lection geometry, and the calibration, these should be reported clearly with
each spectrophotometric curve.
Gloss has a marked effect on the object color perceived but gloss itself
is best measured with instruments such as a goniophotometer. (See Sec-
tion 5.)
The color corresponding to any particular mode of illumination
and observation can, in principle, be determined from separate and inde-
pendent determinations of the color and gloss of any sample.
In a spectrophotometer a spectroscope disperses the light into its com-
ponents and a photometer measures the amount of light of each wavelength
transmitted or reflected by a sample, by comparing the unknown quantity
with a standard. In early models, the judgment of match was made by
eye. This was time-consuming, even if measurements were made only at
0.02- or 0.04-micron wavelength intervals. Also, if a tungsten filament
lamp is used as the light source in a visual instrument, it provides so little
light in the blue end of the spectrum that it is very difficult to make either
precise or accurate judgments.
However, photoelectric spectrophotometers are not as greatly handi-
capped in this way and several are now available in Avhich the illumination
is satisfactorily provided by a tungsten lamp chosen because it is con-
venient and emits a continuous spectrum. The latter is a usual require-
ment in spectrophotometry for if the illumination falling on a sample
surface has no energy in some part of its spectrum, then no energy can be
reflected or transmitted for measurement in that part of the spectrum, no
matter how much a sample may be able to reflect or transmit in that
region.
Present commercial models of the best-known automatic recording in-
strument, shown in Fig. 4-14A, illuminate the sample about 6 degrees from
the normal, and view it diffusely by gathering light from the white interior
surface of a hollow sphere. The results correspond to the appearance of
the sample when held perpendicular to the line of sight in completely
diffused indirect lighting.
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'
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A manual type of instrument is shown in
Fig. 4-14B.
35
'
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The optics of any spectrophotometer must be designed to utilize as much
as possible of the available energy so that narrow slit widths may be used
in making measurements. A good spectrophotometer source must emit
enough energy in all portions of the spectrum so that measurements may
be made with slit widths that admit light from bands 0.01 micron or less
in width.

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