Review

Recent developments in advanced aircraft aluminium alloys

Tolga Dursun
a,
, Costas Soutis
b
a
Aselsan Inc, Ankara 06750, Turkey
b
Aerospace Research Institute, University of Manchester, Manchester M13 9PL, UK
a r t i c l e i n f o
Article history:
Received 16 September 2013
Accepted 2 December 2013
Available online 13 December 2013
Keywords:
Aircraft structures
Aluminium alloys
AlLi alloys
Composites
Mechanical properties
a b s t r a c t
Aluminium alloys have been the primary material for the structural parts of aircraft for more than
80 years because of their well known performance, well established design methods, manufacturing
and reliable inspection techniques. Nearly for a decade composites have started to be used more widely
in large commercial jet airliners for the fuselage, wing as well as other structural components in place of
aluminium alloys due their high specic properties, reduced weight, fatigue performance and corrosion
resistance. Although the increased use of composite materials reduced the role of aluminium up to some
extent, high strength aluminium alloys remain important in airframe construction. Aluminium is a rela-
tively low cost, light weight metal that can be heat treated and loaded to relatively high level of stresses,
and it is one of the most easily produced of the high performance materials, which results in lower man-
ufacturing and maintenance costs. There have been important recent advances in aluminium aircraft
alloys that can effectively compete with modern composite materials. This study covers latest develop-
ments in enhanced mechanical properties of aluminium alloys, and high performance joining techniques.
The mechanical properties on newly developed 2000, 7000 series aluminium alloys and new generation
AlLi alloys are compared with the traditional aluminium alloys. The advantages and disadvantages of
the joining methods, laser beam welding and friction stir welding, are also discussed.
2013 Elsevier Ltd. All rights reserved.
1. Introduction
The cost reduction for aircraft purchase and operation has be-
come a driving force in many airline companies. Cost reduction
can be achieved by decreasing the fuel consumption, maintenance
cost, operational costs, frequency of periodical controls and
increasing the service life and carrying more passengers at a time.
Therefore aircraft manufacturers are competing to meet the
requirements of their airline customers. Weight reduction can im-
prove fuel consumption, increase payload and increase range.
Additionally, improved and optimised mechanical properties of
the materials can result in increased period between maintenance
and reduce repair costs. Since the material has a great impact on
cost reduction, airframe manufacturers and material producers fo-
cus on the development of new materials to meet customer
requirements. Hence, a current challenge is to develop materials
that can be used in fuselage and wing construction with improve-
ments in both structural performance and life cycle cost. According
to the design trials it is seen that an effective way of reducing the
aircraft weight is by reducing the material density. It is found that
the decrease in density is about 35 times more effective than
increasing tensile strength, elastic modulus or damage tolerance
[1]. Airframe durability is another parameter that directly affects
costs. The cost of service and maintenance over the 30-year life
of the aircraft are estimated to exceed the original purchase price
by a factor of two [1]. Therefore, both material producers and air-
craft designers are working in harmony to reduce weight, improve
damage tolerance, fatigue and corrosion resistance of the new
metallic alloys. As a result, near future primary aircraft structures
will show an extended service life and require reduced frequency
of inspections.
Composite materials are increasingly being used in aircraft pri-
mary structures (B787, Airbus A380, F35, and Typhoon). Fig. 1
shows the increased usage of composites in several types of Boeing
aircraft. The attractiveness of composites in the manufacturing of
high performance structures relies on their superior mechanical
properties when compared to metals, such as higher specic stiff-
ness, specic strength (normalised by density), fatigue and corro-
sion resistance. Although composites are thought to be the
preferable material for wing and fuselage structures, their higher
certication and production costs, relatively low resistance to im-
pact and complicated mechanical behaviour due to change in envi-
ronmental conditions (moisture absorption, getting soft/brittle
when exposed to hot/cold environments) make designers to ex-
plore alternative material systems. Fibre metal laminates such as
GLARE which combines aluminium layers with glass bre epoxy
0261-3069/$ - see front matter 2013 Elsevier Ltd. All rights reserved.
http://dx.doi.org/10.1016/j.matdes.2013.12.002

Correspondng author. Tel.: +90 312 847 53 00.

E-mail addresses: [email protected] (T. Dursun), constantinos.soutis@
manchester.ac.uk (C. Soutis).
Materials and Design 56 (2014) 862871
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j our nal homepage: www. el sevi er . com/ l ocat e/ mat des
plies to improve tensile strength and more importantly damage
tolerance are nding great use in aerospace applications [312].
Impact resistance, effect of damage on stiffness/strength especially
when loaded in compression and damage identication and detec-
tion, in addition to joints, repair and recycling remain big chal-
lenges for composites with the need of further research [1318].
Aluminium alloys have been the primary structural material for
commercial and military aircraft for almost 80 years due to their
well known mechanical behaviour, easiness with design, mature
manufacturing processes and inspection techniques, and will re-
main so for some time to come. However, the non-metallic mate-
rials, despite the issues mentioned earlier, due to their superior
specic strength properties provide a very competitive alternative,
so aluminium producers need to keep investing and put great
effort in improving the thermo-mechanical properties of the alu-
minium alloys they produce.
Density, strength, Youngs modulus, fatigue resistance, fracture
toughness and corrosion resistance are all important parameters
that need to be improved. Depending on the particular component
under consideration, material properties have to outperform those
offered by polymer composites. Chemical composition and
processing control the microstructural features such as precipi-
tates, dispersoids, degree of recrystallization, grain size and shape,
crystallographic texture and intermetallic constituent particles.
These properties affect the physical, mechanical and corrosion
characteristics of aluminium alloys. Therefore material producers
working closely with aircraft designers could design different types
of metallic alloys where the physical and mechanical properties
have been tailored to the specied needs. For instance, the upper
side of the wing is mainly subjected to compression loading during
ight, but also exposed to tension during static weight and taxiing,
while the opposite happens to the lower part of the wing, hence
careful optimisation of tensile and compressive strength properties
is required. Damage tolerance, fatigue and corrosion resistance are
also needed making the selection and optimisation more
challenging.
During the design of Boeing 777, aluminium manufacturers
were asked for improvements in upper-wing structure and fuse-
lage. Higher compressive yield strength was needed for the upper
wing structure. Improved corrosion resistance was also desirable.
For the case of fuselage, higher damage tolerance and durability
than the incumbent 2024-T3 was needed. Aluminium manufactur-
ers accounting for the designers needs developed the 7055-T7751
plate and 7055-T77511 extrusions for the upper wing structure,
and Alclad 2524-T3 sheet and 2524-T351 plate for the fuselage
skin. They also developed 7150-T7751 extrusions for the support-
ing members of the fuselage structure. The application of these
materials saved thousands of pounds of weight for the Boeing
777 [19].
The aircraft manufacturers are also working to decrease the
number of parts in new aircraft. These needs could be met by
applying several approaches. The rst method is producing large
and thick plates having fatigue and fracture characteristics equiv-
alent to those of a thin plate. The second method is implementa-
tion of joining technologies such as friction stir welding that
allows the manufacture of large integrally stiffened panels that
can be used for wing and fuselage skins [20].
This review article covers the latest developments related to
aluminium alloys used as aircraft primary structures and high-
lights performance improvements in the 2000, 7000 series alumin-
ium alloys as well as the new generation of AlLi alloys. Currently
the 7000 series AlZn alloys are used where the main limiting de-
sign parameter is strength; 2000 series AlCu alloys are used for
fatigue critical applications since these alloys are more damage tol-
erant, while AlLi alloys are chosen where high stiffness and lower
density are required. The advantages and disadvantages of the
joining techniques, laser beam welding and friction stir welding,
are also discussed.
2. Developments in 2000 series AlCu aluminium alloys
The aluminiumcopper (2000 series) alloys are the primary al-
loys used in airframe structural applications where the main de-
sign criterion is damage tolerance. The 2000 series alloys
containing magnesium have higher strength resulting from the
precipitation of Al
2
Cu and Al
2
CuMg phases and superior damage
tolerance and good resistance to fatigue crack growth compared
to other series of aluminium alloys. 2024 and 2014 are well known
examples for AlCuMg alloys. It is well known that due to differ-
ent loading conditions each component of the airframe requires
different material properties for optimum and reliable design.
The fuselage is subject to cabin pressure (tension) and shear loads,
longitudinal stringers are exposed to the longitudinal tension and
compression loads due to bending, circumferential frames have
to sustain the fuselage shape and redistribute loads into the skin.
Strength, stiffness, fatigue crack initiation resistance, fatigue crack
growth rate, fracture toughness and corrosion resistance all are
important, but fracture toughness (resistance to crack growth) is
Fig. 1. Combination of materials used in Boeing Aircrafts. The gure is based on [2].
T. Dursun, C. Soutis / Materials and Design 56 (2014) 862871 863
often the limiting design parameter [21]. The wing can be
considered as a cantilever type of beam that is loaded in bending
during ight but also torsion. The wing supports both the static
weight of the aircraft and any additional loads subjected in service.
Additional wing loads also come from the landing gear during
taxiing, take-off and landing and from the leading and trailing
edge the aps and slats that are deployed during take-off and
landing to create additional low speed lift. The upper surface
of the wing is primarily loaded in compression because of the
upward bending moment during ight but can be loaded in
tension while taxiing [21]. Chemical compositions and mechan-
ical properties of some of 2000 series aluminium alloys widely
used in airframe design are given in Tables 1 and 2
respectively.
The 2024-T3 has been one of the most widely used alloys in
fuselage construction. It has moderate yield strength, very good
resistance to fatigue crack growth and good fracture toughness.
The 2024 aluminium alloy remains as an important aircraft struc-
tural material due to its extremely good damage tolerance and
high resistance to fatigue crack propagation in T3 aged condition.
The low yield stress level and relatively low fracture toughness,
limit the application of this alloy in the highly stressed regions
[23]. Microstructural effects on the fatigue properties of alumin-
ium alloys are being investigated intensively. Improvements in
compositional control and processing have continually produced
new alloys. It is known that inclusions have substantial effects
on the fatigue crack propagation. Higher fracture toughness values
and better resistance to fatigue crack initiation and crack growth
were achieved by reducing impurities, especially iron and silicon.
It has been announced that for the fuselage applications the alloy
2524-T3 has a 1520% improvement in fracture toughness and
twice fatigue crack growth resistance of 2024-T3 [24]. This
improvement leads to weight savings and 3040% longer service
life [25]. The 2524 aluminium alloy has replaced the 2024 as fuse-
lage skin in the Boeing 777 aircraft. Fatigue tests on the 2524 alloy
showed that fatigue strength of this alloy is 70% of the yield
strength whereas for 2024-T351 fatigue strength is about 45% of
the yield strength [26]. For the lower wing skin applications [27]
the 2224-T351 and 2324-T39 alloys offer higher strength values
compared to incumbent 2024-T351 with similar fracture tough-
ness and corrosion resistance. Compared to 2024, both composi-
tional and processing changes for 2224-T351 and 2324-T39
alloys resulted in improved properties. A lower volume fraction
of intermetallic compounds improved fracture toughness. For in-
stance the maximum iron content is 0.12% and silicon is 0.10% in
2224-T351 whereas in 2024 0.50% for both impurities. A newly
developed aluminium alloy 2026 is based on 2024 but it contains
fewer impurities such as iron and silicon. Additionally, 2026 con-
tains a small amount of zirconium which inhibits recrystallization
[28]. 2026 has higher damage tolerance, higher tensile strength,
higher fatigue performance and acceptable fracture toughness
compared to 2024 and 2224 [29].
Although the contribution of Cu and Mg in intermetallic phases
results in high strength however, due to the intermetallic phase
particles the corrosion resistance of the alloy signicantly drops.
Several investigations have been done in order to increase both
corrosion and fatigue resistance of 2000 series alloys [3032].
3. Developments in 7000 series AlZn aluminium alloys
The 7000 series of aluminiumalloys show higher strength when
compared to other classes of aluminium alloys and are selected in
the fabrication of upper wing skins, stringers and horizontal/verti-
cal stabilizers. The compressive strength and the fatigue resistance
are the critical parameters in the design of upper wing structural
components. The tail of the airplane, also called the empennage,
consists of a horizontal stabilizer, a vertical stabilizer or n, and
control surfaces e.g. elevators and rudder. Structural design of both
the horizontal and vertical stabilizers is essentially the same as for
the wing. Both the upper and lower surfaces of the horizontal sta-
bilizer are often critical in compression loading due to bending
[21].
High strength aluminium alloys such as the 7075-T6 are widely
used in aircraft structures due to their high strength-to-weight ra-
tio, machinability and relatively low cost. However, due to their
compositions, these alloys are susceptible to corrosion. It is well
known that corrosion reduces the life of aircraft structures consid-
erably. During normal operation aircraft are subjected to natural
corrosive environments due to humidity, rain, temperature, oil,
hydraulic uids and salt water. Among the issues facing ageing air-
craft, corrosion in combination with fatigue is extremely undesir-
able [27] .
The 7000 series alloys are also heat treatable, and the AlZn
MgCu versions provide the highest strengths of all aluminium al-
loys. Some of the 7000 series alloys contain about 2% copper in
combination with magnesium and zinc to improve their strength.
These alloys although are the strongest they are the least corrosion
resistant of the 7000 series. However, newer 7000 series alloys
introduced have higher fatigue and corrosion resistance which
may result in weight savings. Newer alloys such as the 7055-T77,
have higher strength and damage tolerance than the 7075-T6 [1].
The 7475 (AlZnMgCu) aluminium alloy is a modied version
of 7075 alloy. The 7475 alloy is developed for applications that re-
quire a combination of higher strength, fracture toughness and
resistance to fatigue crack propagation both in air and corrosive
environment. Both strength and fracture toughness properties of
7075 alloy are improved by decreasing its contents of iron and sil-
icon, and changing both quenching and ageing conditions. The to-
tal iron and silicon content in 7075 is 0.90% whereas in 7475 the
total content is limited to 0.22%. These changes in the 7075 alloy
resulted in the development of the 7475 alloy which is having a
ne grain size, optimum dispersion and highest toughness value
among the aluminium alloys available at high strength level. It is
also reported that the corrosion resistance and corrosion fatigue
behaviour of the 7475 alloy are excellent. In general, its perfor-
mance is better than that of much commercially available high
strength aerospace aluminium alloys such as 7050 and 7075 alloys
[23]. Yield strength, % elongation, and K
IC
properties of widely used
2024 and 7075 alloys are compared with 7050 and 7475 in Fig. 2.
It may be seen in Fig. 2 that the 2024-T351 alloy has high duc-
tility and good fracture toughness (both in TL and LT orientations)
but has relatively low yield strength. On the other hand, the 7075
alloy under T651 temper condition has yield strength of over
500 MPa. The reported fracture toughness of this alloy (7075-
T651) in TL and LT orientations is nearly 24 MPa
p
m and
Table 1
Chemical composition of some 2000 series aerospace aluminium alloys [22].
2000 Series Cu Zn Mg Mn Fe Si Cr Zr Ti Al
2024 4.4 1.5 0.6 60.5 60.5 0.1 0.15 Remainder
2026 3.64.3 0.1 1.01.6 0.30.8 0.07 0.05 0.050.25 0.06 Remainder
2224 4.1 1.5 0.6 60.15 60.12 Remainder
2324 3.84.4 0.25 1.21.8 0.30.9 0.12 0.1 0.1 0.15 Remainder
2524 4.04.5 0.15 1.21.6 0.450.7 0.12 0.06 0.05 0.1 Remainder
864 T. Dursun, C. Soutis / Materials and Design 56 (2014) 862871
27 MPa
p
m, respectively which corresponds to low level of ductil-
ity. The 7475-T7351 alloy has higher fracture toughness
(42 MPa
p
m and 52 MPa
p
m in TL and LT orientations, respec-
tively) whereas, in comparison to the 7075-T651 alloy, the 7475-
T7351 alloy has marginally inferior yield strength but slightly
superior ductility. In view of these facts, the use of appropriately
treated 7475 alloy is expected to safely reduce the overall weight
of aerospace structure, an important criterion for such applications
[23].
In Fig. 3 fatigue crack growth rates for different aluminium al-
loys are compared. It is shown that the 7475 has higher fatigue
resistance compared to the 2024, while the 7075-T6 has the lowest
fatigue resistance.
Corrosion resistance and fatigue behaviour of alloy 7475 are
equal to/or better than many of the high strength aluminiumalloys
such as the 7075, 7050 and 2024. Alloy 7475 plate and sheet are
currently being selected for fracture critical components of high
performance aircraft applications [33].
Alloy 7050 is another important alloy having the good balance
of strength, stress corrosion cracking (SCC) resistance and
toughness. It is particularly suited for plate applications in the
76152 mm thickness range. Alloy 7050 exhibits better tough-
ness/corrosion resistance characteristics than alloy 7075 because
it is less quench sensitive than most aerospace aluminium alloys.
The 7050 retains its strength properties in thicker sections while
maintaining good stress corrosion cracking resistance and fracture
toughness levels. Typical applications for alloy 7050 plates include
fuselage frames and bulkheads where section thicknesses are
50152 mm. On the other hand alloy 7050 sheets are used in wing
skins applications. Long-term controlled and in-service evaluations
have shown that alloy 7050 plate and sheet products remain
equal exfoliation and stress corrosion resistance at higher stress
levels compared with other high strength aluminium alloys such
as 7075.
A recent alloy, the 7055-T7751 (Al8Zn2.05Mg2.3Cu
0.16Zr), has a yield stress that may exceed 620 MPa and the esti-
mated weight saving attributed to its use for components in the
Boeing aircraft 777 is 635 kg [34]. This alloy provided a nearly
10% gain in strength, with higher toughness and signicantly im-
proved corrosion resistance [24]. T77 temper consists of three step
ageing process that produces a higher strength and damage toler-
ance combinations compared to 7050-T76 and 7150-T651 or
T7751. The improved fracture toughness is a result of controlled
volume fraction of coarse intermetallic particles and uncrystallized
grain structure. Good combination of strength and corrosion resis-
tance is attributed to the size and spatial distribution and the cop-
per content of the strengthening precipitates.
There exists a continuous improvement in the mechanical prop-
erties of aerospace aluminium alloys. This has resulted in the
development of high strength 7xxx alloys (e.g. 7075, 7150, 7055,
7449, in chronological order of application). These high strength al-
loys are generally used in compression-dominated parts such as
upper wing skins where damage tolerance considerations are sec-
ondary. However, recent developments show that modications in
solute content and in particular in Zn/Mg/Cu ratios can enable the
development of high strength products with signicant improve-
ments in damage tolerance such as AA7040, AA7140 and
AA7085. 7085 has been developed as the new generation high
strength thick plate alloy to be alternative for 7050/7010 products.
Due to the higher Zinc and lower Cu contents, higher fracture
toughness and slowquench sensitivity were obtained. This product
was selected for wing spar applications on the Airbus A380. There
is also an effort to obtain a good combination of high strength and
good corrosion resistance through the applications of different
heat treatment methods [35]. Two important metallurgical princi-
ples resulting in improvements are: a decrease in the Mg/Zn ratio,
and an overall reduction in saturation of the composition with re-
spect to the theoretical maximum solubility. The strong impact of
Mg concentration increases on strength (benecial) and on tough-
ness (detrimental) is well known. The basis of the Mg/Zn adjust-
ments is the observation that a partial replacement of Mg with
Table 2
Mechanical properties of some 2000 series aerospace aluminium alloys [22].
2000 Series UTS (MPa) Yield Strength (MPa) Fracture Toughness, K
IC
(MPa m
1/2
) Elongation (%)
2024-T351 428 324 37 21
2026-T3511 496 365 NA 11
2224-T39 476 345 53 10
2324-T39 475 370 38.544.0 8
2524-T3 434 306 40 (TL) 24
0
100
200
300
400
500
600
2024-T351 7050-T73651 7075-T651 7475-T7351
Y
S

(
M
P
a
)
,

%
E
l
x
0
.
1
,

K

c
x
0
.
1
M
P
a
.
m
1
/
2
Yield Strength % Elongation Kc TL Direction Kc LT Direction
Fig. 2. Comparative representation of yield strength, % elongation, and K
IC
in
different aluminium alloys. The gure is based on [23].
Fig. 3. SN curves for different aluminium alloys [23].
T. Dursun, C. Soutis / Materials and Design 56 (2014) 862871 865
Zn (a slightly less effective hardener per wt.%) enables an increase
in toughness while maintaining adequate strength. The overall
reduction in solute saturation directly affects the quench sensitiv-
ity, which is critical for damage tolerance properties of high solute
alloys. AA7056-T79, developed for the upper wing skin of large
commercial aircraft is good example of the improvements in
strength-toughness balance [34]. On the other hand the addition
of Mn and Zr in aluminium alloys can form ne dispersoids which
affect recrystallization characteristics and grain structure. These
dispersoids retards recrystallization and grain growth. Zr content
in aluminium alloys can form A1
3
Zr dispersoid, which have a rela-
tionship with the matrix and signicantly renes the grain size.
The addition of Zn increases the strength of the alloy, whereas
the addition of Mn increases the fracture toughness of the alloy
due to the formation of the secondary phase containing Mn and
Fe, which decreases the adverse effects of Fe on fracture toughness
[36]. Chemical composition of some of the important 7000 series
aluminium alloys are given in Table 3.
Fretting, a special type of wear process that occurs at the con-
tact area between two materials under load and subject to very
small amount of relative motion, is another important issue
needed to be understood in bolted/pinned aircraft joints. There is
a current focus on the prevention of fretting in the aerospace
industry since due to fretting, cracks can initiate at stresses (fret-
ting zone), well below the fatigue limit of non-fretted materials
and the structures resistance to fatigue can be decreased by 50
70%. Introduction of compressive residual stresses at the surface
of hole, reduction in coefcient of friction, increased surface hard-
ness, changing the surface chemistry and increasing the surface
roughness are the main methods that are applied to reduce the
nucleation and growth of fretting cracks and improve the fatigue
life of aerospace joints and improve fretting resistance [3742].
4. Developments in aluminiumlithium alloys
Reducing the density of materials is accepted as the most effec-
tive way of lowering the structural weight of aircraft. Li (density
0.54 g/cm
3
) is one of the few elements that have a high solubility
in aluminium. This is signicant because, for each 1% added, the
density of an aluminium alloy is reduced by 3%. Lithium is also un-
ique amongst the more soluble alloying elements in that it causes a
considerable increase in the elastic modulus (6% for each 1%Li
added). Additional advantage is that, aluminium alloys containing
Li respond to age hardening [43].
The use of aluminiumlithium (AlLi) alloys in aerospace appli-
cations goes back to 1950s with the development of alloy 2020. In
the 1980s, 2nd generation of AlLi alloys were developed. The sec-
ond generation alloys included the 2090, 2091, 8090 and 8091. The
AlLi alloys 2090, 2091, 8090 and 8091 contain 1.92.7% lithium,
which results in an about 10% lower density and 25% higher spe-
cic stiffness than the 2000 and 7000 series alloys. However, due
to technical problems such as anisotropy in the mechanical prop-
erties, low toughness, poor corrosion resistance, manufacturing is-
sues (hole cracking and delamination during drilling), 2nd
generation AlLi alloys did not nd wide use in aircraft industry.
The anisotropy experienced by these alloys is a result of the strong
crystallographic textures that develop during processing, with the
fracture toughness problem being one of primarily low strength in
the short transverse direction [1,21,44,45].
The pressure for higher strength and improved fracture tough-
ness with reduced weight in aircraft applications have resulted in
the development of new generation of AlLi alloys. The new gener-
ation of AlLi alloys provides not only weight savings, due to lower
density, but also overcomes the disadvantage of the previous prob-
lems with increased corrosion resistance, good spectrum fatigue
crack growth performance, a good strength and toughness combi-
nation and compatibility with standard manufacturing techniques.
This results in well-balanced, light weight and high performance
aluminium alloys [1,44,46]. In the new generation (3rd) AlLi
alloys Li concentration was reduced to 0.751.8 wt.%. The addition
of alloying elements in the 3rd generation AlLi alloys is used to
improve the mechanical properties. Poor corrosion resistance of
2nd generation AlLi alloys is eliminated in 3rd generation AlLi
alloys by optimising alloy composition and temper. Also Zn
additions improved corrosion resistance. The additions of Cu, Li
and Mg form the strengthening precipitates and small additions
of the dispersoid-forming elements Zr and Mn control the grain
structure and crystallographic texture during thermo-mechanical
processing. Crack deviation occurs due to high crystallographic
texture in addition with slip planarity. Deviation from expected
direction of crack propagation makes it difcult to dene inspec-
tion points and the positioning of crack arresters. It was found that
in addition to reduction of the texture components, the severity of
slip planarity had to be decreased. This reduction was achieved by
decreasing the amount of (Al
3
Li) phase. This can be achieved by
keeping the amount of Li additions below 1.8 wt ptc. The fracture
toughness of 2nd generation AlLi alloys was often lower than the
incumbent 2024 alloy products for designs where damage toler-
ance is the driving parameter. It was determined that fracture
toughness is affected only by insoluble second-phase particles. In
3rd generation AlLi alloys like 2199 this disadvantageous condi-
tion was eliminated by composition optimisation, thermal
mechanical processing and precipitate microstructure control.
Chemical compositions and mechanical properties of some of
the widely used AlLi alloys are shown in Tables 4 and 5
respectively.
Alloy 2195, a new generation AlLi alloy, has a lower copper
content and has replaced the 2219 for the cryogenic fuel tank on
the space shuttle where it provides a higher strength, higher mod-
ulus and lower density than the 2219. Other alloys, including the
2096, 2097 and 2197, also have lower copper contents but also
have slightly higher lithium contents than 2195 [1]. New genera-
tion of AlLi alloys have higher Cu/Li ratio than the second gener-
ation alloys (2090 and 2091) as illustrated in Fig. 4.
The new generation of 2199 AlLi alloys sheet and plates found
applications in the aircraft for fuselage and lower wing applica-
tions, respectively and the 2099 extrusions for internal structure.
It was determined that the 2199-T8E79 plate for the lower wing
skin, the 2099-T83 extrusions for lower wing stringers and the
2199-T8 prime sheet for fuselage skin would provide the most
benet for the given applications examined. It is stated that com-
pared to 2024, the 2199 plates have lower density, signicantly
better stress corrosion and exfoliation corrosion resistance, signif-
icantly better spectrum fatigue crack growth performance, better
Table 3
Chemical composition of some 7000 series aerospace aluminium alloys [22].
7000 Series Cu Zn Mg Mn Fe Si Cr Zr Ti Al
7050 2.3 6.2 2.25 60.15 60.12 0.1 Remainder
7055 2.02.6 7.68.4 1.82.3 0.05 0.15 0.1 0.04 0.080.25 0.06 Remainder
7075 1.22.0 5.16.1 2.12.9 0.3 0.5 0.4 0.180.28 0.2 Remainder
7150 1.92.5 5.96.9 2.02.7 0.1 0.15 0.12 0.04 0.080.15 0.06 Remainder
7475 1.21.9 5.26.2 1.92.6 0.06 0.12 0.10 0.180.25 0.06 Remainder
866 T. Dursun, C. Soutis / Materials and Design 56 (2014) 862871
toughness, and higher tensile yield and compressive yield
strengths. The ultimate tensile strength, bearing and shear
strengths for the T8E80 temper are similar to those for 2024, while
for the T8E79 temper, these strengths tend to be lower. However,
this reduction in tensile yield strength provides the higher spec-
trum fatigue crack growth performance. Thus, one of the two tem-
pers of 2199 may be more suitable for a given application,
depending on the design criterion [44].
AlLi 2099 alloy has low density, high stiffness, superior dam-
age tolerance, excellent corrosion resistance and weldability for
use in aerospace structures that require high strength. Alloy 2099
extrusions can replace 2xxx, 6xxx, and 7xxx aluminium alloys in
applications such as statically and dynamically loaded fuselage
structures and lower wing stringers. 2nd generation AlLi alloys
were susceptible to cracking and delamination during installation
of interference t fasteners as a result of cold working. Low elonga-
tion and work hardening properties were the results of these prob-
lems. In the 3rd generation AlLi alloys elongation and cold
working capability were improved. Alloy 2099 extrusions have
good machining, forming, fastening, and surface nishing proper-
ties. The 2099 plate and forgings have better strength, modulus,
density and corrosion performance than the7075-T73 and 7050-
T74 plate products. The T8E67 temper has much higher strength
than the 2024-T3511 or 2026-T3511 with better toughness, much
better corrosion resistance (Fig. 5) and lower density. The fatigue
crack growth resistance of alloy 2099 also shows improvement
with respect to the 2024-T3511, which has been a baseline alloy
for fatigue critical components [47].
The effects of normal heat treatments and thermomechanical
heat treatments on the mechanical properties and fracture tough-
ness of the 2A97 new generation AlLi alloy were studied by Yuan
et al. [48]. The aim was to improve the relationships of strength,
ductility and fracture toughness, and make possible their applica-
tions in the aeronautical industries. The AlLi 2A97 alloy was
developed primarily in an attempt to be used for plates and for-
gings as a promising aerospace material. It was stated that the
problem with this alloy is that it yields low ductility and fracture
toughness in T8 temper with a high tensile strength, and it yields
low strength in T6 temper with a high ductility and fracture tough-
ness. With 4% deformation after low temperature underaging, the
ductility and fracture toughness were improved for the 2A97 alu-
miniumlithium alloy. The K
q
value of 43.5 MPa
p
m in the T8 tem-
per higher than that of 42.5 MPa
p
m in the T6 temper was
obtained, by heat-treatment process and thermomechanical heat-
treatment process [48].
Another new generation AlCuLi alloy 2050 was developed to
replace the 2000 series and 7000 series alloys where medium to
high strength and high damage tolerance are needed [49].
Strength, corrosion resistance, fatigue initiation and crack growth
resistance properties were compared and according to the test re-
sults it was concluded that the 2050-T84 alloy in addition to its
density benet, offers improvements over the 2024-T351 in sta-
tic-related properties and corrosion resistance. When compared
to incumbent alloy 7050-T7451, the 2050-T84 offers an improved
(strength, toughness) balance, at 5% lower density and signicantly
improved stress corrosion resistance without any redesign and
when strength, stiffness and fatigue properties are taken into ac-
count, it can lead to weight reduction up to a total of about 10%,
depending on the part design drivers.
AlLi alloy 2198 was developed to replace 2024 and 2524 in air-
craft structures where damage tolerance is the critical design fac-
tor. It has a wt.% Cu composition ranging from 2.9% to 3.3% and
respective of Li from 0.9% to 1.1%. Under constant amplitude load-
ing and stress ratio R = 0.1 the fatigue endurance limit is almost
40% below the 2024 yield stress, while for 2198-T351 is only 8%
lower than the respective yield stress. When taking into account
density, 2198 is superior to 2024 in high cycle fatigue and fatigue
endurance limit regimes. For the same normalised applied stresses,
2198 was observed to absorb 23 times more energy to fracture
than 2024 [50,51]. Comparing the fatigue results in air it was ob-
served that 2524-T3 presented a higher fatigue strength and fati-
gue limit than the 2198-T851 AlLi alloy. However, when the
alloys were pre-corroded in saline environment they presented
similar fatigue behaviour [52].
2060 and 2055 are the newest 3rd generation AlLi alloys. 2060
has 0.75 wt.% of Li, 3.95 wt.% of Cu and 0.85 wt.% of Mg whereas
2055 has 1.15 wt.% of Li, 3.7 wt.% of Cu and 0.4 wt.% of Mg. The
wt.% of the other alloying elements are approximately same for
these two alloys. These alloys show improved strength/toughness
relationship. Additionally, these alloys exhibit good thermal
stability. Both 2055 and 2060 have excellent corrosion performance
compared to that of common aerospace aluminium alloys such as
2024-T3 and 7075-T6. Therefore, these alloys could be alternative
materials for fuselage, lower wing and upper wing constructions.
Trade study analyses show that implementation of AlLi alloys
can save signicant weight over the baseline 2000 and 7000 series
aluminium alloys. For instance for fuselage skin applications
2060-T8 can save 7% weight compared to that of 2524-T3, for lower
wing skin applications 2060-T8 can save 14% weight compared to
that of 2024-T351 and for upper wing skin and stringer
applications, 2055-T8 can save 10% weight compared to that of
7055-T7751 [47,53]. The 3rd generation AlLi alloys offers up to
10% weight savings, lower risk and 30% less expensive to manufac-
ture, operate and repair than composite-intensive planes. In
addition, these alloys can provide passenger comfort features that
are equivalent to composite-intensive planes, such as large
Table 4
Chemical composition of some AlLi alloys [22].
AlLi alloys Li Cu Zn Mg Mn Fe Si Cr Zr Ti Others
2050 0.71.3 3.23.9 0.25 0.20.6 0.20.5 0.1 0.08 0.05 0.060.14 0.1 0.20.7 Ag
2090 1.92.6 2.43.0 0.1 0.25 0.05 0.12 0.10 0.05 0.080.15 0.15
2098 0.81.3 3.23.8 0.35 0.250.8 0.35 0.15 0.12 0.040.18 0.1 0.250.6 Ag
2099 1.62.0 2.43.0 0.41.0 0.10.5 0.10.5 0.07 0.05 0.10.5 0.050.12 0.1 0.0001 Be
2199 1.41.8 2.02.9 0.20.9 0.050.4 0.10.5 0.07 0.05 0.050.12 0.1 0.0001 Be
8090 2.22.7 1.01.6 0.25 0.61.3 0.10 0.30 0.20 0.10 0.040.16 0.1
Table 5
Mechanical properties of some AlLi alloys [22].
AlLi
alloys
UTS
(MPa)
Yield Strength
(MPa)
Fracture
Toughness,
K
IC
(Mpa m
1/2
)
Elongation
(%)
2050-T84 540 500 43(LT) NA
2090-T83 531 483 43.9 3
2098-T82 503 476 NA 6
2099-T83 543 520 30 (LT) 7.6
27 (TL)
2199-T8 400 345 53 10
8090-T851 500 455 33 (LT), 30 (TL) 12
12.4 (SL)
T. Dursun, C. Soutis / Materials and Design 56 (2014) 862871 867
windows, higher humidity and higher cabin pressure, due to their
improved fatigue behaviour. According to the test results in addi-
tion to the improvements in material properties, the application
of advanced structural design concept resulted in up to 10 times
improved damage tolerance performance in critical areas. Beside
these advantages aluminiumlithium alloys have fusion welding
capacity and standardised use of tooling, mature assembly tech-
niques, repair and maintenance procedures and ease of recycling
at the end of the aircrafts life make the AlLi alloys compete with
the polymer composites currently used. While AlLi alloys offer
improvements, delaminations in these alloys play a signicant role
in their fracture processes. Therefore, a more complete understand-
ing of the factors that affect the behaviour of these delaminations
and their corresponding effect on the primary crack behaviour
especially near holes need to be well understood [45,54].
5. Developments in joining techniques
Aircraft manufacturers have been continuing their research
activities in the eld of the construction of aircraft fuselage struc-
tures because of the increasing demands on damage tolerance of
fuselage structures, increased cost pressure among aircraft manu-
facturers, and the requirements of airlines for lower aircraft
inspection and maintenance costs. New trends in the construction
and manufacture of aircraft fuselage have therefore emerged in
which welding, bonding, and extrusion are increasingly replacing
the use of rivets [55]. The trend of building larger structures with
fewer parts has led to demands for thicker and longer plate from
which more complex sections can be machined. Alternatively,
smaller parts can be joined together and welding appears as the
most suitable solution [13]. Weldability of aluminium alloys is
presented in Fig. 6. It is shown that all series of aluminium alloys
can be friction stir welded.
The riveting is accepted as the traditional technique of joining
fuselage and wing structures which are generally made of alumin-
ium alloys. However, riveting increases the weight of the airframe.
Riveting also causes stress concentration leading to fatigue crack
initiation and growth. Another way of joining these structures is
by welding. Since fuselage and wing parts are made of high
strength 2000 and 7000 series of aluminium alloys, weldability
of these alloys can be relatively very low. Also in traditional weld-
ing techniques metal is heated until melting point which causes a
large area of heat affected zone (HAZ). HAZ reduces the mechanical
properties of the metals resulting in reduced strength and reduced
resistance to fatigue. The difculties with the welding of the high
strength aluminium alloys can be listed as follows [1]:
a. The stable surface oxide must be removed by either chemi-
cal methods or by thoroughly wire brushing the joint area.
b. Weld cracking or distortion due to residual stresses resulting
from high coefcient of thermal expansion.
c. The high thermal conductivity of aluminium requires the
high heat input during welding further leading to the possi-
bility of distortion or cracking.
d. Weld cracking due to aluminiums high solidication
shrinkage.
e. Aluminiums high solubility for hydrogen when in the mol-
ten state leads to weld porosity.
f. Susceptibility of high strength 2000 and 7000 series alloys to
weld cracking.
After the invention of Friction Stir Welding (FSW) in 1991 as an
alternative way of welding, research effort on the applications of
FSW in aircraft manufacturing technology increased substantially.
Friction stir welding (FSW) is a solid-state process that operates by
generating frictional heat between a rotating tool and the work-
piece. A rotating tool with a shoulder and a threaded pin moves
along the butting surfaces of two rigidly clamped plates placed
on a backing plate as shown in Fig. 7. The shoulder makes rm con-
tact with the top surface of the work piece. Heat generated by fric-
tion at the shoulder softens the material being welded. Higher
plastic deformation on the metal occurs as the tool is moved along
the welding direction. Material is transported from the front of the
tool to the trailing edge where it is forged into a joint. Although
Fig. 7 shows a butt joint for illustration, other types of joints such
as lap joints and llet joints can also be fabricated by FSW [57].
FSW offers several advantages compared to traditional welding
techniques. FSW process takes place in the solid phase below the
melting point of the metals to be joined. Problems related to the
solidication of a fused material are eliminated. Difcult to fusion
weld materials like the high strength 2000 and 7000 series alumin-
ium alloys, could be joined with minor loss in strength.
The main advantages of friction stir welding can be listed as
follows:
a. Welding of butt, lap and T joint congurations are possible.
b. No special need for joint preparation is required.
c. 2000 and 7000 series alloys could be welded.
d. Dissimilar alloys could be welded.
e. No crack formation occurs during the fusion and HAZs.
f. No weld porosity occurs.
g. No ller metals needed.
h. For aluminium no requirement for shielding gases.
In general, mechanical properties obtained by FSW are better
than for many other welding processes. For example the static
properties of the friction stir welded 2024-T351 are between 80%
Fig. 4. Positioning of selected AlCuLi alloys in Li and Cu concentrations [34].
0
50
100
150
200
250
300
350
400
2024-T3 7075-T6 7050-T74 2099-T86 2199-T8E80 2060-T8
S
T

S
C
C

T
h
r
e
s
h
o
l
d

S
t
r
e
s
s
,

M
P
a
3rd Generation Al-Li Alloys
Conventional Aerospace Al
Alloys
Fig. 5. Comparison of corrosion resistance of AlLi alloys with 2000 and 7000 series
alloys. The gure is based on [47,53].
868 T. Dursun, C. Soutis / Materials and Design 56 (2014) 862871
and 90% of the parent metal, and the fatigue properties approach
those of the parent metal [1].
Joints produced by FSW have higher strengths than riveted
joints and much lower residual stresses than typical fusion welded
joints. In welding 7000 series aluminiumalloys, post weld ageing is
necessary to stabilise the microstructure in the friction stir welded
regions. The selected overaging treatments also improve corrosion
resistance of these alloys [58].
Due to the high strength of FSW joints, it allows considerable
weight savings in lightweight construction compared to conven-
tional joining technologies. The use of welded instead of riveted
joints is also advantageous because of the lower production costs.
Therefore, the FSW process has recently been identied as key
technology for fuselage and wing manufacturing by leading aircraft
manufacturers.
As the large aircraft experience higher stresses and shorter fati-
gue life, the technology should be applied carefully. There exist
several parameters which have inuence on the quality and
strength of the friction stir weld. This process must be optimised
for each specic application. In order to optimise the performance
of the FSW joint, it is important to identify the welding parameters.
The main FSW process parameters are the followings [59,60]:
a. Tool geometry (shoulder, probe).
b. Clamping system.
c. Axial Load.
d. Tool rotational direction.
e. Plunge depth of probe in workpieces.
f. Plunge speed of the probe in the workpieces at the start
position.
g. Dwell time at start of the weld.
h. Tilt angle.
i. Preheating/interpass temperature of workpieces.
j. Control during plunge, dwell and weld periods.
k. Welding speed versus rotation speed.
As mentioned above since there are several tools and operating
parameters that affect the quality and strength of the friction stir
weld, researches have been invested to understand the effect of
these parameters [6163].
Another welding technique under interest is the laser beam
welding of high strength aluminium alloys where relatively small
aerospace production of parts is required. With this welding pro-
cess good weld properties can be obtained at high production
speeds. No electrode or ller metal is required and narrow welds
with small HAZs are produced. Laser welding produces a concen-
trated high energy density heat source that results in very narrow
heat affected zones, minimising both distortion and loss of
strength in HAZ [1].
In laser beam welding radiant energy is used to produce the
heat required to melt the materials to be joined. A concentrated
beam of coherent, monochromatic light is guided by optical de-
vices and focused to a small spot, for higher power density, on
the abutting surfaces of the parts being joined. Dissimilar alloys
could be joined in a noncontact process. Pulsed or continuous wave
mode lasers are used to join the metals. The main advantages of la-
ser welding are the shape of the weld and good penetration, high
precision, high mechanical properties of the weld, high welding
speed, low heat input, high exibility and possibility of automa-
tion. Both very local welds and heat-affected zones occur with
the help of the high energy density beam, and therefore good
mechanical properties with relatively low distortion of the work-
piece could be achieved. The main disadvantages are the relatively
high cost of investment and the important requirements related to
the machining of the parts to assure a precise groove (reduced
dimensional tolerances). Higher product quality, in terms of im-
proved in-service properties, could be achieved through: improved
tolerances; accurate control of process parameters; selection of
new materials; and product redesign. EADS Airbus has invested
in laser welding as a replacement for riveting in non-critical appli-
cations. In double-sided laser beam welding of T-joints the incident
beam position, incident beam angle, and beam separation distance
are the most important welding parameters. The incident beam
position has great impact on joint quality. 6xxx series AlMgSi al-
loys are susceptible to hot cracking. Aluminium ller (such as
AA4047) wire containing excess silicon is recommended for 6xxx
series alloys. It is reported that the crack sensitivity decreases if
the Silicon content exceeds 1.5% [64]. One application involves
joining stiffening stringers to the skin of the fuselage. The dam-
age-tolerant alloy 6013 is the base material and 4047 is the ller
material. The stringers are welded from two sides at 10 m/min,
using two 2.5 kW CO
2
laser beams. The joint is designed such that
the HAZ is contained in the stringer, and does not impinge on the
skin. The process was rst used in series production of the Airbus
318, and was then implemented successfully in other aircraft mod-
els [65].
6. Conclusions
Aluminiumalloys have been successfully used as primary mate-
rial for the structural parts of aircraft for more than 80 years. Air-
craft designers possess considerable experience in the design,
production, operation and maintenance of aluminium airframes.
Fig. 6. Weldability of various aluminium alloys. The gure is based on [56].
Fig. 7. Schematic of FSW [57].
T. Dursun, C. Soutis / Materials and Design 56 (2014) 862871 869
The infrastructure and knowledge base has become mature. How-
ever, with the introduction of high performance polymer compos-
ites in the application of airframe designs reduced the role of
aluminium alloys up to some extent due composites high specic
properties, reduced weight, fatigue performance and corrosion
resistance (Boeing 787, Airbus A350). In order for aluminium alloys
to remain attractive in the airframe construction and compete with
and/or be compatible with currently used polymer composites, re-
search activities on the improvement of structural performance,
weight and cost reductions are needed. Recent developments in
high strength AlZn and AlLi alloys, damage tolerant AlCu and
AlLi alloys, have been successful in improving the static strength,
fracture toughness, fatigue and corrosion resistance through the
design and control of chemical composition, and/or through the
development of more effective heat treatments. It has been seen
from this review that major improvements of aerospace alumin-
ium alloys are due to optimised solute content and solute ratios
in order to achieve better property balance. The use of new disper-
soid-processing combinations results in desired grain structures
that provide better damage tolerance. Improvements in under-
standing and modelling of the hardening system and especially
the effect of minor element addition will help improvements in
mechanical properties.
Current research activities for both composites and aluminium
include: improvement on mechanical properties, reduction of
manufacturing, maintenance and repair costs, prevention of corro-
sion and fatigue and ability to perform reliably throughout its ser-
vice life.
In order to use the advantage of improvements in mechanical
properties of advanced aluminium alloys and sustain the structural
integrity in mechanically fastened aircraft structures a special
attention should be paid on the fretting fatigue. There is need to
understand the fretting behaviour of recently developed AlLi al-
loys such as 2050 and 2099 and bre metal laminates in mechan-
ically fastened aircraft joints.
In addition to weight reduction and improvement on the struc-
tural performance the materials, cost reduction through the devel-
opment on the manufacturing techniques is also a key issue.
Manufacturing constitutes the biggest portion of the cost of the air-
frame. Therefore great effort is being spent to reduce the produc-
tion costs and part count via introducing high-speed machining,
novel assembly techniques such as laser beam welding and fric-
tion-stir welding. For example, unlike most conventional aerospace
alloys, the fusion weldability of AlCuLi alloys could introduce
new opportunities in the fabrication of fuselage. Therefore, in addi-
tion to metallurgical developments with the combination of other
manufacturing techniques than the riveting will help reach opti-
mised damage tolerant designs.
High strain-rate superplastic forming and casting are also draw-
ing attention as cost effective solutions. Advanced joining tech-
niques will also make aluminium structures more affordable.
The airframes and other structural parts will continue to be
composed of different materials including aluminium, titanium,
steel, polymer composites and bre metal laminates depending
on the balance of structural and economical factors. Weight sav-
ing through increased specic strength and/or stiffness and
affordability (procurement, maintenance and repair costs) are
the major drivers for the development and selection of materials
for civil airframes. In selecting new materials for aircraft applica-
tions, there should be no reduction on the levels of safety that is
already reached with conventional alloys. Fatigue resistance, cor-
rosion resistance and damage tolerance are all very important
mechanical properties of airframe materials that affect the
inspection, maintenance and repair costs and this is where mod-
ern aluminium alloys could compete effectively with polymer
composites.
It is believed that developments of advanced hybrid materials,
like bre metal laminates could provide additional opportunities
for aluminium alloys and new material options for the airframe
industry.
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